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VHCl(mL) pH VmedioHCl(mL) ΔpH VHCl(mL) ΔpH

0 11.11 1 -0.33 2 0.1175


2 10.45 3 -0.095 4 0.0075 Ch
4 10.26 5 -0.08 6 0.0075 12
6 10.1 7 -0.065 8 -4.44089E-16 11
8 9.97 9 -0.065 10 -0.005 10
10 9.84 11 -0.075 12 0.0075 9
8
12 9.69 13 -0.06 14 -0.0025

Axis Title
7
14 9.57 15 -0.065 16 -0.015
6
16 9.44 17 -0.095 18 -0.025
5
18 9.25 19 -0.145 20 -0.0275 4
20 8.96 21 -0.2 22 -0.175 3
22 8.56 23 -0.55 23.625 0.392 2
0 5 10 15
24 7.46 24.25 -0.06 24.5 -0.4
24.5 7.43 24.75 -0.26 25 -0.04
25 7.3 25.25 -0.28 25.625 0.173333333
25.5 7.16 26 -0.15 26.5 0.01
26.5 7.01 27 -0.14 27.5 0.02 C
27.5 6.87 28 -0.12 28.5 0.08
0
28.5 6.75 29 -0.04 29.5 -0.03 0 5 10 15
29.5 6.71 30 -0.07 30.5 -0.02 -0.2
30.5 6.64 31 -0.09 31.5 -0.02
-0.4
31.5 6.55 32 -0.11 32.5 0.05
32.5 6.44 33 -0.06 33.5 -0.03 -0.6

ΔpH
33.5 6.38 34 -0.09 34.5 0.08 -0.8
34.5 6.29 35 -0.01 35.5 -0.03
-1
35.5 6.28 36 -0.04 36.5 -0.08
36.5 6.24 37 -0.12 37.5 0.11 -1.2
37.5 6.12 38 -0.01 38.5 -0.01 -1.4
38.5 6.11 39 -0.02 39.5 -0.24
39.5 6.09 40 -0.26 40.5 0.16
40.5 5.83 41 -0.1 41.5 0.01
41.5 5.73 42 -0.09 42.5 0.08
42.5 5.64 43 -0.01 43.5 -0.35
43.5 5.63 44 -0.36 44.5 0.06
44.5 5.27 45 -0.3 45.5 -1.01
45.5 4.97 46 -1.31 46.5 0.63
46.5 3.66 47 -0.68
47.5 2.98

Chart Title
0.8

0.6

0.4

0.2

0
0 5 10 15 20 25 30
Axis Title

-0.2

-0.4

-0.6

-0.8
0.2

0
0 5 10 15 20 25 30

Axis Title
-0.2

-0.4

-0.6

-0.8

-1

-1.2

Axis Title
Datos
Patrón primarNa2CO3
Chart Title masa pesada 1.066 g
12 Vdon 100 mL
11 Mmolecular 105.99 g
10 Pureza 99 %
9
n 0.01005755 mol
8
n 0.01015914 mol
Axis Title

7
M Pp 0.10159144 M
6
5
V Pp 25 mL
4 Cálculo [HCl] M
3 Vgastadovalo 23.96 mL
2 MHCl =? 0.05492617 M
0 5 10 15 20 25 30 35 40 45 50
T

Chart Title
0
0 5 10 15 20 25 30 35 40 45 50
-0.2

-0.4

-0.6
ΔpH

-0.8

-1

-1.2

-1.4
Axis Title

Chart Title

15 20 25 30 35 40 45 50
Column F
15 20 25 30 35 40 45 50
Column F

Axis Title
al 99%
al 100%

46.24 mL
VHCl(mL) pH VmedioHCl(mL) ΔpH VHCl(mL) ΔpH
0 1.29 1 0.01 2 0.02 pH
2 1.31 3 0.05 4 -0.005 14
4 1.41 5 0.04 6 0
12
6 1.49 7 0.04 8 0.0075
8 1.57 9 0.055 10 0.005 10
10 1.68 11 0.065 12 0.0075 8

Axis Title
12 1.81 13 0.08 13.75 0.02666667
6
14 1.97 14.5 0.12 15 0.02
15 2.09 15.5 0.14 16 0.07 4
16 2.23 16.5 0.21 17 0.1 2
17 2.44 17.5 0.31 18 7.17
0
18 2.75 18.5 7.48 18.875 -7.94666667 0 5 10 15
19 10.23 19.25 1.52 19.5 -2.16 Axis Title
19.5 10.99 19.75 0.44 20 -0.12
20 11.21 20.25 0.38 20.5 -0.36
20.5 11.4 20.75 0.2 21 -0.08
ΔpH
21 11.5 21.25 0.16 21.5 -0.24
21.5 11.58 21.75 0.04 22.125 0.14666667 8
22 11.6 22.5 0.15 23 -0.07 7
23 11.75 23.5 0.08 6
24 11.83 5

Axis Title
4
3
2
1
0
0 5 10 15
Axis Title

ΔpH
10
8
6
4
2
Axis Title

0
0 5 10 15
-2
-4
-6
-8
-10
Axis Title
Datos
pH Patrón primaHCl
masa pesada 1.066 g
Vdon 100 mL
Mmolecular 105.99 g
Pureza 99 %
n 0.01005755 mol
pH n 0.01015914 mol
M Pp 0.10159144 M
V Pp 25 mL
Cálculo [HCl] M
Vgastadovalo 46.24 mL
5 10 15 20 25 MHCl =? 0.05492617 M
Axis Title

ΔpH

ΔpH

5 10 15 20 25
Axis Title

ΔpH

ΔpH
5 10 15 20 25

Axis Title
al 99%
al 100%
VHCl(mL) pH VmedioHCl(mL) ΔpH VHCl(mL) ΔpH
0 2.77 0.25 0.52 0.5 -0.4
0.5 3.03 0.75 0.32 1 -0.16
1 3.19 1.25 0.24 1.5 0 Valoración alimenta
1.5 3.31 1.75 0.24 2 -0.12 14
2 3.43 2.25 0.18 2.5 -0.08
12
2.5 3.52 2.75 0.14 3 0.08
3 3.59 3.25 0.18 3.5 -0.2 10
3.5 3.68 3.75 0.08 4 0.12 8

Axis Title
4 3.72 4.25 0.14 4.5 -0.12
6
4.5 3.79 4.75 0.08 5 0
5 3.83 5.25 0.08 5.5 0.04 4

5.5 3.87 5.75 0.1 6 -0.04 2


6 3.92 6.25 0.08 6.5 0.08 0
6.5 3.96 6.75 0.12 7 -0.08 0 10 20
7 4.02 7.25 0.08 7.5 -0.04 Axi
7.5 4.06 7.75 0.06 8 0
8 4.09 8.25 0.06 8.5 0
8.5 4.12 8.75 0.06 9 -3.5527E-15
9 4.15 9.25 0.06 9.5 3.55271E-15
9.5 4.18 9.75 0.06 10 0
10 4.21 10.25 0.06 10.5 -0.04
10.5 4.24 10.75 0.04 11 3.55271E-15 ΔpH
11 4.26 11.25 0.04 11.5 -3.5527E-15 4
11.5 4.28 11.75 0.04 12 3.55271E-15 3.5
12 4.3 12.25 0.04 12.5 -3.5527E-15
12.5 4.32 12.75 0.04 13 0.04 3

13 4.34 13.25 0.06 13.5 -0.04 2.5


13.5 4.37 13.75 0.04 14 3.55271E-15
2
14 4.39 14.25 0.04 14.5 -3.5527E-15
14.5 4.41 14.75 0.04 15 3.55271E-15 1.5
15 4.43 15.25 0.04 15.5 -3.5527E-15 1
15.5 4.45 15.75 0.04 16 3.55271E-15
0.5
16 4.47 16.25 0.04 16.5 -3.5527E-15
16.5 4.49 16.75 0.04 17 3.55271E-15 0
0 10 20 30
17 4.51 17.25 0.04 17.5 -0.04
17.5 4.53 17.75 0.02 18 0.08
18 4.54 18.25 0.06 18.5 -0.08
18.5 4.57 18.75 0.02 19 0.04
19 4.58 19.25 0.04 19.5 3.55271E-15
ΔpH
19.5 4.6 19.75 0.04 20 -0.04 4
20 4.62 20.25 0.02 20.5 0.04
3
20.5 4.63 20.75 0.04 21 -3.5527E-15
21 4.65 21.25 0.04 21.5 3.55271E-15 2
21.5 4.67 21.75 0.04 22.125 -0.01333333
1
22 4.69 22.5 0.03 23 0.01
23 4.72 23.5 0.04 24.5 -0.01333333 0
0 10 20 30
-1

-2

-3
2

0
0 10 20 30
24 4.76 25.5 0.01333333 26.5 0.01333333 -1
27 4.8 27.5 0.04 28.25 0
28 4.84 29 0.04 30 0 -2
30 4.92 31 0.04 32 0.0025 -3
32 5 33 0.045 34 0.0025
34 5.09 35 0.05 36 0.0025 -4

36 5.19 37 0.055 37.75 -0.00333333


38 5.3 38.5 0.05 39 0.02
39 5.35 39.5 0.07 40 0.01
40 5.42 40.5 0.08 41 0.01
41 5.5 41.5 0.09 42 0
42 5.59 42.5 0.09 43 0.05
43 5.68 43.5 0.14 44 0.01
44 5.82 44.5 0.15 45 0.15
45 5.97 45.5 0.3 46 0.44
46 6.27 46.5 0.74 47 2.76
47 7.01 47.5 3.5 48 -3.04
48 10.51 48.5 0.46 49 -0.28
49 10.97 49.5 0.18 50 -0.07
50 11.15 50.5 0.11 51 0
51 11.26 51.5 0.11 52 -0.03
52 11.37 52.5 0.08 53 -0.03
53 11.45 53.5 0.05 54 0.01
54 11.5 54.5 0.06 55 -0.02
55 11.56 55.5 0.04
56 11.6
Datos
nuevo PatrónNaOH

Valoración alimentación con NaOH

M Pp 0.11490633 M
V Pp 47.56 mL
Cálculo [alimentación] M
Vgastadovalo 1 mL
MALIMENTAC5.46494486 M

10 20 30 40 50 60
Axis Title

ΔpH

10 20 30 40 50 60

ΔpH

10 20 30 40 50 60
10 20 30 40 50 60
VHCl(mL) pH VmedioHCl(mL) ΔpH VHCl(mL) ΔpH
0 3.06 1 0.475 2 -0.1475 pH
2 4.01 3 0.18 4.075 -0.02507583
14
4 4.37 5.15 0.12608696 6.15 -0.00127877
6.3 4.66 7.15 0.12352941 8.075 0.00079491 12
8 4.87 9 0.125 10 0.0425
10
10 5.12 11 0.21 12 0.8325
12 5.54 13 1.875 13.625 0.9 8
14 9.29 14.25 3 14.5 -4.84
6
14.5 10.79 14.75 0.58 15 -0.68
15 11.08 15.25 0.24 15.5 7.10543E-15 4
15.5 11.2 15.75 0.24 16 -0.16
16 11.32 16.25 0.16 16.5 -0.12 2

16.5 11.4 16.75 0.1 17 0.04 0


17 11.45 17.25 0.12 17.5 1.16 0 5 10
17.5 11.51 17.75 0.7 18 -2.44
18 11.86 18.25 -0.52 18.5 1.2
18.5 11.6 18.75 0.08 19 -0.04
19 11.64 19.25 0.06 ΔpH
19.5 11.67 3.5

2.5

1.5

0.5

0
0 5 10
-0.5

-1

ΔpH
2

0
0 2 4 6 8 10 12
-1

-2

-3

-4

-5

-6
-4

-5

-6
Datos
pH nuevo PatrónNaOH

M Pp 0.11490633 M
V Pp 13.79 mL
Cálculo [destilado] M
Vgastadovalo 1 mL
MDestilado = 1.58455823 M

5 10 15 20 25

ΔpH

5 10 15 20 25

ΔpH

6 8 10 12 14 16 18 20
VHCl(mL) pH VmedioHCl(mL) ΔpH VHCl(mL) ΔpH
0 2.88 1 0.33 2 -0.095 pH
2 3.54 3 0.14 4 -0.025 12
4 3.82 5 0.09 6 -0.0125
6 4 7 0.065 8 -0.005 10
8 4.13 9 0.055 10 -0.0025
10 4.24 11 0.05 12 -0.0025 8
12 4.34 13 0.045 14 -0.0025
6
14 4.43 15 0.04 16 0.0025
16 4.51 17 0.045 18 -0.0025
4
18 4.6 19 0.04 20 0
20 4.68 21 0.04 22 0 2
22 4.76 23 0.04 24 0.0025 ΔpH
24 4.84 25 0.045 26 0 3.5 0 0 5 10 15 20 25
26 4.93 27 0.045 28 2.22045E-16
28 5.02 29 0.045 30 0.005 3
30 5.11 31 0.055 32 0.0025 2.5
32 5.22 33 0.06 34 0.005
34 5.34 35 0.07 36 0.015 2
36 5.48 37 0.1 38 0.03
1.5
38 5.68 39 0.16 40 0.2975
40 6 41 0.755 41.75 1.59666667 1
42 7.51 42.5 3.15 43 -2.81
43 10.66 43.5 0.34 44 -0.17 0.5

44 11 44.5 0.17 45 -0.04 0


45 11.17 45.5 0.13 46 -0.06 0 5 10 15 20 25
46 11.3 46.5 0.07 ΔpH
47 11.37
2

0
0 5 10 15 20 25

-1

-2

-3

-4
Datos
pH nuevo PatrónNaOH

M Pp 0.11490633 M
V Pp 42.14 mL
Cálculo [calderín] M
Vgastadovalo 1 mL
ΔpH Mcalderín =? 4.84215257 M
n, moles 0.00484215 mol
10 15 20 25 30 35 40 45 50

M Pp 0.11490633 M
V Pp 42.14 mL
Cálculo [calderín] M
Vgastadovalo 26 mL
Mcalderín =? 0.18623664 M
Vgastadovalo 1 mL
Mcalderín =? 4.84215257 M

10 15 20 25 30 35 40 45 50

ΔpH

10 15 20 25 30 35 40 45 50
46.24 mL

46.24
Tiempo TemperaturaVolumen don acético-agua Lo ác-agua 1L
Fracción molar del agua xo agua 0.9
97 °C Volumen del destilado D 1 mL
Rectificado, fracción molar Xd
102 °C Calderín, fracción molar Xb

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