21-01-24 JR - Iit Star Co-Sc (Model-B) Jee Adv 2020 (P-I) Wat-36 QP

Sec: JR.
IIT _*CO-SC(MODEL-B) Date: 21-01-24

Time: 3 Hrs Max. Marks: 198
21-01-24_JR.IIT_STAR CO-SC(MODEL-B) _JEE ADV_WAT-36_SYLLABUS
MATHEMATICS: PRESENT WEEK(80%):
Family of Circles, Angle between two Circles, Common chord, Direct,
Transverse, Pair of tangents
PREVIOUS WEEK(20%):
CIRCLE: Equation of Circles (Various forms), Secant, Tangent, Normal,
Chord of Circle, Chord of contact, Chord whose midpoint is given
PHYSICS: PRESENT WEEK(80%):
Gravitation: Complete Gravitation Law of gravitation; Gravitational
potential and field; Acceleration due to gravity; Motion of planets and
satellites in circular orbits; Escape velocity
PREVIOUS WEEK(20%):
Conductors and their properties, Conducting spheres, Induced charges,
Energy density, Electrostatic pressure, Self-energy of bodies with
spherical charge distribution.
CHEMISTRY: PRESENT WEEK(80%):
Alkyl halides: Preparation and Reactions of alkyl halides, Mechanism of
Nucleophilic Substitution reactions (SN1, SN2), Mechanism of
Nucleophilic Substitution reactions (SN1 and NGP), Polyhalogen
compounds NCERT(Exclude: haloform reaction)
PREVIOUS WEEK(20%):
Benzene: Preparations reactions of benzene and alkyl benzenes,
Eletrophilic aromatic substitution, mechanism of halogenations,
nitration, sulphonation, nitrosation, alkylation and acylation, General
EAS ,directive influence of groups and activating –deactivating groups,
Side chain reactions and oxidation reactions of alkyl benzene
(Exclude: substitution in biphenyls, anthracene and heterocyclic
compounds partial rate factor, reactions of phenol and aniline)
Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -2 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -2 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
JR.IIT_*CO-SC Page. No. 2

MATHS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. The line 3x  3 y  7 meets the circle x 2  y 2  2 x  2 y  14  0 in the points A and B. The
equation of the diameter of the circle each making and angle 450 with AB are
A) x  1  0, y  1  0 B) x  1  0, y  1  0 C) x  1  0, y  1  0 D) x  1  0, y  1  0
2. The number of points inside or on the circle x 2  y 2  4 satisfying
tan 4 x  cot 4 x  1  3sin 2 y is
A) 1 B) 2 C) 4 D) 0
3. Consider a family of circles passing through the intersection point of the lines
3  y  1  x  1 and y  1  3  x  1 and having its centre on the acute angle bisector of the
given lines. Then the common chord of each member of the family and the circle
x2  y2  4 x  6 y  5  0 are concurrent at
1 1 1 3 3 3 1 1
A)  ,  B)  ,  C)  ,  D)  , 
2 2 2 2 2 2  2 2 
1 1 1
 1  cx  x  1  2cx  x  2  cx  x
4. lt    4, x1  lt   and r    then equation of the circle which touches
x  0 1  cx x  0 1  2cx
     2  cx 
x  axis at  x1 , 0  and the radius r is
A)  x  4 2   y  2 2  4 B)  x  8 2   y  2 2  4
2 2 2 2
C)  x  16    y  2   4 D)  x  12    y  2   4
5. Let x  x  a   y  y  1  0 be a circle. If two chords from  a,1 bisected by x  axis are drawn
to the circle then the condition is
A) a 2  8 B) a 2  8 C) a 2  4 D) a 2  4

2 2
6. The circle x  y  4 cuts the line joining the points A 1, 0  and B  3, 4  in two points P and
BP BQ
Q. Let   and   then the quadratic equation whose roots are  ,  is
PA QA
A) x 2  2 x  7  0 B) 3x 2  16 x  21  0 C) 2 x 2  2 x  27  0 D) x 2  x  1  0
SECTION - 2 (Maximum Marks : 24)

Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. Circles x 2  y 2  1 and x2  y 2  8 x  11  0 cut off equal intercepts on a line through the

1
point  2,  . The slope of the line is
 2
1  29 1  7 1  29 1  7
A) B) C) D)
14 4 14 4
8. If  ,  ,  are the parameters of points A, B, C on the circle x 2  y 2  a 2 and if the triangle
ABC be equilateral then
A)  cos   0 B)  sin   0 C)  tan   0 D)  cot   0
9. From any point P on the circle x 2  y 2  6 x  8 y  15  0 tangents PA, PB are drawn to the
circle x2  y 2  6 x  8 y  20  0 and the locus of the ortocentre of the PAB is a circle then
A) Centre is  3, 4  B) Centre is  3, 2  C) Radius is 5 D) Radius is 10
10. If PQR is the triangle formed by the common tangents to the circles x2  y 2  6 x  0 and
x 2  y 2  2 x  0 then
A) Centroid of PQR is 1, 0  B) In-centre of PQR is 1, 0 

C) Circum-radius of PQR is 2 units D) In radius of PQR is 1 unit

11. If the curves ax  4 xy  2 y  x  y  5  0 and ax 2  6 xy  5 y 2  2 x  3 y  7  0 intersect of four
2 2
concyclic points then

1 3
A) The value of a is -4 B) Centre of the circle is  , 
 8 8 
1 3 26
C) Centre of the circle is  ,  D) Radius of the circle is
 4 4  8
12. AC is diameter of circle. AB is a tangent. BC meets the circle again at D. AC=1, AB=a,
CD=b then
b 1 b 1
A) ab  1 B) ab  1 C)  D) 
a a2  1 a a2  1
2 2

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. C1 , C2 , C3 are circles of radii 5, 3, 2 respectively C1 and C2 touch each other externally and
C internally. The radius of circle C3 which touches C internally and C2 , C1 externally is
14. A circle of radius 2 has centre at (2,0). A circle of radius 1 has centre at (5,0). A line is
tangent to the two circles at points in the first quadrant. Then the y-intercept of the line
is
15. If angle between tangents drawn to x 2  y 2  12 x  16 y  0 at points where curve is cut by
 k
5 y  5 x  c  c  0  is and c  10k then 
2 5
16. If  ,   is a point on the chord PQ of the circle x 2  y 2  25 , where the coordinates of P
and Q are  3, 4  and  4,3 respectively and K1    K2 and K3    K 4 then k i

is
4
17. The line  x  3 cos    y  4  sin   1 touches a fixed circle  whose radius is
18. If the four circles touches the three lines x  2 y  1  0, 2 x  3 y  5  0, 3x  y  1  0 of radii
3 d d d 
a, b, c, d and a  b  c  d then     is
2 a b c 

PHYSICS MAX.MARKS: 66
19. If suddenly the gravitational force of attraction between earth and satellite revolving
around it becomes zero, then the satellite will
A) continue to move in its orbit with same velocity
B) move tangential to the original orbit with the same velocity
C) becomes stationary in its orbit
D) move towards the earth
20. Two identical spheres each of radius R are placed with their centers at a distance nR,
where n is integer greater than 2. The gravitational force between them will be
proportional to
1 1
A) B) C) R 2 D) R 4
R4 R2
21. Force between two point masses separated by a distance r is F1 . Now mass of one is
reduced by 50% keeping other mass constant. New force between masses
A) decreases by 50% B) increases by 50%
C) remains same D) decreases by 75%
22. Two particles of masses 4kg and 8kg are kept at x  2m and x  4 m respectively. Then
the gravitational field intensity at the origin is
A) G B) 2G C) G/2 D) G/4
23. If g on the surface of the earth is 9.8ms 2 , its value at a depth of 3200km (Radius of the
earth = 6400km) is
A) 9.8ms 2 B) zero C) 4.9ms 2 D) 2.45ms 2
24. A solid sphere having uniform charge density  and radius R is shown in figure. A
R
spherical cavity of radius is hollowed out. What is potential at O? (Assuming potential
2
at infinity to be zero)

11R 2  5 R2  7  R2 3 R2
A) B) C) D)
24 0 12  0 12 0 2 0

correct options.
option.
25. The correct option regarding orbital velocity is/are

1
A) Orbital velocity v for different orbit
r
1
B) Orbital velocity v holds good for different points on the same elliptical orbit
r
C) Orbital velocity depends on the mass of orbiting object.

D) Orbital velocity does not depend on the mass of orbiting object
26. Consider a thin spherical shell of uniform density of mass M and radius R
A) the gravitational field inside the shell will be zero
GM 2
B) the gravitational self-energy of shell is
2R
2
C) attractive force experience by unit area of the shell pull the other half is GM2
2R
GM 2
D) net gravitational force with which one hemisphere of the shell attracts other is
8R 2

27. The gravitational potential changes uniformly from 20 J kg 1 to 40 J kg 1 as one moves
along X – axis from x  1 m to x  1 m . Mark the correct statements
A) the gravitational field intensity at x = 0 must be equal to 10N/kg
B) the gravitational field intensity at x = 0 may be equal to 10N/kg
C) the gravitational field intensity at x = 0 may be greater than 10N/kg.
D) the gravitational field intensity at x = 0 must not be less than 10N/kg
28. Which of the following is correct regarding the motion of a satellite? (V = Velocity of
projection, R = Radius of Earth)
A) V  gR . It may come back to the Earth surface
B) V  2 gR - Hyperbolic trajectory
C) V  gR - Circle
D) 2gR  V  gR - circle.
29. Three particles are projected vertically upward from a point on the surface of the earth
with velocities  2 gR / 3 ,  gR  ,  4 gR / 3 respectively where R is the radius of the earth
and g is the acceleration due to gravity on the surface of the earth. The maximum heights
attained are respectively h1 , h2 , h3 .
A) h1 : h2  2 : 3 B) h2 : h3  3 : 4 C) h1 : h3  1: 4 D) h2  R
30. An ellipsoidal cavity is carved within a perfect conductor. A positive charge ' q ' is placed
at the centre of the cavity. The points A and B are on the cavity surface as shown in the
figure. Then

A

q B
A) Electric field near A in the cavity = Electric field near B in the cavity
B) Charge density at A = Charge density at B
C) Potential at A = Potential at B
D) Total electric field flux through the surface of the cavity is q /  0

31. Two point masses are separated by 5cm. If m1  2 gm and m2  4 gm then the gravitational
force acting between them is x 1015 N . Find x? [Take G = 6  1011 Nm 2 kg 2 ]

32. A body of mass 2 kg is revolving round the earth at an altitude 1600 km, above the
GM
surface of earth of radius 6400 km. Its orbital velocity is 103 ms 1 , where G and
x
M are gravitational constant and mass of earth in SI units. Find the value of x ?
33. A bullet is fired vertically upwards with velocity ' v ' from the surface of a spherical
planet. When it reaches its maximum height, its acceleration due to the planet’s gravity
is 1/4th of its value of the surface of the planet. If the escape velocity from the planet is
vesc  v N , then the value of N is (Ignore energy loss due to atmosphere)
34. Two masses 90kg and 160kg are at a distance 5m apart. The magnitude of intensity of
the gravitational field at a point, distance 3m from the 90kg and 4m from the 160kg
mass is x  G newton / kg. Find x? ( 2  1.4 )
35. The time period of rotation of earth so that the bodies at the equator would weigh 40%
of their actual weight is x. where x in seconds is (Take, Radius of earth R = 6000
kilometers , g = 10 m/s2 and   3.14 )
36. If E is the electric field intensity of an electrostatic field, then the electrostatic energy
density is proportional to E x , then find x ?
CHEMISTRY MAX.MARKS: 66

37. An Alkyl halide with molecular formula C6H13Br on treatment with alcoholic KOH gave
two isomeric alkenes A and B. Ozonolysis of the mixture gave the following
compounds.
H3C C CH3 , H C CHO , H3C CH2 CHO and (H3 C)2HC CHO
3
O
The alkyl halide is
A) 2-Bromohexane B) 3-Bromo-2-Methylpentane
C) 2,2-dimethyl-1-Bromobutane D) 2-Bromo-2,3-dimethylbutane
H
N Br2
38. In the given reaction  X ;  X  is
H Br H
N N N N
A) Br B) C) Br D)
Br
Br Br
Br
39. alc.KOH NBS alc.KOH
A NBS KCN
B C  D  E  product.
Product is
CN
CN CN
CN
A) B) C) D)
40.
I
Me C H KSH
Et C D DMSO
H
SH H H SH
Me C H Me C H HS C Me H C Me
A) B) C) D)
Et C D Et C D Et C D Et C D
H I H H

NaCN
A
41. H3 C CH CH2 Cl , (A) and (B) would be
CH3 B
AgCN
CH3 CH3
A) H3C C CN and H3C CH NC
CH3 CH3
B) H3C CH CH 2 CN and H3C CH CH 2 NC
CH3 CH3
CH3 CH3
C) H3C C CN and H3C CH CH 2 NC
CH3
CH3
D) H3C CH CH2 CN and H3C C NC
CH3 CH3
O
AlCl3 Zn  Hg  , HCl SOCl2 AlCl3
42. + O  A B  C  D
O
Based on the above reaction [C] should be
O
CH2 CH2 Cl
CH2
CH2 C
A) CH2 CH2 CH2 C Cl B)
O
CH2 CH2 OH
CH2 C
C) D)
O
O

correct options.
option.
43. Amongst following the correct statement(s) is/are

A) In SN 2 reactions if reactant has R configurations the product can have S
configuration.
B) In SN2 reactions the configuration of reactant gets inverted.
C) In SN2 reactions if reactant is dextrorotatory the product is laevorotatory.
D) Racemization may take place in SN 1 reaction.
44. Reaction between neo-pentyl bromide and ethanol gives 2-ethoxy-2methylbutane as the
major product because
CH3
H3C CH2Br
CH3
A) This involves 1, 2-hydride shift

B) This involves 1, 2-alkyl shift
C) This occurs through a SN1 mechanism
D) This occurs through carbo cation intermediate.
45. Incorrect order of hydrolysis of the following in increasing order is/are
Br Br Br  CH3 3 CBr
(i) (ii) (iii) (iv)

A) (i) < (ii) < (iii) < (iv) B) (i) < (iv) < (ii) < (iii)
C) (iv) < (iii) < (ii) < (i) D) (i) < (ii) < (iv) < (iii)

46. How many of the following is/are correct statement(s)
A) H 3 C CH 2 CH 2 I will react more readily than  CH3 2 CHI for SN 2 reactions.
B) H 3 C CH 2 CH 2 Cl will react more readily than H 3C CH2 CH2 Br for SN 2
reaction.
C) H 3C CH 2 CH 2 CH 2 Br will react more readily than  H 3C 3 C  CH 2  Br for SN 2
reactions.
D) H3C O C 6H 5 Br will react more readily than O2N C6H5 CH2 Br for SN 2
reaction.
47.
The major Product (B) is :
A) B) C) D)
48. For the following compound, the incorrect order of the reactivity of different bromine
atoms towards SN1
Br 
P
O Br  Q
Br N Br  R 
 S
A) P > Q > R > S B) S > Q > P > RC) S > R > P > Q D) P > S > Q > R

49. From the list of compounds given below ‘X’ is the number of compounds do not show
SN 2 then the value ‘X’?
Cl Br Cl
CH 2 CH 2 CH2 Br Cl
,
, , , ,
,
50. When a mixture containing PCl3 and PCl5 is heated with ethyl alcohol, total of 4 moles
of ethyl chloride is formed. Mole ratio of PCl3 and PCl5 in the mixture is X : Y
respectively then X + Y = ___________.
51. The number of compounds which give white precipitate with alcoholic AgNO3 is
52.
CH 3
X2
CH CH 2  CH3 
h

CH 3 2 5 6
4
1 3

Which of the above hydrogen can be abstracted easily by halogen in presence of sunlight
53. From the given structure find the sum of positions of highest and least nucleophilicity
sites?
O O
(4)
(1)
(3)
O
O S
O O
(2) O
54. From the following compounds find the multiplication of the number of compound with
highest and least reactivity towards solvolysis.
1) H 5 C 6 CH 2 Br
2) H5C6 CH C2H5
Br
CH3
3)
Br
Br
4) CH

21-01-24 JR - Iit Star Co-Sc (Model-B) Jee Adv 2020 (P-I) Wat-36 QP

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Sec: JR.

IIT _*CO-SC(MODEL-B) Date: 21-01-24

JR.IIT_*CO-SC Page. No. 2

SECTION – 1 (Maximum Marks: 18)

x  axis at  x1 , 0  and the radius r is

JR.IIT_*CO-SC Page. No. 3

SECTION - 2 (Maximum Marks : 24)

7. Circles x 2  y 2  1 and x2  y 2  8 x  11  0 cut off equal intercepts on a line through the

A) Centroid of PQR is 1, 0  B) In-centre of PQR is 1, 0 

JR.IIT_*CO-SC Page. No. 4

concyclic points then

SECTION - 3 (Maximum Marks : 24)

16. If  ,   is a point on the chord PQ of the circle x 2  y 2  25 , where the coordinates of P

and Q are  3, 4  and  4,3 respectively and K1    K2 and K3    K 4 then k i

JR.IIT_*CO-SC Page. No. 5

JR.IIT_*CO-SC Page. No. 6

SECTION - 2 (Maximum Marks : 24)

25. The correct option regarding orbital velocity is/are

C) Orbital velocity depends on the mass of orbiting object.

JR.IIT_*CO-SC Page. No. 7

JR.IIT_*CO-SC Page. No. 8

force acting between them is x 1015 N . Find x? [Take G = 6  1011 Nm 2 kg 2 ]

JR.IIT_*CO-SC Page. No. 9

JR.IIT_*CO-SC Page. No. 10

A) H3C C CN and H3C CH NC

C) H3C C CN and H3C CH CH 2 NC

JR.IIT_*CO-SC Page. No. 11

43. Amongst following the correct statement(s) is/are

A) This involves 1, 2-hydride shift

(i) (ii) (iii) (iv)

JR.IIT_*CO-SC Page. No. 12

The major Product (B) is :

JR.IIT_*CO-SC Page. No. 13

JR.IIT_*CO-SC Page. No. 14

JR.IIT_*CO-SC Page. No. 15

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