Titrasi

asam
lemah
dengan
NaOH 0,1
M

1,       Penentuan kurva titrasi normal dan kurva turunan I dan II

Titrasi Normal Turunan I Turunan II
V NaOH /
pH V’ ΔpH/ΔV V’’
mL
0 3.33
0.5 3.53 0.25 0.4
2 3.88 1.25 0.2333333 0.75 -0.111111111
2.5 3.98 2.25 0.2 1.75 -0.066666667
3 4.08 2.75 0.2 2.5 0
3.2 4.12 3.1 0.2 2.925 0
Kurva
3.4 4.16 3.3 0.2 3.2 0 12
3.6 4.19 3.5 0.15 3.4 -0.25
10
4 4.24 3.8 0.125 3.65 -0.0625
4.4 4.31 4.2 0.175 4 0.125 8
4.8 4.36 4.6 0.125 4.4 -0.125
6

PH
5.2 4.43 5 0.175 4.8 0.125
5.6 4.47 5.4 0.1 5.2 -0.1875 4
6 4.51 5.8 0.1 5.6 0
6.4 4.56 6.2 0.125 6 0.0625 2
6.8 4.61 6.6 0.125 6.4 6.245005E-15
0
7.2 4.66 7 0.125 6.8 -6.245E-15 0 2.5 5
7.6 4.71 7.4 0.125 7.2 0
8 4.76 7.8 0.125 7.6 0
8.4 4.83 8.2 0.175 8 0.125
8.8 4.87 8.6 0.1 8.4 -0.1875
9.2 4.93 9 0.15 8.8 0.125
9.6 4.98 9.4 0.125 9.2 -0.0625
10 5.04 9.8 0.15 9.6 0.0625
10.4 5.1 10.2 0.15 10 0
10.8 5.18 10.6 0.2 10.4 0.125
11.2 5.25 11 0.175 10.8 -0.0625
11.6 5.33 11.4 0.2 11.2 0.0625 Ku
12 5.43 11.8 0.25 11.6 0.125 15
12.4 5.53 12.2 0.25 12 5.551115E-15
10
12.8 5.67 12.6 0.35 12.4 0.25
13.2 5.83 13 0.4 12.8 0.125 5
13.6 6.11 13.4 0.7 13.2 0.75
Δ(ΔpH/ΔV)

14 6.63 13.8 1.3 13.6 1.5 0

0 2 4
14.4 9.19 14.2 6.4 14 12.75 -5
14.6 9.74 14.5 2.75 14.35 -18.25
-10

-15

-20
 Δ(ΔpH/ΔV)
0
0 2 4
-5

14.8 10.06 14.7 1.6 14.6 -5.75 -10

15 10.3 14.9 1.2 14.8 -2 -15
15.2 10.5 15.1 1 15 -1
15.4 10.67 15.3 0.85 15.2 -0.75 -20
15.6 10.8 15.5 0.65 15.4 -1
15.8 10.9 15.7 0.5 15.6 -0.75
16 10.97 15.9 0.35 15.8 -0.75
16.2 11.03 16.1 0.3 16 -0.25
Keterangan:
 Kurva Titrasi Normal Chart Title
12
14
10 12 f(x) = 28.125 x − 381
R² = 1
8 10
8
6
PH

Axis Title 6
4 4

2 2
0
0 13.5 13.6 13.7 13.8 13.9 14
0 2.5 5 7.5 10 12.5 15 17.5
Volume Axis Title

Kurva T
Kurva Turunan II
15 7
6
10
5
5
(ΔpH/ΔV)

4
Δ(ΔpH/ΔV)

0 3
0 2 4 6 8 10 12 14 16 18
2
-5
1
-10
0
-15 0 2 4 6

-20
Δ(ΔpH/ΔV)

(ΔpH/
0 3
0 2 4 6 8 10 12 14 16 18
2
-5
1
-10
0
-15 0 2 4 6

-20
Volume
 Kurva Turunan II

Δ(ΔpH/ΔV)
15
10
5
0
Chart Title -5
0 2 4 6 8 10 12 14 16

-10
x) = 28.125 x − 381
²=1 -15
-20
Column G Volume
Linear (Column G)

13.7 13.8 13.9 14 14.1

Axis Title

Kurva Turunan I

2 4 6 8 10 12 14 16 18
Volume
2 4 6 8 10 12 14 16 18
Volume
n II
Kurva Turunan I
7
6
5
(ΔpH/ΔV)

12 14 16 18 4
3
2
1
0
0 2.5 5 7.5 10 12.5 15 17.5
Volume
Titrasi asam lemah dengan NaOH

Titrasi Normal Turunan I Turunan II

V NaOH /
pH V’ ΔpH/ΔV V’’
mL
0.5 2.36
1 2.39 0.75 0.06
1.5 2.43 1.25 0.08 1 0.04
2 2.48 1.75 0.1 1.5 0.04
2.5 2.55 2.25 0.14 2 0.08
3 2.65 2.75 0.2 2.5 0.12
3.5 2.8 3.25 0.3 3 0.2
4 3.01 3.75 0.42 3.5 0.24
4.5 3.27 4.25 0.52 4 0.2
5 3.49 4.75 0.44 4.5 -0.16
5.5 3.71 5.25 0.44 5 0
6 3.91 5.75 0.4 5.5 -0.08
6.1 3.96 6.05 0.5 5.9 1
6.2 4.03 6.15 0.7 6.1 2
6.3 4.11 6.25 0.8 6.2 1
6.4 4.18 6.35 0.7 6.3 -1 100

6.5 4.24 6.45 0.6 6.4 -1

6.6 4.38 6.55 1.4 6.5 8 50
6.7 4.49 6.65 1.1 6.6 -3
6.8 4.57 6.75 0.8 6.7 -3 0
6.9 4.69 6.85 1.2 6.8 4 0 5
7 4.84 6.95 1.5 6.9 3
-50
7.1 5.1 7.05 2.6 7 11
7.2 5.47 7.15 3.7 7.1 11
7.3 5.89 7.25 4.2 7.2 5
7.4 6.36 7.35 4.7 7.3 5
7.6 9.23 7.5 14.35 7.425 48.25
7.7 9.46 7.65 2.3 7.575 -120.5
7.8 9.63 7.75 1.7 7.7 -6
7.9 9.78 7.85 1.5 7.8 -2
8 9.92 7.95 1.4 7.9 -1
8.5 10.39 8.25 0.94 8.1 -0.92
9 10.6 8.75 0.42 8.5 -1.04
9.5 10.75 9.25 0.3 9 -0.24
10 10.84 9.75 0.18 9.5 -0.24
10.5 10.92 10.25 0.16 10 -0.04
11 10.98 10.75 0.12 10.5 -0.08
11.5 11.04 11.25 0.12 11 -7.105427E-15
 12 11.1 11.75 0.12 11.5 7.1054274E-15
12.5 11.15 12.25 0.1 12 -0.04
13 11.2 12.75 0.1 12.5 -7.105427E-15
13.5 11.24 13.25 0.08 13 -0.04
14 11.28 13.75 0.08 13.5 -7.105427E-15
14.5 11.31 14.25 0.06 14 -0.04
15 11.35 14.75 0.08 14.5 0.04
15.5 11.38 15.25 0.06 15 -0.04
16 11.4 15.75 0.04 15.5 -0.04
16.5 11.43 16.25 0.06 16 0.04
17 11.46 16.75 0.06 16.5 7.1054274E-15
17.5 11.49 17.25 0.06 17 -7.105427E-15
18 11.51 17.75 0.04 17.5 -0.04
18.5 11.53 18.25 0.04 18 0
19 11.56 18.75 0.06 18.5 0.04
19.5 11.58 19.25 0.04 19 -0.04
20 11.6 19.75 0.04 19.5 0
16

14

12

10

8
Column E
6

0
0 5 10 15 20 25

100

50

0
0 5 10 15 20 25
Column G

-50

Chart Title
60
40 f(x) = − 1125 x + 8401.37499999997
20 R² = 1
0
Axis Title

-20 7.4 7.42 7.44 7.46 7.48 7.5 7.52 7.54 7.56 7.58 7.6 Column G
-40 Linear (Column G)
-60
-80
-100
-120
-140
Axis Title
-100
-120
-140
Axis Title
 Titrasi asam kuat dan basa kuat dengan indicator pp,
Volume HCl → 50 mL ditambah 2 tetes indicator pp
Volume NaOH yang dititrasi
-         14,5 mL
-         14,1 mL
Volume rata-rata 14,3 mL

Reaksi yang terjadi

            HCl + NaOH → NaCl + H2O                            (larutan berwarna merah muda)

2,     Titrasi asam kuat dan basa kuat secara potensiometri

Volume HCl = 25 mL

Titrasi Normal Turunan I Turunan II

V NaOH /
pH V’ ΔpH/ΔV V’’
mL
5 0.42
10 0.76 10
7.5 0.068
11 0.89 10.5 0.13 9 0.062
5
12 1.03 11.5 0.14 11 0.01
13 1.31 12.5 0.28 12 0.14 0
14 6.68 13.5 5.37 13 5.09 8 10 12 14
14.1 7.29 14.05 6.1 13.775 7.3 -5
14.2 7.69 14.15 4 14.1 -21
14.3 7.87 14.25 1.8 14.2 -22 -10
14.4 8.04 14.35 1.7 14.3 -1
-15
14.5 8.18 14.45 1.4 14.4 -3
14.6 8.33 14.55 1.5 14.5 1 -20
14.7 8.38 14.65 0.5 14.6 -10
14.8 8.43 14.75 0.5 14.7 -2.66E-13 -25
14.9 8.49 14.85 0.6 14.8 1
15 8.54 14.95 0.5 14.9 -1
20 9.38 17.5 0.168 16.225 -0.0664
25 9.64 22.5 0.052 20 -0.0232

10
5 f(x) = − 8
R² = 1
0
13.75 13.8 13.
Axis Title

-5
-10
-15
-20
-25
 -10

Axi
-15
-20
-25
10 12 14 16 18 20 22

Column G

Chart Title
10
5 f(x) = − 87.0769230769249 x + 1206.78461538464
R² = 1
0
13.75 13.8 13.85 13.9 13.95 14 14.05 14.1 14.15
Axis Title

-5 Column G
Linear (Column G)
-10
-15
-20
-25
Axis Title
 -10

Axi
-15
-20
-25
Axis Title