2023-2215 Name: EXcEL EDUCATIONAL CENTRE, AL-THUMAMA @ Seance pefead Methods tapes encenration of b 05m ne © 212m 4 075m 1 Which often varie wih ron temper! 1. The molto NAOH in 250 slat Moly " 8 Moly 02m © Mole tsion 6 0am 4. None ort © osm Am 05m 2. Which ofthe flowing it bets meted (=. forexresingconatinonaf slater? 8, Theft fleeting empet ofan olay evan ean Motiy Mla eae €. Molen D)_ Malay case 4 Now of tin 6) Malefxcon often Awa 3) Masset eae 3. Whi te fling isa sonst gent To V0 ey inet peer youre of ctor 4. TM Gy solution i tess concentrated 9, Molarty of 9.8% by mass of sulphuric acid than tq soli. solution wiose density 1-25g/mL is xc Sdonmir sno 1 2M coast tan Leslie, tM Botta equal connate 25M Cantte prt os0M AmB Ans 4 Theme tin sole nolo 10, Te density of sotto repre bs olan dissing 20g {oer mas 60 ») 0176 Mage Ehenty | in000got wales Spin he molniy D) 0tte Meenee se? gtthesauion 3) 02r Sézortoa 17M 021 tow AB 3) 2osat 5. Aseton| One mlaragteos ston ison tor concent thon ml gto ‘Ans Chit id mast poly onion the toma) [Ressen : One molar aqueous solution 11. 30ml of 0.5M HpSOs is diluted in 10 500ml. Covet rout ofr and ae the oly of faa colton Tomer fils ofl corpare ent On pola 2 soon 6 0mm ins © 0M 6 Theallly of 6% by soliton of ue in a uM ri fas 16m pateNo 2021-22/5 eo 12,6022 x 10 Na" ions st dissolved per 500 rl of lake water the molarity of the so 3) 02M b) 902M ©) 0M ) 005M Ans A. 13, 16,02 x 10 molecules of wea present in 100m ofits soltion. The concentration of| soltion is 3) 002M b) 001M €} 0.001M 04M ‘Ans B ‘Heery’s aw 14, The patil pressure of pas in vapour phase is proportional tothe mele faction of gin the solution” thisstafement fs known z ane Mahesh Kumar PGI Chemisty, © Koblrausch’s iow —— Mige, Bed, SET a. Both and b 66267903, Ans A. 15. The people living in higher attude has aw thinking eapacity ( Anoxia because of 8, More oxygen disolved in blood Less surrounding pressure «Les oxygen dissolved in blood 4. Both band © Ans 16. The value of of Henry law constant 4) Increases wit ineease in temperature 1b) Decreases with increas in temperature ©) Remain constan &)_ First nereases then decreases, Ang Name: EXCEL EDUCATIONAL CENTRE, AL-THUMAMA CHEMISTRY ~ Solution (objective) 17. The Ku values of some gases a 293K is given below. Arrange them in the increasing ‘order of solubility Gas [Ki Valueikbar Hie fva497 Ne | 76a [69.16 0: 34.86 He “species than hot water b. At Taw temperature more oxygen gas will dissolve in water Ata temperature less oxyan gat will dissolve in water 4 Botha and Ans B 19. The solbilty of pure nitrogen gas at 25°C And | atm is 6810 mo Ll, What i the ‘concentration of nitrogen dissolved in water under atmosphere conditions? The patil pressure of nitrogen gas in the atmosphere is 0.78 am. a) 5.308% 10% b) 25x 10% ©) 38x10 16x10 Ans A 20. "The partial pressure of ethane aver & saturated solution containing 6.5610? g of ethane is I bar ithe solution contains 5.010" gof ethane, then what wil ke the partial pressure ofthe gas? a) 0.56 bar b) 0:76bar ©) 1312bar 4) 028 bar Ans Bwenoarnas | GO 21, Assertion: Solubility of sli in guid inereases with nereasein temperature Reason: with increase in temperature more 22. 2. 24, as 26, 2. 28, Name: EXCEL EDUCATIONAL CENTRE, AL-THUMAMA CHEMISTRY ~ Solution (objective) ‘Reason: Henry's lav is applicable fora solution of as ina liquid whereas Raoult's law is applicable fortwo volatile Kiguid enon Suny ag aati Maes Kumar” inversely proportional t9 K yj value ‘Msc, BEd, SET) | Components must have almost same eal PP vss oe nap Meer en onan tite i Mitre, alia pe eal Cia ‘in higher tersperature Ans A ‘Aas. 31. For an ideal solusion| “Assertion: Its bttr to dink soft drinks 8) A—A , BB interaction is stronger ‘unde chilled condition than normal than A~B interaction temperature b) A-A ,B Binteraction is weaker Reason: CO, has less solubility in water at than AB interaction lower teperture ©) A-A.,B-Binteracton is equal to Ans€ AB intergetion Assertion: Ky value of helium is hier than 8) None ofthese that of oxygen, AnsC Reason: Helium ha les solubility in blood 32, Which ofthe following will show pesitive than oxygen. deviation? AnsB 3) Methanol and acetone ‘aR 1b) Chloroform and acetone Rauits law is applicable for ©) Nitric ae and water 2) Mixture of two roavolatileliguids 4) Phenol ana anttine 1) A solution of gas in tguid Ans A ©) solution oft volatile liguid 33, Which ofthe following will show negative eoaipcnne deviation from Raults lw? @)_Allof the above 8) Chloroform and acetone ‘Ans © b) Alcohol and water Assertion: Raoul's lw isa modifiation of| Henry's law ©) chloromethane and bromometane 8) Benzene and toluene Ans Aee a » 3 a 3) » 0 o Ans A. BY » 9 % ‘Ans B a » ° 6 shows ) » °) % renearnars —] Name: EXCEL EDUCATIONAL CENTRE, AL-THUMAMA CHEMISTRY ~ Solution (objective) 54. On mixing two components the outer ». suefice ofthe beaker become beter the deviation from Raults lw observed is Positive deviation Negative deviation [deal solution None ofthese Ans B 40 35. On mining two components the outer surface ofthe solution becomes cold the 'ype of deviation from Raults law is Positive deviation Nepitvedevitin Mahesh Kumar Pat chamistry ‘eal solution Meo, Bo, SET ‘None af these 166267903 36, On mixing liquid X and liquid ¥, volume of the resulting solution deeeases, What chang in heat energy would you observe ates mixing liquids X and ¥? 4 “Heat is absorbed Heat is released Nochange First absorbing of hat then release 2 Azeotropie mixture 37. A mixture containing 68% of HNOs and 32% of water is Minimum boiling azeotpe Maximum boiling zeotope Either a orb None ofthese a 38. A solution of two liquids boils ata temperature more than the boiling point of ‘ther them. Hence the binary sclution Negative deviation from Raout’s law Positive deviation from Raoult's law 4 [No deviation from Raoult’ aw Positive or negative deviation from aoul’s law depending upon the composition ‘Ans A “The system that ean form maximum boing aagotrope is 18) Carbondisuphide-acetone by Benzene-toluene ©) Acetone-chloofeem 1) n-hexane-n-heptane Ans C “Two liquids A and B form minimum boiling azeotrope the 8) AA , B-B interaction is stronger than A~B interaction by AA , BB interaction is weaker than AB inaction ©) AA. BB interaction is equal 0 ‘AB iteration None ofthese Ans B ‘Assrtion:- A solution containing 95% ‘ethanol and 5% water isa minimum boiling azeotrope Reason : Azeotropic mixtures have same ‘composition of components in liquid and ‘vapour form Ans B ‘Assertion: A mixture containing 68% of. HINO; and 32% of water is a maximum boiling azeotope Reason: A mixture of ta liquids forms ‘Which ofthe following is nota colligative property? 4) Elevation in boiling point, 1) Onmatie pressure ©) Freezing point 8) Relative lowering of vapour pressure Ans C ‘When concentration of solute particle is increased fora sotion its 4) Boiling point increases while vapour pressure decreases 1) Boiling point decreases while vapour Pressure increases (ppgio 2023-2215 Name EXCEL EDUCATIONAL CENTRE, AL-THUMAMA a enon a cae) ©) Freeing point decreases while o 58 ‘apour pressure inereases 0% | 6, Freezing pint increases while AnsA } ‘vapour pressure decreases 49. 18g of glucose dissolved in 90 gofwater | | Ans A the lative lowering of vapour presste of || 45, Assertion: solation of 120g rea in Mite the sluton is [ Take Ky Forwateras08K | | wate as high boing point than tht oa vy al | solution of 180g elucos in oe lite water ) 6 Reason : Elevation in bing point is « ma colligatve property whch depends only on 341 te numberof moles of solute paticies are @ 00. called AnsD Ans 50, The unit of ebullioseopie constant is 46, Which one of the statements given below Kagan! covering properties of solution descrbes a Peace colligatve effect? ©) kgmel-! Kt 4) Boiling point of pure water Kumolky decreases by the adition of ethanol an 1), Vapour pressure of pure water 51. To observe an elevation in boiling pint of| Aecreases by edition of nite acid (0.050€ the amount oF slue[ molecalar ‘9. Vapour pressure of pure benzene ‘ss 100g/maf] be added in 100 of desreases by aition of naphthalene ‘waters [eb for water take a8 0.5K] 4) Boiling pint ofpure benzene 26 increases by aditon of toluone noe Amc 3 Ie non-volatile solute in 290g of Wate. Ithas a {52 The boiling point of solution containing 47. A solution is prepared by dissolving 10g of 0.758 ‘Ans | ‘pour pressure of 31 84min of ig st 308 0.18 got loose (Cos0. dso in Khe mola sf te slits. 4 potter, (ke fur water =0.52 (vapour pressure of pe water 3308 K= 2) 10008 ‘32mm Hg). +b) 100,06'C a) 18g/mol Mahesh Kumar ©} 100.05"C ©) badger Bar Gromit 4) imno2te 8) Stgiet Meo BE SET anc &) 60gimol 53. A solution containing 8g of a substance in Ans 100g of diethyl ether boils at 38.62°C, 48, Calealate the mass of non-volatile solute then pre eer oils #36 0. (molar mass = 40g moll), which should be ‘Determine the molecular mass of the solute solved in 114g of octane to reduce its (or ether K »"2.02Kky mol) ‘vapour pressure to 80%, (Consider the a) 45g/mol soliton iit] b) Ggimol (Molar mas of eta 14g ol. ©) Boyinal a) te gel by bE Ans C ps paged2021-22/8 ‘Name: EXCEL EDUCATIONAL CENTRE, AL-THUMAMA Gu) GAEMISTRY — Solution fobjective) 54, What mass of ethylene glycol (molar mass ‘Reason: non-volatile solute ean inerease the 62.0 mol-1) must be added t0 5.50 Ky of Freezing point of water. water to lower he freezing poi of water Ans from OC to 9.3907 {EK for water = L86K ky mol 60, Which ofthe following is corest relate to a) 128k the following two solutions separated by by 1705kg semi permeable membrane? ©) 123k od) 1S2kg ott ada AmB 62g of ethylene glycol (CaHsOs} i mived ‘with 600g of water. Caleulate Tye freezing point depression is. s ce 1) Solvent moves fom B to 8 (Grenier 6b 2) Crow move on A WB 2 ae 3) Sonne ton 8 8 3 lk 5, Savion ove on Bo A oex ane md 61-10 gor dae in rongh 6 Logcta mnt vn setae Sof lon ths sin tla afb nce Ist umae tof Tecan often 02h 2°, Thema mse he pth marasotuesiaes 00s Cam aol) (Rtfrbewores3 2 ts cae ga pe 1») 2S6g/mol c) 2x10 g/mol <) 142g/mol d) 4x10" gimol Ans A. © Aero! 62, At 300K ,30 g glucose present per litte of its ‘Ans B 57. A solution of urea in water has oiling point 0f 373 52K, calculate the feeziag point of same solution { ky 1.86 K kg moll and solution has an osmotic pressure of Shar. if ‘the osmotic pressure of anther lucose solution per fie is 2 bar at the same temperature, what would be the mass of y= 052 K kg mob} cose in second solution? 3) 180 Manesh Kumar *s) 9 by) L268 Par chemistry Dg 3 rare Msc, 6a, SEY i ic 66267903 aie fe Ans A (63.18% by mas of ehcosesoltion is isotonic 58, Assertion: Ethylene elycol is used in car with station owen soe X the radiators Reason: non-volatile sole car derease the molar mass of X is a) 180 g/mol freezing point of water ee a by 6Og/mot 59, Asserton: common salt is usec to remove Ce ) 99g/mot snow from the roads Ans Bho 20282015 GO Name EXCEL EDUCATIONAL CENTRE, AL-THUMAMA CHEMISTRY Solution (objective) (64, The empiriel formula ofa nomelectrolyte is CHO. A solution centaining 3 goF the compound exets the sme esmotic pressure es that of 005M glucose solution. The molecular formula of te compound is a) CHO by CaHO> ©) CHOs CHO, ‘Ans B 4 NAOH is dissolvedto make one litre solution. Which ofthe following i isotonic ‘with this solution? 6s 8) O.1MNa:SOy PGT Chemisty ») O.IMKcL Mse, BE, SET 3 outta 66267903 ) OAMCaCle Ans B (6, Which ofthe beater method for determining ‘molectlar mass of unknowe solute of mero molecules? 4) Elevation in being point 1) Depression in eezing point ©) Relative lowering of vapour pressure 4) Osmotic presse ‘AnsD. For finding moleenla ass of unknown solute osmotic pessue method ia better method because of 4) team be measired at room temperature Will give measurable value with ess snount of solute paticles ©) Molarty is used instead of molatiy 4) Allofthe abore ‘Ans D. Assertion: Osmotic pressure method isa better method for determining molar mass of macromolecules Reason: osmotic presure is temperate depend Ans B Assortion‘Two solutions with same osmotic pressure are called isctonie soltions ‘Reason isotonic sliions have same umber of moles of solute partils Ans 7, » ©, Mahesh Kumar 5) 10, Which of the flo boiling point? 8) LOM NaOH by LOM NaSOs ©) LOMNHiNOs 4) LOMKNO, Ans B “1. The depression in foezing point of water ‘observed for the same malar concetrations ‘of sete acid, trichloroacetic acid and teifluroaeetic acid is ')._ CILCOON ) OIMKCI ©) O.1M Urea @ OIMCaCh Ans “14, Which oF he following solution hs high depression in feezing point? 4) OAMNeSOr b) OIMKCL ©) O1MUra 4) OAM CaCls aasD 75, Which of the following solution his igh Fieezing point? 8) O.1MNaSOu b) OIMKCI ©) 01M Urea 8) OAM CaCl fos tee |