Excel Educational Centre, Villa #25, Street #818, Al Thumama, Doha, Qatar

EXCEL EDUCATIONAL CENTRE,DOHA -QATAR
MOCK EXAMINATION-2,NOVEMBER 2021

CHEMISTRY-087
Time : 90 Minutes
General Instructions
1.The Question Paper contains three sections.
2. Section A has 25 questions. Attempt any 20 questions.
3. Section B has 24 questions. Attempt any 20 questions.
4. Section C has 6 questions. Attempt any 5 questions.
5. All questions carry equal marks. 6. There is no negative marking.
Given below are two statements labelled as Assertion (A) and Reason (R).
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false and R is also false.
SECTION-A
This section consists of 25 multiple choice questions with overall choice to attempt any 20
questions. In case more than desirable number of questions are attempted, ONLY first 20
will be considered for evaluation.
1. An ideal solution is formed when its components
(a) have no volume change on mixing
(b) have no enthalpy change on mixing
(c) have both the above characteristics
(d) have high solubility.
2. Which one of the following is non-ideal solution
(a) Benzene + toluene
(b) n-hexane + n-heptane
(c) Ethyl bromide + ethyl iodide
(d) CCl4 + CHCl3
3. Which of the following liquid pairs shows a positive deviation from Raoult’s law ?
(a) Water - Nitric acid
(b) Benzene - Methanol
(c) Water - Hydrochloric acid
(d) Acetone - Chloroform
4. The vapour pressure of two liquids ‘P’ and ‘Q’ are 80 and 60 torr, respectively. The total
vapour pressure of solution obtained by mixing 3 mole of P and 2 mole of Q would be
(a) 72 torr (b) 140 torr (c) 68 torr (d) 20 torr
5. Assertion : Molarity of a solution in liquid state changes with temperature.
Reason : The volume of a solution changes with change in temperature.
6. Value of Henry's constant KH _______.
(a) increases with increase in temperature.
(b) decreases with increase in temperature.
(c) remains constant.
(d) first increases then decreases.
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CHEMISTRY-087
7. In nitrogen family, the H-M-H bond angle in the hydrides gradually becomes closer to
90º on going from N to Sb. This shows that gradually
(a) The basic strength of the hydrides increases
(b) Almost pure p-orbitals are used for M-H bonding
(c) The bond energies of M-H bonds increase
(d) The bond pairs of electrons become nearer to the central atom
8. A solution of sucrose (molar mass = 342 g mol–1) has been prepared by dissolving 68.5 g
of sucrose in 1000 g of water. The freezing point of the solution obtained will be (Kf for
water = 1.86 K kg mol–1).
(a) – 0.372°C (b) – 0.520°C (d) + 0.372°C (d) – 0.570°C
9. An ether is more volatile than an alcohol having the same molecular formula. This is due
to
(a) dipolar character of ethers
(b) alcohols having resonance structures
(c) inter-molecular hydrogen bonding in ethers
(d) inter-molecular hydrogen bonding in alcohols
10. Which of the following has strongest hydrogen bonding?
(a) Ethyl amine (b) Ethanal (c) Ethyl alcohol (d) Diethyl ether
11. Isopropyl alcohol is obtained by reacting which of the following alkenes with
concentrated H2 SO4 followed by boiling with H2O?
(a) Ethylene (b) Propylene (c) 2-Methylpropene (d) Isoprene
12. Which of the following cannot be made by using Williamson’s synthesis?
(a) Methoxybenzene
(b) Benzyl p-nitrophenyl ether
(c) Methyl tertiary butyl ether
(d) Di-tert-butyl ether
13. Aryl halides can not be prepared by the reaction of aryl alcohols with PCl3 , PCl5 or SOCl2
because
(a) phenols are highly stable compounds.
(b) carbon-oxygen bond in phenols has a partial double bond character
(c) carbon-oxygen bond is highly polar
(d) all of these.
14. Which of the following statements are correct ?
(i) In phenols, the —OH group is attached to sp2 hybridised carbon of an aromatic ring
(ii) The carbon – oxygen bond length (136 pm) in phenol is slightly more than that in
methanol
(iii) Partial double bond character is due to the conjugation of unshared electron pair of
oxygen with the aromatic ring.
(iv) Phenol has sp2 hybridised state of carbon to which oxygen is attached.
(a) (i), (ii) and (v) (b) (i), (ii) and (iii) (c) (i), (iii) and (iv) (d) (i) and (iv)
15. Assertion : tert-butyl bromide undergoes Wurtz reaction to give 2, 2, 3, 3-
tetramethylbutane.
Reason : In Wurtz reaction, alkyl halides react with sodium in dry ether to give
hydrocarbon containing double the number of carbon atoms present in the halide.
CHEMISTRY-087
16. Ethyl alcohol reacts with thionyl chloride in the presence of pyridine to give
(a) CH3CH2Cl + H2O + SO2
(b) CH3CH2Cl + HCl
(c) CH3CH2Cl + HCl + SO2
(d) CH3CH2Cl + SO2 + Cl2
17. CH3CH2OH can be converted into CH3CHO by ........ .
(a) catalytic hydrogenation
(b) treatment with LiAlH4
(c) treatment with pyridinium chlorochromate
(d) treatment with KMnO4
18. The compound HOCH2CH2OH is
(a) ethane glycol (b) ethylene glycol (c) ethylidene alcohol (d) dimethyl alcohol
19. The best method for the conversion of an alcohol into an alkyl chloride is by treating the
alcohol with
(a) PCl5
(b) dry HCl in the presence of anhydrous ZnCl2
(c) SOCl2 in presence of pyridine
(d) none of these
20. Proteins are condensation polymers of
(a) D-amino acids (b) E-amino acids (c) D-hydroxy acids (d) E-hydroxy acids
21. Which of the following is correct about H-bonding in nucleotide?
(a) A --- A and T --- T (b) G --- T and A --- C (c) A --- G and T --- C (d) A --- T and G --- C
22. Primary structure of a protein is
(a) sequence in which D-amino acids are linked to one another
(b) sequence in which amino acids of one polypeptide chain are joined to other chain
(c) the folding patterns of polypeptide chains
(d) the pattern in which the polypeptide chains are arranged
23. Which of the following analogy is incorrect?

(a) Optically inactive amino acid : Glycine : : Optically active protein : Lysine
(b) Essential amino acid : Lysine : : Non essential amino acid : Glycine
(c) Basic amino acid : Aspartate : : Acidic amino acid : Histidine
(d) Glucose : Pyranose : : Fructose : Furanose
24. The α-D glucose and β-D glucose differ from each other due to difference in carbon
atom with respect to its
(a) conformation (b) configuration (c) number of OH groups (d) size of hemiacetal ring
25. Denaturation of proteins leads to loss of its biological activity by

(a) Formation of amino acids
(b) Loss of primary structure
(c) Loss of both primary and secondary structures
(d) Loss of both secondary and tertiary structures
CHEMISTRY-087
SECTION-B
This section consists of 24 multiple choice questions with overall choice to
attempt any 20 questions. In case more than desirable number of questions are
attempted, ONLY first 20 will be considered for evaluation .
26. If the elevation in boiling point of a solution of 10 gm of solute (mol. wt. = 100) in 100
gm of water is ∆Tb , the ebullioscopic constant of water is
(a) 10 (b) 10∆Tb (c) ∆Tb (d) ∆𝑇𝑏/10
27. 1 M, 2.5 litre NaOH solution is mixed with another 0.5 M, 3 litre NaOH solution. Then
find out the molarity of resultant solution
(a) 0.80 M (b) 1.0 M (c) 0.73 M (d) 0.50 M
28. Assertion : One molal aqueous solution of glucose contains 180 g of glucose in 1 kg of
water.
Reason : Solution containing one mole of solute in 1000 g solvent is called one molal
solution
29. Correctly analogy is
(a) Soda water: gas in liquid :: Sugar solution: solid in liquid.
(b) German silver: solid in solid :: Sugar solution: liquid in solid.
(c) Air: gas in gas : : Soda water : liquid in gas
(d) Sugar solution : liquid in solid : : Air : gas in gas
30. Which will form maximum boiling point azeotrope
(a) HNO3 + H2O solution
(b) C2H5OH + H2O solution
(c) C6H6 + C6H5CH3 solution
(d) None of these
31. Low concentration of oxygen in the blood and tissues of people living at high altitude is
due to .............. .
(a) low temperature
(b) low atmospheric pressure
(c) high atmospheric pressure
(d) Both low temperature and high atmospheric pressure
32. For a dilute solution, Raoult's law states that:
(a) the lowering of vapour pressure is equal to the mole fraction of solute
(b) the relative lowering of vapour pressure is equal to the mole fraction of solute
(c) the relative lowering of vapour pressure is proportional to the amount of solute in
solution
(d) the vapour pressure of the solution is equal to the mole fraction of solvent
33. The vapour pressure of an aqueous solution of sucrose at 373 K is found to be 750 mm
Hg. The molality of the solution at the same temperature will be :
(a) 0.26 (b) 0.73 (c) 0.74 (d) 0.039
34. Which of the following analogies is correct?
CHEMISTRY-087
(a) Minimum Boiling mixure : Maximum Boiling mixture : : –ve deviation : +ve deviation
(b) Mass percentage : Volume percentage : : Industrial chemical application : Liquid
solution
(c) PPM : Mole fraction : : Industrial chemical application : concentration of pollutant in
water
(d) ∆Tb : ∆Tf : : KfM : KbM
35. When phenol is treated with excess bromine water, it gives:
(a) m-bromophenol
(b) o- and p-bromophenol
(c) 2, 4-dibromophenol
(d) 2, 4, 6-tribromophenol
36. Assertion : Ethers behave as bases in the presence of mineral acids.

Reason : Due to the presence of lone pairs of electrons on oxygen.
37. An aromatic ether is not cleaved by HI even at 525 K. The compound is
(a) C6 H5 OCH3 (b) C6 H5 OC6 H5 (c) C6 H5 OC3 H7 (d) Tetrahydrofuran
38. The compound which reacts fastest with Lucas reagent at room temperature is
(a) butan-1-ol (b) butan-2-ol (c) 2-methylpropan-1-ol (d) 2-methylpropan-2-ol
39. Phenol is less acidic than ............. .
(a) ethanol (b) o - nitrophenol (c) o-methylphenol (d) o-methoxyphenol
40. Arrange the following compounds in increasing order of boiling point. Propan - 1- ol,
butan - 1 - ol, butan - 2 - ol, pentan - 1 - ol
(a) Propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol
(b) Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
(c) Pentan-1-ol, butan-2-ol, butan-1-ol, propan-1-ol
(d) Pentan-1-ol, butan-1-ol, butan-2-ol, propan-1-ol
41. Assertion : Lower alcohols are soluble in water.
Reason : Lower alcohols do not form hydrogen bonding with water molecules
42. Assertion : Symmetric and unsymmetric ethers can be prepared by Williamson’s
synthesis.
Reason : Williamson’s synthesis is an example of nucleophilic substitution reaction
43. Assertion : Lucas reagent [HCl + ZnCl2 (anhydrous)] on reaction with tertiary alcohols
immediately produces turbidity.
Reason : This is because tertiary alcohols easily form halides which are immiscibe in
water.
44. Assertion: ter-butyl methyl ether is not prepared by the reaction of ter-butyl bromide
with sodium methoxide.
Reason: Sodium methoxide is a strong nucleophile.
45. The function of DNA in an organism is
(a) to assist in the synthesis of RNA molecule
(b) to store information of heredity characteristics (c) to assist in the synthesis of
proteins and polypeptides (d) all of these.
46. Nucleic acids are the polymers of...... (a) nucleosides (b) nucleotides (c) bases (d) sugars
CHEMISTRY-087
47. Dinucleotide is obtained by joining two nucleotides together by phosphodiester linkage.
Between which carbon atoms of pentose sugars of nucleotides are these linkages
present?
(a) 5' and 3' (b) 1' and 5' (c) 5' and 5' (d) 3' and 3'
48. The correct statement regarding RNA and DNA, respectively is
(a) The sugar component in RNA is arabinose and the sugar component in DNA is 2'-
deoxyribose.
(b) The sugar component in RNA is ribose and the sugar component in DNA is 2'-
deoxyribose.
(c) The sugar component in RNA is arabinose
(d) The sugar component in RNA is 2'-deoxyribose and the sugar component in DNA is
arabinose
49. A D-carbohydrate is:
(a) Always dextrorotatory (b) Always laevorotatory (c) Always the mirror of the
corresponding L-carbohydrate (d) None of these.
SECTION-C
This section consists of 6 multiple choice questions with an overall choice to
attempt any 5. In case more than desirable number of questions are
attempted, ONLY first 5 will be considered for evaluation.
50. Colligative properties of the solution depend on
(a) Nature of solute
(b) Nature of solvent
(c) Number of particles present in the solution
(d) Number of moles of solvent only
51. A Pressure cooker reduces cooking time because
(a) the heat is more easily distributed
(b) the higher pressure tenderizes the food
(c) the boiling point of the water inside is elevated
(d) a larger flame is used
52. Which of the following is not true in case of reaction with heated copper at 300°C?
(a) Phenol → Benzyl alcohol
(b) Secondary alcohol → Ketone
(c) Primary alcohol → Aldehyde
(d) Tertiary alcohol → Olefin
53. Acid catalyzed hydration of alkenes except ethene leads to the formation of
(a) primary alcohol
(b) secondary or tertiary alcohol
(c) mixture of primary and secondary alcohols
(d) mixture of secondary and tertiary alcohols
54. The two forms of D–glucopyranose obtained from the solution of D-glucose are better
called (a) isomers (b) anomers (c) epimers (d) enantiomers
55. The incorrect statement among the following is:
(a) α D-glucose and β-D-glucose are anomers.
(b) α-D-glucose and β-D-glucose are enantiomers.
CHEMISTRY-087
(c) Cellulose is a straight chain polysaccharide made up of only α-D-glucose units.
(d) The penta acetate of glucose does not react with hydroxyl amine.

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EXCEL EDUCATIONAL CENTRE,DOHA -QATAR

MOCK EXAMINATION-2,NOVEMBER 2021

23. Which of the following analogy is incorrect?

25. Denaturation of proteins leads to loss of its biological activity by

34. Which of the following analogies is correct?

36. Assertion : Ethers behave as bases in the presence of mineral acids.

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