30-10-23 - SR - Iit - Star Co-Sc (Model-A&b) - Jee Adv - Pta-12 - Syllabus

SEC: SR_*CO-SC(MODEL-A,B&C) Date: 30-10-23
Time: 3 Hrs Max. Marks: 180

30-10-23_SR.IIT_STAR CO-SC(MODEL-A&B) _JEE ADV_PTA-12_SYLLABUS
MATHEMATICS: PRESENTWEEK (100%): Application of Derivatives: geometrical
interpretation of the derivative, tangents and normals, increasing and
decreasing functions, maximum and minimum values of a function
rolle’s theorem and lagrange’s mean value theorem. Rate of change of
bodies, use of derivatives in approximation.
PHYSICS: PRESENTWEEK (100%): EMI & AC: Electromagnetic induction:

Faraday’s law, Lenz’s law; Self and mutual inductance; RC, LR and LC
circuits with d.c. and a.c. sources.
CHEMISTRY: PRESENTWEEK (100%): Stoichiometry: Concept of atoms and

molecules; Dalton’s atomic theory; Mole concept; Chemical formulae;
Balanced chemical equations; Calculations (based on mole concept and
stoichiometry) involving common oxidation- reduction, neutralisation,
and displacement reactions; Concentration in terms of mole fraction,
molarity, molality and normality. Titrations
Solid State: Classification of solids, crystalline state, seven crystal
systems (cell parameters a, b, c, α, β, γ), close packed structure of
solids (cubic and hexagonal), packing in fcc, bcc and hcp lattices;
Nearest neighbours, ionic radii and radius ratio, point defects.
Gaseous and Liquid State: Gas laws and ideal gas equation, absolute
scale of temperature; Deviation from ideality, van der Waals equation;
Kinetic theory of gases, average, root mean square and most probable
velocities and their relation with temperature; Law of partial pressures;
Diffusion of gases. Intermolecular interactions: types, distance
dependence, and their effect on properties; Liquids: vapour pressure,
surface tension, viscosity.
Narayana IIT Academy 30-10-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-12_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value Type
Sec – I (Q.N : 1 – 8) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +3 0 8 24
‐127.30)
One of More Correct Options Type
Sec – II (Q.N : 9 – 14) +4 -2 6 24
(partial marking scheme) (+1)
Sec – III (Q.N : 15 – 18) Matrix Matching Type +3 -1 4 12
Total 18 60
PHYSICS:
Sec – I (Q.N : 19 – 26) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +3 0 8 24
‐127.30)
Sec – II (Q.N : 27 – 32) +4 -2 6 24
Total 18 60
CHEMISTRY:
Sec – I (Q.N : 37 – 44) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, +3 0 8 24
‐127.30)
Sec – II (Q.N : 45 – 50) +4 -2 6 24
Total 18 60
SR.IIT_*CO SC Page No:2

MATHEMATICS Max. Marks: 60
SECTION - I
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
1. If the acute angle between the tangents drawn from (0,1) to the graph of
m
y  x3  3x 2  3x is tan 1   , where m and n are co-prime natural numbers. Then the
n
value of (m  n) .
 
2. The number of solutions of the equation sin(cos(sin x))  cos(sin(cos x)) in 0,  is __
 2
3. If the shortest distance between 2 y 2  2 x  1  0 and 2 x 2  2 y  1  0 is d, then the
number of solution(s) of the equation | sin  | 2 2d in the interval [  , 2 ]
( x  1)3 ,  2  x  1
 2

4. Let f ( x)   x 3  1,  1  x  1 then the total number of points at which f attains
 ( x  1) 2 , 1  x  2


either a local maximum or a local minimum.
2 x  log 1 (k 2  6k  8),  2  x  1


5. Let F(x) =  2 Then the sum of all possible
 x  3x  4 x  1,
3 2
1 x  3
positive integer(s) in the range of k such that F(x) has the smallest value at x = -1.
6. If p1 and p2 are the length of the perpendiculars from origin on the tangent and normal
2 2 2
respectively drawn to the curve x  y  6 , then the value of  4 p12  p22  .
3 3 3

x3 x 2
7. Let f ( x )    x  2 and g '( x)  ( x 2  9)( x 2  4 x  3)( x 2  3x  2)( x 2  2 x  3) . If
3 2
n1 & n2 denote the number of points of local minima and the number of points of local
maxima of the function f ( g ( x)) then find the value of (n1  n2 ) .
2
 x12 
8. The minimum value of ( x1  x2 )    (17  x2 )( x2  13)  , where
2
 20 
k
x1  R  , x2  (13,17) is ( k 2  2) 2 then is
10
SECTION – II
This section contains SIX(06) multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE THAN ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
9. Let f ( x) be a twice differentiable function such that f "( x)  0 in [0,2]. Then which of
the following must be true?
A) f (0)  f (2)  2 f (c) for atleast one c  (0,2)
B) f (0)  f (2)  2 f (1)
C) f (0)  f (2)  2 f (1)
2
D) 2 f (0)  f (2)  3 f  
3
10. Let f ( x)  1  x ln( x  x 2  1)  1  x 2 and
h( x)  f ( x)  f 2 ( x)  f 3 ( x) . Then which of the following options is/are correct?
A) h(x) is increasing in (0, ) B) h(x) is decreasing in (,0)
C) h(x) is increasing on R D) h(x) in decreasing on R

11. Let f be a twice differentiable function defined in [-4, 4] such that
x
f '(4)  10, f '(4)  14 and f "( x)  3x  [4,4] . If g ( x)   f (t )dt and f (0)  0 ,
0
then which of the following options is/are correct?
A) g ( x) increases in (-4,0)
B) g ( x) decreases in (0, 4)
C) graph of g ( x) is concave down in (0, 4)
D) f ( x) has maximum value at x  2
12. Suppose f :R R is a twice differentiable function such that f (0)  1, f '(0)  0 and for
x  [0,  ), f "( x )  5 f ( x )  6 f ( x )  0 then which of the following options is/are
correct?
A) ( f '( x)  2 f ( x))e3 x is an increasing function in [0, )

B) ( f '( x)  2 f ( x))e3 x is an decreasing function in [0, )
C) f ( x)  3e2 x  2e3 x , x [0, )
D) f ( x)  3e2 x  2e3 x , x [0, )
e x
13. For the equation   which of the following statement(s) is/are CORRECT?
1 x
A) When   (0, ) equation has 2 real and distinct roots
B) When   (, e 2 ) equation has 2 real and distinct roots

C) When   (0, ) equation has 1 real root
D) When   (e,0) equation has no real root
x 4 3x 2
14. If the curve y    px  3 has three distinct tangents parallel to x  axis , then
4 2
p can be
A) -1 B) 0 C) 1 D) 2

SECTION - III
(Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has TWO (02) matching lists: LIST-I and LIST-II.
FOUR options are given representing matching of elements from LIST-I and LIST-II. ONLY ONE of these four
options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
Full Marks : +3 If ONLY the option corresponding to the correct matching is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
15. Consider the following Lists:
Column – I Column – II
64sin 3 x.cos x
(A) The maximum value of the function f ( x )  is
1  tan 2 x (P) 10
equal to
(B) Let f : (0,2 )  R be defined as

x
f ( x)  sin x.e sin 2 x
  esin 2t (sin t  cos t ) dt . Then the number of (Q) 8
0
points of local minima of f ( x) is equal to
lnx
(C) If the curves C1 : y  and C2 : y   x 2 (where  is
x (R) 6
constant) touches each other, then the value of  is less than
1
x (S) 3
(D) The value of lim  (t sin(10t )  5)dt is equal to
x 0 x
x (T) 2
The correct option is:
A) ( I )  (Q); ( II )  (T ); ( III )  ( P, Q, R, S , T ); ( IV )  ( P)
B) ( I )  (Q); ( II )  ( R); ( III )  ( S , T ); ( IV )  ( P)
C) ( I )  (Q); ( II )  ( S ); ( III )  ( S , T ); ( IV )  ( P)
D) ( I )  (Q); ( II )  ( P, Q); ( III )  ( S ); ( IV )  ( P)

A) x-coordinate of a point on the curve f ( x)  x 2  1 at which tangent (P) 2
line is parallel to chord join points (-1,2) and (0,1) is
B) The number of critical point(s) on (Q) 1
f ( x)  ( x  1) | x  2 |  ( x  2) | x  1 is
C) Least positive integral value of x for which f ( x)  (2 x  1)(2 x  3) (R) more than 2
strictly increases is
D) Given A( x)  (| x |, x 2  1, x 2  x  1,ln | x |) then number of function in 1
(S) 
A(x) for which Rolle’s theorem holds for the interval [-1,1] 2
(T) 0
A) ( I )  (S); ( II )  (P); ( III )  (T ); ( IV )  ( P)
B) ( I )  ( P); ( II )  (Q); ( III )  ( R); ( IV )  ( S )
C) ( I )  ( S ); ( II )  ( R); ( III )  ( P); ( IV )  (Q)
D) ( I )  (S); ( II )  (P); ( III )  (T ); ( IV )  ( S )
(A) Values of x satisfying the inequality   
(P)  , 
1  log 2 (sin x)  log 2 (sin 3x)  0 in (0,  ) contains 6 4
(B) Values of x in (0,  ) in which f ( x )  3 sin x  cos x is   

(Q)  , 
decreasing contains 4 3
(C) Point of extrema of the function g ( x)  6sin x  4sin 3 x can lie   2 

(R)  , 
in interval 3 3 
1
 2 3 
2 (S)  , 
 (sin( x )  x  1)dx lies in  3 4 
5 3
(D) The value of definite integral
1
 2 
, 
2
(T) 
interval  3 

A) ( I )  (Q); ( II )  ( P); ( III )  ( R); ( IV )  (T )
B) ( I )  ( P); ( II )  ( S , T ); ( III )  ( R, T ); ( IV )  ( R)
C) ( I )  (T ); ( II )  ( S , T ); ( III )  ( P, Q); ( IV )  ( S )
D) ( I )  ( P); ( II )  ( P, Q); ( III )  ( P, Q); ( IV )  ( S )
x3  4 x3  4
18. Let f ( x)  for all x  R  {1} and h( x)  for all x  R  {1} .
( x  1)3 ( x  1)3
Match the entries in column – I with column – II.
(A) Number of distinct real roots of equation f ( x)  k where k [4, )
(P) 0
can be
(B) Number of distinct real roots of equation h( x)  k where k [1, )
(Q) 1
can be
(C) Number of distinct real roots of equation f ( x)  k where k  [0,1]
(R) 2
can be
(D) Number of distinct real roots of equation h( x)  k where k  (0,1) (S) 3
can be (T) 4
A) ( I )  ( P); ( II )  (QR); ( III )  (Q, R); ( IV )  (Q, R, S )
B) ( I )  ( PT ); ( II )  (T ); ( III )  ( S , T ); ( IV )  (Q, R)
C) ( I )  (Q, R); ( II )  (Q, R, S ); ( III )  (Q, R, S ); ( IV )  (Q, R, S )
D) ( I )  ( P, T ); ( II )  ( P, T ); ( III )  (Q, S ); ( IV )  ( P, T )

PHYSICS Max. Marks: 60
SECTION - I
19. A conducting loop having a radius 2a is held co-axially near the end of a tightly wound
semi-infinite solenoid carrying a current i and having ‘n’ number of turns per unit
length. The radius of the solenoid is a. Now the loop is moved co-axially somewhere
towards the middle of the solenoid as shown. If the resistance of the loop is R, the
0 ni a 2
amount of the charge that flows through the loop in the process is then K is
KR
20. Figure shows cross-section view of a solenoid. There exists uniform time dependent
magnetic field t  At 2  Bt along the axis of solenoid. A square  a  a  conducting
frame is kept in solenoid keeping it’s plane perpendicular to axis of solenoid. The side
of square closest to axis of solenoid is at a distance a/2 from axis. Find ratio of
magnitude of potential difference in branch CD to AB? Resistance per unit length of
square frame is uniform.

21. Three alternating voltage sources V1  3sin t volt, V2  5sin t  1  volt and
V3  5sin t  2  volt connected across a resistance R  2 as shown in the figure (
where 1 and  2 corresponds to 600 and 600 respectively). Find the peak current (in
amp.) through the resistor.
22. In the given A.C circuit the r.m.s voltage of the source is 60V then the r.m.s current
passing through the source is 10  x  A then the value of x is
23. In the AC circuit shown in figure the capacitance of the capacitor is chosen in such a
way that the average power P delivered by the source to the circuit is maximum. If
R  10  then the values of P is N  100 W . Where N is
L
R
4R
XL 
C 3
~   100sin t

24. A circuit shown consists of three resistors, one capacitor, 2 ideal AC voltmeters and an
alternating voltage source of angular frequency  . Take RC  1 . If the reading of V1
V n
is V, then the reading of V2 is , then n is
3 2
25. A cylindrical region of radius 1m has instantaneous homogenous magnetic field of 3

6
T and it is increasing at a rate of T / s . A regular hexagonal loop ABCDEFA of side

1m is being drawn in to the region with a constant speed of 1 m/s as shown in the
figure. What is the magnitude of emf developed in the loop just after the shown instant
instant when the corner A of the hexagon is coinciding with the centre of the circle?
26. A conductor ACDG consists of a straight segment AC = 0.5m and a semi-circular arc
CDG of radius a = 20cm. A uniform vertical magnetic field B = 5 Tesla is existing in
the region. Now the conductor is rotated with a constant angular velocity   10 rad / s
about a vertical axis MN parallel to the magnetic field as shown. Then find the emf (in
volt) induced between the points A and D of the conductor as shown.

SECTION – II
cases
27. A conducting loop is shown figure, it is made of seven identical wires each of length a,
resistivity  , area of cross-section S0 . The frame lies in a vertical plane. XX ' is an
imaginary boundary separating space in two parts. Right to XX ' , a uniform gravitational

field g exists (figure) whereas no gravitational field is present left of XX ' .
Instantaneously frame is accelerating in leftwards with acceleration g m / s 2 . e and m is
electronic charge and mass electron respectively. Ignore inductive and capacitive
properties of loop. Instantaneously
gms2
7 mga
A) The magnitude of potential difference between points P and Q is
15 e
8 mga
B) The magnitude of potential difference between points P and Q is
15 e
mgS0
C) Current in branch RS is
15e
4mgS0
D) Current in branch RS is
15e

28. A very long solenoid perpendicular to the page generates a magnetic field in to the
page whose magnitude increases with time. Two bulb A and B connected by a wire is
glowing due to induced current in loop. Now two points diametrically opposite are
shorted with another wire lying to the right of bulb in the plane of page. After the
shortening wire is inserted
A) Bulb A goes out (Turns off) B) Bulb A gets dimmer
C) Bulb B goes out (Turns off) D) Bulb A gets brighter
29. A thin conducting rod of length l is moved such that its end B moves along the x-axis
while end A moves along the y – axis. A uniform magnetic field B  B0 k exists in the
region. At some instant, velocity of end B is v and the rod makes an angle of  with the
x-axis as shown in the figure. Then at this instant
V
A) Angular speed of rod AB is w 
L sin 
V
B) Angular speed of rod AB is w 
L cos 
Bv sin 2
C) emf induced in rod AB is
2cos 
Bv cos 2
D) emf induced in rod AB is
2sin 

30. A thin non-conducting ring of mass m, radius ‘a’ carrying a charge q can rotate freely
about its own axis which is vertical. At the initial moment the ring was at rest and no
magnetic field was present. At instant t  0, a uniform magnetic field is switched on
which is vertically downwards and increases with time according to the law B  B0 sin t .
Neglecting magnetism induced due to rotational motion of the ring, which of the
following statements is/are correct:
qB0
A) angular acceleration of the ring is cos t
2m
qB0
B) angular acceleration of the ring is sin t
m
q 2 B02 a 2 sin 2t
C) power developed by forces on the ring as a function of time is
8m
 q 2 B02 a 2 cos 2 t 
D) power developed by forces on the ring as a function of time is  t
 4m 
31. Consider a series LRC circuit with an ac voltage VS of varying frequency  , as shown
in the figure. A circuit which allows low frequency voltages, but blocks high frequency
voltages is called low pass filter (LPF) and circuit which allows high frequency
voltages but blocks low frequency voltages is called High-pass filter (HPF). When the
output voltage  V0  is measured :-
V0 V
A) across A and B, the circuit behaves like a LPF because lim  1.0 and lim 0  0 .
 0 VS  V
S
V0 V
B) across B and C, the circuit behaves like a HPF because lim  0 and lim 0  1.0 .
 VS  0 V
S
V0 V
C) across B and C, the circuit behaves like a HPF because lim  0 and lim 0  1.0 .
 0 VS  V
S
V0 V
D) across A and B, the circuit behaves like a LPF because lim  0 and lim 0  1.0 .
 0 VS  V
S

32. An ideal toroid is wound uniformly over a soft iron core. The two end points of wire
used for toroid are joined at point ‘A’ as shown in figure. Two points ‘B’ and ‘C’ are
selected on it so that point ‘B’ divides toroid in two identical half’s and ‘C’ divides in
three quarter and one quarter. The self inductance of one half toroid in between point A
0.4
and B is L  H . This toroid is fed with an ac source of emf e   200V  sin 100 t

along with a series resistor of resistance R  40  in two different ways. In case-I point
‘A’ and ‘B’ are feeding point while in case-II ‘A’ and ‘C’. Consider the ohmic
resistance of the coil is negligible and toroid has no magnetic field outside. Ignore any
inductance due to remaining parts of the loop.
B
R A
R A
~ ~
Case-II
Case-I
A) Current across source of emf in case-I is  5A  sin 100 t 
B) Current across source of emf in case-I is  4 5A  sin 100 t  tan1 
1
 2
C) Current across source of emf in case-II is   5A  sin 100 t 
D) Current across source of emf in case-II is 3A sin 100 t  37 
SECTION - III
(Maximum Marks: 12)
33.
Current is allowed to grow in the inductor by closing switch at t = 0.

PB = Power supplied by battery
PR = Power dissipated in resistor
dU
= Rate of increase of energy stored in inductor
dt
A) t = 0 P) Power supplied by battery is minimum
L
B) t  n2 Q) Power dissipated in resistor is minimum
R
L
C) t  R) Rate of increase of energy in inductor is maximum
R
dU
D) t   S) PB  PR 
dt
dU
T) PR 
dt
A) A - PST, B-RST, C- S, D – S B) A – PQST, B – RST, C – ST, D – S
C) A – PQST, B – RST, C –S, D – S D) A – PQST, B – PRST, C –S, D – ST
34. Column-I represents moving conductor in uniform magnetic field (Present only in the
square region) and column-II represents induced emf across the elements of
conductors. Then match column-I with Column-II.

A) P) VA  VB  B 
2

B) Q) VB  VA  B 
2

C) R) VA  VB  0
D) S) VC  VD  B
T) VC  VD  0
A) A-P, B-QR, C-SR, D-T B) A-PS, B-QS, C-RST, D-PQRS
C) A-S, B-QT, C-PT, D-RT D) A-S, B-T, C-PT, D-RT
35. The magnetic field in the cylindrical region shown in figure increases at a constant rate
of 10.0 mT/s. Each side of the square loop abcd and defa has a length of 2.00cm and
resistance of 2.00  . Correctly match the current in the wire ad along with its direction
in four different situations as listed in column-I with the values given in column-II.
The switch S1 is closed but S2 is
A) P) 5  107 A,d to a
open
B) S1 is open but S2 is closed Q) 5  107 A, a to d
C) Both S1 and S2 are open R) 2.5  108 A, d to a
D) Both S1 and S2 are closed S) No current flows

A) A – Q ; B – Q ; C – S ; D – R B) A – P ; B – Q ; C – S ; D – S
C) A – S ; B – Q ; C – S ; D – P D) A – Q ; B – P ; C – S ; D - S

36. Consider four cases in which conducting wire is moved with constant velocity v or
rotated with constant angular velocity  in uniform and constant magnetic field B0 ,
which is same for all cases and extended upto infinity. Distance between points A and
B directly in each case is l . In case of pure rotation plane of rotation is perpendicular to
direction of magnetic field. Potential difference between points B and A is VB  VA .
Match the following:

Column I Column II
(A) VB  VA  B0lv (p) Case I
dA
(B) Rate of area swept by the conductor   vl (q) Case II
dt
(C) Uniform electric field in the conductor (r) Case III
When velocity or angular velocity remains
(D) constant, then the external force required on the (s) Case IV
conductor is zero
A) A - PQRS ; B - PQR ; C - QS ; D – QS
B) A - PQRS ; B - PQRS ; C - QS ; D – PQRS
C) A - PQRS ; B - PQRS ; C - QS ; D – QS
D) A - PQRS ; B - PQRS ; C - PQR ; D - PQRS

CHEMISTRY Max. Marks: 60
SECTION - I
37. Identical solid atoms are arranged in a cubic packing which leads to formation of lattice
of imperfect face centred unit cell in which no atom touches each other. If sepration
between two corner atoms along edge length and body diagonal is a and b respectively,
then the ratio of radius of atom to edge length of cube will be given by: (If a:b = 1:2)
38. To measure the quantity of MnCl2 dissolved in an aqueous solution, it was completely
converted to KMnO4 using the reaction,
MnCl2 + K2S2O8 + H2O  KMnO4 + H2SO4 + HCl (equation not balanced).
Few drops of concentrated HCl were added to this solution and gently warmed.
Further, oxalic acid (225 mg) was added in portions till the colour of the permanganate
ion disappeared. The quantity of MnCl2 (in mg) present in the initial solution is ____.
(Atomic weights in g mol-1: Mn = 55, Cl = 35.5, molecular weight of oxalic acid in g
mol-1 = 90) (Assume there is no reaction between HCl and KMnO4.)
39. In two different experiments, gas X and gas Y are effused in vacuum.
Experiment I: 2mol of gas X is present in 1 L container at 327°C and gas is escaping
into vacuum through a tiny hole of cross-sectional area A.
Experiment II: 1mol of gas Y is present in 1L container at 27°C and gas is escaping in
vacuum through a tiny hole of same cross sectional area A.
From both experiments, it is found that the rate of effusion is same for the gases, then
ratio of molar mass of gas X to that of gas Y is____

40. A 200 ml sample of a citrus fruit drinks containing ascorbic acid (vitamin C) was
acidified with H2SO4 and 10 ml of 0.025 M-I2 was added. Some of the I2 was reduced
by the ascorbic acid to I−. The excess of I2 required 2.5 ml of 0.01 M-Na2S2O3 for
reduction. What was the vitamin C content of the drink in microgram vitamin per ml
drink?
C6H8O6 + I2 → C6H6O6 + 2HI
5H2O + S2O32− + 4I2 → 2SO42− + 8I− +10H+
41. A 0.8 gm sample of impure mercury (II) oxide was dissolved in excess of KI. Reaction
is HgO(s) + 4I– + H2O → HgI42– + 2OH– .
Calculate % of HgO in the sample if titration of liberated hydroxide requires 40 ml of
0.1M HCl. [Given: Atomic weight of Hg = 200u, O = 16u, I = 127u, H =1u]
42. A big RED spherical balloon (radius = 6a) is filled up with gas. On this balloon six
small GREEN spherical balloons (radius = a) are stuck on the surface in a specific
manner. As RED balloon is slowly deflated, a point comes when all these six GREEN
balloons touch and green balloons arrange themselves in a 3-D closed packing
arrangement. Find the ratio of initial to final radius of RED balloon.
(Given that – for octahedral void r+/r- = 0.414)
43. If four atoms of same radius are placed at the alternate corners of a cube and are
touching each other, then the length of body diagonal of the cube is equal to x  R ,
where R is the radius of atom. Find the value of x?
44. Initial volume of H2 gas saturated with water vapour is confined under a piston in a
container is 10 litres as shown in the given figure.
The container also contains some liquid water. The total pressure over liquid water is
80 cm of Hg. Now the piston is pulled in such a manner that volume of container is
doubled, and final total pressure over liquid water in the container becomes P. If vapour
pressure of water is 20 cm of Hg and volume of liquid is negligible. The value of P is
__

SECTION – II
cases
45. Select the CORRECCT statements:
Given that: [rc = radius of cation, ra = radius of anion]
3
A) For CsCl unit cell (edge-length = a), rc  ra  a
2

B) For NaCl unit cell (edge-length =  ), rc  ra 
2
C) The packing fraction of metal in a b.c.c. unit cell is 0.68
D) The void fraction in a face-centered cubic unit cell is 0.74
46. Graph according to Charles' law for an ideal gas can be plotted as shown.
Note: P and n are kept constant along lines L1 and L2

Which of the following is/are correct?
A) P2 = P1 if n1 = 2n2
B) P2 > P1 if n1 < 2n2
C) P2 > P1 if n1 > 2n2
D) At points A and B, Boyle's law can be applied if n1= n2

47. A definite volume of ammonia gas is passed through a series of electric sparks by
which the volume becomes 90 ml. On washing with dilute orthophosphoric acid, the
volume is reduced to 84 ml. Which of the following statement(s) is/are correct
regarding the original ammonia sample?
A) Its original volume was 48 ml
B) Its original volume was 58 ml
C) 12.5% of the original ammonia has decomposed.
D) 87.5% of the original ammonia has decomposed
48. Which of the following option(s) is /are CORRECT?
[Take H2O to be solvent in every case and solute is completely soluble]
(Given that – atomic mass of Ca = 40u, atomic mass of Br = 80u)
A) If mass fraction of CaBr2 and H2O are same then molality of CaBr2 is 5 m.
B) If equal moles of NaCl and H2O are taken then molality of NaCl is 55.56 m.
C) If in place of NaCl we use NaBr as solute in option (B) then molality of resultant
solution changes.
D) If mole fraction of NaCl is same as that of H2O then molality of NaCl will be
55.55m.
49. The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure
is (are)
A) The number of the nearest neighbours of an atom present in the topmost layer is 12
B) The efficiency of solid packing is 74%
C) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
D) The unit cell edge length is 2 2 times the radius of the atom

50. Two containers A & B (containing equal mass of an ideal gas) fitted with frictionless
piston are maintained at pressure 2 atm & 4 atm respectively, are heated. Then V–T
curve are not
A) Parabolic with same curvature B) Parabolic with different curvature
C) Linear with same slope D) Linear with different slope
SECTION - III
(Maximum Marks: 12)
51. Match the following List-I with List-II.
List- I List- II
Fraction of total voids (tetrahedral + octahedral)

(P) Rock salt (1)
occupied = 1/3
(Q) Zinc Blende (2) Anion constitute lattice.
(R) Anti-fluorite (3) Cations occupy tetrahedral voids.
(S) CsCl type (4) Co-ordination number of cation and Anion is same
(5) Cations occupy octahedral voids.
Code:
A) P –1,2,4,5; Q –1,2,3,4; R –2,3; S –2,4
B) P –1,2,4,5; Q –1,2,3,4; R –3,4; S –1,4
C) P –1,2,4; Q –1,2,3,4; R –3,4; S –1,4
D) P –1,2,5; Q –1,2,3; R –2,3; S –2,3

52. Match the property of an ideal gas sample in Column-A with that of Column-B.
Given that:  is mean free path
Z1 is number of collisions made by a single molecule with other molecules per unit
time
Z11 is number of Bimolecular collisions per unit time
List- I List- II
(P) Average speed of a gas molecule (1) T (constant P)
(Q)  (2) P (constant T)
(R) Z1 (3) T (constant P)
(S) Z11 (4) T 3/ 2 (constant P)
(5) T 1/ 2 (constant P)

Code:
A) P – 3, Q – 1, R – 2,5, S – 4 B) P – 2, Q – 1, R – 3, S – 4
C) P – 3, Q – 1, R – 4, S – 5 D) P –1 , Q – 3, R – 5, S – 2
53. Match the columns (assume the unit cell edge length equal to a).
List- I (Distance) List- II (Property)

Two times the smallest distance between two similarly
(P) a (1)
charged ions in fluorite structure.
(Q) a/√2 (2) Distance between the next nearest anions in NaCl structure
Distance between the nearest particle in FCC unit cell
(R) √3 a (3)
made of one element.
Four times the smallest distance of tetrahedral voids from
(S) √2 a (4)
the corner of FCC unit cell.
Smallest distance between the next nearest neighbor of
(5)
similarly charged ions in anti-fluorite structure.

Code:
A) P -1, 2; Q -3,5; R -4; S -1 B) P -1, 2, 3; Q -5; R -1; S -4
C) P -1, 2, 3; Q -3,5; R -3; S -1 D) P -1, 2, 3; Q -5; R -4; S -1,4
54. Match the following List-I with List-II.
List- II (Moles of HNO3

-
List I (Metal vs HNO3 reaction)
required per mole of metal)
(P) Cu + HNO3 → NO + Cu(NO3)2 + H2O (1) 4
(Q) Zn + HNO3 → Zn(NO3)2 + N2O + H2O (2) 8/3
(R) Zn + HNO3 → Zn(NO3)2 + NH4NO3 + H2O (3) 2/5
(S) Zn + HNO3 → Zn(NO3)2 + NO2 + H2O (4) 5/2
(5) 2/3
Code:
A) P- 4 ; Q - 3; R- 4; S -5 B) P -2; Q -4; R -4; S -1
C) P -1; Q -2; R-3; S -4 D) P -5; Q – 4; R -2; S -1

SPACE FOR ROUGH WORK



30-10-23 - SR - Iit - Star Co-Sc (Model-A&b) - Jee Adv - Pta-12 - Syllabus

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SEC: SR_*CO-SC(MODEL-A,B&C) Date: 30-10-23

Time: 3 Hrs Max. Marks: 180

PHYSICS: PRESENTWEEK (100%): EMI & AC: Electromagnetic induction:

CHEMISTRY: PRESENTWEEK (100%): Stoichiometry: Concept of atoms and

SR.IIT_*CO SC Page No:2

3. If the shortest distance between 2 y 2  2 x  1  0 and 2 x 2  2 y  1  0 is d, then the

number of solution(s) of the equation | sin  | 2 2d in the interval [  , 2 ]

2 x  log 1 (k 2  6k  8),  2  x  1

SR.IIT_*CO SC Page No:3

A) f (0)  f (2)  2 f (c) for atleast one c  (0,2)

B) f (0)  f (2)  2 f (1)

C) f (0)  f (2)  2 f (1)

10. Let f ( x)  1  x ln( x  x 2  1)  1  x 2 and

h( x)  f ( x)  f 2 ( x)  f 3 ( x) . Then which of the following options is/are correct?

A) h(x) is increasing in (0, ) B) h(x) is decreasing in (,0)

C) h(x) is increasing on R D) h(x) in decreasing on R

SR.IIT_*CO SC Page No:4

then which of the following options is/are correct?

C) graph of g ( x) is concave down in (0, 4)

D) f ( x) has maximum value at x  2

A) ( f '( x)  2 f ( x))e3 x is an increasing function in [0, )

B) When   (, e 2 ) equation has 2 real and distinct roots

D) When   (e,0) equation has no real root

SR.IIT_*CO SC Page No:5

(B) Let f : (0,2 )  R be defined as

points of local minima of f ( x) is equal to

The correct option is:

B) ( I )  (Q); ( II )  ( R); ( III )  ( S , T ); ( IV )  ( P)

D) ( I )  (Q); ( II )  ( P, Q); ( III )  ( S ); ( IV )  ( P)

SR.IIT_*CO SC Page No:6

A) ( I )  (S); ( II )  (P); ( III )  (T ); ( IV )  ( P)

B) ( I )  ( P); ( II )  (Q); ( III )  ( R); ( IV )  ( S )

C) ( I )  ( S ); ( II )  ( R); ( III )  ( P); ( IV )  (Q)

D) ( I )  (S); ( II )  (P); ( III )  (T ); ( IV )  ( S )

17. Consider the following Lists:

(B) Values of x in (0,  ) in which f ( x )  3 sin x  cos x is   

(C) Point of extrema of the function g ( x)  6sin x  4sin 3 x can lie   2 

SR.IIT_*CO SC Page No:7

A) ( I )  (Q); ( II )  ( P); ( III )  ( R); ( IV )  (T )

D) ( I )  ( P); ( II )  ( P, Q); ( III )  ( P, Q); ( IV )  ( S )

Match the entries in column – I with column – II.

A) ( I )  ( P); ( II )  (QR); ( III )  (Q, R); ( IV )  (Q, R, S )

C) ( I )  (Q, R); ( II )  (Q, R, S ); ( III )  (Q, R, S ); ( IV )  (Q, R, S )

SR.IIT_*CO SC Page No:8

SR.IIT_*CO SC Page No:9

V3  5sin t  2  volt connected across a resistance R  2 as shown in the figure (

SR.IIT_*CO SC Page No:10

25. A cylindrical region of radius 1m has instantaneous homogenous magnetic field of 3

SR.IIT_*CO SC Page No:11

SR.IIT_*CO SC Page No:12

A) Bulb A goes out (Turns off) B) Bulb A gets dimmer

C) Bulb B goes out (Turns off) D) Bulb A gets brighter

SR.IIT_*CO SC Page No:13

SR.IIT_*CO SC Page No:14

Current is allowed to grow in the inductor by closing switch at t = 0.

SR.IIT_*CO SC Page No:15

PR = Power dissipated in resistor

C) A – PQST, B – RST, C –S, D – S D) A – PQST, B – PRST, C –S, D – ST

SR.IIT_*CO SC Page No:16

A) A-P, B-QR, C-SR, D-T B) A-PS, B-QS, C-RST, D-PQRS

C) A-S, B-QT, C-PT, D-RT D) A-S, B-T, C-PT, D-RT

C) Both S1 and S2 are open R) 2.5  108 A, d to a