CHEMISTRY TEST “ATERIAL IN THE FOLLOWING TABLE MAY BE USEFUL IN ANSWERING THE QUESTIONS IN THIS IXAMINATION, O90) | TSE) | TREE) | UIST] Wee) | CIS | CD | aE) | HD | He | SO TEE] OER | OTL] POET 27) ON) PW) Mt) sa] JO) AG) HO) wy) ma] dN] a | ea | ay, | 2228 epmmyy gor} zor} tor | oor} 65 | 86 | w | 96 | so | w | cs | zo | 16 | 06 Usrci] FELT] Co¥9i| Sc e9T| eevOT] Oscoil EwasT| seust| Le IST) POST | Ge | rewnT| TORT] ZrorT MT) 4A) WL! aa) On| Ad] aL) PS) ma) wg) wa) PN) ad | aD | sen2s opweinmey, wim | 6 | 9 | ow} | | | o | wo} | | 6 | a LEE] ELROD | ORGY | BY | COR | BY | COD | CHORD TeoTee | BEE] CET aurou 194 10NS 8 8 | 8 (aW) sh] ua} 3s | aa} ya | ow) ea a : zu_| mi} ort | oor | sor | cor | oor | sor} vor} os | ge | us Ce [TOTO | i) | RWC] CLUE [SEHE Os OE | To 96T| SOSGT] T car | Com | FeveT | SeEsT| S6ORT/aract| Tower [te LET] TaeeT ma) av | ed it | dd | BH ev dd | so] om | Mm | ek ete) ea) 80 | os_| sa| vj ce | ce | is | oe | ow | w | uw | ow | x | w | xe | x | us | os | co GEUET] 69K] OPLEL| SETAE] TL WIT) eeeTE| VrciT| BLOT | eroOT | TéTOT Go) [F6S6 | Tees | IG | T8e | Te] Se ox 1 | aL) as 4 P| BV) Pal wa) ma) on ow aN | az) XK | as | ae | ws | es | es | is ov | sy | ty | o | ow | w | er | er | w | o | oe | se | cc | De) O62 | W6RE) GORE WO] |S | GR | COR | GEST [ROPE OTS | TSO] OTF | BSE | GOOF | OTe aM) td | 9S | sy "91 4Z) 9) IN) OD ad UW) AD A | | os | eo) oc | se | te | ce w jo lel elelex}zizelelele|o| o BSE] Ges] BOE rL6Oe ws ore | weet wiepl|s|a Iv 3W | &N s_| a | st | alu Sree] Ost | HOST Teor TOS | 6H n| 4/0 a a | 11 o|e6{sjezlol|s rie a0 S00 oH H : SLNAWATA AHL AO ATAVL O1GOnddd = “MO0d WOT HOV LON Oda CHEMISTRY TEST Note; For all questions involving solutions, assume that the solvent is water unless otherwise stated, ‘Throughout the test the following symbols have the definitions specified unless otherwise noted. H = enthalpy M = molar nh = number of moles P= pressure R= molar gas constant S$ = entropy T= temperature V = volume atm = atmosphere(s) g = gram(s) J = joule(s) KI = kilojoule(s) L_ = liter(s) mL = mililter(s) mm = millimeter(s) mol = mole(s) Vo = volts) Directions: Each set of lettered choices below refers to the numbered statements or questions immediately fol- lowing it. Select the one lettered choice that best fits each statement of answers each question and then fill in the corresponding circle on the answer sheet. A choice may be used once, more than once, or not at all in each set. Questions 1-3 refer to the following molecules. (A) Ny 3) CH, \C) NH; (D) CO, &) ccl, 1, A molecule that has atoms joined by a triple covalent bond ‘A molecule that is polar 3. A molecule having a 180° bond angle 4BAC Questions 4-7 refer to the following separation. methods. (A) Treatment with water followed by filtration (B) Fractional distillation (©) Evaporation () Paper chromatography (©) Gaseous diffusion 4, Most appropriate for separating several components of ink 5. Most appropriate for obtaining salt from salt-water solutions 6. Most appropriate for separating sand and sugar 7. Most appropriate for separating methyl alcohol and water~~ (CHEMISTRY TE Questions 8-10 refer to the figure below, which represents the phase diagram of pure water. Pressure ‘Temperature For each of the following questions, select the etter corresponding to the appropriate point on the shase diagram, 8. The triple point 9. The critical point 0. The normal boiling point Questions 11-13 refer to the atoms with the ollowing electron configurations. (A) 1s? 252 2p6 351 (B) Ls? 2s? 2p6 352 3p5 (C) 1s? 2s? 2p8 352 3p 4s! (D) Is? 2s? 2p6 352 3p6 3a 4s? (E) Ls? 25% 2p8 35? 3p% 3a! 4s? 1. Is a transition element that can exhibit several oxidation states 2. Forms a diatomic gas that is a halogen 3. Has the lowest first ionization energy (potential) ‘—Continued A ‘Questions 14-16 refer to the following types of substances, (A) Hydride (B) Halide (C) Hydroxide (D) Hydrate (B) Hydrocarbon 14. A crystalline substance in which water is one of the structural units 15. A crystalline compound that contains only metal atoms and hydrogen atoms 16. An organic compound Questions 17-18 refer to the following substances at room temperature, (A) CO, (B) N,0 (©) NO, (D) Sio, © C20 17. Is an ionic solid 18, Is a gas in which each molecule has an unpaired electronCHEMISTRY TEST—Continued Questions 19-21 (A) Oxidation (B) Decomposition (C) Precipitation (D) Acid-base (E) Reduction Which of the above best describes the reaction represented by each of the following equations? 19, CaCO4(s) + CaO(s) + CO,(g) 20. Pb**(ag) + 21-(ag) + PbIL{s) (ag) > Fe*(aq) + &‘uestions 22-24 refer to the following energy diagram. Principal Quantum Numbers 3 0 i 3 2 ry) 3 e+ 70 g a : ~140 ‘The diagram above is a plot of the energy levels for the electron of the hydrogen atom (roughly to scale) according to the Bohr theory. The vertical lines represent possible transitions (increases or decreases of energy) that can occur 22. The transition from the ground state to the first excited state of hydrogen 23, Of the transitions shown, the one that involves the LEAST energy 24. The transition that represents the ionization energy (potential) of hydrogenwy CHEMISTRY TEST—Continued yy * "ASE GO TO THE SPECIAL SECTION AT THE LOWER LEFT-HAND CORNER ~. HE PAGE OF THE ANSWER SHEET YOU ARE WORKING ON AND ANSWER QUESTIONS 101-115 ACCORDING TO THE FOLLOWING DIRECTIONS. Part B Directions: Each question below consists of two statements, I in the left-hand column and IT in the right-hand column. For each question, determine whether statement I is true or false and whether statement II is true or false and fill in the corresponding T or F citcles on your answer sheet, Fill n-citcle CE only if statement It is a comect, explanation of the true statement [ EXAMPLES: I a | EX 1. H,S0, isastrong acid BECAUSE 1,80, contains sulfur. EX 2, Anatom of oxygen is BECAUSE an oxygen atom contains an equal electrically neutral number of protons and electrons, SAMPLE ANSWERS ri SEY Stent ex1]@ ©[@ ©) O ExI@ ©1@ © @ 1 af 101. The volume of agas at constant pressure _-«»«BECAUSE_ the average speed of gas molecules decreases increases with increasing temperature with increasing temperature 102. HCl(aq) is a weak acid BECAUSE chlorine is a very electronegative element. Hyg) + Ife) @ 2 HIG) 103, Equilibrium for the reaction represented BECAUSE. rates of reaction increase with increasing above can be reached more quickly by temperature. increasing the temperature 104, The covalent bond between O and Hin BECAUSE the HO molecule is linear. H,0 is polar 105. Mendeleev was able to predict correctly the BECAUSE on the basis of periodic relationships, gallium physical properties of gallium, Ga, before its ‘would be expected to have the same total discovery ‘number of electrons as aluminum. 106, Metallic copper is an electrical conductor BECAUSE in metallic copper, the atoms of copper are covalently bonded. rrI 07. Acetic acid, HC3H,0,., is stronger acid than sulfuric acid 08. The decomposition of water by electrolysis to yield H,(g) and 0,(g) is an endothermic process 09, When some of the liquid in an insulated vessel evaporates, the temperature of the remaining liquid decreases 10. The first ionization energy of K is greater than that of Li 11, Catalysts increase the rates of chemical reactions 12. The hydrogen carbonate ion, HCO;-(aq), is both a Bronsted-Lowry acid and a Bronsted- Lowry base 13, Lithium, sodium, and potassium have similar chemical properties 14, The CH, molecule has a square planar geometry 15, At25°C, the average speed of Hy(g) ‘molecules is less than the average speed of Ox{g) molecules. CHEMISTRY TEST—Continued BECAUSE, BECAUSE BECAUSE BECAUSE BECAUSE, BECAUSE BECAUSE BECAUSE, BECAUSE u acetic acid has more hydrogen atoms in its molecular structure than does sulfuric acid, converting a pure liquid to its vapor phase increases the entropy of the system, the first molecules to leave the liquid are those with the higher kinetic energies and the remaining molecitles have lower average kinetic energies. the Li atom has a smaller radius than the K atom, the activation energy of a reaction is lowered by a catalyst for the reaction, the hydrogen carbonate ion can either donate or accept a proton, lithium, sodium, and potassium all have the same number of valence electrons. all the bonds in the CH, molecule are equal in length. at 25°C, the average kinetic energy of H,(g) ‘molecules is less than the average kinetic energy of O,(g) molecules. TURN TO THE SECTION OF YOUR ANSWER SHEET YOU STARTED FOR CHEMISTRY AND NSWER QUESTIONS 25-70.ay CHEMISTRY TEST—Continued yy Part © Directions: Each of the questions or incomplete statements below is followed by five suggested answers or completions. Select the one that is best in each case and then fill in the corresponding circle on the answer sheet, 25. Given solutions with the following pH values, 28. Tons of charge 2+ are formed readily from the which has the greatest concentration of H* ions? elements whose atoms have which of the following electronic configurations? a 1 ®) 5 11s? 20! (©) 7 IL i? 2? D9 TIL 15? 25%2p8 352 @®u (A) only 26, In the compound RbBrO,, the oxidation number io ve 0 | : and IT only eee (D) Hand 1 only -i (©) [,1,and 1 (B) +1 + - (D) 45 NH,(g) +... 04g) 9... Nig) +... 1,08) ©) +7 29. When the equation for the reaction represented above is balanced with all the coefficients reduced CyHg(g) + 5.O,g) > 3CO3(g) + 4 H,0(g) to the lowest whole-number terms, the coefficient for Ox(g) is «sow many moles of water would be produced if 11.0 g of propane (molar mass 44 g/mol) were @)1 burned completely to carbon dioxide and water ey according to the equation represented above? oa a (A) 10 mol 6 (B) 2.0 mol (©) 3.00 mol () 40 mol ) 50 mol> CHEMISTRY TEST—Continued ). What is the number of moles of NaOH (molar mass 40. g/mol) present in 250 mL of 0.10 M NaOH(ag) ? (A) 0.025 mol @B) 0.10 mol () 1.0mol ©) 40mol © 25 mot ‘ On co) a co, Carbon dioxide may be prepared by the two processes above, where AH represents the energy change in the steps indicated, From the law of conservation of energy, one concludes that (A) All, = Al + AH, F(MMy + AH) (Ay ~ AH) AH, + AH; (B) AM, AH, ~ AR; Sy 32. One isotope of an element contains 13 protons, 13 electrons, and 14 neutrons. Another isotope of this element is (A) TMg, ®) Bal aca (D) Fe oe 33. Which of the following elements can be correctly represented by X in the chemical formula Xj, ? L Fe LB TIL Ca (A) Lonly (B) Monly (©) Monly (D) Land It (©) Wand 34, What is the maximum mass of Al (molar mass 27 g/mol) that can be obtained from 20.4 g of pure Al;O; (molar mass 102 g/mol) ? (A) 270g (B) 540g (C) 810g (D) 108 ) 1638Potential Energy Reaction Coordinate 35. Consider the potential energy diagram above for the reaction W + X — Y + Z. Which of the following statements is correct? (A) The reaction is endothermic (B) The reaction will not occur without a catalyst. (C) E; and By both represent activation energies. (D) Es varies with the catalyst used. (E) W and X represent a lower potential energy state than Y and Z. 2A(g) + Big) & C(g) + Dlg) 56. All of the following can change equilibrium concentrations of reactants and products in the gas-phase reaction represented above EXCEPT. (A) decreasing the temperature of the system (B) decreasing the volume of the system (C) removing one of the products of the reaction from the system (D) adding more of one of the reactants to the system, (B) adding a catalyst for the reaction to the system CHEMISTRY TEST—Continued 37. 38. 39. yy Of the following, the conditions under which the ‘molar volume of gaseous helium is greatest are (A) 237K and 1 atm (B) 300K and 1 atm (C) 400K and 1 atm (D) 500K and 2 atm (B) 600K and 2.atm How many grams of RbNO, (molar mass 147 g/mol) are required to produce 0.500 L ‘of a 0.200 M RbNO; solution? (A) 7358 (B) 29.62 © 1472 (D) 296g ©) 147g ‘The boiling points of NH3, H,0, and HF are all higher than would be expected on the basis of their molecular masses because of the (A) low kinetic energy of the molecules (B) unusual isotopic distribution of N, O, and F in nature (C) high ionization energies of N, O, and F (D) high potential energy of the molecules (E) hydrogen bonding between the moleculesSy CHEMISTRY TEST—Continued -(NH),Cr,0,(9) > Cr,03(5) +... No(g) +... HpO(g) 40. When the equation for the reaction represented above is balanced and all coefficients are reduced to the lowest whole-number terms, the coefficient for H,O(g) is nN (B) 2 3 (D) 4 © 8 ee 41. Which of the following solutions has the highest pH ? (A) 0.1M NH, @) 0.1 M NaOH (©) 0.1M HOC! () 0.1M HPO, ©) 0.1 M HCH,0, (acetic acid) 12, At4°C, a 10, mL container filled with water has ‘amass of 35.6 g, The same container filled with methanol has a mass of 33.5 g. Whats the approximate density of methanol? (The density of water at 4°C is 1.00 g/mL.) (A) 0.79 g/ml. B) 1.0 g/ml. (©) 13 g/mL (D) 21 gimL ©) 33 giml 3. A.45 g sample of a pure compound contains 36 g of carbon and 9.0 g of hydrogen. What is its empirical (simplest) formula? (A) CH; @®) CH, © GH, (D) CH ® GH 44. The Fe** ion contains how many electrons? (A) 23 (B) 26 © 29 (D) 31 ©) 33 HY(aq) + .. -CaCO,) > 45. When 1 mol of solid CaCO, is added to fan excess of HCI according to the reaction represented above, which of the following will be produced? I. 1 mol of Ca**(aq) TL. 2 mol of CO,(g) ILL. 6 x 10° molecules of HO (A) Tonly (B) Tonly © Land only (D) Tand Mi only (&) 1,0, and Iyy © Tar an atom of cobalt in its ground state, the 47. + energy sublevel contains (A) 10 electrons (B) 9electrons (©) Belectrons (D) 7electrons (B) Selectrons Ag,COx(s) @ 2 Agi(ag) + CO;?(ag) Some solid AgyCO, is shaken with $0 mL of ‘water and the equilibrium system represented above is established. The equilibrium would be shifted to the left by the addition of which of the following substances? (A) Solid Ag,CO, B) 50 mL H,0 © 05 M HCI (D) 05 M Na,CO, () 05 M NaNO, > general, when are deviations from ideal gas ‘avior greatest? (A) At standard temperature and pressure (B) When both pressure and temperature are high (©) When both pressure and temperature are low (D) When pressure is high and temperature is low (E) When pressure is low and temperature is high CHEMISTRY TEST—Continued wy CiHOH + CO, + HC;H,O, > H,0 + aspirin 49. Phenol (CgH;OH), carbon dioxide (CO,), and acetic acid (HCJH,0,) react to form aspitin and H,0 as shown in the balanced equation above. What is the chemical formula for aspirin? (A) Coys B) CHO, (©) Celis (D) CyH,0, (E) C3H30, 50. Which of the following best describes the type of bonding between iodine atoms in 2 molecule of Ib? (A) Tonic bonding (B) Metallic bonding (©) Hydrogen bonding (D) Covalent bonding (E) Dispersion (London) force interactions SI. A glass vessel contains 2.0 mol of N,(g) and 3.0 mol of Ar(g). The total pressure is 1.5 atm, What is the partial pressure of the Ar(g) ? (A) 0.2 atm (B) 0.6 atm (©) 0.9 atm () 1.0 atm @®) 15 atma> CHEMISTRY TEST—Continued A 2. Which of the following statements is true of a solution of 0.10 M HCl(ag) ? (A) The pH is 1 (B) The concentration of CI-(ag) is greater than. the concentration of H*(aq). (C) The concentration of Ci-(ag) is equal to the concentration of OH (ag). (D) The concentration of H*(ag) is equal to the concentration of OH"(aq). (E) The indicator phenolphthalein turns pink ‘when added to the acid solution. 3. The half-life for the radioactive decay of 732Pu 25,000 years. I 100. g of °22Pu are present initially, how many grams of 73{Pu will remain after 50,000 years? (A) 100. g B) 500g (©) 25.08 ) 1252 ©) 0.000g Nak cl 7 Cl He HOW ‘cl 1 1 1 4, Which of the formulas above represent isomers of one another? (A) None (B) Land IT only (©) Land IM only (D) Hand Mf only (B) 1,0, and ttt 5. Which of the following is always characteristic of an oxidizing agent? (A) Itcontains oxygen. (B) Itis soluble in water. (©) I contains a transition element (D) Itcan be reduced (B) It forms an ionic lattice. 56. Which of the following statements about a liquid that evaporates readily at room temperature is correct? (A) It has strong intermolecular forces. (B) It has a high vapor pressure. (©) Itis considered to be nonvolatile. (D) It would make its container feel warm to the touch. (B) It should be stored in an open container. 57. Correct statements about a solution of sodium chloride include which of the following? I. Ithas a normal boiling point identical with that of pure water. : TL, Tthas a greater density than pure water at the same temperature, IIL. Ithas a lower freezing point than pure water. (A) Lonly (B) Honly (©) Monly {D) Hand Ill only (®) 1M, and 58, A4L sample of hydrogen and a 3 L sample of oxygen, each at 20°C and I atm, are mixed, exploded to form as much water as possible, and then cooled back to the initial temperature and pressure. At the end of the experiment, there remains in the system. (A) 3 Lof hydrogen (B) 2L of hydrogen (©) 2Lof oxygen (D) 1 Lofoxygen (B) no gas at all, 59, Each of the following ions has ten electrons, Which one has the smallest radius? (a) NE (B) OF aes (D) Nat (B) Mg? am neeneree cee ane\ id CHEMISTRY TEST—Continued ++ CgHsOH() + ...0,(g) > CO,(g) +... H,O(g) ‘60, When the combustion reaction represented by the equation above is balanced using the lowest whole-number coefficients, What isthe coefficient of O,(g) ? (a2 (B) 3 (4 (D) 5 ©) 6 61, If 100. mL of 0.50 M NaOH(aq) exactly neutralizes 50. mL of a solution of HCKaq), the molarity of the HCl(aq) is (A) 0.10. (B) 0.25 M (C) 050M (D) Lom (©) 20M 62. A.9.00 g sample of liquid water has which of the following? I. 1.00 mol of hydrogen atoms IL. 8.50 g of oxygen TIL A volume of 11.2 L at standard temperature and pressure (A) Tonly (B) Tonly (C) Monly (D) Land Tl only © 1,0, and 63. How much energy is required to heat 100. g of HO from 20.0°C to 40.0°C 7 (The specific heat of HOU) is 4.18 Mg°C).) A), 93.65 (B) * 4827 (©) 2,000) (D) 41805 (©) 83607 64, Ifa student were to accurately analyze a mixture of solid NaCl and solid NaOH by titration of the hydroxide ion with a standardized solution of HCI, which of the following would be LEAST useful? (A) Bunsen bummer (B) Analytical balance (© Buret () Erlenmeyer flask ©) Indicatora CHEMISTRY TEST—Continued Hg) + Chg) > 2HCig) AH = -18510 5. According to the equation for the reaction represented above, what is AH for the production of 0.100 mol of HCK(g) ? (A) 37.00 (B) -18.5 0 (©) -925) (D) +9254 (B) #18510 2SO,Cg) + Ox(g) 2 2S8O,(g) + heat 6. For the system represented above, which of the following actions will shift the position of equilibrium to the left? (A) Increasing the pressure (B) Increasing the temperature (C) Potting the mixture in a smaller container (D) Adding some 02) (E) Removing some SO3(g) Na(s) +... H,0) 3 7. Products of the reaction represented above include which of the following? 1. Na‘(ag) IL OF(ag) TIL. Hy(g) (A) Lonly (B) Ionly (© Land I only (D) Land M only (©) 1,0, and I ww 68, When the following air pollutants are present in small amounts, which is LEAST hazardous to humans? (A) Ammonia, NH; (B) Carbon dioxide, CO, (©) Sulfur dioxide, $0, (D) Nitrogen dioxide, NO, (B) Hydrogen sulfide, H,S 69. A compound containing only carbon and hydrogen is found to have a molar mass of 100 g/mol and to consist of 16 percent hydrogen by mass. The number of carbon atoms in one molecule of the compound is, wt (B) 3 (4 (D) 6 ®7 70. A 21 g sample of NaF(s) (molar mass 42 g/mol) is dissolved in enough water to yield 2.0 L of solution, What is the molar concentration of Nav(aq)? (A) 0.010 (B) 0.050 M (©) 010M () 025M (&) 050M STOP IF YOU FINISH BEFORE TIME IS CALLED, YOU MAY CHECK YOUR WORK ON THIS TEST ONLY. DO NOT TURN TO ANY OTHER TEST IN THIS BOOK.