@ NARAYANA DPP-13 Ether 1. Soph, A+B, So A and B would be (b) Mel and Ph—CH, —OH (a) MeOH and Ph—I (d) Mel and Ph—OH (c) MeOH and Ph—CH, —I 0, ~~ ups 1,0 2. heat OH -d starti terial etic (a) recovered starting material (no reaction) (b) Cr Be Br Br oft Br A @ Cr HOSA Major products of the following reaction are:° ‘MeOH, H* 3. ————> ? Major product of the following reaction is: Optically active OH OMe fo OMe ) b) © (d) None ‘OH ‘OMe ‘OMe 4. What starting material is needed to synthesize the following compounds? 1. KMn0,, cold HO, HO, 0. NaOH ? Nall, DMF D + ‘> Br Br @ G ©) 7~™sr CO @ cS 5. What reagents are needed to accomplish the following transformation? O. 0. oe. 7 x cre — ‘O 0" (a) KMnO,,NaOH,H,0, heat (b) 1. LiAIH,, Et 0 ; 2.2H,0,H2SO, (©) CrO3, HCI, pyridine (d) H,CrO 4, acetone, 35°C 6. What is the product of the following synthesis? 1. HNO,, H,S0, 2. Fe, HCI 3. NaOH : 4. HONO, ice bath “ “ 5. CuCl cl a © LT A. ® Ho On cl cl © Ch @ AT 7. What is the major product of the following reaction ? ° CHa /\ + CHS —Htt > 2 cH, 3CH, ZL 7 - 2 @_ OCH,GH Gi) CHa 7 \ _Uscuy vo, SHS CH SCH, SO SCH, b 7ois t* Gil) CH, (iv) CH;—€_On w) HOCH,CSCH, Ls CH. CHy SCH 7 CH; (a) i (>) ii © iii @ iv ©v ° 8. \_ 9 7 8%, ; Product of this reaction is: HH @ . (b) , CH3CHO ieee aa © An, H @ AY , AY O—CHs Qin 9%. cor —Cane. HL, mole of HI is consumed Hy Conc. HI —Sone HI, y mole of HI is consumed sum of (x+y =2): (@.2 ) 3 © 4 @ 5 O—CH, Cone. HI 10. exces) ? Products ; Products of this reaction are: O—CH, I CH (a) + 2CHgI () + 2CH,OHOH OH © + 2CHgI @ + 2CHgI OH I 11. CH, —CH, —O—CH, —CH, = 2; Major product of the reaction is: (a) 2EtOH (b) 2Ed (c) EtOH, Etl (d) 2H,C =CH) 1 uN oro HL 2; Major produets of this reaction are: 1 CH,OH OH CO" -O™ & OCH,OH 1 OCH,I oo" GO wor. OF CH,O1 OH Oo ) (a) I (b) I © 0: LY ye 13. Cr 140°, product of the reaction is: OH HH @ © © © Both (@) and (b) (4) No reaction 14. The reagent which will be suitable to distinguish 1-methoxy-3-methyl-2-butene from isomeric 4-methyl-3-penten-1-ol is: (a) bromine in chloroform (b) alkaline potassium permanganate (© ammoniacal silver nitrate (@) sodium metal suspended in hexane CHL OH Hi @ Vv Ov15. —*—> Products are: 18. OH OH (a) oO O (b) Ph—OH 18 (c) Ph—OH (d) No reaction 16. Compare the reactivities of ethers given in two pairs, towards hydrolysis : @ Ph—0— Ph Ph—O—CH, (b) oO @ (a) 1-a, 2-c (b) 1-b,2-c (c) 1-b,2-d (ad) 1-a,2-d CH3 17. CH3 —C—O—CH, —2*#1,; This mechanism followed by the reaction is: CH3 (a) Sy (b) Sy2 (c) SN-AR (d) NGP 1s. Sy #20" , product ; Product of the reaction is: ae (a) 2CH3CHO (b) 3HCHO. (c) 3HCO2H (d) 3CH3;0H ‘O- -O- °° 19. CuO ——*—, ; Major product of the reaction is: SI 7 HEE ctet ® Ho~Ho OH © J2% @ eee et° 20. cr — 180", ; Products obtained in this reaction are: OH (a) EtOH, O ) CH; —CHO (©) CH,CO2H, (d) EtOH, 21. Which of the following is most reactive towards hydrolysis ? M@AgXnK oO —~ol © ox @ )-oX 22. CH; —O—CH a ; Product of the reaction is: ¥ (a) No reaction (b) 2CH,0H (©) 2CH, (d) Et-H 7 B40) 23. CL —** =: ; product of the reaction is: ‘0 ‘OEt Sk , EtOH @ Ho ‘OH ®) Ho S oO Sk + EtOH @oF S fe} 8 Cone. HI iam ie 24, Ph—O—CH, "41, ; products of the reaction is: 18 18 (a) Ph—OH, CHy —I (b) Ph—I, CH; OH (© Ph—I, CH, — (@) Ph—OH, CHI CH | 25. ()} Peete , This ether is best prepared by: CH; @ yo +-Br ) Op +>-0° © C02 +-0H @ (0° +>-0°26. cx40-{O)-0{O)-0-{O)-0at How many moles of HI consumed in above reaction ? @1 (b) 2 © 3 27. Compare rate of reaction with OH™ : w \o/ w 6 (a) i>ii>iii (b) i>iii>ii (©) iii>ii>i 28, PhMgBr +Et —O —Et—- ; Product is: (diethyl ether) (a)Ph —OEt (b) Ph—OH (©) Ph—Et Answers Ethers (@) ii>i>iii (d) no reaction 1 Jolz{@]s]@]a]o]s Jal se Jol x Jo 2a. | (by | 22. | (ar | 23. | (by | 24. | @| 25. | ey} 26. || 27. | (a 28. 10. | (0) 20. | (b)