25.09.22 - SR - STAR CO-SC (MODEL-A&B) - Jee - Adv - 2020 - P1 - PTA-2 - QP

Sec: SR.
IIT_*CO-SC(MODEL-A&B) Date: 25-09-22

Time: 3HRS Max. Marks: 198
Name of the Student: ___________________ H.T. NO:
25-09-22_SR.STAR CO-SUPERCHAINA(MODEL-A&B)_JEE-ADV_PTA-2_SYLLABUS
PHYSICS: Friction: Static and dynamic friction
Circular motion + Work power energy: Uniform circular motion,
Kinetic and potential energy; Work and power; mechanical energy.
CHEMISTRY: GOC: aromaticity; Hydrogen bonding effects; Inductive, Resonance and

Hyper conjugative effects; Acidity and basicity of organic compounds;
Reactive intermediates produced during homolytic and heterolytic bond
cleavage; Formation, structure and stability of carbocations, carbanions
and free radicals. Tautomerism
MATHEMATICS: Continuity, Differentiability Derivatives :Continuity Of Composite

Functions, Intermediate Value Property Of Continuous Functions,
Derivative of a function, derivative of the sum, difference, product and
quotient of two functions, chain rule, derivatives of polynomial,
rational, trigonometric, inverse trigonometric, exponential and
logarithmic functions. derivatives of implicit functions, derivatives
up to order two
Narayana IIT Academy 25-09-22_SR.IIT_*CO-SC(MODEL-A&B )_JEE-Adv_PTA-2_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -1 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -1 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
SR.IIT_*CO-SC Page. No. 2

PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. A body is moved along a straight line by a machine delivering constant power. The
distance moved by the body in time t is proportional to
A) t1/2 B) t3/4 C) t3/2 D) t2
2. A particle A moves along a circle of radius R = 50 cm so that its radius vector r relative
to the point O (figure) rotates with the constant angular velocity  = 0.40 rad/s. Then
modulus of the velocity of the particle, and the modulus of its total acceleration will be
A) v = 0.4 m/s, a = 0.4 m/s2 B) v = 0.32 m/s, a = 0.32 m/s2
C) v = 0.32 m/s, a = 0.4 m/s2 D) v = 0.4 m/s, a = 0.32 m/s2
3. ABCD is a smooth horizontal fixed plane on which mass m1 = 0.1 kg is moving in a

circular path of radius 1 m. It is connected by an ideal string which is passing through a
1
smooth hole and connects mass m2 = kg at the other end as shown. m2 also moves in a
2
horizontal circle of same radius of 1 m with a speed of 10 m/s. If g = 10 m/s2, then the
speed of m1 is
A B
m1
D C
m2
A) 10 m/s B) 10 m/s C) 1
m/s D) None of these
10

4. A particle of mass m is fixed to one end of a light spring of force constant k and
unstretched length . The system is rotated about the other end of the spring with an
angular velocity , in gravity free space. The increase in length of the spring in steady
state will be

k m
m 2  m 2  m 2 
A) B) C) D) None of these
k k  m 2
k  m 2
5. Starting from rest. A flat car is given a constant acceleration a0 = 2 m/s2. A cable is
connected to a crate A of mass 50 kg as shown. Neglect the friction between floor and
car wheels and mass of pulley. Calculate corresponding tension in the cable. The
coefficient of friction between crate & floor the car is  = 0.3. The tension in cable is
a0
A) 700 N B) 350 N C) 175 N D) 0
6. In the arrangement shown in the figure mass of the block B and A are 2m and 8m
respectively. Surface between B and floor is smooth. The block B is connected to block
C by means of a pulley. If a whole system is released then the minimum value of mass
of the block C so that the block A remains stationary with respect to B is
(Co-efficient of friction between A and B is µ)
A) m
B) 2m
C) 10m
D) 10m
  1 1  (  1)

SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. In the arrangement shown in figure pulley is smooth and mass less and string is light.
Friction coefficient between A and B is µ. Friction is absent between A and plane.
Select the correct alternative(s)
B
A
 Fixed
A) acceleration of the system is zero if µ  (m B  m A ) tan  and mB> mA

2m B
B) force of friction between A and B is zero if mA = mB

C) B moves upwards if mA <mB
D) tension in the string is mg(sin  – µ cos) if mA = mB = m
8. On a train moving along east with a constant speed v, a boy revolves a bob with string of
length  on smooth horizontal surface of the train, with equal constant speed ‘v’ relative
to the train. Mark the correct option (s)
A) Maximum speed of bob is 2v in ground frame

4mv 2
B) Tension in string connecting bob is at an instant

mv 2
C) Tension in string is at all the moments

D) Minimum speed of bob is zero in ground frame

9. A particle of mass m is released from height h on a smooth curved surface which ends
into a vertical loop of radius r as shown. If h0 = 2r then,
m u=0
r
h0 O

A) The particle reaches the top of the loop with zero velocity
B) The particle cannot reach the top of the loop
C) The particle breaks off at a height h = r from base
D) The particle breaks off at a height r < h < 2r
10. A body is moving with constant velocity on the path shown.
Vertical plane
A C
B D
A) Normal reaction exerted on body by path is greatest at NB

B) Normal reaction exerted on body by path is least at NC
C) Normal fore is greater than weight at B
D) Normal force is lesser than weight at A, D
11. Figure shows net interaction force between two particles A and B against the distance
between them, when the distance between them varies from x1 to x4 ? Then
Attraction
x1
O
x2 x3 x4
Repulsion
A) potential energy of the system increases from x1 and x2

B) potential energy of the system increases from x2 and x3
C) potential energy of the system increases from x3 and x4
D) kinetic energy increases from x1 to x2 and decreases from x2 to x3if system is moving
due to interaction force only

12. A man pushes a block of 30 kg along a level floor at constant speed with a force directed
at 45º below the horizontal. If the coefficient of friction is 0.20, then
A) net force on the block is zero
B) work done by the man on the block in pushing it through 10 m is 750 J
C) work done by the force of gravity is zero
D)work done by all the forces exerted by the surface on the block in 20 metres is -1500 J
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. A block of mass m = 1kg moving on horizontal surface with speed u = 2m/s enters a
rough horizontal patch ranging from x = 0.10 m to x = 2.00m. If the retarding force fr on
the block in this range is inversely proportional to x over this range i.e.
k
fr = 0.10 < x < 2.00
x
=0 for x < 0.10 and x > 2.00

If k = 0.5 J then the speed of this block as it crosses the patch (use n 20 = 3) (in m/s) is
14. A force shown in the F – x graph is applied to a 5 kg cart, which then coast up a ramp as
shown. Calculate the maximum height ,ymax, at which cart can reach? (g = 10 m/s2)
F(N)
50
ymax
F
1 2 3 4 5 x(m) x=1 5m
15. A small bead of mass m can move on a smooth circular wire (radius R) under the action
Km
of a force F = directed (r = distance of bead from P & K = constant) towards a point
r2
P within the circle at a distance R/2 from the centre. What should be the minimum
velocity (in m/s) of bead at the point of the wire nearest the centre of force (P) so that
k
bead will complete the circle (Take = 8 unit)
3R
F
O P
R R/2

16. A small particle initially at point p starts moving from rest. The whole space where
particle will move is divided into three regions as shown in figure. In region (i) particle
accelerates through (5 m/s2) where direction of acceleration is along the normal of the
screen while in region (ii) the acceleration acts in such a way that it is always
perpendicular to the direction of motion resulting the particle to move on a circular track
20
having radius m. There is uniform acceleration in region (iii) in such a manner that
3
velocity of particle become thrice (without change in direction) when it just reaches the
screen. Find the average speed of a particle (in m/s)
17. Two blocks of mass 2 kg and 4 kg are connected through a massless inextensible string.
Coefficient of friction between 2 kg block and ground is 0.4 and between 4 kg block and
ground is 0.6. Two forces F1 = 10 N and F2 = 20 N are applied on the block as shown in
figure with F1 applied first. Friction force (in N )acting on 4 kg block minus 10 N is
10 N 2 kg 4 kg 20 N
 = 0.4  = 0.6
18. Two blocks 1 and 2 of mass 2kg and 4kg are kept over a frictionless inclined surface
(angle of inclination = 30º). Coefficient of friction between two blocks is µ = 0.2.
Friction force on block 1 is equal to (in Newton)
30º

CHEMISTRY MAX.MARKS: 66
19. Compare the bond energy of different C – H bonds shown in the following molecule:
A) a > b > c > d > e B) c > e > b > a > d
C) c > b > e > a > d D) a > c > b > e > d
20. The CORRECT statement of the following structures is
A) 1, 2 and 3 are resonance structures
B) 1 and 2 are resonance structures, whereas 3 is an isomer of 1 and 2
C) 1 and 3 are resonance structures, whereas 3 is an isomer of 1 and 3
D) 1, 2 and 3 are constitutional isomers

21. The CORRECT projection of given structure [Q] is/are
A) B) C) D)
22. Compare acidic strength among the given compounds.
A) I > II B) II > I C) I = II D) Cannot be compared

23. The correct stability order of the following resonance structure is
A) I > II > III > IV B) I > III > II > IV C) II > I > III > IV D) III > I > IV > II
24. The IUPAC name of compound
A) 1, 2, 3 – tricarboxypropan – 2 – ol
B) 2 – hydroxypropane – 1, 2, 3, - tricarboxylicacid
C) 3 – hydroxyl – 3 – carboxypent – 1, 5 – dioic acid
D) none of the above

correct options.
option.
25. Which order regarding basicity is/are correct?
A) B)
C) D)
26. CORRECT statement(s) regarding given compounds is/are –
A) Basic strength order is I > II > III
B) In compound (I) y is more basic than (x)
C) In compounds (I) two lone pair, in compound II & III one lone pair are delocalized.
D) In compounds (I) & (III) one lone pair is delocalized.

27. Which of the following is CORRECT?
A)
B)
C)
D)
28. Consider the following four compounds I, II, III and IV:
Choose the CORRECT statement (s):
A) The order of acidity is II > IV > I > III.
B) The magnitude of pKa difference between I and II is more than that between III and
IV.
C) Intra H – bonding is more in IV than in III.
D) Intra H – Bonding makes compound II most acidic among all.

29. Select the correct statement/s
A) Tautomerism is an Intramolecular Acid – base reaction
B) has more enol content than the its keto content.

C) Cyclohexanone has more enol content than the cyclobutanone
D) has more stable enol form than its keto form
30. Identify the INCORRECT relation to the bond length of the following molecule
a  C1  C 2 b  C 2  C3 c  C3  C 6
(where a, b and c represents bond lengths)

A) b > c > a B) c > b > a C) b > a > c D) c > a > b
31. X is the number of below compounds which are more basic than aniline?
O – toluidine, o – anisidine, p – anisidine, p – chloroaniline, m – toluidine
CH 3CONH 2
Y is the number of below compounds which are more acidic than benzoic acid
Picric acid, 2, 4 – dinitro phenol

The value of (X/Y) is….

32. Among the following, the number of molecules that are aromatic is _______.
33. How many out of the given stereo isomers of pentane 2, 3, 4 – triol show optical
isomerism?
34. How many Hydrogen atom are replaced by D in the following Tantomerization
35. How many total number of structural Isomers are possible for C4 H 7 Cl having parent
chain of four Carbon?
36. How many diastero isomers are possible for the given molecules?

MATHEMATICS MAX.MARKS: 66
37. If f : R  R is a continuous function satisfying f  0   1 and f  2 x   f  x   x x  R and
  x 
lim
x   f  x  f  n    P  x  then P  x  is
  2 
A) A constant function B) A linear polynomial in x
C) A quadratic polynomial in x D) A cubic polynomial in x
38. Let the functions f :  1,1  R and g :  1,1  be defined as f  x   3x  2  3x  2 and

g  x   x   x  (where  x  denotes greatest integer less than or equal to x ). Let fog :
 1,1  R be the composite function defined by  fog  x   f  g  x   . Suppose c is the

number of points in the interval  1,1 at which fog is NOT continuous and suppose d is
the number of points in the interval  1,1 at which fog is NOT differentiable, then
A) c = 0 B) c = 2 C) d = 3 D) d = 2
39. Let f  x, y   ax 2  2hxy  by 2  2 gx  2 fy  c such that abc  2 fgh  af 2  bg 2  ch 2  0 and
dy dy dy
h 2  ab . If f  2,3  f  1, 4   f  7, 12   f  0, 0   0 and  , then is equal
dx  2,3 dx  7, 12  dx  0,0 
to
1
A) 2 B)  C) – 4 D) 4
4
40. Let f :[0, )  [2, ) be a derivable function which is also surjective such that f  0   2 and
satisfying f 2  x   f 2  y   3 f  x   3 f  y   x  y . If g is the inverse function of f then
d  4 
  at x  3 is equal to
dx  g  x  
A) – 6 B) – 3 C) 3 D) 6

41. Let f  x   x  1  1 and g  x   max f  t  ; x  t  x  1, x  R . The number of points of non-
differentiability of g  x  is
A) 7 B) 8 C) 9 D) 5
42. Let f  x  
 x   1 , for  5 1 
f : 0,    ,3 , (where  x  and  x are integral and fractional part
 x  1  2 2 
of x ,) then which of the these are true
A) f  x  is injective continuous function
B) f  x  is non bijective and non-differentiable function
C) min  lim
x 1
f  x  ,lim

x 1
f  x    f 1

D) f  x  is bijective

correct options.
option.
43. Which of the following statements are INCORRECT? (where 
. denotes the fractional
part of function)
 2x 1  
A) f  x    x cos 2      is differentiable for all x  R
 2  
B) f  x   sin x cos 1  cos x  is differentiable x   0, 2 
C) f  x   x  2  x  6 3 x  2 x  1 is not differentiable at 3 points
D) f  x    x sin  x is not differentiable at all integers

44. f , g , h : R  R, f  x  , g  x  , h  x  are all continuous, differentiable functions which satisfy the
relation f  x  y   g  x   h  y  for all x, y  R
A) f   0   f  1 B) g   x   h  x   1
C) h  x   g  x  x  R  0 if h  0   g  0  D) f  0   g  0   h  0 
2 x ; x  3
45. If f  x   2 x  1  x  1  3 x  2  2 x  1 and h  x    , then choose the correct
1 ; x3
statements
A) y  h  f  x   is continuous x  R
B) y  h  f  x   is discontinuous at 3 points
C) y  h  f  x   is not differentiable at 3 points
D) y  h  f  x   is not differentiable at 4 points
 x 2  2 x  3 ; x   2, 0 
46. Let f  x    x3  x 2  2 ; x   0, 2 , then
 3  2x ; x  (2, 6]

A) f  f  x   is discontinuous at 4 points B) f  f  x   is discontinuous at 3 points
C) f  f  0    1 D) f  f  2    9
47. Let f :   ,1   , n 2  be a function defined as f  x   n x  1  x 2 and



2 
1 
 
x2
g  x  . If f  x0   n 2 , then
f  x
A) f  x0   n 2, then B) g  x0   log 2 e
C) g   x0   2 2 log 2 e D) g   x0   2 log e 2
(where g   x0  denotes
d
dx
 g  x   at x  x0 )

48. For the function f :  0,1  R, f  x    2n x   2m x ,  n, m  N , n  m  , the number of points of
discontinuity of the function can be (where  x  ,  x represent G.I.F. and fractional part
respectively)
A) 24 B) 28 C) 26 D) 496

h 1  x   h 1 1
49. If f  x   x  1, g  x   x  x  1 and g  f  x    h  x  , then
1 3 lim
x 1 is equal to____
x 1
Let f :  0,     0,   be a differentiable function such that f    

a x
50. where a is
 x  f  x
positive constant and f  1  1, f   2   2, then f  5 is equal to
51. Let f  x  be a differentiable function with f   0   2 and f  0   3 such that

f  x  n  f  x f  5
f  x  x  R and n  N , then is
n f 1
52. For the function f  x   lim

 
ln 1  9 x 2   9n x 2 n cos  9 x 2 
number of points of discontinuity
n 
1  9n x 2 n
in  3,3 is (where . denotes G.I.F)
53. Let f  x  be a differentiable function such that f   x   f  x   4 xe x sin 2x and f  0   0 . If

7
  4n  1    4  e  k  1 
 f   e    , then k is equal to
n 0  4   e 1 
54. Let f : R  R be a continuous function and f   x   g  x  and f  0   1, g  x  is defined as
1, x  (0,1] f 3 x

g  ln x    , then lim
is equal to
 x; x  1,   f  x
x 

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Sec: SR.

IIT_*CO-SC(MODEL-A&B) Date: 25-09-22

Name of the Student: ___________________ H.T. NO:

CHEMISTRY: GOC: aromaticity; Hydrogen bonding effects; Inductive, Resonance and

MATHEMATICS: Continuity, Differentiability Derivatives :Continuity Of Composite

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A) t1/2 B) t3/4 C) t3/2 D) t2

A) v = 0.4 m/s, a = 0.4 m/s2 B) v = 0.32 m/s, a = 0.32 m/s2

C) v = 0.32 m/s, a = 0.4 m/s2 D) v = 0.4 m/s, a = 0.32 m/s2

3. ABCD is a smooth horizontal fixed plane on which mass m1 = 0.1 kg is moving in a

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A) 700 N B) 350 N C) 175 N D) 0

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A) acceleration of the system is zero if µ  (m B  m A ) tan  and mB> mA

B) force of friction between A and B is zero if mA = mB

A) Maximum speed of bob is 2v in ground frame

D) Minimum speed of bob is zero in ground frame

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A) Normal reaction exerted on body by path is greatest at NB

A) potential energy of the system increases from x1 and x2

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=0 for x < 0.10 and x > 2.00

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A) a > b > c > d > e B) c > e > b > a > d

C) c > b > e > a > d D) a > c > b > e > d

20. The CORRECT statement of the following structures is

A) 1, 2 and 3 are resonance structures

B) 1 and 2 are resonance structures, whereas 3 is an isomer of 1 and 2

C) 1 and 3 are resonance structures, whereas 3 is an isomer of 1 and 3

D) 1, 2 and 3 are constitutional isomers

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A) I > II B) II > I C) I = II D) Cannot be compared

24. The IUPAC name of compound

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26. CORRECT statement(s) regarding given compounds is/are –

A) Basic strength order is I > II > III

B) In compound (I) y is more basic than (x)

D) In compounds (I) & (III) one lone pair is delocalized.

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Choose the CORRECT statement (s):

A) The order of acidity is II > IV > I > III.

C) Intra H – bonding is more in IV than in III.

D) Intra H – Bonding makes compound II most acidic among all.

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B) has more enol content than the its keto content.

(where a, b and c represents bond lengths)

Picric acid, 2, 4 – dinitro phenol

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A) A constant function B) A linear polynomial in x

C) A quadratic polynomial in x D) A cubic polynomial in x

38. Let the functions f :  1,1  R and g :  1,1  be defined as f  x   3x  2  3x  2 and

 1,1  R be the composite function defined by  fog  x   f  g  x   . Suppose c is the

39. Let f  x, y   ax 2  2hxy  by 2  2 gx  2 fy  c such that abc  2 fgh  af 2  bg 2  ch 2  0 and

satisfying f 2  x   f 2  y   3 f  x   3 f  y   x  y . If g is the inverse function of f then

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of x ,) then which of the these are true

A) f  x  is injective continuous function

B) f  x  is non bijective and non-differentiable function

SECTION - 2 (Maximum Marks : 24)

B) f  x   sin x cos 1  cos x  is differentiable x   0, 2 