Sec: Sr.

IIT_N-SUPER CHAINA/N-CHAINA Date: 10-09-20

Time: 3hrs Max. Marks: 180

Name of the Student: ___________________ H.T. NO:

10-09-20_SR.N-SUPER CHAINA/N-CHAINA_Jee-Adv_GTA-9(P1)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEAMTICS : TOTAL SYLLABUS

Narayana IIT Academy 10-09-2020_Sr.IIT_GTA-9_Paper-1_2018-P-1_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

CHEMISTRY:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19 – 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 33-36) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N:37 – 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec –III(Q.N : 51-54) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

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PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. L, C and R represent the physical quantities inductance, capacitance and resistance
respectively. The combinations which have the dimensions of frequency are
(A) 1/RC (B) R/L (C) 1/ LC (D) C/L
2. The mass of a box measured by a grocer’s balance is 2.300 kg. Two gold pieces of masses
20.15 g and 20.17 g are added to the box. (Respond according to correct significant
figures)
(A) Mass of the box + contents is 2.3 kg
(B) Total mass box + contents is 2.340 kg
(C) Difference in masses of pieces is 0.02 g
(D) Difference in masses of pieces is 0.00 g
3. MA = 3 kg, MB = 4 kg, and MC = 8 kg. Coefficient of friction between any two surfaces is
0.25. Pulley is frictionless and string is massless. A is connected to wall through a
massless rigid rod.

(A) Value of F to keep C moving with constant speed is 80 N

(B) Value of F to keep C moving with constant speed is 120 N
(C) If F is 200 N then acceleration of B is 10 ms-2
(D) To slide C towards left, F should be at least 50 N (Take g = 10 ms-2)

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4. An object of mass 0.8 kg is attached to one end of a spring and the system is set into
simple harmonic motion. The displacement x of the object as function of time is shown in
the figure. With the aid of the data, choose the correct statement :

(A) Magnitude of acceleration of the particle at t = 1.0 sec is 0.197 ms-2

(B) Magnitude of maximum velocity of the particle is 1 ms-1
(C) Angular frequency of the oscillation is about 1.57 rad s-1.
(D) Spring constant of the spring is about 4 N/m.

5. A heavy disc with radius R is rolling down hanging on two non-stretched string wound
around the disc very tightly. The free ends of the string are attached to a fixed horizontal
support. The strings are always tensed during the motion. At some instant, the angular
speed of the disc is  , and the angle between the strings is  .

R
(A) Speed of enter of mass of disc is
cos( / 2)
R
(B) Speed of CM of disc is
sin( / 2)
(C) The instantaneous axis of the disc lies at the circumference of the disc
(D) The instantaneous axis of the disc is at infinity

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6. Process undergone by an ideal gas sample is described in terms of thermodynamic

temperature (T) and volume occupied by gas (V) by the equation TVx= constant.

Unfrozen degrees of freedom of the gas sample is f. Choose the correct statements.

A) For f  x  2 , the process represents adiabatic.

B) For f  x  1 , temperature of the gas sample should decrease if heat is supplied to the

gas.

C) For x  1 , coefficient of volumetric expansion of the gas is equal to reciprocal of

thermodynamic temperature.

D) For x  1 , bulk modulus of the gas sample is zero.

SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. Light of wavelength 488 nm is produced by an Argon laser which is used in the
photoelectric effect. When light from this spectral line is incident on the emitter, the
stopping (cut-off) potential of photo electrons is 0.38 V. Find the work function (in eV )of
the material from which the emitter is made. (Given that hc  1242eV  nm )
8. There are two vessels. Each of them contains one mole of a monoatomic ideal gas. Initial
volume of the gas in each vessel is 8.3 103 m3 at 270 C. Equal amount of heat is supplied
to each vessel. In one of the vessel, the volume of the gas is doubled without change in its
internal energy, whereas the volume of the gas is held constant in the second vessel. The
vessels are now connected to allow free mixing of the gas. Find the final temperature of
the combined gas in Kelvin. (take n2  0.6931)

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9. A coil of inductance L = 5H and resistance R = 55  is connected in series to the mains
alternating voltage of frequency f = 50 Hz in series. What can be the non-zero capacitance
of the capacitor (in  F ) connected in series with the coil if the power dissipated has to
remain unchanged. (take  2  10 )
10. A glass sphere of refractive index 1.5 forms the real image of object O at point I as shown
in the figure when kept in air of refractive index 1. If the value of x is kR. Find k.

11. In the circuit shown, all the capacitors are initially uncharged. Find the current through
the battery just after closing the switch ‘S’.(in Amperes )

12. A charged hemispherical shell has a uniform charge density  . Calculate the ratio of
electric field due to shell at A to that at B

13. Two thin circular discs of mass m and 4m, having radii of a and 2a, respectively, are
rigidly fixed by a massless, rigid rod of length l  24a through their centers. This
assembly is laid on a firm and flat surface, and set rolling without slipping on the surface
so that the angular speed about the axis of the rod is  . The angular momentum of the

entire assembly about the point ‘O’ is L (see the figure).

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The angular speed of the rigid body as seen from ground is x . Then what is the value of
x rounded off to two decimals?

14. A parallel-plate capacitor is placed in such a way that its plates are horizontal and the
lower plate is dipped into a liquid of dielectric constant K and density  . Each plate has
an area A. The plates are now connected to a battery which supplies a positive charge of
magnitude Q to the upper plate. Find the rise in the level of the liquid in the space
between the plates.

(k n  1) 2
If your answer is , Report m + n.
2 0 k m  g

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

Paragraph for Question Nos. 15 to 16

A uniform ring of mass m is lying at a distance 3 a from the centre of a sphere of mass
M just over the sphere where a is the radius of the ring as well as that of the sphere.

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15. Then gravitational force exerted by the sphere on the ring is :
GMm GMm GMm GMm
(A) (B) (C) 3 (D) 3
8a 2 3a 2 a2 8a 2
16. For the situation, as the ring and sphere come closer due to mutual gravitational attraction,
what happens to the gravitational force between them?
(A) It first increases and then decreases
(B) It first decreases and then increases
(C) It decreases monotonically
(D) It increases monotonically
Paragraph for Question Nos. 17 to 18
A rubber tube AB is connected to a glass tube BC. The glass tube consists of n = 5
identical inverted U-sections. Diameter of the tubes are negligible as compared to height h
= 10 cm of these sections. Now water is poured very slowly through a funnel into the
rubber tube at its open end A. Neglect capillary action and viscosity.

17. What should be the minimum height H of the end A, so that water starts flowing out of
the end C of the glass tube? Neglect capillary action and viscosity.
(A) H  4h (B) H  6h (C) H  5h (D) H  8h
18. When the water just starts emerging near end C, at that time: (P0 = atmospheric pressure)
(A) Pressure in the vertical portion nearest to C is P0/2
(B) Pressure in vertical column nearest to point B is P0 + 3 gh
(C) Pressure in vertical portion nearest to C is P0
(D) Pressure throughout the Bent tube is P0.

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CHEMISTRY Max. Marks: 60
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
19. Which of the following liberate O2 gas on heating?
A) NaNO3 B) Pb(NO3 )2 C) KMnO 4 D) Pb3O 4

20. Choose the correct statement(s) regarding binary metal carbonyl V  CO 6 :

a) total number of valence shell electrons at metal centre is 19

b) it is a low spin complex
c) it acts as oxidising agent
d) CO stretching frequency increases when it acts as oxidising agent.
21. [Zn(OH) 4 ]2  A 
X  Zn  NaOH(conc.) 

A  O 2 
B(Catalyst )
 C (paramagnetic)

C  O 2  H 2 O 
X  Y

Y 
 X  H 2O  C
The missing reagents and catalyst are
(A) A is N 2 H 4 (B) Bis Pt (C) Cis NO 2 (D) X is HNO3
22. An one mole ideal monoatomic gas under goes a state change between two states
State 1 : P = 1 atm , T = 300k
state 2 : P = 8 atm , T = 300k
between these two states only two processes are possible: Isobaric reversible and
adiabatic reversible Given 42 / 5  2.3 83/ 5  3.48
(A) |Wmin| = 425 R between two states
(B) |Wmin| = 350 R between two states
(C) If the gas operates between state 1 and state ‘2’ in two step, then W max 425R
(D) Maximum efficiency if the gas undergoes a cyclic process between state 1 and state
2 is 56.41.

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23. Select option(s) in which correct major product is not given:
(A)

(B)

(C)

(D)

24. Which order regarding basicity is correct?

(A) (B)

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Narayana IIT Academy 10-09-2020_Sr.IIT_GTA-9_Paper-1_2018-P-1_Q’P
(C) (D)

SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 8 questions. Each question is numerical value. For each question, enter the correct
numerical value (in decimal notation, truncated/rounded-off to second decimal place.
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
25. The number of spices which are paramagnetic in following collection of molecule / ions
are:
(A) MnO3 (B) K 2 [PtCl4 ] (C) K 2 [Fe(CN)5 (NO)] (D) Na in liq NH3
(E) KO3 (F) O 2 (G) O3 (H) N 2 O3

(I) Hg 2 (NO3 )2
26. An alkyl halide of formula Cn H 2n  2 yCl y is analyzed as follows:

1. 1.4 g of chloride which combusted gave 2.2 g of CO2

2. 1.4 g is fused with Na. Its Na Extract with AgNO3 gave 2.86 g ppt. The molecular
weight of compound is. Given (Ag = 108 u Cl = 35 u)
27. Fe has a BCC structure beyond 1000 k when Fe is crystallized during the extraction at
1800 k, it incorporates 6% by mass of carbon. The number of ‘C’ atoms per unit cell in
the lattice, is x 101 . Closest Integer (Fe = 56 u C = 12u) value of ‘x’ is?
1
28. A curve is drawn between vs Co m of a weak acid. It is a straight line with y-
m

1 1 2
intercept  S Cm mole and slope = 0.25
200
Then Ka of weak acid is A 10 B in standard notation then A + B is?
29. Calculate weight of water formed in grams when 1 mole of white phosphorus is oxidised
by concentrated HNO3 is:

(Molecular weight of H 2O is 18gmol1 )

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30. How many of the following are carbonate ores?
Limonite, Cerrusite, Siderite, Bauxite, Calamine, argentite, Magnetite, dolomite,
Azurite.
31. Calculate the solubility (S) of CaCO3 in a saturated solution of CO2, having
concentration of CO2 as 0.1M.
Ksp CaCO3  4 1013
 HCO3  H 3O  ka1  106
CO2( aq )  H 2O 

 H   CO32
HCO3  ka2  1011

Give your answer in terms of – log S.

32. A salt can permeate through SPM till their ionic product on either side becomes identical
i.e for salt AxBy
[A y ]x [Bx  ]y becomes same on either side.
In the fallowing arrangement:
Only Na+ and Cl- ins are permeable, but R- is not permeable.
Calculate freezing point of part ‘A’ at steady state
Kf = 20 C / molal. Assume molarity equal to molality

Only Na+ and Cl- are permeable

round off your answer up to two significant figure.

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SECTION – III
(COMPREHENSIN TYPE)
This section contains 2 Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph For Questions 33 and 34

33. Identify P11.

(A) CH4 (B) C2H6 (C) C3H8 (D) C4H10
34. What is correct about P10 .
(A) It can not give Bromine water test
(B) It cannot decolorize Bayer’s reagent
(C) It will give same product with HBr in presence or absence of peroxides
(D) It can give red ppt with Cu2Cl2/NH4OH

Paragraph for Questions 35 and 36

There are four major types of polar elimination reactions in which a proton and a leaving
group, H-LG, are lost to form an alkene. Three of them E1, E2 and E1cb, describe a
continuous spectrum of possible mechanisms in which the leaving group LG-leaves first,
H and LG leave together (anti periplanar is preferred over syn periplanar in most casses),
or H  leaves first

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35. Which of the following reactions gives corresponding olefin at fastest rate?
Br

Reaction-1 Ph NaOEt
Ph Alkene
EtOH
Me

Br

Ph NaOEt
Ph Alkene
Reaction-2 EtOH
Me

a) Reaction-1 b) Reaction-II
c) Reaction-I = Reaction-II d) Can't predict
36. Identify the products, R and S, in the following reactions
Br

Ph NaOEt
Ph R (major product)
EtOH
Me

Br

Ph NaOEt
Ph S (major product)
EtOH
Me

Me Ph Me Ph Me Ph Ph Ph

A) R = Ph B) S = Ph C) R = S = Ph D) R = S = Me

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MATHEMATICS Max. Marks: 60
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
37. Let S  {1, 2,3,....., n} and f n be the number of those subsets of S which do not contain
consecutive elements of S, then
(A) f n is even, if n  3k  1, k  W (B) f n is odd, only if n  3k , k  W
(C) Half of f1 , f 2 , f3 ,..., f10 are primes (D) f1 , f 2 , f3 ,..., f10 contains no perfect square
38.  sin 8 x cos 6 x dx 
sin 9 x.cos5 x 5 sin 7 x.cos 7 x 7
(A)   sin 8 x.cos 4 x dx (B)    sin 6 x.cos 6 x dx
14 14 14 14
7 9 7 7
sin x.cos x 5 sin x.cos x 5
(C)   sin 8 x.cos 4 x dx (D)    sin 6 x.cos 6 x dx
14 14 14 14

39. In a triangle PQR, let PQR  30 and the sides PQ and QR have lengths 10 3 and 10
respectively. Then which of the following statement(s) is(are) TRUE?
A) QPR  45

B) The area of the triangle PQR is 25 3 and QRP  120

C) The radius of the incircle of the triangle PQR is 10 3  15

D) The area of the circumcircle of the triangle PQR is 100
40. PQ is a chord of the parabola x 2  4 y which subtends right angle at the vertex of the
parabola. If S is the focus of the given parabola, then the locus of centroid of triangle
PSQ, passes through the point/s

(B)  , 
2 10
(A)  3, 0  (C)  2, 6  (D)  2, 6 
3 3 

 b,
41. a,  c are some unit vectors such that for some other nonzero-vector d , we have

 
d  d  a  b  d  c . Then select the CORRECT alternative/s

 c,
(A) The vectors b,  d must be co-planar

 b,
(B) The vectors a,  c must be co-planar

 c must be antiparallel
(C) The vectors b,

 d must be parallel
(D) The vectors a,
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2cos t, if i  j

42. Let A  t   a ij  is a matrix of order 3  3 given by a ij  1 if i  j  1 where
0
 otherwise

A  t  is determinant value of matrix A(t), then which of the following are correct?

a) lim A  4t  is equal to 16
t 0

b) maximum value of A  t  A  3t  is equal to 16


c)  A  t  A  4t  dt is equal to 0
0

    4 
d) A   A   is equal to 1
 17   17 
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 8 questions. Each question is numerical value. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to second decimal place.
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
k n
1
43. Let f (k )  2k then the value of lim16
n 
f (n)
 k 1 2 2 f (k )
 2 f ( k )  1
is


44. The graphs of y  sin x, y  cos x, y  tan x and y  cos ec x are drawn from 0 to . A vertical
2
line is drawn through the point where the graphs of y  cos x and y  tan x cross ,
intersecting the other two graphs at points A and B. The length of the line segment AB
is:
45. Let  ,  be the integer roots of equation 10 x 2  px  q  0 such that p  q  210, then the
sum of all different possible values of  +  is
46. If an onto function f : (,1]  (,1] satisfies the functional equation
f ( x  f ( y ))  f ( f ( y ))  xf ( y )  f ( x)  1; x, y  R, then the greatest value of ' a ' for which

f (a )  7 , is

47. If f  x   sin x  cos x  tan x  sin 1 x  cos 1 x  tan 1 x then the sum of the maximum

and minimum values of f  x  is k  2cos1 where K 

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sin( x 2 )  2 cos(bx)  ax 4  2 25
48. Given that the limit lim
x 0 3 3
exists and is equal to , then the
a x 8
e  1  ax  2 x 
ax 2

6
maximum possible value of a 2 is
49. An ellipse has semi major axis 2 and variable eccentricity x. Let S1 , S2 be its foci and P
is any point on the ellipse. For a given value of x, let f ( x) be the minimum
circumradius of the triangle PS1S2 , then the area under y  f ( x) and the x-axis is
50. Line 3 y  2 x  6 intersects y  axis at point A. It is rotated by an angle '  ' in
anticlockwise direction about point 'A ' such that it meets y  6 at point B with AB  5
unit, then the value of cot  is

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2 Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Questions 51 to 52
x
Let f ( x) be non-positive continuous function on x  0 and F ( x)   f (t )dtx  0. . Also
0

f ( x)  cF ( x) , where c0 and x  0 . Let g :[0, )  R, be a function such that

dg ( x)
 g ( x)x  0 and g  0   0.
dx
51. The total number of roots of the equation f ( x)  g ( x) is/are
(A) infinite (B) 1 (C) 2 (D) 0
52. The total number of solutions of the equation x 2  x  6  f ( x)  g ( x) is/are

(A) 2 (B) 1 (C) 0 (D) 3

Paragraph for Questions 53 to 54
Lines L1 : 5iˆ  3 ˆj    iˆ  ˆj  and L2 : 5iˆ  3 ˆj    iˆ  ˆj  intersect at point A . A plane P : ax  by  cz  5 ,

where a, b, c  0 intersects line L1 at B and line L 2 at C such that AB  AC  3 2 . Distance of

plane P from origin is 4 and plane P cuts positive x  axis . On the basis of above information
answer the following:

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Narayana IIT Academy 10-09-2020_Sr.IIT_GTA-9_Paper-1_2018-P-1_Q’P
53. Value of (a  b  c) is equal to
(A) 1 (B) 1/4 (C) 7 (D) 7/4
54. If D  , ,   is foot of perpendicular from origin on plane P, then      is equal to
28 28
(A) 5 (B) 5 (C) (D) 
5 5

JR.IIT N C/N-120 The size of your success depends on the depth of your desire. Page. No. 18