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16 Water Treatment Technology
16 Water Treatment Technology
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Chapter Content
Introduction
@ Introduction Government of India enacted the Water (Prevention
@ Water Pollutants and Control of Pollution) Act 1974 to maintain
@ Effects of Water Pollutants wholesomeness of aquatic resources. The act prescribes
@ Drinking Water Treatment Technologies various functions for the Central Pollution Control Board
@ Waste Water Treatment Technology (CPCB) at the apex level and State Pollution Control
@ Reference Boards at the state level. Water pollution in natural water
bodies can be identified and quantified on the basis of
various parameters, such as, dissolved oxygen (DO),
biochemical oxygen demand (BOD), coliform organisms,
pH etc. As per the water quality criteria, the DO levels in
drinking water should be = 6 mg/L and BOD levels should
be < 2 mg/L. Moreover coliforms level should not exceed 50
MPN/100 mL in water which is safe for drinking purpose. If
the water quality of any source is not complying with these
criteria, the water can not be used for drinking purpose
without undergoing complete treatment. Water pollution
can be controlled by diluting the water pollutants in a
reservoir. The various methods for the control of water
pollution can be summarized as follows: 1. The sewage
pollutants are required to be treated in sewage treatment
plants before their discharge in natural water bodies. 2.
Water pollution due to organic insecticides and pesticides
can be reduced by the use of very specific and less stable
chemicals in the manufacture of insecticides/pesticides.
Moreover, use of bio-fertilizers needs to be promoted. 3.
Oxidation ponds can be useful in removing low level of
radioactive wastes. 4. Hot water should not be disposed
directly into the river, as it adversely affects the life of
aquatic organisms.
164
Thermal pollution can be reduced by employing techniques such as cooling, cooling ponds,
evaporative or wet cooling towers and dry cooling towers. 5. Domestic and industrial waste waters
should be treated properly in waste water treatment plants, before discharge in the natural aquatic
systems. 6. Strict implementation of legislations for water treatment should be done. 7. No solid waste
should be dumped into water bodies. 8. Dead bodies of animals/human should not be floated in water
sources. 9. Bathing, washing of clothes, and idol immersion should be strictly restricted in natural water
bodies. Factors behind high pollution of rivers are Chemicals & Effluents,Industrialisation,Failure of
regulatory agencies and implementation of laws,Garbage Dumping, Washing & Sewage, Defecation and
Cremation around river banks, Cremation etc. Direct sources of water pollution include effluent
outfalls from factories, refineries, industries etc. that emit fluids of varying quality directly into water
bodies. Indirect sources of water pollution include contaminants that enter the water supply from
soils/groundwater systems and from the atmosphere via rain water. Soils and groundwaters contain the
residue of human agricultural practices (fertilizers, pesticides, etc.) and improperly disposed of
industrial wastes. Atmospheric contaminants are also derived from human practices (such as gaseous
emissions from automobiles, factories and even bakeries).
Water Pollutants
The substances which are responsible for causing water pollution are called water pollutants.Based
on source, water pollutants can be classified as follows:
1. Domestic wastes and sewage 2. Surface run-off
3. Industrial effluents 4. Thermal pollution
5. Marine pollution
Domestic Wastes and Sewage
Domestic waste and sewage is the biggest polluter of surface and ground water sources in India. This
is due to the big lacuna between the amount of sewage generation and the facilities to dispose it off. The
problem is not only the lack of facilities; rather, the non-functioning of existing facilities / treatment
plants is more critical.
Surface Run-off
The pollutants present on the surface of land, fertilizers, and pesticides added to the soils are washed
down into natural water courses during rains. The flow of fertilizer rich water into streams and lakes
gives rise to eutrophication. Excess of pesticides in water also adversely affect the aquatic life.
Industrial Effluents
Effluents generated from industries which are directly disposed off into the water streams without
any treatment are a very important cause of water pollution. Industrial wastes contain a number of toxic
chemicals such as mercury (Hg), lead (Pb), cadmium (Cd), arsenic (As) etc. Several types of liquid
effluents having toxic chemicals, acids and bases, etc. are also added into the rivers which kills fish and
other aquatic life besides being toxic to human beings. Examples of large scale effluent addition into the
rivers are Yamuna (near Okhla, Delhi), Gomti (near Lucknow), Ganga (near Kanpur), and Hoogli (near
Kolkata) etc.
Thermal Pollution
Temperature above the normal range is called as thermal pollution or Calefaction. Thermal pollution
occurs as a result of the entry of heated water from industries and power generation plants. Various
processes involved in generating thermal pollution are
• Water for cooling condensers • Feeding boilers for steam generation
• Auxillary plant cooling • Ash handling
• Gas washing, etc.
Water Treatment Technology 165
Very fine suspended mud particles can be Treatment with Potassium Permanganate (KMnO4)
removed easily by increasing their size by This is popular for disinfecting well water supplies in villages.
changing them into flocculated particles. For Besides killing bacteria, it also helps in oxidizing the taste producing
this, chemical coagulants are added to water. organic matter. KMnO4, although cheap, handy, and quite useful,
The use of coagulants is generally necessary yet cannot guarantee 100% removal of bacteria. It can remove
for clarifying raw waters containing about 98% bacteria.
turbidities greater than 30-50 mg/L. Some of Treatment with Silver or Electro-katadyn Process
the common coagulants used for the water
Metallic silver ions are introduced into the water by passing it
treatment are alum (Aluminium sulphate, through a tube containing solid silver electrodes. The so introduced
Al2(SO4)3·18H2O), copperas (Ferrous silver ions have a strong germicidal action, and thus act as
sulphate, FeSO4·7H2O), chlorinated disinfectant. However, the use of silver is very costly, and hence
copperas (Ferric sulphate + ferric chloride, not adopted for treating public water supplies.
Fe2(SO4)3 + FeCl3), sodium aluminate
(Na2Al2O4) etc.
Filtration
The process of passing the water through the beds of granular materials (called filters) is known as
filtration. Filtration may help in removing colour, odour, turbidity, and pathogenic bacteria from the
water. Two types of filters are commonly used for treating municipal water supplies.
Water Treatment Technology 167
These are
¡ low sand gravity filters, and Major Methods of Disinfection
¡ rapid sand gravity filters. Sand, either Major method of disinfection is treatment of water with chlorine
fine or coarse, is generally used as filter (Cl2), also known as Chlorination. Chlorination is a process in
medium. which, water is made disinfected by the action of chlorine. It is a
major method of disinfection of public water supplies. Cl2 is cheap,
The mechanisms through which the reliable, easy to handle, easily measurable, and above all, it is
filtration helps in treating water are – capable of providing residual disinfecting effects for long periods,
¡ Mechanical straining thus affording complete protection against future
¡ Flocculation and sedimentation recontamination of water in the distribution system. Various forms
in which chlorine can be applied in water treatment systems are:
¡ Biological metabolism
As free Chlorine
¡ Electrolytic changes
i. In the form of liquid chloride ion (Cl¯),
Disinfection or Sterilisation ii. As Cl2 gas
As Combined Chlorine
The filtered water which is obtained after
going through above procedures normally i. In the form of hypochlorites or bleaching powder (Ca(OCl)2),
contains some harmful disease causing ii. In the form of chloramines (NH2Cl) i.e. a mixture of ammonia and
chlorine,
bacteria in it. These bacteria must be killed
in order to make the water safe for drinking. iii. In the form of chlorine dioxide gas (ClO2)
Disinfection means killing of only the Chlorine tablets are available in the market under various trade
diseases producing bacteria, where as, names, such as “Halazone tablets”. A single tablet of 0.5 g is
sufficient to disinfect about 20 litres of water.
sterilization means killing of bacteria of all
types. The chemical which is used as a
disinfectant must be able to give protection against re-contamination, thus it must have the residual
sterilising effect.
Softening
The reduction or removal of hardness from water is known as water softening. It is not essential to
soften the water in order to make the water safe for drinking purposes. The advantage of softening lies
chiefly in the reduction of soap consumption. The hardness in water can be of two types:
¡ Temporary Hardness It is also called as carbonate hardness, since it is caused by carbonates and
bicarbonates of calcium (Ca) and magnesium (Mg). It can be removed by boiling of water or by
adding lime.
¡ Permanent Hardness It is also called as the non-carbonate hardness. It is caused by the sulphate
(SO4¯ ¯), chlorides (Cl¯), and nitrates (NO3¯) of Ca and Mg.
The permissible hardness for public supplies normally ranges between 75 – 115 mg/L.
Miscellaneous Treatments
¡ Removal of colours, odours, and taste from water
The special treatments for the removal of colours, odours, and tastes are
Aeration – application of oxygen (O2)
Activated carbon treatment – Specially treated carbon which possesses the property of
absorbing and attracting impurities, such as gases, liquids, and finely dissolved solids.
Treatment with copper sulphate (CuSO4·7H2O) – It helps in removing colours, tastes, and
odours from water.
Treatment with oxidizing agents – Oxidizing agents used are KMnO4, Cl2, O3 etc.
168
Waste Water Treatment Some of the waste waters may contain minerals, which may
Technology interfere with the efficiency of the anaerobic microbes.
Pertreatment of waste water with screening and grit removal
Sewage, before being discharged of either are usually found necessary for direct anaerobic treatment.
in river streams or on land, has to be treated Although there are some drawbacks, but UASB system responds
so as to make it safe. The degree of treatment well for the treatment of high strength soluble waste waters, like
required, however, depends upon the those from municipalities and industries like food processing,
characteristics of the source of disposal. edible oils, distallaries, wineries, brewries, dairies, cheese
Sewage can be treated in different ways. processing, organic chemicals etc.
Treatment processes are often classified as
1. Preliminary treatment
2. Primary treatment Common Effluent Treatment Plant (CETP)
3. Secondary (or Biological) treatment Common effluent treatment plant (CETP) is the collective
treatment of effluents of various industries at a centralized facility.
Preliminary Treatment This concept is similar to the concept of Municipal Corporation
treating sewage of all the individual houses. The main objective of
Preliminary treatment consists solely in CETP is to reduce the treatment cost for individual units while
separating the floating materials (like dead protecting the environment.
animals, tree branches, papers, pieces of CETP of 35 MLD capacity at Bawana, Delhi
rags, wood etc.) and also heavy settleable
inorganic solids. It also helps in removing Advantages
the oils and greases etc. from sewage. It facilitates ‘economy of scale’ in waste treatment, thereby
The processes used in preliminary reducing the cost of pollution abatement for individual small
and medium scale enterprises.
treatment are
It addresses ‘lack of space’ issue.
¡ Screening – for removing floating
It has relatively better hydraulic stability.
papers, rags, clothes etc.
It facilitates small scale units, which often can not internalize the
¡ Grit chambers or Detritus tanks – externalities due to control of pollution.
for removing grit and sand
It eliminates multiple discharges in the area and provides
¡ Skimming tanks – for removing oils opportunity for better enforcement i.e. proper treatment and
and greases. disposal.
It provides opportunity to improve the recycling and reuse
Primary Treatment possibilities.
Primary treatment consists in removing It also facilitates better organization of treated effluent and
large suspended organic solids. This is sludge disposal.
usually accomplished by sedimentation in
Disadvantages
settling basins. The organic solids, which are
It operates on ‘one size fits all’ basis.
separated out in the sedimentation tanks (in
Improper management of treatment units at common facility
primary treatment), are often stabilized by
anaerobic decomposition in a digestion tank There is build-up of varied nature and scale of industries along
with the addition of industries in a haphazard manner, without
or are incinerated. The residue is used for
proper planning.
landfills or soil conditioners. The liquid
There is no provision to tackle the fluctuations in the pollution
effluent from primary treatment often
load and quantities, at individual member industries.
contains a large amount of suspended organic
No separate treatment units to deal with hazardous and toxic
material. It also has a high biochemical
effluents.
oxygen demand (BOD).
The processes used in primary treatment are
¡ Sedimentation for removing part of the organic matter from the sewage effluent as in drinking
water purification
¡ Sedimentation aided with coagulation similar to drinking water purification
170
¡ Imhoff tanks An Imhoff tank is an improvement over septic tank, in which the incoming sewage is
not allowed to get mixed up with the sludge produced, and the outgoing effluent is not allowed to
carry with it large amount of organic load, as in the case of septic tank.
These are very economical and do not require skilled supervision during operations. There is 60 –
65% removal of solids and 30 – 40% removal of BOD.
Acknowledgement
The various data/information retrieved from a number of sources like IPCCC, UNSCO, WHO, Government of India website,
Wikipedia, World Bank, NABARD, Policy Papers of eminent scientists and from various institutional websites are duly
acknowledged.
Reference
Nair AT, Ahammed MM. The reuse of water treatment sludge as a coagulant for post treatment of UASB reactor treating urban
water. Journal of Cleaner Production. 2015;96:272-281
Kausley SB, Malhotra CP, Pandit AB. Treatment and reuse of shale gas wastewater: Electrocoagulation system for enhanced
removal of organic contamination and scale causing divalent cations. Journal of Water Process Engineering. 2017;16:149-162
Buscio V, Marín MJ, Crespi M, Gutiérrez-Bouzàn C. Reuse of textile wastewater after homogenization-decantation coupled to
PVDF ultrafiltration membranes. Chemical Engineering Journal. 2015;265:122-128.
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