VELAMMAL IIT ACADEMY

Sec: XI_IIT JEE ADVANCE MODEL DATE: 03/04/2022

TIME: 03:00 Hrs WAT-25 Max Mark: 186

JEE ADVANCED-2019-P2
PHYSICS
Section Question Type +Ve - Ve No.of Total
Marks Marks Qs marks
Sec – I (Q.N : 1 – 8) One of More Correct Options Type +4 -1 8 32
(partial marking scheme) (+1)
Sec – II (Q.N : 9 – 14) Questions with Numerical Value Type +3 0 6 18
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27,
‐127.30)
Sec – III (Q.N : 15 – 18) Matrix Matching Type +3 -1 4 12
(Each match consist of 2 questions)

CHEMISTRY
Section Question Type +Ve - Ve No.of Total
Marks Marks Qs Marks
Sec – I (Q.N : 19 – 26) One of More Correct Options Type +4 -1 8 32
(partial marking scheme) (+1)
Sec – II (Q.N : 27 – 32) Questions with Numerical Value Type +3 0 6 18
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27,
‐127.30)
Sec – III (Q.N : 33 – 36) Matrix Matching Type +3 -1 4 12
(Each match consist of 2 questions)

MATHEMATICS
Section Question Type +Ve - Ve No.of Total
Marks Marks Qs Marks
Sec – I (Q.N : 37 – 44) One of More Correct Options Type +4 -1 8 32
(partial marking scheme) (+1)
Sec – II (Q.N : 45 – 50) Questions with Numerical Value Type +3 0 6 18
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27,
‐127.30)
Sec – III (Q.N : 51 – 54) Matrix Matching Type +3 -1 4 12
(Each match consist of 2 questions)

Page 1
PHYSICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer, 0 if not attempted and -1 in all other cases.
01. Standing waves can be produced
A) On a string clamped at both the ends
B) On a string clamped at one end and free at the other
C) When incident wave gets reflected from a wall
D) When two identical waves with a phase difference of  are moving in the same
direction.

02.

03. A metal rod when dropped vertically on a hard floor with its length in the horizontal
position, it vibrates with its two ends as vibration antinodes. The length of the rod is 0.6
m and its minimum frequency of 2 kHz.
A) The velocity of sound in the rod is 2.4 km s1
B) When the rod is clamped at centre its fundamental resonance is at 2 kHz
C) When clamped at centre its 2nd overtone is 6 kHz
D) When clamped at one end its fundamental resonant frequency is 1 kHz
0.8
04. y  x, t   represents a moving pulse, where x and y are in metre and t is in
 4x  5t 
2
5
second, then
A) Pulse is moving in +x direction
B) In 2s it will travel a distance of 2.5 m
C) Its maximum displacement is 0.16 m
D) It is a symmetric pulse at t=0
05. P, Q and R are three particles of a medium which lie on the x-axis. A sine wave of
wavelength  is travelling through the medium in the x-direction, P and Q always have
the same speed (but not constant). P and R always have same velocity (but not
constant). The minimum distance between
A) P and Q is /2 B) P and Q is 
C) P and R is /2 D) P and R is 
06. y-x curve at an instant for a transverse wave travelling along x axis on a string is shown.
Angle made by tangent with horizontal at the point A on the curve is 530, as shown

Page 2
 A) Transverse velocity of the particle at point A is parallel to positive y direction if the
wave is travelling along positive x axis.
B) Transverse velocity of the particle at point A is parallel to positive y direction if the
wave is travelling along negative x direction
C) Magnitude of transverse velocity of the particle at point A is greater than the wave
speed
D) Magnitude of transverse velocity of the particle at point A is lesser than the wave
speed
07. A plane progressive transverse wave is passing through medium along the positive x-
axis. At the given instant of time, the nature of the displacement, position (y – x) graph
is as shown in figure. Which of the following statements are correct? (Consider A, B, C
are three particles of the vibrating string)

A) Elastic potential energy per unit length of the string at the point B is more than that
at points A and C
B) Elastic potential energy per unit length of the string at the point C is more than that
at points A and B
C) Velocity of the particle at A is along negative y direction
D) Velocity of the particle at C is along positive y direction.
08. One end of a string of length L is tied to the ceiling of a lift accelerating upwards with
an acceleration 2g. The other end of the string is free. The linear mass density of the
string varies linearly from 0 to  from bottom to top.
A) The velocity of the wave in the string will be 0.
B) The acceleration of the wave on the string will be 3g/4 everywhere.
C) The time taken by a pulse to reach from bottom to top will be 8𝐿/3𝑔.
D) The time taken by a pulse to reach from bottom to top will be 4𝐿/3𝑔.

Page 3
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 6 questions. The answer to each question is a Numerical values comprising of
positive or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +3 for correct answer, 0 in all other cases.
09. The ends of a stretched wire of length L are fixed at x = 0 and x = L. In one
experiment, the displacement of the wire is y1  A sinx/L  . sint and energy is E1
and in another experiment its displacement is y2  A sin2x/L  . sint and energy is
E1
E2. Then the ratio is ____
E2
10. A string of length 0.5 m and mass 20 g, is stretched between two points with tension
of 2 N. When a pulse travels along it, the shape of the string is the same at times t and
t  t. Then the minimum value of t is equal to (in seconds) _____
11. A 20 cm long string, having a mass of 1.0 g is fixed at both the ends. The tension in
the string is 0.5 N. The string is set into vibrations using an external vibrator of
frequency 100 Hz. The separation between the successive nodes on the string is (in
cm)
12. Two harmonic waves travelling in the same medium have frequency ratio 1:2 and
intensity ratio 1:36. Then the addition of the wave’s amplitude is (in SI units).
(Assume smaller amplitude of one of the waves is 1 SI unit)
13. In the figure shown below, a source of sound having power 12 x 10-6 W is kept at O,
which is emitting sound wave in all the directions. Two surfaces are labelled as 1 and
2 having areas A1 = 2 x 10-3 m2 and A1 = 4 x 10-3 m2 respectively.

The ratio of the intensity at both the surfaces 1 and 2 is ____

14. In the sixth harmonic on a string fixed at both ends, the difference between the number
of nodes and antinodes is ____
.

Page 4
 SECTION – III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the
correct match are provided as (A), (B), (C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
15.

(A) (a) → p (b) → q (c) → s (d) → r

(B) (a) → q (b) → p (c) → r (d) → s
(C) (a) → q (b) → r (c) → s (d) → r
(D) (a) → q (b) → s (c) → s (d) → r
16.

(A) (a) → p (b) → r (c) → r (d) → s

(B) (a) → r (b) → p (c) → r (d) → s
(C) (a) → q (b) → r (c) → s (d) → r
(D) (a) → s (b) → r (c) → p (d) → q
17.

(A) (a) → p (b) → r (c) → p (d) → s

(B) (a) → r (b) → p (c) → r (d) → s
(C) (a) → q (b) → q (c) → q (d) → r
(D) (a) → p (b) → p (c) → p (d) → r

Page 5
18.

(A) (a) → r (b) → s (c) → p (d) → q

(B) (a) → s (b) → p (c) → r (d) → s
(C) (a) → s (b) → s (c) → p (d) → r
(D) (a) → p (b) → s (c) → p (d) → r

CHEMISTRY Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer, 0 if not attempted and -1 in all other cases.
19. An organic compound (a) C4H6 on ozonolysis gives formaldehyde and glyoxoal. Which of the
following about possible isomers of C4H6 are true ?
(a) It can decolourise Br2 water and by catalytic hydrogenation using 1mole of H2 and
subsequent oxidation with alk. KMnO4 gives CH3COOH.
(b) can react with ammonical AgNO3
(c) Does not react with ammonical AgNO3, but with hot alkaline KMnO4 gives CH3COOH
(d) can form acetone on ozonolysis.
20. A  C5 H 9 Br  does not decolourise Baeyer’s reagent. A on treatment with alc. KOH gives B  C5 H 8 
which decolourises Br2 water. Reductive Ozonolysis of B forms C   C5 H8O2  .
(a) A can be a cyclic compound
(b) There can be 3 possible structures of A
(c) B contains two double bonds
(d) C can be a dicarboxylic acid.
21.

Which of the following statements are true?

(a)B is a single compound and is optically inactive

Page 6
 (b)D is a single compound and is optically inactive
(c)B is an equimolar mixture of two enantiomeric compounds
(d)D is an equimolar mixture of two enantiomeric compounds
22. A hydrocarbon of molecular formula, C6H10 reacts with sodamide and the same on ozonolysis
followed by hydrogen peroxide oxidation gives two molecules of carboxylic acids, one being optically
active.
Then the hydrocarbon may not be:
(a) 1–hexyne (b) 2–hexyne (c) 3–hexyne (d) 3–methyl–1–pentyne
23. The reaction,

(a) hydroxylation (b) ozonolysis (c) Prileschaiev’s reaction (d) epoxidation

24.

25. Using Huckel rule, predict which of the following hydrocarbons will exhibit aromatic stabilisation

26. Which of the following are the best methods for the preparation of n-propyl benzene (A) ?

Page 7
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 6 questions. The answer to each question is a Numerical values comprising of
positive or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +3 for correct answer, 0 in all other cases.
27. Total number of moelcules which are antiaromatic?

28. What is the number of delocalised  electrons in anthracene  C14 H10  ?

CH3

O3/CH2Cl2
X+Y
H 2O2
29.
H PO
‘X’ is aromatic & ‘Y’ is aliphatic compound. X 
3
Δ  Y. What is the total number of sp hybrid
4 2

orbitals of carbon involved in bonding?

CH3 CH3
CH3
OH + OH + Y
X/OH-
30.
OH OH
X and Y are the compounds of a 3d-series transition metal. If the O.S’s of the metal in X and Y are +a
and +b, what will be the product of a and b?

Page 8
31. a) CH 3  C  CH + Na NH 2 
CH3
O3/CCl4
(CH3)2S
b) c) HC  CH  Na 
d) Ph  C  CH  CH3MgBr  e) HC  CH  NaoH 

C  C  H  CaH 2
f)
In how many of these reactions a gaseous product is evolved?
i  Sia2 BH Hg 2
32. a) Ph  C  CH   b) Ph  C  C  CH 3 
H 2 SO4  dil 

ii  H 2O2
CH 3 Ph
CH3
CH3
CH 3  i  O / CH Cl O / CH Cl

3
 ii  H O
2 2
 CH 3 
3 2 2

CH 3
2 2 CH S 
3 2
c) d)
CH3

 i  O3 / CH 2Cl2 MnO4

 ii  Zn / H 2O
 
H SO 
2 4
CH3
e) f)
In how many of these reactions aldehyde is one of the products?
SECTION – III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the
correct match are provided as (A), (B), (C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
I. Isopentene (Column-I) undergoes hydration and alcoholation by different methods of hydration and
alcoholation like acid catalysed hydration, hydroboration-oxidation, oxymercuration-demercuration,
alkoxymercuration-demercuration to give alcohol or ether (Column-II)

Page 9
33. Which of the following is correct regarding the hydration proceeding through carbocation
intermediate?
a) A-r b) C-q c) D-s d) C-r
34. Which of the following is correct regarding the formation of Markovni-kove’s product without
rearrangement?
a) C-q b) B-p c) D-s d) C-r
II. Aromaticity is an exceptional stabilisation factor. According Huckel’s rule compounds having cyclic
planar molecules with (4n+2)  electrons in full conjugation are aromatic and highly stable and those
with (4n)  electrons in full conjugation are anti aromatic and highly unstable. Any of these conditions
are not fulfilled, the compound is non-aromatic.
Column -I Column -II

A) (Non planar) p) Anti aromatic

B) q) Aromatic
.
. . ..
. . ..

C) (Planar) r) Non aromatic

.
. . .
. . ..
.

D) (Planar) s) General formula = CnHn

35. Which of the following is correct regarding the least stable species?
A) D-p B) D-q C) A-p D) C-p
36. Which of the following is correct combination regarding the species having stability higher than of D
and, less than that of C
A) D-p B) B-r C) A-r D) Both B & C

MATHS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer, 0 if not attempted and -1 in all other cases.
1
37. If f  x   log e  x  2   , then
x
A) f  x  is monotonically increasing for x   2,  
B) f  x  is monotonically decreasing for x   2,  

Page 10
 C) f  x  is always concave upward
D) f   x  is monotonically increasing wherever defined.
38. If 0  x  1 , then
x2 1
A) x log x    0
2 2
x2 1
B) x log e x    0
2 2
x2 1
C) graph of x log e x   is concave upward
2 2
x2 1
D) graph of x log e x   is concave downward
2 2
 x   27
2

39. If g  x   2f    f   x 2  , where f   x   0 for all x  R , then
 2   2 
A) in  0,3  , g  x  increases B) in  , 3 , g  x  increases
C) in  3,   , g  x  decreases D) in  3, 0  , g  x  decreases
x2 x2
40. If f  x   and g  x   , where 0  x  1 , then
2  2 cos x 6x  6sin x
A) f is increasing function B) g is increasing function
C) f is decreasing function D) g is decreasing function
41. The function f  x   a  x  1  ax  b  , where a, b  R and a  0 , has
2

A) a local maximum at certain x  R  B) a local minimum at certain x  R 

C) a local maximum at certain x  R  D) a local minimum at certain x  R 
42. At x  0, f  x    3  x  e 2 x  4xe x  x
A) has a minimum B) has a maximum
C) has no extremum D) has point of inflection
43. The curve y  ax 3  bx 2  cx is inclined at 45 to x-axis at  0, 0  but it touches x-axis at 1, 0  , then
A) f  1  0 B) f  1  2 C) f   2   12 D) f  2   2
44. For the curve x  2a sin t  a sin t cos t; y  a cos t
2 3


A) normal is inclined at an angle  t with x-axis
2
B) normal is inclined at an angle t with x-axis
C) portion of normal contained between the coordinate axes is equal to 2a
D) portion of normal contained between the coordinate axes is equal to 4a

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 6 questions. The answer to each question is a Numerical values comprising of
positive or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +3 for correct answer, 0 in all other cases.
45. A line through origin is tangent to the curve y  x 3  x  16 , then slope of line is 5k  3 , then k equals

46. Number of critical points of the function f  x   x  x is …………

Page 11
 x 2
47. The function f  x    has a local minimum at
2 x

k  2x, if x  1
48. Let f : B  R be defined by f  x    . If f has a local minimum at x  1 , then a
2x  3, if x  1
possible value of k + 1 is

49. If the function f  x   2x 3  9ax 2  12a 2 x  1 , where a  0 , attains its maximum and minimum at p and q,
respectively, such that p 2  q , then a equals

 2  x 3 , 3  x  1
50. The total number of local maxima and local minima of the function f  x   
2/3
 x , 1  x  2
is

SECTION – III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the
correct match are provided as (A), (B), (C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
I) Let f  x  is a derivable function which is increasing for all x  R (having no critical point).
Column-I Column-II
P) f   x  is 1) Decreasing for all x
1
Q) f  3  4x  is 2) Increasing for x 
2
R) f  x 2  x  is 3) Increasing for all x
Cannot say whether increasing
 f  x 
3
S) is 4)
or decreasing
51. Which of the following is correct?
A) P  4;Q  3 B) Q  1; R  3 C) P  4; R  2 D) R  2;S  4
52. Which of the following is correct?
A) Q-1, S-3 B) P-2, R-4 C) Q-2, S-1 D) R-4, P-1

II) Consider the local maximum and local minimum of f  x  

 x  a  x  b  . Then
 x  3 x  6 
Column-I Column-II
P) No maximum, No minimum 1) a  1, b  2
Q) One maximum, No minimum 2) a  2, b  7
R) One minimum, No maximum 3) a  4, b  5
S) One maximum, One minimum 4) a  2, b  4
53. Which of the following is correct?
A) P  2, R  3 B) Q  3,S  2 C) P  4,S  1 D) R – 4,S – 2

54. Which of the following is correct?

A) Q-2, R – 1 B) Q-3, R-2 C) S-2, P-4 D) R-1, R-2

Page 12