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SEC:SR_*CO-SC(MODEL-A&B) Date: 15-10-23

Time: 3 Hrs Max. Marks: 212


15-10-23_SR.IIT_STAR CO-SC(MODEL-A,B&C) _JEE ADV_PTA-11_SYLLABUS
MATHEMATICS: PRESENTWEEK (100%): Areas: application of definite integrals to the
determination of areas involving simple curves.
Differential Equations : Solution of homogeneous differential
equations, separation of variables method Formation of ordinary
differential equations,linear first order differential equations.

PHYSICS: PRESENTWEEK (100%): Moving charges and Magnetism:


Biot–Savart’s law and Ampere’s law; Magnetic field near a current-
carrying straight wire, along the axis of a circular coil and inside a long
straight solenoid; Force on a moving charge and on a current-carrying
wire in a uniform magnetic field. Magnetic moment of a current loop;
Effect of a uniform magnetic field on a current loop; Moving coil
galvanometer, voltmeter, ammeter and their conversions.
Magnetism & matter: Current loop as a magnetic dipole and its
magnetic dipole moment. Bar magnet as an equivalent solenoid,
magnetic field lines; Earth's magnetic field and magnetic elements.
Para-, dia- and ferromagnetic substances. Magnetic susceptibility and
permeability. Hysteresis. Electromagnets and permanent magnets.

CHEMISTRY: PRESENTWEEK (100%): Biomolecules: Carbohydrates:


Classification; Mono- and di-saccharides (glucose and sucrose);
Oxidation; Reduction; Glycoside formation and hydrolysis of
disaccharides (sucrose, maltose, lactose); Anomers.
Proteins: Amino acids; Peptide linkage; Structure of peptides (primary
and secondary); Types of proteins (fibrous and globular).
Nucleic acids: Chemical composition and structure of DNA and RNA.
Vitamins
Purification of organic compounds & Qualitative and quantitative
analysis
Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
Time: 3 hrs. IMPORTANT INSTRUCTIONS Max Marks: 222
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 4 -2 10 40
Questions with Comprehension Type Integer
Sec – II(Q.N : 11 – 16) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 17 – 20) Matrix Matching Type 4 -2 4 16
Total 20 74

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 4 -2 10 40
Questions with Comprehension Type Integer
Sec – II(Q.N : 31 – 36) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 37 – 40) Matrix Matching Type 4 -2 4 16
Total 20 74

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 4 -2 10 40
Questions with Comprehension Type Integer
Sec – II(Q.N : 51 – 56) (3 Comprehensions – 2 +2+2 = 6Q) 3 -1 6 18
Sec – III(Q.N : 57 – 60) Matrix Matching Type 4 -2 4 16
Total 20 74

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
MATHEMATICS MAX.MARKS: 74
SECTION-I
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
1. The curves satisfying the differential equation 1  x 2
dy
dx
 
 xy  ax are

A) Ellipses and hyperbolas B) Ellipses and parabolas


C) Ellipses and straight lines D) Circles and ellipses
2. Let f : (1,1)  IR be a differentiable function satisfying (f '(x)) 4  16(f (x)) 2 for all
x 1
x  ( 1,1) and f (0)  0 . Let N be the number of such functions. Then lim 
x N x 1
5 5
A) 3 B) C) D) 1
3 4
x

Let g be a differentiable function satisfying  (x  t  1)g(t)dt  x  x  ax  b,  x  0


4 2
3.
0

6(a  g '(0))
1

then  g '(x)  g(x)  b  10 dx 


0

   
A) B) C) D)
6 3 4 2
4. A point P lying in the first quadrant inside the semicircle y  2ax  x 2 is moving such
that its shortest distance from the curve at any position is greater than its distance
from x – axis. The point P encloses a region whose area is equal to
a 2 3  4  2
D) 
a2 2a 2
A) B) C) a
2 3 3  6 
5. Area bounded by y  n(x  1), y  1  nx and their common tangent is
1 1
A) 1  n(e  1) B) n(e  1)  C) n(e  1)  D) n(e  1)  1
2 2
x
6. The area enclosed by the curve | x  60 |  | y | is
4
A) 240 sq. units B) 360 sq. units C) 480 sq. units D) 600 sq. units
Let A   , 0  , B   , 0  , C   , 0  be 3 – points on xy – plane. P is another point on
1 3 5
7.
2  2  2 
the same plane satisfying min {PA  PB, PB  PC}  2 . If the area of the region of P is
 3
3    then a  b  ______
a b 
5
A) 7 B) 5 C) 9 D) 
2

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
8. Let g(x)  f (x)  1 is a differentiable function where
  
x x
f (x)   f (x  t) tan(x  t)dt    tan(x  t)dt for x    ,  , then area enclosed by g(x)
0 0  2 2

with x – axis & ordinates x   is  where  4 is
4
A) 3 B) 4 C) 5 D) 6
9. The solution of the differential equation
y  x   
xy(x  y) dx  y xy(x  y)  x dy  0 is

x 2  y2 y x 2  y2 x
A)  tan 1 c B)  2 tan 1 c
2 x 2 y

x 2  y2 x
C)  2 cot 1 c D) None of these
2 y

10. Let f (x)  x 3  x 2  2x  8 and g(x) is inverse of f(x). Then area bounded by y  g(x) , x
– axis between x  12 , and x  6 is
7 4 22 325
A) sq. units B) sq. units C) sq. units D) sq. units
2 3 3 6
SECTION-II
(Paragraph Type With Integer )
This section contains 6 Integer Type questions relating to three paragraphs with two questions on each
paragraph. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. For each
question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer
and zero mark if no bubbles are darkened. In all other cases, minus one (-1) mark will be awarded
Paragraph for Questions 11 & 12:
dy 1  y2
Consider the differential equation  . Also x  1 at y  0
dx 1  y2 cos y  xy

11. The minimum value of x  y  R is



12. Let L be the value of x for y  , then the value of (2  4)L2 =
2
Paragraph for Questions 13 & 14:
Let f(x) be a differentiable function in its domain such that
3
1  
x x

0 
x 2  0
 x  R  {0} ,f(1) = 1.
3
(f (t)) dt  f (t) dt

If f (x)  f (y)  x  y , x, y  R x 2  y2  0 then f   ?


1
13.
2

14. If  atleast one (x, y)  R 2 , xy  0 , such that f (x)  f (y) for x  y , then f (2)  ?

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
Paragraph for Questions 15 & 16:
Five regions are defined as follows :
1 1
C1 :| x  y | 1, C2 :| x  y | 1, C3 :| x | , C4 :| y |
2 2
C 5 : 3x 2  3y 2  1


15. If the area bounded by C1 , C2 which doesn’t contain area of C5 is 2  then k =
k
16. The part of area contained in C1 , C2 but not in both C3 and C 4 is :
SECTION-III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct match are
provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
17. Match the family of curves mentioned in List I with their respective differential
equations mentioned in List II :
List – I List - II
2 2
Parabola whose axes is parallel to x – axis  dy   dy 
1)
and having latus rectum 1 unit
A)  y  x   1  
 dx   dx 
Straight lines at unit distance from the dy 2xy
2) B)  2
origin. dx x  y 2
3
Family of circles touching x – axis at the d2 y  dy 
3) C)  2   0
origin dx 2
 dx 

Family of curves given by ax 2  by 2  1 , a, d2 y  dy  dy


2

4) D) xy. 2  x    y 0
b are arbitrary constants. dx  dx  dx

A) 1  C,2  A,3  B,4  D B) 1  D,2  A,3  B,4  C


C) 1  A,2  D,3  C,4  B D) 1  A,2  B,3  C,4  D
18. Match the following:
List – I List – II
1
A) xdy  y(dx  ydy), y(1)  1 and y(x 0 )  3 , then x 0  p)
3
dy
If y(t) is solution of (t  1)  ty  1 , t  1 y(0)  1,
B) dt q) 15
then y(1) 
1
C) (x 2  y 2 )dy  xydx and y(1)  1and y(x 0 )  e, then x 0 = r) 
2
dy 
D) If (2  sin x)  (y  1) cos x  0 , y(0)  1, then y    ? s) 3e
dx 2
A) A  Q,B  R,C  P,D  S B) A  R,B  Q,C  S,D  P
C) A  Q,B  R,C  S,D  P D) A  R,B  S,C  P,D  Q

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
19. Match the following:

Column – I Column – II
Area bounded by region 32
A) p)
0  y  4x  x  32
3
Area of the region enclosed by
B) q) 1/ 2
y 2  8x and y  2x is

The area bounded by | x |  | y | 1 and


C) r) 8/3
| x | 1/ 2 is
D) Area bounded by x  4  y 2 and x  0 s) 4/3
A) A  R,B  S,C  Q,D  P B) A  S,B  S,C  Q,D  P

C) A  R,B  Q,C  P,D  S D) A  Q,B  R,C  P,D  Q

20. Match the following

List – I List – II
If A is the area inside the circle
x 2  2x  y 2  4y  1  0 and outside the ellipse
A) P) 4
A
x 2  2x  4y 2  16y  13  0 , then 


The value of ‘a’  0  a   for which the sum of
 2
the area of the regions bounded by the curves
B)  Q) 2
f (x)  sin 3 x  sin x , y  f (a) , x  0 and x  is
2

minimum. Is then k =
k
If area of the region bounded by the curve
C) R) 8
y2  2y  x and the y –axis is A then 3A 

D) The area of the loop y 2  x(x  1) 2 is A then 15A  S) 6

A) A  S,B  Q,C  R,D  P B) A  Q,B  P,C  P,D  R

C) A  R,B  S,C  Q,D  P D) A  R,B  Q,C  P,D  S

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
PHYSICS MAX.MARKS: 74
SECTION-I
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
21. A charge Q is uniformly distributed over the slant surface of a thin-walled right
circular cone of semi-vertex angle  , height hand radius R. The cone is uniformly
rotated about its axis at angular velocity  . The magnetic dipole moment associated
with the cone is __________.

1 1 1 1
A) Q R 2 tan 2  B) Q h 2 tan 2  C) Q R 2 tan 2  D) Q h 2 tan 2 
4 3 3 4
22. A long horizontal wire AB, which is free to move in a vertical plane and carries a
steady current of 20A, is in equilibrium at a height of 0.01 m over another parallel long
wire CD which is fixed in a horizontal plane and carries a steady current of 30 A, as
shown in figure. Show that when AB is slightly depressed, it executes simple hormonic
motion. Find the time period of small oscillations.  g   2 m / s 2 

A) 2 sec B) 0.2 sec C) 1 sec D) 0.1 sec


6 10
23. A positively charged particle having charge 10 C and mass 10 kg is fired from the
middle of the plates making an angle 300 with plane of the plates. Length of the plates
is 0.17 m and the plates separation is 0.1 m. An electric field E  103 NC 1 is present
between the plates and just outside the plates a magnetic field is present. Find
magnitude of the magnetic field perpendicular to the plane of the figure, if it has to
graze the plate at Q and P parallel to the surface of the plate (Neglect Gravity).
Take 3  1.7 

A) 1.7 mT B) 6.8 mT C) 3.4 mT D) 0.34 mT

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P

24. A particle of mass m and charge q enters a region of electric field E as shown in the
figure with some velocity at point P. At the moment the particle collides elastically

with smooth surface at N, the electric effect E is switched off and a magnetic field
perpendicular to the plane of paper automatically switched on. If the particle hits the
surface at point O, Then the magnetic induction B is .(neglect gravity)

mE 2mE mE mE
A) 2 B) C) D)
qd qd qd 2qd

25. For a current carrying circular coil, the ratio of the magnetic field at the center of the
circular coil to its magnetic moment is x. on doubling the radius and the current ,the x
value
x x 7x 7x
A) decreases by B) Increases by C) decreases by D) Increases by
8 8 8 8

26. A conducting ring of mass 2kg and radius 0.5 m is placed vertically on a smooth
horizontal plane. The ring carries a current I=4 A. A horizontal magnetic field B= 10 T
is switched on at time t=0 as shown in figure. The initial angular acceleration of the
ring is

A) 5  s 2 B)15  s 2 C) 20  s 2 D) 40  s 2
27. A uniform magnetic field of intensity 1 T is applied in a circular region of radius 0.1 m,
directed into the plane of paper . A charged particle of mass 5 105 kg and charge
1
q  5  104 C enters the field with velocity ms 1 making an angle  with a radial line
3
of circular region in such a way that it passes through centre of applied filed then the
angle  is
A) 300 B) 450 C) 600 D) 900

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
28. A small sphere of mass m and radius r is suspended by a silk thread inside a current
carrying long solenoid. The solenoid carries a current I and has n numbers of turns per
unit length. The sphere is wrapped by a single tum of coil carrying a current I 0 as
shown in the diagram. The time period of small oscillations of the sphere is

m 2m m 5m
A) 2 B) 2 C) 2 D) 2
50 nII 0 50 nII 0 20 nII 0 20 nII 0

29. A parallel plate capacitor consists of square plates of edge length a separated by a
distance d that is much smaller that the edge length. It is charged to a potential V and
made to move with a constant velocity v directed along one of its edges. How much
magnetic field exists inside the capacitor ?
0 0 vV 0 0 vV 0 0 vV
A) B) C) D) none of these
d a a2

30. A current carrying wire carries a current of 2A, which is out of the page, another wire
carrying current of 4A in same direction lies parallel to the first, as shown in figure.
 
Then around which loop linking both the wires,  B.dl is zero

A) B)

C) D)

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
SECTION-II
(Paragraph Type With Integer )
This section contains 6 Integer Type questions relating to three paragraphs with two questions on each
paragraph. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. For each
question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer
and zero mark if no bubbles are darkened. In all other cases, minus one (-1) mark will be awarded
Paragraph for Questions 31 & 32:
Consider a long current carrying cylindrical conductor of radius R. Current density J
inside the conductor is uniform over its cross section.
31. The force of interaction per unit length between two halves that are obtained by
1
dividing the conductor by a plane containing the axis of the conductor is 0 J b R c .
a
Where a, b and c are integers then a+b+c is
R 3
32. The radial pressure at distance from the axis is 0 J a R b . Where a, b are integers
2 16
then a+b is
Paragraph for Questions 33 & 34:
A charged particle of m and charge q is projected on a rough horizontal 
X-Y plane,
both electric and magnetic fields are acting in the region and given by E   E0 kˆ and

B   B0 kˆ , respectively

At t=0, the particle enters into the field at  A0 , 0, 0  with velocity v  v0 ˆj . The particle
starts moving into a spiral path on the plane. If coefficient of friction between the
particle and the plane is   1 , then calculate the
2

a mv0
13. The Time after which the particle comes to rest is . Where a, b are integers
b  mg  qE 
then a+b is
a mv02
14. Length of the path travelled by the particle when it comes to rest is . Where
b  mg  qE 
a, b are integers then a+b is

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
Paragraph for Questions 35 & 36:
An equilateral triangular frame PQR of mass M and side a is at rest in vertical plane is
under the influence of horizontal magnetic field B and gravitational field as shown in
the figure.

n Mg
15. The magnitude of current in the frame so that the frame remains at rest is . Where
aB
n is an integer .Then the value of n is

16. If the frame is slightly displaced in its plane perpendicular to PQ, then it executes
simple harmonic motion with time period ‘T’(Neglect EMF induced due to motion of
n2 a
the loop).Then T is equal to n1 . Where n1 , n2 are integers, Then the value of
g
n1  n2 is

SECTION-III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct match are
provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
37. Three charged particles 1,2 and 3 of mass m, 2m and 3m having charges q, -2q and 6q
are projected into a magnetic field B with same speed as shown in figure. At t=0 they
enter into the region of magnetic field (from same point). Ignore electric and magnetic
effects due to charges on themselves.

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
m
At t  Match the following
2 Bq

SECTION-I SECTION-II
A) Distance between 1 and 3 P) 2v0
B) Distance between 2 and 3 Q) 2v0
C) Magnitude of velocity of 1 with mv0
R) 5
respect to 2 Bq

D) Magnitude of velocity of 2 with mv0


S)
respect to 3 Bq
A) A-S, B-R, C-P, D-Q B) A-R, B-S, C-Q, D-P
C) A-S, B-R, C-Q, D-P D) A-P, B-R, C-Q, D-S
38. A particle of mass m , charge q (positive) is released from the origin O with velocity
  B 3B0 ˆ
v  v0iˆ in a uniform magnetic field B  0 iˆ  j . Assuming that the field extends all
2 2
2 m
over the space. At t  Match the following
B0 q

SECTION-I SECTION-II
3 mv0
A) X-co-ordinate of the particle P)
2 B0 q
 mv0
B) Y-co-ordinate of the particle Q)
B0 q
 mv0
C) Z-co-ordinate of the particle R)
2B0 q

D) Distance of the particle from origin S) Zero


A) A-R, B-P, C-S, D-Q B) A-R, B-P, C-Q, D-S
C) A-R, B-S, C-P, D-Q D) A-Q, B-P, C-S, D-R
39. A long straight conductor of radius R carries a current I as shown. The current density j
varies as a function of radial distance r from the axis according to the equation j  br
where b is constant. B is the magnetic field produced by the current at radial distance r
from the axis. Match the quantities in COLUMN-I WITH COLUMN-II

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
SECTION-I SECTION-II
A) B at r  R P) Maximum
0br 2
B) B at r  R Q)
3

2 br 3
C) B at r  R R)
3

0bR3
D) Current I at r  R S)
3r
A) A-Q, B-P, C-R, D-S B)A-Q, B-P, C-S, D-R
C) A-Q, B-S, C-P, D-R D) A-R, B-P, C-S, D-Q

40. A particle having charge q and mass m is dropped from a large height from the ground.
There exists a uniform horizontal magnetic field B in the entire space as shown in the
fig. Assume that the acceleration due to gravity remains constant over the entire height
involved.

SECTION-I SECTION-II
A) The time after which the displacement in m
P)
vertical direction is maximum 2Bq

B) The time after which particle again comes to 2 m


Q)
rest 3Bq

C) The time after which the vertical component of m


R)
velocity is maximum Bq

D) The time after which the depth from starting


2 m
3m2 g S)
point becomes 2 2 Bq
2q B

A) A-P, B-S, C-R, D-Q B) A-R, B-Q, C-P, D-S

C) A-P, B-S, C-Q, D-R D) A-R, B-S, C-P, D-Q

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
CHEMISTRY MAX.MARKS: 74
SECTION-I
(Only one Option correct Type)
This section contains 10 Multiple Choice questions. Each Question has Four choices (A), (B), (C) and (D). Out of
Which Only One is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
41. The major products [P] and [Q] formed in the following reactions are:
Me
1. NaN3/DMF
[P]
Br 2. LiAlH 4

COCl
1. NH3 (2eq)
[Q]
Me 2. Br2/NaOH

A) Identical B) Enantiomers C) Diastereomers D) Homologues


42. Following chromatogram was developed by adsorption of compound ‘P’ on a 6 cm
TLC glass plate. Retardation factor (Rf) of the compound ‘P’ is:

0.5 cm
Solvent Front
Compound P

3.5 cm

0.5 cm

A) 0.4 B) 0.5 D) 0.58 D) 0.6


43. The sum of number of lone pairs of electrons present in [P], [Q] and [R] is:

1. KOH
2. PhCH 2Br
Phthalimide [P] + [Q]
3. NaOH(aq), 

CHCl 3/KOH
[Q] [R]

(foul smell)

A) 9 B) 10 C) 11 D) 12

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
44. The major product [R] formed in the following reaction sequence is:

NH2

NaNO 2/HCl N,N-dimethyl aniline NaOH


[P] [Q] [R]
273 K
(Methyl orange)

SO 3H
(Sulphanilic acid)

SO 3H SO 3Na
NMe 2
N N
N N

A) B) Me2N
SO 3Na SO 3H
NMe2
N N
N N

C) D) Me2N
45. The correct statement about the nitrogenous bases considering the structures I to V is:
NH2 NH2 O

N Me
N N NH

NH N NH O NH O

[I] [II] [III]

O O

N
NH NH

NH O NH N NH2

[IV] [V]

A) Except [III] all are present in DNA.

B) Except [IV] all are present in RNA.

C) In DNA [II] pairs with [V] with three hydrogen bonds.

D) In DNA [I] pairs with [IV] with two hydrogen bonds.

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
46. The isoelectric point (pI) of the following amino acid is:
O

HS OH
pka=8.3 + pka=1.7
NH3
pka=10.8

A) 5.0 B) 6.25 C) 9.55 D) 10.4

47. A mixture containing 0.02 mole of each nitrobenzene and aniline is Kjeldahlised and
the liberated NH3 is absorbed in y mL of 0.2 M H2SO4. The left over acid required 40
mL of 0.1 M NaOH. The value of y is:

A) 60 mL B) 110 mL C) 120 mL D) 220 mL

48. The weight of major organic product [S] formed in the following reaction sequence is:

OH +
H2N H (cat.)/  LiAlH 4 then H2O CH 3COCl
[P] [Q] [R]
O -H2O 75% yield Pyridine
LiAlH 4 then
(1 mol) 100% yield 100% yield H2O
75% yield

[S]
(Use: Atomic weight H=1, C=12, N=14, O=16, Cl=35.5)

A) 55.69 g B) 64.69 g C) 74.25 g D) 99.0 g


49. Given below are isomeric amines. The incorrect statement about them from the
following is:

Me Me Me
Me NH2 NH
NH2 N

Me

Et
[S]
[P] [Q] [R]

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
A) [P] and [Q] can be distinguished by azo dye test.

B) Reaction of all amines with HCl is exothermic

C) Reaction of benzene sulphonyl chloride with [S] gives a solid that is insoluble in
NaOH.

D) [R] has highest basicity among these.

50. Which of the following statement(s) is(are) incorrect for the following disaccharide?

I) It is a nonreducing sugar. II) It forms an osazone.

III) It exists in two anomeric forms. IV) It undergoes mutarotation.

A) I, II only B) II, III only C) II, IV only D) II, III, IV only

SECTION-II
(Paragraph Type With Integer )
This section contains 6 Integer Type questions relating to three paragraphs with two questions on each
paragraph. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. For each
question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer
and zero mark if no bubbles are darkened. In all other cases, minus one (-1) mark will be awarded
Paragraph for Questions 51 & 52:
NH2

conc. HNO 3/H2SO 4


[P] + [Q] + [R]

(2%) [47%] [51%]

1. Br2(excess)/CH3CO 2H 1. Sn/HCl
2. NaNO 2/HCl, 273 K 2. NaNO 2/HCl, 273 K
[R] [S] [T]
3. EtOH 3. HBr/CuBr
(Major) (Major)
1. H2/Pd-Ethanol
[P] [U]
2. NaNO 2/HCl, 273 K (Major)

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
51. On estimation of bromine in 5.0 g of [T] using Carius method, the amount of AgBr
formed (in g) is ______. [Round off to nearest integer]
[Given: Atomic mass of H = 1, C = 12, N=14, O = 16, Cl = 35.5, Br = 80, Ag = 108]
52. The degree of unsaturation of [U] is ______.
Paragraph for Questions 53 & 54:
Paragraph for Q.53 and Q.54

[R]
+
3 eq PhNHNH 2/H - ppt +
3 eq PhNHNH 2/H

+
H3O Br 2/H2O
D- sucrose [P] + [Q] No effect

1. NaBH 4
x eq of (CH3CO) 2O z eq of (CH 3CO) 2O
2. y eq of (CH3CO) 2O

[S] [T] [U]

53. The total number of heteroatoms in [R] is____.


(Atoms other than C and H are considered as heteroatoms)
54. The value of x+y-z is____.
Paragraph for Questions 55 & 56:
The following is a partial sequence of the active site of pepsin.
OH

HO OH
O O O
H2N NH NH OH
NH NH NH
O OH O O

55. The net charge on this peptide at pH=2.0, 5.0 and 11.0, respectively, is z1, z2 and z3.
The value of z1 + z 2 + z 3 is____.

56. If ‘x’ is the number of chiral carbons and ‘y’ is the number of peptide bonds present in
the sequence. Then the value of x-y is ____.

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
SECTION-III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct match are
provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme +4 for correct answer, 0 if not attempted and -2 in all other cases.
57. Match the compounds in List-I with observations in List-II, and choose the correct
option.

List-I List-II
P) Sodium fusion extract of the compound on
I) Methionine boiling with FeSO4, followed by acidification
with conc. H2SO4, gives Prussian blue color
Q) Sodium fusion extract of the compound on
II) Tyrosine
treatment with FeCl3 gives red colour.
R) Treating the compound with nitrous acid at
III) Aniline
273 K gives effervescence of N2
IV) Proline S) Decolorizes bromine water.
A) I→P, R; II→P, Q; III→Q, S; IV→P, R
B) I→P, R; II→P, R, S; III→P, S; IV→P, R
C) I→Q, R; II→P, S; III→P, R, S; IV→P
D) I→Q, R; II→P, R, S; III→P, S; IV→P
58. Match the carbohydrates in List-I with their characteristics in List-II, and choose the
correct option.
List-I List-II
I) Sucrose P)   glycosidic linkage
II) lactose Q)   glycosidic linkage
III) Maltose R) reducing sugar
IV) Cellulose S) C1  C2 linkage
T) C1-C4 linkage
A) IP, S; IIP, R, T; IIIP, R, T; IVQ, T

B) IP, S; IIQ, R, T; IIIP, R, T; IVQ, T

C) IQ, R; IIP, R, T; IIIQ, R, T; IVQ, T

D) IQ, R; IIQ, R, T; IIIQ, R, T; IVQ, T

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
59. Match the mixtures in List-I with their purification process in List-II, and choose the
correct option.
List-I List-II
I) Naphthalene and Sodium chloride P) Crystallization
II) Water and Aniline Q) Sublimation
III) Benzoic acid and Naphthalene R) Distillation
IV) Chloroform and Aniline S) Steam distillation
A) I  P ; II  S; III Q ; IV R. B) I  Q; II S ; III P ; IV R
C) I Q ; II R ; III P ; IV S D) I  P ; II  R; III  Q; IV S
60. The major products obtained from the reactions in List-II are the reactants for the
named reactions mentioned in List-I. Match List-I with List-II, and choose the correct
option.
List-I List-II
NH2
1. NaNO 2, HCl/273 K
2. CuCN/KCN
I) Perkin reaction
3. SnCl 2/HCl
+
then H 3O
P)
Me
-
1. KMnO 4, OH , 
II) Gattermann reaction +
2. H3O

3. NH3, 
Q)
CONH 2

1. Br2/NaOH
III) Carbylamine reaction
2. NaNO 2, HCl
R) 273 K
Me

IV) Hofmann bromamide 1. NBS, h

reaction 2. KCN

S) 3. Na- Hg/EtOH
NH2

1. NaNO 2, HCl/273 K

2. CuCN/KCN
T)
A) I  T ; II R ; III S ; IV  Q B) I  R ; II T ; III Q ; IV S
C) I  Q ; II R ; III S ; IV P D) I  P; II  R; III  S; IV Q

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SPACE FOR ROUGH WORK

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Narayana IIT Academy 15-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-11_Q’P
SPACE FOR ROUGH WORK

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SPACE FOR ROUGH WORK

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