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Enhanced Adsorption Removal of Methyl Orange from Aqueous Solution by

Nanostructured Proton-Containing δ-MnO2

Article · February 2015

DOI: 10.1039/C4TA07112C

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6 authors, including:

Yan Liu Haizhen Li

University of Science and Technology of China Beijing Forestry University
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Lanzhou University
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Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A.
This journal is © The Royal Society of Chemistry 2015

Supporting Information for

Enhanced Adsorption Removal of Methyl Orange from Aqueous

Solution by Nanostructured Proton-Containing δ-MnO2

Yan Liua, Chao Luoa,b, Jian Suna, Haizhen Lia, Zebin Suna, Shiqiang Yana*

a College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou

730000, PR China

b CNOOC Tianjin Chemical Research & Design Institute, Tianjin 30000, P. R. China

*Corresponding author. Tel./fax: +86 931 8912582

E-mail address: yansq@lzu.edu.cn (S. Yan)

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SEM image and EDX results of K-δ-MnO2 nanosheets:

Element Weight% Atomic%

KK 17.05 22.41

Mn K 82.95 77.59

Totals 100.00 100.00

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SEM image and EDX results of H-δ-MnO2 nanosheets:

Element Weight% Atomic%

KK 2.53 3.52

Mn K 97.47 96.48

Totals 100.00 100.00

3
SEM image and EDX results of K-δ-MnO2 nanoparticles:

Element Weight% Atomic%

KK 18.98 24.76

Mn K 81.02 75.24

Totals 100.00 100.00

4
SEM image and EDX results of H-δ-MnO2 nanoparticles:

Element Weight% Atomic%

KK 2.60 3.62

Mn K 97.60 96.38

Totals 100.00 100.00

5
Fig. S1 N2 adsorption-desorption isotherm of K-δ-MnO2 nanosheets, H-δ-MnO2

nanosheets (a), K-δ-MnO2 nanoparticles and K-δ-MnO2 nanoparticles (b).

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Fig. S2 Plot of the pseudo-first-order kinetic model for MO adsorption on different δ-

MnO2 materials.

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Fig. S3 Plot of the pseudo-second-order kinetic model for MO adsorption on different

δ-MnO2 materials.

8
Fig. S4 Langmuir adsorption isotherm plots for MO adsorption onto different δ-

MnO2 materials.

9
Fig. S5 Freundlich adsorption isotherm plots for MO adsorption onto different δ-

MnO2 materials.

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 Fig. S6 Plots of ln qe/Ce vs. qe for calculation of thermodynamic parameters.

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