Sec: XII C/F IIT Date : 02-05-2022

Time : 3 Hrs. CTM – 01 Max. Marks : 300

JEE MAIN Model
PHYSICS :
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 1 – 20)
Sec – II Questions with Numerical
4 –1 10 20
(Q.N : 21 – 30) Answer Type
Total 30 100

CHEMISTRY :
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 31 – 50)
Sec – II Questions with Numerical
4 –1 10 20
(Q.N : 51 – 60) Answer Type
Total 30 100

MATHEMATICS :
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs marks
Sec – I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 61 – 80)
Sec – II Questions with Numerical
4 –1 10 20
(Q.N : 81 – 90) Answer Type
Total 30 100
Narayana IIT/NEET Academy XII C/F IIT EX. DT. : 02-05-2022
PHYSICS Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A) , (B) , (C) and (D)
for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
1. The position x of a particle varies with time (t ) as x  at 2  bt 3 . The acceleration at time 𝑡 of
the particle will be equal to zero, where 𝑡 is equal to
2a a a
(A) (B) (C) (D) Zero
3b b 3b
2. The given graph shows the variation of velocity with displacement. Which one of the graph
given below correctly represents the variation of acceleration with displacement?

(A) (B)

(C) (D)

3. A particle is projected at an angle of elevation 𝛼 and after 𝑡 second, it appears to have an

angle of elevation 𝛽 as seen from point of projection. The initial velocity will be
gt gt cos 
(A) (B)
2sin     2sin    
sin     2sin    
(C) (D)
2gt gt cos 
4. The given plot shows the variation of 𝑈, the potential energy of intersection between two
particles, with the distance separating team, 𝑟

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(1) 𝐵 and 𝐷 are equilibrium points

(2) 𝐶 is a point of stable equilibrium
(3) The force of interaction between the two particles is attractive between points 𝐶 and 𝐵,
and repulsive between points 𝐷 and 𝐸 on the curve
(4) The force of intersection between the particles is repulsive between points 𝐶 and 𝐴
Which of the above statement are correct?
(A) 1 and 3 (B) 1 and 4 (C) 2 and 4 (D) 2 and 3
5. Two particles 𝑃 and 𝒬 are projected simultaneously away from each other from a point 𝐴 as
shown in figure. The velocity of 𝑃 relative to 𝒬 in ms at the instant when the motion of 𝑃 is
horizontal is

(A) 10 4  3 (B) 20 4  3 (C) 10 4  3 (D) 20 4  3

6. In Fig, the angle of inclination of the inclined plane is 30°. Find the horizontal velocity 𝑉 so
that the particle hits the inclined plane perpendicularly

2gH 2gH gH gH
(A) V0  (B) V0  (C) V0  (D) V0 
5 7 5 7
7. A block of mass 𝑚 is placed on another block of mass𝑀, which itself is lying on a horizontal
surface. The coefficient of friction between two blocks is 𝜇 and that between the block of
mass 𝑀 and horizontal surface is𝜇 . What maximum horizontal force can be applied to the
lower block so that the two blocks move without separation?

(A)  M  m  2  1  g (B)  M  m  2  1  g
(C)  M  m  2  1  g (D)  M  m  2  1  g
8. Two trolleys 1 and 2 are moving with accelerations 𝑎 and𝑎 , respectively, in the same
direction. A block of mass 𝑚 on trolley 1 is in equilibrium from the frame of observer
stationary with respect to trolley 2. The magnitude of friction force on block due to trolley is
(assume that no horizontal force other than friction force is acting on block)

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(A) m  a1  a2  (B) ma2 (C) ma1 (D) Data insufficient

9. The system shown in the figure is released from rest. The spring gets elongated

(Neglect friction and masses of pulley, string, and spring)

(A) If M  m (B) If M  2m (C) If M  m / 2 (D) For any value of 𝑀
10. Block 𝐵 has mass 𝑚 and is released from rest when it is on top of wedge𝐴, which has a
mass3𝑚. Determine the tension in cord 𝐶𝐷 needed to hold the wedge from moving while 𝐵 is
sliding down𝐴. Neglect friction

mg mg
(A) 2 mg cos  (B) cos  (C) sin  (D) mg sin 2
2 2
11. If block 𝐵 moves towards right with acceleration 𝑏, find the net acceleration of block 𝐴

(A) bi  4b j (B) bi  b j (C) bi  2b j (D) None of these

12. A mass less platform is kept on alight elastic spring as shown in figure. When a particle of
mass 0.1 kg is dropped on the pan from a height of 0.24 m, the particle strikes the pan, and
the spring is compressed by 0.01 m. From what height should the particle be dropped to
cause a compression of 0.04 m?

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(A) 0.96 m (B) 2.96 m (C) 3.96 m (D) 0.48 m

13. Two small particles of equal masses start moving in opposite directions from a point 𝐴 in a
horizontal circular orbit. Their tangential velocities are 𝑣and 2𝑣, respectively, as shown in
the figure. Between collisions, the particles move with constant speeds. After making how
many elastic collisions, other than that at 𝐴, these two particles will again reach the point 𝐴

(A) 4 (B) 3 (C) 2 (D) 1

14. A block of mass 𝑚 is being pulled up a rough incline by an agent delivering constant power𝑃.
The coefficient of friction between the block and the incline is𝜇. The maximum speed of the
block during the course of ascent is

P P
(A) v  (B) v 
mg sin    mg cos  mg sin    mg cos 
2P 3P
(C) v  (D) v 
mg sin    mg cos  mg sin    mg cos 
15. A particle free to move along the 𝑥-axis has potential energy given by
U  x   k 1  exp   x 2   for   x   , where 𝑘 is a positive constant of appropriate
dimensions. Then
(A) At point away from the origin, the particle is in unstable equilibrium
(B) For any finite non-zero value of 𝑥, there is a force directed away from the origin
(C) If its total mechanical energy is 𝑘/2, it has its minimum kinetic energy at the origin
(D) For small displacements from 𝑥 = 0, the motion is simple harmonic
16. Three objects 𝐴, 𝐵 and 𝐶 are kept in a straight line on a frictionless horizontal surface. These
have masses 𝑚, 2𝑚 and 𝑚 respectively. The object 𝐴 moves towards 𝐵 with a speed 9 𝑚/𝑠
and makes an elastic collision with it. Thereafter, 𝐵 makes completely inelastic collision with
𝐶. All motions occur on the same straight line. Find the final speed (in 𝑚/𝑠) of the object 𝐶

(A) 3m / s (B) 4m / s (C) 5m / s (D) 1m / s

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17. A particle of mass 𝑚 is moving in a circular path of constant radius 𝑟 such that its centripetal
acceleration 𝑎 is varying with time 𝑡 as 𝑎 = 𝑘 𝑟𝑡 , where 𝑘 is a constant. The power
delivered to the particle by the forces acting on it is
(A) Zero (B) mk 2 r 2t 2 (C) mk 2 r 2t (D) mk 2 rt
18. A particle of mass 𝑚 moving towards the east with speed 𝑣 collides with another particle of
the same mass and same speed 𝑣 moving towards the north. If the two particles stick to each
other, the new particle of mass 2𝑚 will have a speed of
v
(A) v (B) v / 2 (C) (D) v 2
2
19. A ball of mass moving with constant velocity 𝑢 collides with a smooth horizontal surface at 𝑂
as shown in Figure. Neglect gravity and friction. The 𝑦-axis is drawn normal to the horizontal
surface at the point of impact 𝑂 and 𝑥-axis is horizontal as shown. About which point will the
angular momentum of ball be conserved?

(A) Point 𝐴 (B) Point 𝐵 (C) Point 𝐶 (D) None of these

20. A ball of mass 0.2 𝑘𝑔 rests on a vertical post of height 5 𝑚. A bullet of mass 0.01 𝑘𝑔, travelling
with a velocity 𝑉 𝑚/𝑠 in a horizontal direction, hits the centre of the ball. After the collision,
the ball and bullet travel independently. The ball hits the ground at a distance of 20 𝑚 and
the bullet at a distance of 100 𝑚from the foot of the post. The initial velocity 𝑉 of the bullet is

(A) 250 𝑚/𝑠 (B) 250√2 𝑚/𝑠 (C) 400 𝑚/𝑠 (D) 500 𝑚/𝑠
SECTION – II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical values.
[Answer any Five (5) Integer Questions]
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A body is thrown up with a velocity 100 ms . It travels 5 m in the last second of its journey.
If the same body is thrown up with a velocity 200 ms , how much distance (in metre will it
travel in the last second (g = 10 ms )?
22. A cat, on seeing a rat at a distance 𝑑 = 5 m, starts with velocity 𝑢 = 5 ms and moves with
acceleration 𝛼 = 2.5 ms in order to catch it, while the rate with acceleration 𝛽 starts from
rest. For what value of 𝛽 will the cat overtake the rat? (in ms )
23. A particle is moving in a circular path of radius 1 m. Under the action of a centripetal force,
the speed (√2)𝜋 m/s of the particle is constant. Find the average velocity (in m/s) between 𝐴
and 𝐵

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24. A block is placed on an inclined plane moving towards right horizontally with an
acceleration𝑎 = 𝑔. The length of the plane 𝐴𝐶 = 1 m. Friction is absent everywhere. Find
the time taken (in second) by the block to reach from 𝐶 to 𝐴

25. Figure represents a painter in a crate which hangs alongside a building. When the painter of
mass 100 kg pulls the rope, the force exerted by him on the floor of the crate is 450 N, If the
crate weights 25 kg, find the acceleration (in ms ) of the painter

26. A car travelling on a smooth road passes through a curved portion of the road in the form of
an arc of circle of radius 10 m. If the mass of car is 120 kg, find the reaction (in kN) on car at
lowest point 𝑃 where its speed is 20 ms

27. A block of mass 0.18 𝑘𝑔 is attached to a spring of force-constant 2 𝑁/𝑚. The coefficient of
friction between the block and the floor is 0.1. Initially the block is at rest and the spring is
un-stretched. An impulse is given to the block as shown in the figure. The block slides a
distance of 0.06 𝑚 and comes to rest for the first time. The initial velocity of the block in 𝑚/
𝑠is 𝑉 = 𝑁/10. Then 𝑁 is

28. In the situation shown in figure all contact surfaces are smooth. The force constant of the
spring is𝐾. Two forces 𝐹 are applied as shown. the maximum elongation produced in the
spring is how many times of 𝐹/𝐾 (initially the spring is relaxed)?

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29. A child of mass 4 kg jumps from cart 𝐵 to cart 𝐴 and then immediately back to cart 𝐵. The
mass of each cart is 20 kg and they are initially at rest. In both the cases the child jumps at 6
m/s relative to the cart. If the cart moves along the same line with negligible friction with the
final velocities of 𝑉 and𝑉 , respectively, find the ratio of 6𝑣 and 5𝑣

30. Three balls 𝐴, 𝐵 and 𝐶(𝑚 = 𝑚 = 4𝑚 ) are placed on a smooth horizontal surface. Ball 𝐵
collides with ball 𝐶 with an initial velocity 𝑣 as shown in Fig. Find the total number of
collisions between the balls (all collisions are elastic)

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Narayana IIT/NEET Academy XII C/F IIT EX. DT. : 02-05-2022

CHEMISTRY Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A) , (B) , (C) and (D)
for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.

31. The compound having molecular formula C4 H10O can show:

(A) Metamerism (B) Functional isomerism
(C) Positional isomerism (D) All of these
32. Geometrical isomerism is not shown by:
(A) (B)

(C) (D)
33. The stability of 2, 3-dimethyl but-2-ene is more than 2-butene. This can be explained in terms of
(A) Resonance (B) Hyperconjugation
(C) Electrometric effect (D) Inductive effect
34. In the dehydration reaction, CH 3CONH 2  P2O5
 CH 3C  N , the hybridization state of carbon
changes from:
(A) sp 3 to sp 2 (B) sp to sp
2
(C) sp to sp (D) sp to sp 3
35. The most stable carbocation is
(A) (B)

(C) (D)

36. In the following carbocations, the stability order is

(A) III > II > IV > I (B) IV > I > II > III

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(C) IV > III > II > I (D) III > IV > II > I
37. What is the correct order of decreasing stability of the following cations?

(A) II > I > III (B) II > III > I

(C) III > I > II (D) I > II > III
38. Select the most reactive cycloalkane:
(A) Cyclopropane (B) Cyclobutane
(C) Cyclopentane (D) Cyclohexane
39. The pair of structures given below represents:

(A) Enantiomers (B) Position isomers

(C) Conformers (D) None of these
40. Intermediate product formed in the acid catalysed dehydration of n  propyl alcohol is:
(A) CH 3  CH 2  CH 3 (B) CH 3  CH  CH 2
 
(C) CH 3  C H  CH 3 (D) CH 3  CH 3  C H 2
41. CH 3  CHCl  CH 2  CH 3 has a chiral centre. Which one of the following represent is R-
configuration?
(A) (B)

(C) (D)

42. Base strength of,

 
(1) H 3C C H 2 (2) H 2C  C H and

(3) H  C  C is in the order of:
(A) (3) > (2) > (1) (B) (1) > (3) > (2)
(C) (1) > (2) > (3) (D) (2) > (1) > (3)
43. In the hydrocarbon,
C H3  C H  C H  C H 2  C  C H
6 5 4 3 2 1

The state of hybridization of carbons 1, 3 and 5 are in the following sequence:

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(A) sp, sp 3 , sp 2 (B) sp, sp 2 , sp 3
(C) sp 3 , sp 2 , sp (D) sp 2 , sp, sp 3
44. Consider the following compounds:

Hyperconjugation occurs in:

(A) II only (B) III only
(C) I and III (D) I only
45. The most stable carbocation, among the following is:
 
(A) CH 3  CH 2  C H 2 (B)  CH 3 3 C  C H  CH 3
 
(C) CH 3  CH 2  C H  CH 2  CH 3 (D) CH 3  C H  CH 2  CH 2  CH 3
46. Which of the following will have meso isomers also?
(A) 2-hydroxy propanoic acid (B) 2, 3 – dichlorobutane
(C) 2, 3 – dichloropentane (D) 2 – chlorobutane
47. The optically active alkane with lowest molar mass is:
(A) (B)

(C)
(D)

48. The correct stability order of the following resonance structures is

(A) I > II > IV > III (B) I > III > II > IV
(C) II > I > III > IV (D) III > I > IV > II
49. Write the correct order of basicity:

(A) A > B > D > E > C (B) A > B > E > D > C
(C) B > A > D > C > E (D) C > E > D > B > A
50. The enolic form of acetone contains
(A) 9 sigma bonds, 1 pi bond and 2 lone pairs

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(B) 8 sigma bonds, 2 pi bonds and 2 lone pairs
(C) 10 sigma bonds, 1 pi bond and 1 lone pair
(D) 9 sigma bonds, 2 pi bonds and 1 lone pair

SECTION – II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is Numerical values.
[Answer any Five (5) Integer Questions]
Marking scheme: +4 for correct answer, -1 in all other cases.

51. The number of isomers for the aromatic compound of the formula C7 H 8O is
52. How many isomers are possible for the compound having molecular formula C3 H 5 Br3 ?
53. On monochlorination of n  pentane, the number of isomers formed is (including stereo isomers)
54. The structural formulae for the isomeric alcohols having the molecular formula C 4H10O is/are:
55. The molecular formula of diphenyl methane is C13 H12 .

How many structural isomers are possible when one of the hydrogen is replced by a chlorine
atom?
56. How many optically active stereoisomers are possible for butane-2, 3-diol?
57. The number of isomers for the compound with molecular formula C2 BrClFI is
58. The number of stereoisomers possible for a compound of the molecular formula
CH 3  CH  CH  CH (OH )  Me is
59. The total number of contributing structures showing hyperconjugation (involving C – H bonds) for
the following carbocation is

60. The total number of cyclic isomers possible for a hydrocarbon with the molecular C 4H6 is

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MATHEMATICS Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B) , (C) and (D) for
its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
61. The value of the expression -
sin 2 y 1 cos y sin y
1– + – is equal to -
1  cos y sin y 1  cos y
(A) 0 (B) 1 (C) sin y (D) cos y
   3 
62. The value of 1  cos  1  cos 
 8  8 
 5   7 
1  cos  1  cos  is -
 8   8 
1  1 1 2
(A) (B) cos (C) (D)
2 8 8 2 2
63. The value of sin 20° sin 40° sin 60° sin 80° is -
3 1 3
(A) (B) (C) (D) None of these
8 8 16
 P Q
64. In a triangle PQR, R = . If tan   and tan   are the roots of the equation
2 2
  2
ax2 + bx + c = 0 (a  0), then-
(A) a + b = c (B) b + c = a (C) a + c = b (D) b = c
 
65. For a positive integer n, let fn() =  tan  (1+ sec) (1+ sec 2)(1+ sec 4)....(1+ sec 2n  ). Then-
 2

    
(A) f2  = 2 (B) f3  = 1 (C) f4  = 0 (D) None of these
 16   32   64 
66. If cos 3x = –1, where 0º  x  360º, then x =
(A) 60º, 180º, 300º (B) 180º
(C) 60º, 180º (D) 180º, 300º
67. If sin 3 = sin, then the general value of  is
 
(A) 2n, (2n + 1) , n  I (B) n, (2n + 1) , n I
3 4

(C) n, (2n + 1) , nI (D) None of these
3
68. The smallest positive root of the equation tan x – x = 0 lies on-
      3   3 
(A)  0,  (B)  ,   (C)  ,  (D)  , 2 
 2 2   2   2 

69. General value of  satisfying equation tan2 + sec 2 = 1 is- ( n  I )

 
(A) n (B) n + (C) n – (D) all of these
3 3

70. The set of all real numbers x for which x 2  x  2  x  0, is

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(A)  , 2    2,   
(B) ,  2    2,  
(C)  , 1  1,   (D)  2,  
Solve the inequality  x  3 3 x  2   7  x   5 x  8   0
5 3 2
71.

2   8
(A)  , 3   , 7      (B)  , 3   7,  
 3   5
2 
(C)  , 3   , 7  (D) None of these
3 
72. The inequality 2 x  3  1 is valid when x lies in the interval
(A) (3, 4) (B) (1, 2) (C) (-1, 2) (D) (-4, 3)
73. If log 330  c, log 530  d , then the value of log830
(A) 2(1 – c – d) (B) 3(1 + c + d) (C) 3(1 + c – d) (D) 3(1 – c – d)
4 5 x
74. The solution set of log 2  2, is
8  4 8 8 
(A)  ,   (B)  ,  (C)  , 0    ,   (D) None of these
5  5 5 5 
x2  5x  6
75. If  0 , then x belong to
x2  x  1
(A) (0, 3) (B) (3,  ) (C) (2, 3) (D) (-  , 2)  (3,  )
76. If log 3 (1  log 3 (2 x  7)  1 then x is
(A) 1 (B) 2 (C) 3 (D) 4
5  4x
77. If  4, then
3x 2  x  4
 7  7  4   7  7 4 
(A) x   , 
    1,    ,  (B) x   ,      1,  ,
 2   2   3  
 2   2   3 

 7  7
(C) x   ,     1,  (D) None of these
 2   2 

2x  6
78. If log 7  0 then x belong to
2x 1
(A)  , 0  (B)  0,1/ 2  (C)  , 1/ 2  (D) R
15 12
79. If sin   and cos   , where  and  lies in first quadrant then the value of tan(   ) is
17 13
220 171 220 171
(A) (B) (C) (D)
221 221 21 21
80. The value of tan 75o  cot 75o is
(A) 4 (B) 6 (C) 8 (D) 0

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Narayana IIT/NEET Academy XII C/F IIT EX. DT. : 02-05-2022
SECTION – II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is Numerical values.
[Answer any Five (5) Integer Questions]
Marking scheme: +4 for correct answer, -1 in all other cases.

81. tan 9° – tan27° – tan 63° + tan 81° is equals to –

 3    
82. The expression 3 sin 4   
    sin 4 (3   ) – 2 sin 6      sin 6 (5   ) is equal to
  2    2  
83. 3(sin x – cos x)4 + 6(sin x + cos x)2 + 4 (sin6x + cos6x) =
84. The number of solutions of equation, sin 5x cos 3x = sin 6x cos 2x, in the interval [0, ] are –
85. The number of solutions of the equation tan x + sec x = 2 cos x lying in the interval [0, 2] is
86. The number of integral values of k for which the equation 7 cos x + 5 sin x = 2k + 1 has a solution
is-
87. The number of solution of log 4 ( x  1)  log 2 ( x  3), is
88. The value of x satisfying log 2 (3 x  2)  log1/x 2 , is
 x 2  4 x 5 
log 7
89. Find the product of real roots of the equation 7  x 1 .
90. The number of real solutions of the equation x  3 x  2  0, is
2

DETAILS OF PAPER SETTER :

BRANCH DWARKA
PHYSICS CHEMISTRY MATH
MR. LALIT KUMAR MR. UDIT KUMAR MR. UMESH KUMAR


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