03-07-23 Cluster-299 Phase-II (X) Jee Adv 2019 (P-II) Rat-5 QP Star-A

Sec: CLUSTER-2@99_PHASE-II(X) RAT-5(PAPER-A*) Date: 03-07-23
Time: 3 Hrs Max. Marks: 186

03-07-23_ CLUSTER-2@99_PHASE-II(X)_JEE ADV_RAT-5_SYLLABUS
PHYSICS: PRESENTWEEK (60%): COLLISIONS: 2D collisions, variable mass

system, impulsive tension
PREVIOUS WEEK (20%): WORK AND ENERGY: Miscellaneous
problems on work power energy, vertical circular motion, analysis on
multiple particle system in c-frame
CUMULATIVE (20%): SYLLABUS COVERED FROM 08.05.23 TO 30.06.23
CHEMISTRY: PRESENTWEEK (60%): GOC-1: Inductive effect(without applications),

resonance, mesomeric effect (without applications), hyper
conjugation(without applications)
PREVIOUS WEEK (20%): OPTICAL ISOMERISM: enantiomers,
diastereomers, racemic mixture, meso compounds, resolution chemical
methods, properties of enantiomers and diastereomers, relative
configuration, threo - erythro configuration, absolute configuration,
absolute configuration, basic introduction for anomers and epimers,
calculation of no.of stereo isomers
MATHEMATICS: PRESENTWEEK (60%): Onto, into, one-one, many-one functions, Range

of a function (avoid use of differentiation )
PREVIOUS WEEK (20%): FUNCTIONS-I : Real valued function of a real
variable & their Domains, Sum, difference, product and quotient of two
functions, Odd / even / periodic functions
Narayana IIT Academy 03-07-23_ CLUSTER-2@99_PHASE-II(X)_JEE ADV_RAT-5_QP
TIME:3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 1 – 8) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 9 – 14) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Matrix Matching Type
Sec – III (Q.N : 15 – 18) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
CHEMISTRY
Sec – I (Q.N : 19 – 26) +4 -1 8 32
Sec – II (Q.N : 27 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Sec – III (Q.N : 33 – 36) +3 -1 4 12
(Each match consist of 2 questions)
Total 18 62
MATHEMATICS
Sec – I (Q.N : 37 – 44) +4 -1 8 32
Sec – II (Q.N : 45 – 50) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Sec – III (Q.N : 51 – 54) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
CLUSTER-2@99_PHASE-II(X) Page. No. 2

PHYSICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
1. In a one dimensional collision between two identical particles A and B, B is stationary
and A has momentum p before impact. During impact, B gives impulse J to A.
A) The total momentum of the ‘A plus B’ system is p before and after the impact, and
(p-J) during the impact.
B) During the impact A gives impulse of magnitude J to B
2J
C) The coefficient of restitution is 1
p
J
D) The coefficient of restitution is 1
p
2. A particle is given a velocity at the bottom most position in a smooth spherical shell of
radius 2m. It just complete a vertical circular motion. Then
A) Acceleration of particle when the velocity of the particle is in
vertically upward direction is g 10
B) Acceleration of particle when the velocity of the particle is in
vertically downward direction is g 10
C) Acceleration of the particle at the top most point of path is g
D) Acceleration of the particle at the bottom most point is 5 g
3. A fan and a sail are mounted vertically on a cart that is initially at rest on a horizontal
table as shown in the diagram. When the fan is turned on, an air stream is blown towards
the night and is incident on the sail. The cart is free to move with negligible resistance
forces. After the fan has been turned on the cart will
A) move to the right and then to the left B) remain at rest

C) move towards the right D) move towards the left

4. Two particles A and B of mass 2m and m respectively are attached to the ends of a light
inextensible string of length 4a which passes over a small smooth peg at a height 3a
from an inelastic table. The system is released from rest with each particle at a height a
from the table.
2ag
A) The speed of B when A strikes the table is
3
3v
B) The time that clapses before A first hits the table is Let v is the speed of B when
g
A strikes the table
C) The time for which A is resting on the table after the first collision & before it is
3v
first jerked off is Let v is the speed of B when A strikes the table
g
2ag
D) The speed of A when A strikes the table is
3
5. A block is kept on a rough surface and applied with a horizontal force as shown which is
gradually increasing from zero. The coefficient of static and kinetic friction are 1/ 3
then
A) When F is less than the limiting friction, angle made by net force on the block by the
surface is less than 30° with vertical.
B) When the block is just about to move, the angle made by net force by the surface on
the block becomes equal to 30" with vertical,
C) When the block starts to accelerate. the angle made by net force by the surface on the
block becomes constant and equal to 30° vertical
D) The angle made by net force with vertical on the block by the surface, depends
on the mass of the block when F is less than the limiting friction.

6. A particle is shifted from A to B and then from B to C where A, B and C are the
 
midpoints of the corresponding faces of a cube of side 2m. If a force F  3i  4 j  5k N is
continuously acting on the particle, then select correct alternative:-
A) Work done from A to B is 7 J B) Work done from B to C is 1 J

C) Work done A to C is 8 J D) F is a conservative force
7. A ball of mass m collides horizontally with a stationary wedge on a rough horizontal
surface, in the two orientations as shown Neglect friction between ball and wedge. Two
student comment on system of ball and wedge in these situations Saurav: Momentum of
system in x-direction will change by significant amount in both cases. Rahul: There are
no impulsive external forces in y-direction in both cases hence the total momentum of
system in y-direction can be treated as conserved in both cases.
A) Saurav is wrong B) Saurav is correct

C) Rahul is correct D) Rahul is wrong
8. A blast breaks a body initially at rest of mass 0.5 kg into three pieces, two smaller pieces
of equal mass and the third double the mass of either of small piece. After the blast the
two smaller masses move at right angles to one another with equal speed. Find the
statements that is/are true for this case assuming that the energy of blast is totally
transferred to masses.
A) All the three pieces share the energy of blast equally
B) The speed of bigger mass is 2 times the speed of either of the smaller mass
C) The direction of motion of bigger mass makes an angle of 1350 with the direction of
smaller pieces
D)The bigger piece carries double the energy of either piece.

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
9. Two smooth balls A and B, each of mass m and radius R. have their centres at (0.0.R)
and at (5R.-R.R) respectively, in a coordinate system as shown. Ball A. moving along
positive x axis, collides with ball B. Just before the collision, speed of ball A is 4 m/s
and ball B is stationary. The collision between the balls is elastic. Impulse of the force
exerted by A on B during the collision is x m Find x.
10. Two particles, each of mass m, are connected by a light inextensible string of length 2l .
Initially they lic on a smooth horizontal table at points A and B l distant apart. The
particle at A is projected across the table with velocity u. the speed with which the
second particle begins to move if the direction of u is at an angle of 120° with AB, is
u x
. Find x
8
11. Two balls of masses 1 kg each are connected by an inextensible massless string The
system is resting on a smooth horizontal surface. An impulse of 10 Ns is applied to one
of the balls at an angle 30° with the line joining two balls in horizontal direction as
shown in the figure. Assuming that the string remains taut after the impulse, the
x
magnitude of impulse of tension is Ns .Find x
2

12. A force exerts an impulse I on a particle changing its speed from u to 2u. The applied
force and the initial velocity are oppositely directed along the same line. The work done
2Iu
by the force is . Find x
x
13. On a smooth carom board, a coin moving in negative y direction with a speed of 3 m/s is
being hit at the point (4, 6) by a striker moving along negative x-axis. The line joining
centres of the coin and the striker just before the collision is parallel to x-axis. After
collision the coin goes into the hole located at the origin. Masses of the striker and the
coin are equal. Considering the collision to be clastic, the initial speeds of the striker in
m/s will be
14. An open water tight railway wagon of mass 5 103 kg coasts at an initial velocity 1.2 m/s
without friction on a railway track. Rain drops fall vertically downwards into the wagon.
The velocity of the wagon after it has collected 103 kg of water will be ______ m/s.
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.15 and Q.16 by appropriately matching the lists based on the information
given in the paragraph.
In column-ll different situations are shown in which one object collides with the another
object. In each case friction is absent and neglect effect of non-impulsive forces. In
column-l different direction are given. You have to match the directions for each case in
which momentum conservation can be applied on object A or object B or system A & B.
(Assume that objects do not bounce off the ground)

List – I List – II
A) Along the line of impact P)
B) Perpendicular to line of impact Q)
C) In horizontal direction R)
D) In vertical direction S)
T)
15. Which of the following is correct
A) P-will be match 1,2,3,4 B) Q-will be match 1,2,3,4
C) P-will be match 1,2,3 D) Q-will be match 2,3,4
A) R-will be match 1,2,3,4 B) S-will be match 1,2,3,4
C) T-will be match 1,2,3,4 D) None of these

given in the paragraph
Four balls A,B,C and D are kept on a smooth horizontal surface as shown in figure. Ball
A is given velocity u towards B-(Assume each collision to be elastic)
4mu
A) Total impulse of all collisions on A P)
9
4mu
B) Total impulse of all collisions on B Q)
27
4mu
C) Total impulse of all collision on C R)
3
52
D) Total impulse of all collisions on D S) mu
27
A) 1will be match with R B) 1 will be match with Q
C) 2 will be match with Q D) 2 will be match with P
A) 3 will be match with S B) 3 will be match with P
C) 4 will be match with S D) 4 will be match with Q

CHEMISTRY Max.Marks:62
SECTION – I
19. Which of the following compounds cannot show hyper conjugation?
CCl3
A) B) C) O D)
20. Which of the following statement is/are correct
A) the resonance energy of hybrid structure is always less than that of any resonance
structure
B) the resonance structure are hypothetical structures and they do not represent any real
molecule
C) kekules structure have large contribution than Dewar’s structure in hybrid structure
of benzene
D) In delocalised structure of benzene the pie-charge cloud is spread equally above and
below the plane of molecule
21. Identify the correct statements about inductive effect
A) Increases as a distance from the source increases
B) It is permanent effect
C) it implies the transfer of lone pair of electrons from less electronegative atom to more
electronegative atom
D) Property of sigma bond

22. Resonance energy will be more if :
A) Canonical structures are equivalent than if canonical structures are non – equivalent
B) Molecule is aromatic than if molecule is not aromatic.
C) Dancing resonance is responsible for stability of tricycle propyl methyl carbocation.
D) Resonance with 2p-2p overlapping than resonance with 3p-2p overlapping.
23. Which of the structure is/are diastereomer of X?
(X)
A) B) C) D)
24. Which of the following statements would be false about this compound :
A) All three C – N bonds are of same length.

B) Cl-N and C3-N bonds are of same length but shorter than C5-N bond
C) Cl-N and C3-N bonds are of same length but longer than C5-N bond
D) Cl-N and C3-N bonds are of different length but both longer than C5-N bond
25. In which of the following molecules  -electron density in ring is maximum than ‘A’
A) B) C) D)
26. In which of the following molecules resonance takes place though out the entire system
except
A) B) C) D)
SECTION – II
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
27. The number of resonance structure for N is :
28. The number of geometrical isomers for molecule x is A, number of optically active
isomers for x is B, the number of stereo isomers for x is C then A+B-C = ?
(X)
29. The total number of contributing structures showing hyper conjugation (involving C – H
bonds) for the following carbocation is …………….
30. Number of hyperconjugatin structure in given compound are:
31. X = number of Resonance structure contributed in Resonance Hybrid of
Y = number of Resonance Structure contributed in Resonance Hybrid of
Find the sum of X + Y

32. Number of C-atoms where + charge is delocalized in its resonance hybrid.
SECTION-III
I) Group donate e inductively but does not donate / P) -OH

withdraw by resonance
II) Group withdraw e inductively but does not donate / Q)  NO2
withdraw by resonance
III) Group withdraw e inductively & withdraw e by R) CH 2  CH 3
resonance
IV) Group withdraw e inductively & withdraw e by S) 

 N H3
resonance
T)  NH 2
33. Which of the following options has correct combination considering List I and List II?
A) I – R, II – T B) III – P, IV – P
C) I-R, II – S D) III – Q, IV – T
A) I – R, II – PT B) II – S, III – PT
C) I-R, II – S D) III – Q, IV – T

I) P) Identical
II) Q) Enantiomer
III) R) Diastereomer
Structural
IV) S)
Isomerism
A) I – S, IV – R B) II – P, III – R
C) I-R, IV – S D) II – P, III – S
A) I – S, IV – R B) II – P, III – R
C) II-R, III – P D) II – P, III - S

MATHEMATICS Max.Marks:62
SECTION – I
37. Let f  x   sin6 x  cos6 x, then-
A) f  x    ,1 x 
1
B) f  x   0 has no solution
2 
C) f  x    ,1 x 
1
D) f  x  is an injective function
4 
38. The range of the function f  x   cos  x , for  / 2  x   / 2 , contains which of the
following numbers?
A) 0 B) 1 C) cos1 D) cos 2
3  2x
39. Let f : R  R be defined by f  x    x and g  x   then
4
A) f is neither one-one nor onto B) g is one-one and onto
C) f is one-one and g is onto D) neither f nor g is onto
40. The function f : R  R, defined as f  x    x 2  x  21 x 2  x  39  . Which of the following is
(are) correct?
A) Neither injective nor surjective
B) Minimum value of f  x  is -81
C) f  x   0 has 4 real and distinct roots
D) f  x  is an even function.
41. Let f : R  R be defined as f  x   3 x  3x  sgn  e x   2 (where sgn x denotes signum
function of x). Then which of the following is/are correct?
A) f is one-one B) f is not one-one
C) f is onto D) f is not onto

 x  3x  4: x  3
2
x  6 :x4
42. Let f  x    and g  x   2 , then which of the following is/are
 x  7 :x  3 x  x  2 : x  4
true-
A)  f  g 1  9 B)  f  g 3.5  1
f  8
C)  f g  0  24 D)    5 
g 3
2
43. If  x  &  x   x  [ x  {x  .......100 times]}  5, then (where [.] & {.} denotes greatest
3
integer function & fractional part function respectively)
B)  x  5 D)  x  4
14 17
A) x  C) x 
3 3
1 a a2
44. cos  xz  yz  cos xz cos  xz  yz  depends on which of the following parameters?
sin  xz  yz  sin xz sin  xz  yz 
A) x B) y C) z D) a
SECTION – II
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
45. Let d be the number of integers in the range of the function
4, if  4  x  2

f  x    x , if  2  x  7 . Also roots of P  x   x2  mx  4m  20 are  and  . If

 x , if 7  x  14
d 3 d 3
    and the smallest integral value of m is k,
4 2
then find the value of (k – 5).

46. If f :[2, )  [8, ) is a surjective function defined by
f  x   x2   p  2 x  3 p  2, p  R then sum of values of p is m  n , where m, n  N . Find
n
the value of .
m

3x  mx  n
2
47. f : R  R, f  x   . If the range of this function is [4,3) then find the value of
x2  1
m2  n2 .
48. If A and B are two distinct matrices such that A3  B3 and A2 B  B2 A, then det  A2  B 2  is
The sum of all the integral roots of  log5 x   log 5 x  5 / x   1 is

2
49.
50. The smallest value of k for which both the roots of the equation
x 2  8kx  16  k 2  k  1  0 are real and distinct and have least value 4, is
SECTION-III
 1 1 4 4
f  ,    , 
 2 2 7 3
A) P) Injective mapping
1
f  x  2
x  x 1
f :  2, 2   1,1
B) Q) Non-injective mapping
f  x   sin x
f :RZ  R
C) f  x   ln x (where {.} represents R) Surjective mapping
fractional part function)
S) Non-surjective mapping
T) Bijective mapping
51. Which of the following is the correct option?
A) A-PS B) B-PT C) C-QS D) C-PR
A) A-PQR B) B-QR C) C-PRT D) B-PS

List – I (Number of integers in) List – II
A) Domain of f  x   ln x P) 0
Domain of
B) Q) 2
 1
f  x   sec  sin x    x    10   x 
2
 x
C) Range of f  x   x  2x  2, x 0, 2
2
R) 3
D) Range of f  x   25   x2 S) Less than 3
T) More than 3
(where [.] and {.} denote greatest integer function and fractional part function
respectively)
A) A-PR B) B-QS C) C-T D) D-T
A) Q-R 2) B-T 3) C-QS 4) D-R

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Sec: CLUSTER-2@99_PHASE-II(X) RAT-5(PAPER-A*) Date: 03-07-23

Time: 3 Hrs Max. Marks: 186

PHYSICS: PRESENTWEEK (60%): COLLISIONS: 2D collisions, variable mass

CHEMISTRY: PRESENTWEEK (60%): GOC-1: Inductive effect(without applications),

MATHEMATICS: PRESENTWEEK (60%): Onto, into, one-one, many-one functions, Range

CLUSTER-2@99_PHASE-II(X) Page. No. 2

A) move to the right and then to the left B) remain at rest

CLUSTER-2@99_PHASE-II(X) Page. No. 3

CLUSTER-2@99_PHASE-II(X) Page. No. 4

A) Work done from A to B is 7 J B) Work done from B to C is 1 J

A) Saurav is wrong B) Saurav is correct

CLUSTER-2@99_PHASE-II(X) Page. No. 5

CLUSTER-2@99_PHASE-II(X) Page. No. 6

CLUSTER-2@99_PHASE-II(X) Page. No. 7

A) Along the line of impact P)

B) Perpendicular to line of impact Q)

15. Which of the following is correct

A) P-will be match 1,2,3,4 B) Q-will be match 1,2,3,4

C) P-will be match 1,2,3 D) Q-will be match 2,3,4

16. Which of the following is correct

A) R-will be match 1,2,3,4 B) S-will be match 1,2,3,4

C) T-will be match 1,2,3,4 D) None of these

CLUSTER-2@99_PHASE-II(X) Page. No. 8

17. Which of the following is correct

A) 1will be match with R B) 1 will be match with Q

C) 2 will be match with Q D) 2 will be match with P

18. Which of the following is correct

A) 3 will be match with S B) 3 will be match with P

C) 4 will be match with S D) 4 will be match with Q

CLUSTER-2@99_PHASE-II(X) Page. No. 9

20. Which of the following statement is/are correct

21. Identify the correct statements about inductive effect

A) Increases as a distance from the source increases

D) Property of sigma bond

CLUSTER-2@99_PHASE-II(X) Page. No. 10

A) All three C – N bonds are of same length.

30. Number of hyperconjugatin structure in given compound are:

31. X = number of Resonance structure contributed in Resonance Hybrid of

Y = number of Resonance Structure contributed in Resonance Hybrid of

Find the sum of X + Y

CLUSTER-2@99_PHASE-II(X) Page. No. 12

I) Group donate e inductively but does not donate / P) -OH

II) Group withdraw e inductively but does not donate / Q)  NO2

III) Group withdraw e inductively & withdraw e by R) CH 2  CH 3

IV) Group withdraw e inductively & withdraw e by S) 

CLUSTER-2@99_PHASE-II(X) Page. No. 13

C) II-R, III – P D) II – P, III - S

CLUSTER-2@99_PHASE-II(X) Page. No. 14

A) f is neither one-one nor onto B) g is one-one and onto

C) f is one-one and g is onto D) neither f nor g is onto

40. The function f : R  R, defined as f  x    x 2  x  21 x 2  x  39  . Which of the following is

A) Neither injective nor surjective

B) Minimum value of f  x  is -81

C) f  x   0 has 4 real and distinct roots

41. Let f : R  R be defined as f  x   3 x  3x  sgn  e x   2 (where sgn x denotes signum

function of x). Then which of the following is/are correct?

A) f is one-one B) f is not one-one

C) f is onto D) f is not onto

CLUSTER-2@99_PHASE-II(X) Page. No. 15

then find the value of (k – 5).

CLUSTER-2@99_PHASE-II(X) Page. No. 16

The sum of all the integral roots of  log5 x   log 5 x  5 / x   1 is

x 2  8kx  16  k 2  k  1  0 are real and distinct and have least value 4, is