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SEC: INC.

SR_*CO-SC Date: 18-06-22


Time: 3 Hrs Max. Marks: 198
18-06-22_INC.SR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-50_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Potentiometer, Applications, Experiments:
Resistivity of the material of a given wire using metre bridge,
Resistance of a given wire using Ohm's Law,Potentiometer-
1.Comparision of emf of two primary cells.2. determination of
internal resistance of a cell, RC-circuits (Including Experiments -
Verification of Ohm’s law using voltmeter and ammeter, and specific
resistance of the material of a wire using meter bridge and post office
box.)
PREVIOUS WEEK (20%): Kirchoff's laws & Circuit problems for
finding equivalent resistance, Wheatstone bridge, Conversion of
galvanometer into ammeter and voltmeter, Meter bridge
CHEMISTRY: PRESENT WEEK (80%): Alcohols: Preparation of alcohols from
alkene, akyl halides, amines, aldehydes, ketones and carboxylic acid
and derivatives, Physical propertties, reactions: esterification,
dehydration, reaction with metals, conversion into alkyl chlorides,
oxidation into aldehyde, ketones and carboxylic acids, Lucas test,
victor meyer test (Exclude:MPV reduction, exceptions of LAH & SBH,
swern oxidation, oppenauer oxidation),
Glycol and glycerol: Preparation, reaction with conc. HI, PI3, HIO4
with oxalic acid, pinacol-pinacolone rearrangement
PREVIOUS WEEK (20%): Aryl halides: preparation using EAS,
Sandmayer reaction, Mechanism of SNAr reactions
(Exclude: Benzyne mechanism & cine substitution) and EAS
Reactions chlorobenzene, Fittig, Wurtz-Fittig reactions
Grignard reagent: Preparation and properties of Grignard reagent

MATHEMATICS: PRESENT WEEK (80%): AREA: Application of Definite integrals to


find the area involving simple curves
PREVIOUS WEEK (20%): Leibnitz Rule, Definite integrals, Inequation,
Approximation, Definite integrals - Reduction formula
Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 24) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 25 – 30) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 42) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 43 – 48) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. In a metre bridge, the gaps are closed by two reistances P and Q and the balance point
is obtained at 40 cm. When Q is shunted by a resistance of 10  , the balance point
shifts to 50 cm. The values of P and Q are

10
A) ,5 B) 20, 30
3

15
C) 10,15 D) 5, 
2

2. In the circuitshown , the cell will deliver maximum power to the network ,if the value
of ‘R’ is

2 4 1 5
A)  B)  C)  D) 
3 3 3 3

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
3. In the circuit diagram, the current through the battery immediately after the switch S is
closed is given as :

E E E
A) Zero B) C) D)
R1 R1  R 2 R R
R1  2 3
R 2  R3

4. A capacitor is initially connected to a battery of EMF of 3 V as shown in figure . At


t=0 , switch is thrown to B state. Now charge on capacitor at any instant is given by

A) q  C V  2Ve  t / RC  B) q  C V  2Ve  t / RC 

q  C V  2Ve  t / 2 RC  q  C V  2Ve 2t / RC 


C) D)

5. A voltmeter consists of a 25  coil connected in series with a 575  resistor. The coil
takes 10 mA for full scale deflection. What maximum potential difference (V) can be
measured on this voltmeter?

A) 3 B) 6 C) 2 D) 10

6. A potentiometer wire of length 100cm has a resistance 5ohm .It is connected in series
with a resistance and cell of emf of 2V and of negligible internal resistance .A source
of emf 5mV balanced by 10cm length of potentiometer wire . The value of external
resistance is ______

A) 540 B) 195 3) 190 D) 990

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
7. A voltmeter and an ammeter are connected in series to an ideal cell of emf E to form a
circuit. The voltmeter reading is V and the ammeter reading is I.
A) V<E
B) the voltmeter resistance is V/I
C) the potential difference across the ammeter is (E-V).
D) Voltmeter resistance plus ammeter resistance = E/I
8. The potential of certain points in the circuit are maintained at the values indicated.
The voltmeter, ammeter and all cells are ideal. Then

2 4
A) Potential at ‘O’ is V B) Potential at ‘O’ is V
3 3
1 37
C) Ammeter reading is A D) Voltmeter reading is V
15 3
9. An electrical circuit is shown in the given figure. The resistance of each voltmeter is
infinite and each ammeter is 100  . The charge on the capacitor of 100  F in steady
state is 4mC. Choose correct statement(s) regarding the given circuit

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P

A) Reading of voltmeter V2 is 16 V
B) Reading of ammeter A1 is zero and A2 is 1/25 A

C) Reading of voltmeter V1 is 40 V
D) EMF of the cell may be 46 V
10. In charging of a capacitor in presence of resistor, (Choose the correct statements)

A) there is growth of charge and decay of current

B) it takes very long time for capacitor to get charged

C) initially say at t=0, capacitor offer zero resistance for the flow of current

D) capacitive time constant is defined as time taken for capacitor to get charged to
63% of its steady state charge

11. A capacitor of capacitance C is charged to a potential difference V and then connected


in series with an open key and a pure resistor R. At time t=0, the key is closed. If I 0 is
the current at time t=0, a plot of log I against t is shown as (1) in the graph . Later one
of the parameters, i.e., V, R and C is changed, keeping the other two constant and
graph (2) is recorded. Then

A) C is reduced B) C is increased
C) R is reduced D) R is increased

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
12. The two plates of a capacitor of capacitance C are given charges Q1 and Q2 .This
capacitor is connected across a resistance R as shown key is closed at t  0 .Find the
charges on the plates after time t

Q1  Q2  Q1  Q2   RCt
A)Total charge of thre right plate q2   e
2  2 

Q1  Q2  Q1  Q2   RCt
B) Total charge on the left plate q   e
2  2 

Q1  Q2
C) Initial potential difference across the plates is given by
2C

Q1  Q2
D) Initial potential difference across the plates is given by
2C

SECTION - 3 (Maximum Marks : 24)


This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. The resistance of the galvanometer G in the circuit is 25 ohm .The meter deflects full
scale for a current of 10mA .The meter behaves as an ammeter of three different
ranges .The range is 0-10A when the terminals O and P are taken .The range is 0-1A
between O and Q. The range is 0-0.1A between O and R .The value of R3 measured in
ohm is…

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
14. The resistance of the potentiometer wire is 16  and its length is 4 m. The

galvanometer shows no deflection at point J. The distance of point J from point A is

5  N cm. Find N

12 V
8

A J
B
2V 2

1V 1
G
4

4V 6

15. A battery of emf 2V and negligible internal resistance is connected across a uniform

wire of length 10m and resistance 30 . A cell of emf 1.0 V and internal resistance 1

is connected to one end of the wire and the other terminal of the cell is connected

through a sensitive galvanometer to a slider on the wire. What length of the wire '  '

(in metre) will be required to produce zero deflection of the galvanometer ?

r =1
vvvv
1V
G

 2V

Battery

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
16. In the circuit shown, the potential difference in volts between point A and B in steady
state is

10 F
10 
A

>>
>

>>
>

>
>
10 
5 F >
>
>10 
> >
> 10 
>
B
100 V

>>
>
>
10 

17. In the given circuit all the capacitors are uncharged. Now if key k is closed at t  0.

The ratio of maximum and minimum currents in the battery is

18. Calculate the charge in micro coulomb on the capacitor long time after the assembling
of the circuit:

1
4V
3

3
1

 F

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
19.

A) B)

C) D)

20.

A) B)

C) D)

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
21.

A) B)

C) D)

22. The major end product of the following reaction is

A) B)

C) D)

23.

A) B)

C) D)

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
24. The end product of following reaction is

A)  ,   diketone B)  -Hydroxy acidC)1,2 – Diol D)  -Hydroxy acid

SECTION - 2 (Maximum Marks : 24)


This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
25. In the reaction given below.

The correct statement regarding the outcome of the above reaction is/are

A) A pure enantiomer of alcohol is formed

B) Racemic mixture of alcohol is formed

C)Product alcohol has deuterium attached to oxygen

D) Product alcohol has deuterium attached to carbonyl- carbon atom

26. In the following conversion  X  can be

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P

A) B)

C) D)

27. Which of the following reduction methods is suitable for preparing an alcohol?

A) CH 3COOC2 H 5  NaBH 4  B) CH 3COOC2 H 5  Na / EtOH 


C) CH 3CH 2COCl  LiAIH 4  D) CH 3COOH  H 2  Ni

28. Point out the following Incorrect Grignard synthesis

A)

B)

C)

D)

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
29.

The possible product (s) in the above reaction is /are:

A) B)

C) D)

30. An optically active alcohol A  C8 H16O  on oxidation givens B. A on acidic heating


gives C  C8 H14  as major product. C on ozonolysis produces D  C5 H 8O  and D on
reduction with LiAIH4, gave

Identify correct answer:

A) B)
a is B is

C) D)
C is D is

SECTION - 3 (Maximum Marks : 24)


This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. How many of the following compounds are more reactive than 4-flouronitrobenzene
towards activated nucleophilic aromatic substitution?

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P

32. An organic compound A  C10 H18O8  on treatment with excess of CH 3COCI gives a fully
acetylated product whose molar mass is found to be 518 g/mole. How many hydroxyl
functional groups are present in A?

33.

How many of the following statements are correct with respect above scheme of
reactions?

I) ‘Z’ is primary alcohol

II) ‘Y’ form turbidity with Lucas reagent after 5-10 minutes and gives yellow ppt with
aqueous bleaching powder and I2

(III) ‘X’ is tertiary alcohol and gives red ppt in victor mayer test

(IV) Both ‘Y’ and ‘Z’ are 20 alcohols, give positive test in haloform reaction

(V) All change the orange colour of acidified potassium dichromate to green under
normal conditions.

(VI) ‘X’ is racemic mixture

(VII) ‘Y’ optically active

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
34. The number of reagents among the following which effect the given conversion is

(i) PCC
(ii) PDC
(iii) K 2Cr2O7 / Con.H 2 SO4
(iv) Br2 / NaoH
(v) Alkaline KMnO4
(vi) Cu, 573K
(vii) NaBH 4
(viii) LiAIH 4
35. How many among compounds are not oxidized by HIO4

36. Moles of RMgX consumed when reacted with one mole of the following molecule is

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
37. If the area bounded by y  x 2  2 x  3 and the line y  kx  1is least, then the least area
in square units is

31 32 34 35
A) B) C) D)
3 3 3 3

38.

If f  x   
 x , x z
and g  x    x .(where 
2
. denotes fractional part of x), then
 1, x z
area bounded by f  x  and g  x  for x   0,10 is

5 10 20
A) B) 5 C) D)
3 3 3

39. A square ABCD is inscribed in a circle of radius 4. A point P moves inside the circle
such that d  P, AB   min d  P, BC  , d  P, DA  where d  P, AB  is the distance of a

point P from line AB. The area of region covered by the moving point P in square
units is

A) 4 B) 8 C) 8  16 D) 4  4

The area bounded by the curves y  sin 1 sin x and y   sin 1 sin x  , 0  x  2 , in
2
40.

square units is

1 2 1 3 4  3
A)  B)  C) 2 D)   2  
3 4 6 8 3  6 

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
1
41. The area enclosed between the curves y  ln  x  e  , x  ln   and x  axis in square
 y
units is

A) 1 B) 2 C) 3 D) 6

42. The area of region represented by  x  y    x  y   5 , for x  y , x  0 , y  0 in


square units is

3 5 2 3
A) B) C) D)
2 3 3 5

SECTION - 2 (Maximum Marks : 24)


This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
The area (in square units) of the region bounded by the curves y  e x and the line
2
43.
y  e is equal to

 
e 1 1 1
A) 2  ln y dy B) 2  x e dx C)  e  e x2
D) 2e   e x dx
2
x
dx
1 0 1 1

44. Let f : R  R , g : R  R be two functions defined by f  x   2 x  x 2 and g  x   x n

1
where n  N . If the area between f  x  and g  x  is square units, then n is a divisor
2
of

A) 12 B) 15 C) 24 D) 30

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Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
45. If f :  0,    R be a continuous and strictly increasing function such that
x
f 3
 x    t f 2  t  dt ,  x  0 . The area enclosed by y  f  x  , x  axis and the
0

m
ordinate x  3 is , where m and n are positive integers with greatest common
n
divisor 1, then
A) m  n  3 B) m  n  5 C) mn  6 D) mn  2
1 1
46. Let f  x   , g  x   . Let  be the value of a  a  2  for which the area
x2 4  x  1
1
between the curves f  x  , g  x  and ordinates x  2 and x  a is , and  be the
a
value of b  1, 2  for which the area between the curves f  x  , g  x  and ordinates
1
x  b and x  2 is 1  then
b
A)   e 2  1 B)   e2  2 C)   1  e1 D)   1  e2

47. Which of the following statement( s) is/are correct?


A) The area bounded by  y  sin 1 x   x  x 2 is
2
square units
4


B) The area bounded by  y  sin 1 x   x  x 2 is
2
square units
2

C) The area bounded between x  y 2 and x  3  2 y 2 is 4 square units

 4
D) The area of region bounded by  x, y  : x 2  y 2  1 and y 2  1  x is  square
2 3
units

3 bi
48. If Ai is the area bounded by x  ai  y  bi , i  N . If ai 1  ai  bi , bi 1  and
2 2
a1  0 , b1  32 , then

n
213 n
212
A) A3  128 B) A3  256 C) lim  Ai  D) lim  Ai 
n 3 n 3
i 1 i 1

Inc.SR.IIT_*CO SC Page No: 19


Narayana IIT Academy 18-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-50_Q’P
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
49. The area enclosed by the graph y 2  2 xy  40 x  400 in square unitsis______

If f  x    x    x (where [.] and {.} denote greatest integer and fractional part of x
2
50.

3
respectively) and the area bounded by y  f  x  , y  f 1  x  , x  0 and x  is
2
a7 2
then the value of a  b  c is equal to______
b c

1
51. Let f  x   sin 1 x  cos 1 x  tan 1 x  tan 1 . The area bounded by y  f  x  , y  axis
x

and the line 2 y    x  1 is equal to . Then the value of k is equal to_____
k

 1
52. Let f  x   max sin x,cos x,  then the area of region bounded by y  f  x  , x  axis,
 2

5 a 3
y  axis and the line x  is   d . Then the value of a  b  c  d is equal
3 b c
to ______

53. The area of the region bounded by the curves y  x 3 , y  x and 1  x  1 in square
units is _______

54. The area (in square units) of the region bounded by the parabola y  x 2  2 and the
lines y  x  1, x  0 and x  3 is ________

Inc.SR.IIT_*CO SC Page No: 20

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