Professional Documents
Culture Documents
Section 1. Identification
Product name : Gasoline (All Grades)
Synonyms : Gasoline, Unleaded Gasoline, Regular Gasoline, Premium Gasoline, Oxyfuel,
Reformulated Gasoline
Relevant identified uses of the substance or mixture and uses advised against
Product use : Use as a fuel - Industrial use
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 1/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, sparks, open
flames and hot surfaces. - No smoking. Use explosion-proof electrical, ventilating,
lighting and all material-handling equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep container tightly closed. Use
only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or
smoke when using this product. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Avoid contact with skin and clothing. Wash thoroughly after handling.
elements
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 2/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove
contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get
medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce
vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter
the lungs. Get medical attention immediately. Call a poison center or physician. Wash
out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Specific hazards arising : Extremely flammable liquid and vapor. In a fire or if heated, a pressure increase will
from the chemical occur and the container may burst, with the risk of a subsequent explosion. The vapor/
gas is heavier than air and will spread along the ground. Vapors may accumulate in low
or confined areas or travel a considerable distance to a source of ignition and flash
back. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 3/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 4/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 5/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 6/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 7/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : Causes damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : May cause genetic defects.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : reduced fetal weight; skeletal malformations
Fertility effects : Suspected of damaging fertility.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 8/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Gasoline 2 to 7 10 to 2500 high
ethanol -0.35 - low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 9/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Transport 3 3 3 3 3 3
hazard class(es)
Packing group II II II II II II
Environmental Yes. Yes. Yes. Yes. No. No.
hazards
Additional Reportable Explosive Special Hazard Emergency Passenger
information quantity Limit and provisions identification schedules and Cargo
400 lbs / 181.6 Limited 243 number (EmS) Aircraft
kg [63.965 gal / Quantity Index 33 F-E, S-E Quantity
242.13 L] 30 limitation: 5 L
Package sizes Limited Packaging
shipped in Passenger quantity instructions:
quantities less Carrying Ship 1L 353
than the Index Cargo Aircraft
product 100 Special OnlyQuantity
reportable provisions limitation: 60 L
quantity are Passenger 534 243 Packaging
not subject to Carrying instructions:
the RQ Road or Rail Tunnel code 364
(reportable Index (D/E) Limited
quantity) 5 Quantities -
transportation Passenger
requirements. Special Aircraft
provisions Quantity
Limited limitation: 1 L
17, 82, 88
quantity Packaging
Yes. instructions:
Y341
Packaging
instruction
Passenger
aircraft
Quantity
limitation: 5 L
Cargo aircraft
Quantity
limitation: 60 L
Special
provisions
144, 177, B1,
B33, IB2, T4,
TP1
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 10/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 11/12
Gasoline (All Grades) HollyFrontier Refining & Marketing LLC
3 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of : 3/18/2014.
revision
Date of previous issue : 8/28/2013.
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
manufacturer, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of
the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 3/18/2014. Date of previous issue : 8/28/2013. Version : 1.01 12/12