(@bohring - Bot) 24 - 12 - 23 - SR - IIT - STAR - CO - SCM (@HeyitsyashXD)

Yashpatil TG~ @bohring_bot
SEC:SR_*CO-SC(MODEL-A,B&C)) Date: 24-12-23

Time: 3 Hrs Max. Marks: 198
24-12-23_SR.IIT_STAR CO
CO-SC(MODEL-A,B&C) _JEE ADV_PTA
PTA-20_SYLLABUS
MATHEMATICS: PRESENTWEEK (100%): P&C, PROBABILITY
PHYSICS: PRESENTWEEK (100%): Rotational dynamics-I: I: Rigid body, moment

of inertia, parallel and perpendicular axes theorems, moment of inertia
of uniform bodies with simple geometrical shapes; Torque; Dynamics of
rigid bodies with fixed axis of rotation; Equilibrium of rigid bodies;
(Exclude
ude Angular Momentum & Collisions & rolling)
CHEMISTRY: PRESENTWEEK (100%): Coordination Compounds: Werner’s theory;

Nomenclature, cis
cis-trans
trans and ionization isomerism, hybridization and
geometries (linear, tetrahedral, square planar and octahedral) of
mononuclear
nuclear coordination compounds; Bonding [VBT and CFT
(octahedral and tetrahedral fields)]; Magnetic properties (spin
(spin- only)
and colour of 3d
3d-series
series coordination compounds; Ligands and
spectrochemical series; Stability; Importance and applications; Metal
carbonyls.
P-BLOCK-I (Group
(Group-15 to 18): Elements General Introduction:
Electronic configuration and general trends in physical and chemical
properties of elements across the periods and down the groups; unique
behaviour of the first element in each group.
Narayana IIT Academy 24-12-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-21_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -2 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -2 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
SR.IIT_*CO SC Page No:2

MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. At a college course 75% of the students are male and 25% are female.
It is further known that 60% of the male students own a bike and 40% of the female
students own a bike.
A student is selected at random.
Given that the student selected owns a bike what is the probability that this student is
female….
1 4 2 3
A) B) C) D)
11 11 11 11
2. A box Contains 5 balls of which 2 are white.

Balls are drawn from the box one after the other, without being replaced, until both the
white balls are picked.
If the second ball picked is white, what is the probability that exactly 4 balls were
picked out of the box.
1 1 1 2
A) B) C) D)
2 3 4 5
3. The possible scores and their corresponding probabilities obtained by a spinner are
summarized in the table below.
Score 0 1 2 3 5
Probability 0.2 0.1 0.25 0.2 0.25
The spinner is spun twice and the product of their scores is recorded.
What is the probability of the product of these scores will be less than 5.
1 217 209 227

A) B) C) D)
2 400 400 400

4. The 7 letters of the word MINIMUM are written on 7 separate pieces of card.
Four of these cards are picked at random, one after other, and are arranged into a four
letter word in the order they were picked.
Then the number of the four letter words which may or may not have meaning that can
be formed is?
A) 114 B) 108 C) 78 D) 102
5. Three randomly chosen integers x,y,z satisfy the condition that their product is 24,000.
The minimum value of x  y  z satisfying the above condition is
A) 87 B) 84 C) 90 D) 91
6. Bag-1 has 4 red and 3 black balls. Bag -2 has 6 red and 8 black balls. 2 balls are taken
from Bag-1 and placed in Bag-2 and then 2 balls are taken from Bag-2 and placed in
Bag-1. A ball is now taken from Bag-1. Probability for it to be red is ___
19 13 4 15
A) B) C) D)
28 28 7 28
SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. Let a fair dice of the shape of regular tetrahedron has it’s four faces numbered 1,2,3,4
are rolled such that “xi” is number obtained on ith turn independently and if
  
a  x1iˆ  x2 ˆj  x3kˆ, b  x4iˆ  x5 ˆj  x6 kˆ, & c  x7iˆ  x8 ˆj  x9 kˆ. Let ‘A’ be the event in
     
which a  b  c ,'B' be the event in which a , b and c are coplanar & ‘C’ be the event
in which atleast 2 of the 3 vectors are parallel. Then which of the following options
is/are correct if P(E) denotes the probability of occurrence of event E?
1 B C  1
A) P  A   B) P    1 C) P    1 D) P  B  C  
212 C  B 16

8. Two players, A and B, are taking penalty shot in turn, with A starting first.
The “winner” is the first player to score 2 goals.
The Probability of A scoring a goal is 0.4.
The Probability of B scoring a goal is 0.7.
Then which of the following options is/are Correct ?
A) Probability that A wins with his second shot is 0.16
B) Probability that B wins with his second shot is 0.4116
C) Probability that A wins with his third shot if its known that ‘B’ doesn’t score any
goal is 0.192
D) Probability that A wins with his third shot and for ‘B’ to score exactly 1 goal before
that is 0.192
9. A spinner is numbered with 0,1,2,4,5 and X represents the number indicated by the
spinner.
Kohli and Rohit play a game with this spinner and the object of the game is to score
more than ten points. Once ten or more points are collected the game is over.
The spinner is spun successively and is not important who spins the spinner, but the
score shown on it.
If the score is odd Kohli collects the number of points, shown and if the score is even
then Rohit collects the number of points shown. If a zero is spun nobody wins.
The spinner is biased as follows.
The P  X  1  P  X  2   0.3 and P  X  4   P  X  5  0.1.
Then which of the following options is/are correct?

1
A) Probability that Kohli wins in two spins is .
100
1
B) Probability that Rohit wins in three spins is .
100
9
C) Probability that Kohli wins in three spins is .
500
1
D) Probability that Kohli wins in three spins is .
50

10. Two numbers are to be chosen at random from each of the two sets
1,2,3,4,5,6,7,8,9 and 1,2,3,4,5,6,7,8,9,11

Then which of the following options is/are Correct?
1
A) Probability that all four numbers are even
45
44
B) Probability that all four numbers are odd is
55
68
C) Probability that sum of all 4 numbers is even is
135
68
D) Probability that sum of all 4 numbers is odd is .
135
11. The two ways table below summarizes the sales of three different types of number of
smart phones classified by their contract length in months.
Length of Contract
12 month 24 month 36 month TOTAL
Hamsung 17 16 17 50
Mokia 29 26 15 70
Ephone 30 27 23 80
TOTAL 76 69 55 200
Let A be the event that a customer chose a Hamsung smart phone.
Let B be the event that a customer chose a 24 month contract.
Let C be the event that a customer chose a Mokia smart phone.
Of the customers who bought a Hamsung phone 26 % bought a styling skin. The
respective percentages of those customers who bought Mokia or Ephone smart phones
buying a styling skin are 60% and 25%.
Then which of the following options is/are correct?

A) P  B   0.69
B) P  B ' C '  0.87
 A  16
C) P   
 B  69
D) Probability that a customer selected at random bought a Ephone given that he did
not buy a skin is 0.4
12. A group of 7 pupils consist of 3 girls and 4 boys. The names of two of the boys in it are
Aditya and Prakash. All seven students sit in a random order on a bench
Then which of the following options is/are Correct?
A) Number of sitting arrangements in which Aditya and Prakash sit next to each other
is 144
B) Number of sitting arrangements in which no two boys sit next to each other is 144
C) Number of sitting arrangements in which the three girls sit together is 720
D) Probability that four boys sit together if it’s known that all three girls sit together is
1
5

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. 4 students S1 , S2 , S3 , S4 are to be given 5 pens “ Pj ” is a pen which can be given to " Si "
only if i  j  1 where j = 1,2,3,4,5. Number of ways of distributing 5 pens such that

each student gets atleast one pen is _______

14. A box contains red and blue cards only, in the ratio 3:2.
Two cards are selected from the box without replacement.
1
If the probability of selecting different colour cards is , and total number of cards
2
initially in the box is M, then M  _______
15. 1,1,2,2,3,3,4,4
The above 8 single digit numbers are written on 8 separate pieces of card. These cards
are placed next to each other at random, forming an 8 digit number.
The number of 8 digit numbers that can be formed which exceed 30,000,000 is  , then
  __
16. Seven rectangular tiles, of which 3 are pink, 2 are blue and 2 are red, are placed in a
straight line, next to each other. Tiles of the same colour are identical.
Then the number of arrangements where the pink tiles are together and the blue tiles
are not next to each other is M, then M = _____
17. Four randomly chosen integers x,y,z,w satisfy x  y  z  w  4. Probability that
1
x 2  y 2  z 2  w2  8 is m , Then = _______
m
18. Let X be a set with 5 elements and Y be a set with 6 elements. Let Mi be the number of
functions from “X” to “Y” in which “i” elements are present in the range of function.
 
Then M 1  M 3  M 5   , then 9    ___ (where 
. denotes fractional part)
9 

PHYSICS MAX.MARKS: 66
19. The moment of inertia of a rectangular lamina of mass ‘m’, length ‘’ and width ‘b’
about an axis passing through its centre of mass, perpendicular to its diagonal and lies
in the plane.
  2  b2  m  4  b4  m   4  b4 
A) m  B)   C)   D) none of these
 12  12   2  b2  6   2  b2 
20. Find velocity of piston A in the given solution if angular velocity of wheel of radius R
is  (constant), in the clockwise sense. (O is fixed point)
xR sin  x 2 sin  xR sin  R 2  sin 

A) B) C) D)
R cos   x R cos   x R cos   x R cos   x
21. A ladder is resting with one end on the vertical wall and other end on a horizontal floor.
It is more likely to slip when a person stands. (Assuming all surfaces to be rough)
A) near the bottom B) near the top
C) at the middle D) independent of the position of the person
22. A triangular frame consists of three identical rods, each of mass m and length l. It rests
upright on a horizontal smooth surface with its lower right corner against a stop about
which the frame could pivot. A horizontal force of magnitude F is applied to the upper
corner of the frame as shown in the figure. What is the largest value of F may have
without causing the frame to pivot upward about the stop ?

mg 3
A) 3 mg B) 3 mg C) D) mg
3 2
23. A uniform solid hemisphere of radius 10 m and mass 64 kg is placed with its curved
surface on the smooth horizontal surface and a string AB of length 4m is attached to
point A on its rim as shown in the figure. Find the tension in the string if hemisphere is
in equilibrium.
A) 320 N B) 640 N C) 180 N D) 360 N

24. A rigid uniform bar AB of length L is slipping from its vertical position on a
frictionless floor (as shown in the figure). At some instant of time, the angle made by
the bar with the vertical is  . Which of the following statements about its motion is
incorrect ?
A) When the bar makes an angle  with the vertical, the displacement of its midpoint
from the initial position is proportional to (1  cos  )
B) The midpoint of the bar will fall vertically downward
C) Instantaneous torque about the point in contact with the floor is proportional to sin 
D) The trajectory of the point A is a parabola

correct options.
option.
25. A massless spool of inner radius r, outer radius R is placed against vertical wall and
tilted split floor as shown in the figure. A light inextensible thread is tightly wound
around the spool through which a mass m is hanging. There exists no friction at point
A, while the coefficient of friction between spool and point B is  . The angle between
two surfaces is  .
A) The magnitude of force on the spool at B in order to maintain equilibrium is

2 2
r  r 1
mg    1  
 R   R  tan 
2
B) The magnitude of force on the spool at B in order to maintain equilibrium is

 r 1
mg 1  
 R  tan 
cot 
C) The minimum value of  for the system to remain in equilibrium is
(R / r) 1
tan 
D) The minimum value of  for the system to remain in equilibrium is
(R / r) 1

26. In the adjacent figure a uniform rod of length  and mass m is kept at rest in horizontal
position on an elevated edge. The value of x (consider the figure) is such that the rod
will have maximum angular acceleration  , as soon as it is set free.
 g 3
A) x is equal to B)  is equal to
2 3 2
g 3 
C)  is equal to D) x is equal to
 3
27. A uniform rod of mass m and (length  is released from rest in the vertical position
(  00 ) on a rough (surface is sufficiently rough to prevent just sliding) square corner
A, as shown in figure, then choose correct options.
A) If the rod just begins to slip when   370 with vertical, then the co-efficient of static
friction  between the rod and the corner is 0.3
B) If the end of the rod is notched so that it cannot slip, then the angle  at which
contact between the rod and the corner ceases is 530
C) If the rod just begins to slip when   37 , then the coefficient of static friction
3
between the rod and the corner is
4
D) If the end of the rod is notched so that it cannot slip, then the angle  at which
contact between the rod and the corner ceases is 370
Narayana IIT Academy 24-12-23_SR.IIT_*CO-SC(MODEL-A,B&
&C)_JEE-ADV_PTA-21_Q’P
28. A uniform rod of length 2 m and mass M = 20 kg is hinged at point O such that it is
free to rotate in a vertical plane about a horizontal axis passing through point O and
perpendicular to the plane of the paper. The rod is kept in equilibrium with the help of
an ideal string.
Then
Mg
A) Tension in the string is
2
5 Mg
B) Tension in the string is
12
Mg
C) Vertical component of hinge reaction on the rod is
2
D) Horizontal component of hinge react
reaction on the rod is zero
29. A rod is connected with the (rigid body) disc at centre of disc at point ‘P’. The disc can
freely rotate about point P where it is hinged with rod. Rod can rotate freely about
fixed hinge Q. Now whole arrangement is released ffrom rom horizontal position as shown
in the diagram.
A) Initial angular acceleration of (rigid body) disc about its centre P is zero.
B) Initial angular acceleration of (rigid body) disc about its centre P is
C) Angular speed of (rigid body) disc about it
itss centre P when rod becomes vertical is
zero.
D) Angular speed of (rigid body) disc about its centre P when rod becomes vertical is
3 g
rad / s
2 

30. A uniform triangular plate ABC of mass m is placed such that the coordinates of A, B
and C are  a, 0, 0  ,  0, b, 0  and  0, 0, c  respectively. Let I x , I y and I z be the moments of
inertia of this plate about x-axis, y-axis and z-axis respectively. Then, which of the
following are correct.
A) If a  c, then I x  I z B) I y is independent of b
m 2 a b c ma 2
C) I z 
3
 a  b2  D) If   , then I x 
5 4 3 6

31. Three identical rings each of mass M and radius R are welded together with their planes
mutually perpendicular to each other. Ring A is vertical and B is also vertical in a plane
perpendicular to A. Ring C is in horizontal plane. The moment of Inertia of this system
about a horizontal axis perpendicular to the plane of the figure passing through point P
(top point of ring A) is nMR 2 . The value of n is ___
32. A uniform thin L shaped rod is placed on the rough horizontal surface and its corner is
pulled by a string as shown in the figure. If it undergoes pure translation then the value
of cot  will be

33. A uniform rod AB bent in the shape of an arc of circle is free to rotate in a vertical
plane about a fixed horizontal axis passing through the mid – point of the wire. The
situation is shown in the figure. The angular acceleration of the rod immediately after
pg
it is released from rest from the position shown is   . Calculate p.
4b
34. A uniform semicircular wire of mass M is hinged at ‘A’ so that it can rotate freely in
vertical plane about a horizontal axis through ‘A’. The semicircle is released from rest
1 1
when its diameter AB is horizontal. Mg  2 is the hinge force at ‘A’ immediately
N 2

after the wire is released. Find N.
35. A uniform smooth rod of mass m  1 kg and length L is balanced in the vertical position
as shown in the figure. When a horizontal force F is applied at end A, the magnitude of
acceleration of top point B at this instant is
36. A rod AB is moving on a fixed circle of radius R m with constant velocity ‘v’ as shown
in fig. ‘P’ is the point of intersection of the rod and the circle. At an instant the rod is
3R
at a distance x    m from centre of the circle. The velocity of the rod is
 5 
perpendicular to the rod and the rod is always parallel to the diameter CD. The speed
of the point of intersection P in ms 1 is nv. Find the value of n.

CHEMISTRY MAX.MARKS: 66
37. Choose the incorrect statement from the following
A) According to Molecular orbital theory, O2 and S2 are paramagnetic.
B) The element Mascovium (Mc) (Z=115)belongs to 15th group in the modern periodic
table
C) Among F2 and I2 species, energy gap between LUMO and HOMO of each species is
same
D) Magnitude of bond dissociation energy of Cl2 is higher than F2.
38. Oxidation state of underlined atoms respectively in
Br3O8 ; S 8 ; H 2 S 2O8 ; H NO4 ; H ClO4
A) 8 / 3 ; 2 ;  7 ;  7 ;  7 B) 8 / 3 ; 0 ;  7 ;  7 ;  7
C) 8 / 3 ; 0 ;  6 ;  5 ;  7 D) 8 / 3 ; 0 ;  7 ;  5 ;  5
39. The correct order of molar conductance of the following formula of complexes
CoCl3 .4 NH 3 CoCl3 .3 NH 3 CoCl3 .6 NH 3 CoCl3 .5 NH 3

(i ) ( ii ) ( iii ) ( iv )
A) iii> iv > ii > i B) ii > iv > iii > i C) i > iv > iii > ii D) iii > iv > i > ii
40. Among the following complexes the one which shows zero crystal field stabilization
energy is (Assume H2O is a weak field ligand in all given complexes)
A) [Co( H 2O)6 ]3 B) [Co( H 2O)6 ]2
C) [ Mn( H 2O)6 ]3 D) [ Fe( H 2O)6 ]3

41. The number of donor sites in dimethyl glyoxime, glycinato, diethylene triamine and
EDTA are respectively. (EDTA- Ethylene Diamine Tetra Acetate)
A) 2, 2, 3 and 4 B) 2, 2, 3 and 6
C) 2, 2, 2 and 6 D) 2, 3, 3 and 6
42. Spin only magnetic moment of complex ion in Hg[Co(SCN)4]is
A) 3 B) 15 C) 24 D) 8

correct options.
option.
43. Choose the correct statement(s) among the following:
A) [Ni(CN)4]-2has square planar geometry
B)[Pt(NH3)2Cl2]has 2 geometrical isomers.
C) Fe in [Fe(CN)6]-3has t2 g eg electronic configuration.

5 0

D) The bond order of CO in  V  CO 6  is more than bond order of CO in [Cr(CO)6]
44. Atomic numbers of Cr and Fe are 24 and 26 respectively, which of the following is/are
diamagnetic?
A) [Cr (CO )6 ] B) [ Fe(CO )5 ] C) [ Fe(CN )6 ]4 D) [Cr ( NH 3 )6 ]3

45. Addition of excess aqueous ammonia to a pink colored aqueous solution of MCl2 .6 H 2O
(X) and NH 4Cl gives an octahedral complex Y in the presence of air. In aqueous
solution, complex Y behaves as 1:3 electrolyte. The reaction of X with excess HCl at
room temperature results in the formation of a blue colored complex of Z. The
calculated spin only magnetic moment of X and Z is 3.87 B.M., where as it is zero for
complex Y.
Among the following options, which statement(s) is/are correct?
A) The hybridization of the central metal ion in Y is d2sp3
B) Addition of excess of silver nitrate to Y gives only two equivalents of silver chloride
C) Conversion of X to Z is endothermic in nature
D) Z is a tetrahedral complex
46. For the complex[CrCl3(OH)2(NH3)]2- ion the correct statement is/are ?
A) It has three geometrical isomers.
B) Only one space isomer is optically active and remaining are inactive
C) There are total four space isomers
D) The magnetic moment of complex ion is 3.87 BM.
47. Choose the correct statement(s) among the following:
A) Ni 2 ion does not form inner orbital octahedral complexes.
B) The complex [ Mn Cl2 Br2 ]2 has two geometrical isomers.
C) [Co(en)3 ]3  [Co(en)2 ( NH 3 ) 2 ]3  [Co(en)( NH 3 )4 ]3  [Co( NH 3 )6 ]3 (Stability order)
D) [ Fe(CO)6 ]2  [ Mn(CO)6 ]  [Cr (CO)6 ]  [V (CO)6 ] (CO stretching frequency order)
48. Select the correct statement(s):
A) Chelated complexes are relatively more stable than non-chelated complexes.
B) Greater the charge on the central metal cation, greater the value of  0 (Crystal field
splitting energy)
C)  0 value varies as Co3  Rh3  Ir 3 for same ligand
D)  0 value varies as Br 
 Cl   F  for same metal ion

49.
Complex Number of geometrical isomers
i) [ Pt ( gly ) 2 ( NH 3 ) 2 ]Cl2 X
ii) [Co( NH 2  CH 2  CH 2  NH 2 ) 2 ( NH 3 )Cl ]2 Y
iii) [CoCl ( H 2O)( NH 3 )4 ]2 Z
Then the value of (X+Y+Z) is
50. Among the 6 given complexes,
[Co(ox)3 ]3 , [CrCl2 (en)2 ] , [CoBrCl (en) 2 ]
[ Pt ( NH 3 )2 Cl2 ], [Co( NH 3 )3 Cl3 ], [Cr ( NH 3 )4 Cl2 ]
the no. of complexes which can exhibit both geometrical and optical isomerism is
51. How many of the following have central metal in (+ 3) oxidation state?
[ Ag (CN )2 ] , [ Fe(CN )6 ]3 , K3[Cr (CN )6 ],

[CoCl (ONO)(en)2 ] , [Co( EDTA)] (Ethylenediaminetetraacetate)
52. The weight of precipitate formed by 200ml 0.1M solution of [CrCl(H2O)5]Cl2.H2Owith

excess AgNO3 in gram is__________
(Gram Atomic weight of Ag = 108, Cr = 52, Cl = 35.5, O = 16, H = 1)
53. Number of optical isomers for [Co(en)3]+3is X and number of geometrical isomer for the
complex [Pt(NH3)(CO)(Py)(Cl)(Br)(H2O)]+2 is Y. What is the value of (Y/X).
54. Number of unpaired electrons in [Cr(H2O)6]+3and [Cr(CN)6]-3are respectively ‘P’ and

‘Q’. Sum of ‘P’ and ‘Q’ value is

Space for Rough Work

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Yashpatil TG~ @bohring_bot

SEC:SR_*CO-SC(MODEL-A,B&C)) Date: 24-12-23

MATHEMATICS: PRESENTWEEK (100%): P&C, PROBABILITY

PHYSICS: PRESENTWEEK (100%): Rotational dynamics-I: I: Rigid body, moment

CHEMISTRY: PRESENTWEEK (100%): Coordination Compounds: Werner’s theory;

SR.IIT_*CO SC Page No:2

A student is selected at random.

2. A box Contains 5 balls of which 2 are white.

1 217 209 227

SR.IIT_*CO SC Page No:3

SR.IIT_*CO SC Page No:4

B) Probability that B wins with his second shot is 0.4116

Then which of the following options is/are correct?

SR.IIT_*CO SC Page No:5

1,2,3,4,5,6,7,8,9 and 1,2,3,4,5,6,7,8,9,11

Let B be the event that a customer chose a 24 month contract.

Let C be the event that a customer chose a Mokia smart phone.

Then which of the following options is/are correct?

SR.IIT_*CO SC Page No:6

B) P  B ' C '  0.87

Then which of the following options is/are Correct?

SECTION - 3 (Maximum Marks : 24)

only if i  j  1 where j = 1,2,3,4,5. Number of ways of distributing 5 pens such that

SR.IIT_*CO SC Page No:7

Two cards are selected from the box without replacement.

17. Four randomly chosen integers x,y,z,w satisfy x  y  z  w  4. Probability that

SR.IIT_*CO SC Page No:8

xR sin  x 2 sin  xR sin  R 2  sin 

A) near the bottom B) near the top

C) at the middle D) independent of the position of the person

SR.IIT_*CO SC Page No:9

A) 320 N B) 640 N C) 180 N D) 360 N

B) The midpoint of the bar will fall vertically downward

D) The trajectory of the point A is a parabola

SR.IIT_*CO SC Page No:10

A) The magnitude of force on the spool at B in order to maintain equilibrium is

B) The magnitude of force on the spool at B in order to maintain equilibrium is

SR.IIT_*CO SC Page No:11

A, as shown in figure, then choose correct options.

SR.IIT_*CO SC Page No:13

SECTION - 3 (Maximum Marks : 24)

SR.IIT_*CO SC Page No:14

SR.IIT_*CO SC Page No:15

A) According to Molecular orbital theory, O2 and S2 are paramagnetic.

D) Magnitude of bond dissociation energy of Cl2 is higher than F2.

38. Oxidation state of underlined atoms respectively in

Br3O8 ; S 8 ; H 2 S 2O8 ; H NO4 ; H ClO4

CoCl3 .4 NH 3 CoCl3 .3 NH 3 CoCl3 .6 NH 3 CoCl3 .5 NH 3

A) [Co( H 2O)6 ]3 B) [Co( H 2O)6 ]2

C) [ Mn( H 2O)6 ]3 D) [ Fe( H 2O)6 ]3

SR.IIT_*CO SC Page No:16

42. Spin only magnetic moment of complex ion in Hg[Co(SCN)4]is

SECTION - 2 (Maximum Marks : 24)

A) [Ni(CN)4]-2has square planar geometry

B)[Pt(NH3)2Cl2]has 2 geometrical isomers.

C) Fe in [Fe(CN)6]-3has t2 g eg electronic configuration.

A) [Cr (CO )6 ] B) [ Fe(CO )5 ] C) [ Fe(CN )6 ]4 D) [Cr ( NH 3 )6 ]3

SR.IIT_*CO SC Page No:17

C) Conversion of X to Z is endothermic in nature

A) Ni 2 ion does not form inner orbital octahedral complexes.

B) The complex [ Mn Cl2 Br2 ]2 has two geometrical isomers.

C)  0 value varies as Co3  Rh3  Ir 3 for same ligand