Sec: XII IC C/F CPT - 3 DATE: 31-05-2021

Time: 03:00 Hrs Max Marks: 300

IMPORTANT INSTRUCTIONS:-

JEE MAIN_MODEL-2021

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs Marks
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 30) 4 0 10 20
(+/ - Decimal Numbers)
Total 30 100

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 31 – 50) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 51 – 60) 4 0 10 20
(+/ - Decimal Numbers)
Total 30 100

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 61 – 80) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 81 – 90) 4 0 10 20
(+/ - Decimal Numbers)
Total 30 100
 PHYSICS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. For charges q1 and q 2 , if force between them for some separation in air is F, then force between them
in a medium of permittivity  will be
  F
(A) 0 F (B) F (C) 0 F (D)
 0 0
2. If r1 and r2 are the position vectors of two positive charges q1 and q 2 with respect to some origin, then
force on q 2 and q1 is directed in the direction given by unit vector
r r r r
(A) rˆ21  2 1 (B) rˆ21  1 2 (C) rˆ21  r2  r1 (D) rˆ21  r1  r2
r2  r1 r2  r1
3. Two small spheres each having the charge +Q are suspended by insulating threads of length L from a
hook. This arrangement is taken in space where there is no gravitational effect, then the angle
between the two suspensions and the tension in each will be
1 Q2 1 Q2 1 Q2 1 Q2
(A) 180, (B) 90 , (C) 180 , (D) 180 ,
40 (2L) 2 40 L2 40 2L2 40 L2
4. Force between two charges varies with distance between them as

(A) (B)

(C) (D)

5. Superposition principle is required

(A) to calculate force on a charge by another charge
(B) to find net charge present at any point
(C) to apply Coulomb’s law between two charges in any medium
(D) to calculate force on a point charge due to a number of charges
6. Three charges q1 , q 2 and q 3 each of 1 C are at the vertices of an equilateral triangle of side l. Force on
a charge Q = 2C placed at the centroid of the triangle is
(A) 3N (B) 3N (C) zero (D) 3 × 10-2N
7. A body can be negatively charged by
(A) Giving excess of electrons to it (B) Removing some electrons from it
(C) Giving some protons to it (D) Removing some neutrons from it
8. A charge q is placed at the centre of the line joining two equal charges Q. The system of the three
charges will be in equilibrium, if q is equal to
Q Q Q Q
(A)  (B)  (C)  (D) 
2 4 4 2
9. Under the influence of the coulomb field of charge +Q, a charge – q is moving around it in an
elliptical orbit. Find out the correct statement (s).
(A) The angular momentum of the charge – q is constant
(B) The linear momentum of the charge –q is constant
(C) The angular velocity of the charge –q is constant
(D) The linear speed of the charge –q is constant
10. The SI unit of electric field is
(A) NC1 (B) NC (C) CN 1 (D) NC2
11. Electric field at a point is defined as the force per unit positive charge placed at that point. However,
if a test charge q is brought at any point Q, force is due to both charges. This difficulty is overcome
by defining field as
F F F
(A) Ε  (B) Ε  (C) Ε  Fq (D) Ε  lim
Qq q q 0 q

12. Two point chares +8q and -2q are located at x = 0 and x = L, respectively. The location of a point on
the X-axis at which the net electric field due to these two point charges is zero, is
(A) 8L (B) 4L (C) 2L (D) L/4
13. Electric field of a system of charges does not depends on
(A) position of charges forming the system
(B) distance of point (at which field is being observed) from the charges forming system
(C) value of test charge used to find out the field
(D) separation of charges forming the system
14. For a linear charge distribution, linear charge density  of the line of charge is
(Q)2  Q 
2
Q
(A)   Q  (l )
2
(B)   (C)   (D)    
(l ) l  l 
2

15. For a long wire of charge density , field at a distance r from the wire is
  kq
(A) . nˆ (B) nˆ (C) 0 (D) 2
2 0 r 40 r 
16. For an infinite plate of charge density , field at a distance r (r is not large compared to any side of
plate) is
 2 
(A) (B) (C) (D) 0
0 0 2 0
17. A circular ring carries a uniformly distributed positive charge and lies in the xy plane with center at
the origin of the coordinate system. If a point (0, 0, z), the electric field is E, then which of the
following graphs is correct?

(A) (B)

(C) (D)

18. Two infinite plane parallel sheets separated by a distance d have equal and opposite uniform charge
densities . Electric field at a point between the sheets is

(A) zero (B)
0

(C) (D) depends upon the location of the point
2 0
19. An object A has a charge of – 2C and the object B has a charge of +C. Which statement is true?
(A) FAB  3FBA (B) FAB  FBA (C) 3FAB  FBA (D) FAB  4FBA
20. A wooden block performs SHM on a frictionless surface with frequency  0 . The block carries a
charge +Q on its surface. If now a uniform electric field E is switched on a shown, then the SHM of
the block will be

(A) of the same frequency and with shifted mean position

(B) of the same frequency and with the same mean position
(C) of changed frequency and with shifted mean position
(D) of changed frequency and with the same mean position

SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, 0 in all other cases.
21. Two particles of masses m and 2m, having same charges q each, are placed in a uniform electric field
E and allowed to move for the same time. Find the ratio of their kinetic energies.
22. A ring of radius R has charges –Q distributed uniformly over it. The charge (q) that should be placed
at the center of the ring such that the electric field becomes zero at a point on the axis of the ring
distance R from the center of the ring. The value of q is (Q / 4) n . Find n.
23. Point charges of +6C and -4C are placed x – axis at x = 8 m and x = 16 m respectively. What
magnitude of charge (in C) must be placed at x = -8 m, so that any charge kept at origin experiences
no electrostatic force?
24. Excess electrons are placed on a small lead sphere of mass 6.90 g so that its net charge is -3.20 ×10-9
C. Find the number of excess electrons (in terms of × 10 10) on the sphere.
25. In the figure shown, find the ratio of the linear charge densities 1 (on semi-infinite straight wire) and
 2 (on semi – circular part) that is 1 /  2 so that the field at O is along y direction.

26. Charges are placed at corners of a square of side a as shown in the following figure. The charge A is
in equilibrium. The ratio q1 / q 2 is n . Find the value of n
27. Two charges q1 and q 2 are placed in vacuum at a distance d and the force acting between them is F.
2F
If a medium of dielectric constant 4 is introduced between them, the force now will be . Find the
n
value of n
28. Two charges of equal magnitudes and at a distance r exert a force F on each other. If the charges are
F
halved and distance between them is doubled, then the new force acting on each charge is . Find
2n
the value of n
29. Two point charges repel each other with a force of 100 N. One of the charges is increased by 10%
198
and the other is reduced 10%. The new force of repulsion at the same distance is N . Find the
n
value of n
30. Three infinitely long charge sheets are placed as shown in figure. The electric field at point P
 n  ˆ
is   (k) . Find the value of n

 0
2
CHEMISTRY Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. In an SN 1 reaction on chiral centres there is
(A) 100% racemization
(B) inversion more than retention leading to partial racemization
(C) 100% retention
(D) 100% inversion
32. In a SN 2 substitution reaction of the type
R  Br  Cl 
DMF
 R  Cl  Br 
Which one of the following has the highest relative rate?
(A) CH3  CH2  CH2 Br (B) CH3  CH  CH 2 Br
|
CH3
CH3
|
(C) CH 3  CH  CH 2 Br (D) CH3CH2 Br
|
CH3
33. CH3  CH 2  CH  CH3 obtained by chlorination of n-butane, will be
|
Cl
(A) l-form (B) d-form (C) Meso form (D) Racemic mixture
34. Which one is most reactive towards SN 1 reaction?
(A) C6 H5CH(C6 H5 )Br (B) C6 H5CH(CH3 )Br
(C) C6 H5C(CH3 )(C6 H5 )Br (D) C6 H5CH 2 Br
35. Fluorobenzene (C6 H5 F) can be synthesized in the laboratory
(A) by direct fluorination of benzene with F2 gas
(B) by reacting bromobenzene with NaF solution
(C) by heating phenol with HF and KF
(D) from aniline by diazotization followed by heating the diazonium salt with HBF4.
36. In SN 2 reactions, the correct order of reactivity for the following compounds
CH3Cl,CH3CH2Cl,(CH3 )2 CHCl and (CH3 )3 CCl is
(A) CH3Cl  (CH3 )2 CHCl  CH3CH 2Cl  (CH3 )3 CCl
(B) CH3Cl  CH3CH 2Cl  (CH3 ) 2 CHCl  (CH3 )3 CCl
(C) CH3CH2Cl  CH3Cl  (CH3 ) 2 CHCl  (CH3 )3 CCl
(D) (CH3 ) 2 CHCl  CH3CH2Cl  CH3Cl  (CH3 )3 CCl
37. What products are formed when the following compounds reacts with Br2 in the presence of FeBr3 ?

(A) (B)
 (C) (D)

38. Which chloro derivative of benzene among the following would undergo hydrolysis most readily with
aqueous sodium hydroxide to furnish the corresponding hydroxyl derivative?

(A) (B)

(C) (D) C6 H5Cl

39. The order of decreasing stability of the cations is
  
(I) CH3 CHCH3 (I) CH2 CHOCH3 (III) CH3 CHCOCH3
(A) III > II > I (B) I > II > III (C) II > I > III (D) I > III > II
40. Consider the following bromides

The correct order of SN 1 reactivity is

(A) B > C > A (B) B > A > C (C) C > B > A (D) A > B > C
41. Chlorobenzene can be prepared by reacting aniline with
(A) hydrochloric acid
(B) cuprous chloride
(C) chlorine in presence of anhydrous aluminium chloride
(D) nitrous acid followed by heating with cuprous chloride
42. Rate of the reaction
R  CH 2  Z  Nu    R  CH 2  Nu  Z
Is fastest when Z is
(A) Cl (B) OCOCH3 (C) OC2 H5 (D) NH 2
43. The relative reactivity of the following halides towards SN 2 reaction follows the order

(A) Q > S > R > P (B) P > S > R > Q (C) S > R > Q > P (D) P > R > S > Q
44. Rate of SN 1 reaction is

(A) S > Q > R > P (B) S > R > P > Q (C) P > Q > R > S (D) S > R > Q > P
45. The major product of the following reaction is
 (A) (B) (C) (D)

46. Which of the following leads to the formation of an alkyl halide?

Red P  Br2
(A) C2 H 5OH   (B) C2 H5OH  SOCl2

KBr  Conc. H 2SO4
(C) C2 H5OH   (D) All of these
47. Identify the compounds which may not NGP reaction

(A) (B)

(C) (D)

48. Which of the following reactions does not free radical as intermediate?

(A) (B)

(C) (D)

49. The order of decreasing nucleophilicities of the following species is

O- O- O- O- O- O-
(A) CH3 S  CH3 O  CH3CO O  CH3OH (B) CH3CO O  CH3 S  CH3 O  CH3OH
O- O- O- O- O- O-
(C) CH3OH  CH3 S  CH3CO O  CH3 O (D) CH3 O  CH3OH  CH3CO O  CH3 S
50. The reaction proceed by the mechanism

(A) SN 1 (B) SN 2 (C) SE 2 (D) SNi

SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, 0 in all other cases.

51. How many chiral compounds are possible on monochlorination of 2-methly butane?
52. In the following monobromination reaction, the number of possible chiral products is

53. How many structures for F are possible?

54. Identify number of substrate those can give SN1andSN 2 reaction both.

55. How many substrates will show rearrangement during SN 1 reaction?

O-
56. When the concentration of alkyl halide is triple and concentration of O H is reduced to half, the rate
of SN 2 reaction increased by …… times.
57. 2-Chlorobutane 
15%aq. solution of ethyl alcohol
P
In this reaction 70% racemisation takes place. % of inverted product would be
CH3
|
58. CH 3  CH  CH 2  Cl  NaOH(aq)
 Intermediate (I)

2- Methylbutan - 2- ol  Intermediate(II)
No. of -(H) of carbocation in intermediate (II) is
59. How many possible alkyl bromide product is formed (including stereoisomes)
CH3  CH  CHD  HBr 
60. How many of the following proceed predominately through SN 1 .
O
||
(CH 3 )3 C  Cl, CH 3  Br, CH 3  C  CH 2  Br, CH 3  O  CH 2  Br
CH 2  CH  Br,
 MATHEMATICS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. A constant function f : A  B will be one – one if
(A) n(A) = n(B) (B) n(A) = 1 (C) n(B) = 1 (D) n(A) < n(B)
62. If f(x) + f(x + a) + f(x + 2a) + …… +f(x + na) = constant; x  R and a > 0 and f(x) is periodic, then
period of f(x) is
(A) (n + 1)a (B) e(n 1)a (C) na (D) e na
x 2  2x  5
63. Let f : R  R be a function defined by f (x)  2 is
x  x 1
(A) one – one and into (B) one – one and onto
(C) may – one and onto (D) many-one and into
e  e x
|x|
64. f : R  R is a function defined by f (x)  x  x then f is
e e
(A) a bijection (B) an injection only
(C) surjection only (D) neither injection nor surjection
    x a 
2
65. If F : R   ,  defined by f (x)  sin 1  2  is an onto functions, then the set of values of ‘a’ is
6 2   x 1 

(A) (, 1) (B) 1 (C) (D) Does not exist
2
66. The period of the real – valued function satisfying f (x)  f (x  4)  f (x  2)  f (x  6) is
(A) 10 (B) 8 (C) 12 (D) 6
67. If f (x) = cos x + {x} where {.} is fractional part function then the period of f(x) is

(A) 2 (B) 1 (C) (D) Does not exist
2
68. Let f(x) be a real valued function with domain R such that
1/3
f (x  p)  1  2  3f (x)  3(f (x)) 2  (f (x))3  holds good x  R and for same +ve constant ‘p’ then
the period of f(x) is
p p
(A) (B) p (C) 2p (D)
2 3
69. The range of tan(log x) is
(A) (0, ) (B) (1,  ) (C) (e, ) (D) (, )
 x7 4
70. If f (x)     , then the range of the function y = sin (2f (x)) is
 x 9 
 1 
(A) [0, 1] (B)  0,
 2 
 1   1 
(C)  0,  ,1 (D)  0,1
 2   2 
71. If f (x)  sgn(x 2  2x  3) then the value of f(x) is
(A) 1 (B) 2 (C) 4 (D) 3
 1 x   1 
72. If h(x)  Ax 5  Bsin x  C log    7 , where A, B, C are non-zero constants and h    6 then
 1 x   2 
 sgn(e ) 
x
the value of h  .
 2 
 (A) 4 (B) 8 (C) 6 (D) 2
 x2 
73. The smallest natural number k for which f (x)  n(x 3  x 6  1)  sin 5x    is an odd function
k
x  [2, 2] is ([y] denotes largest integer  y)
(A) 38 (B) 39 (C) 40 (D) 41
1
74. The value of cos(2cos1 x  sin 1 x) at x  is
5
2 6 2 6 3 6
(A) (B)  (C)  (D) None of these
5 5 5
x 1 x 1 
75. If tan 1  tan 1  , then x =
x2 x2 4
1 1 1
(A) (B)  (C) (D)  2
2 2 2
76. cos 1[cos[2 cot 1 ( 2  1)]] is equal to
 3
(A) 2  1 (B) 1  2 (C) (D)
4 4
y 3
77. The positive integral solution of tan 1 x  cos 1  sin 1 is
1 y 2
10
(A) x = 1, y = 2; x = 2, y = 7 (B) x = 1, y = 3; x = 2, y = 4
(C) x = 0, y = 0; x = 3, y = 4 (D) None of these
3 1 3 1
78. If   sin 1  sin 1 and   cos 1  cos 1 , then
2 3 2 3
(A)  >  (B)  =  (C)  <  (D)  +  = 2
79. If [tan 1 x]2  2[tan 1 x]  1  0 , where [.] denotes greatest integer  x, x belongs to
 
(A) [tan1, tan 2) (B)  ,  (C) (tan 1, ] (D) None of these
4 2
80. sin{cot 1[cos(tan 1 x)]}, x  0
1 x2 1 x2 1 x2 2  x2
(A) (B) (C) (D)
2  x2 2  x2 2  x2 1 x2

SECTI)ON-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, 0 in all other cases.
81. If f(x) is a function that is odd and even simultaneously, then f(3) – f(2) is equal to
82. Period of f (x)  e x [x] where [x] is greatest integer less than or equal to x is
83. If [x]2  7[x]  10  0and 4[y]2 16[y]  7  0 , then [x + y] maximum is ([.] denotes greatest integer
function)
84. If f(x) and g(x) are periodic functions with period 9 and 5 then period of t(x) = f(x/2) g(x) + g(x/2)
f(x) is
85. Period of f(x) = sin 3 {x} + tan  [x], where [.] and {.} denote the greatest integer function and
fractional part respectively, is
x 
86. If tan 1  , x  N , then the maximum value of x is
 3
 1   x 1 x2  
87. Given 0  x  , then the value of tan sin 1     sin 1 x  is
2   2 2  

 x 2 x3   x4 x6 
88. If sin 1  x    .....   cos 1  x    ... 
 2 4   2 4 

 for 0 < |x| < 2 , then x equals
2
 1  1  1  1  1 
89. If 3tan 1    tan  x   tan  2  , then x is equal to
 2 3     
x 5 
90. If sin 1    cosec 1    , then a value of x is
5 4 2