05-09-21 JR - Iit Star Co-Sc (Model-A) Jee Adv 2018 (P-I) Wat-18 QP

SEC: JR_*CO-SC Date: 05-09-21
Time: 3 Hrs Max. Marks: 180

05-09-21_JR.IIT_STAR CO-SC (MODEL-A)_JEE ADV_WAT-18_SYLLABUS
PHYSICS: PRESENTWEEK (80%): ROTATIONAL MECHANICS: Calculation of
Torque, static Rotational equilibrium of rigid bodies, toppling,
Kinematics of Rotation of rigid body about fixed axis of rotation
(Exclude: Moment of Inertia, τ =Iα, Fixed Axis Rotation, T+R Motion,
Rotational Collisions)
PREVIOUS WEEK (20%): Impulse, 2D collision & Variable mass
systems
CHEMISTRY: PRESENTWEEK (80%): VBT, hybridisation, Bond parameters Dipole
moment, Bridge bonding,Back bonding,Bents rule, Drago's rule
PREVIOUS WEEK (20%): Chemical Bonding and Molecular
Strucuture: Kossel – Lewis approach to chemical bond formation,
concept of ionic and covalent bonds, Lewis structures, Formal Charge,
Ionic Bonding: Formation of ionic bonds, factors affecting the
formation of ionic bonds; calculation of lattice enthalpy, Fajan's rules
Ionic Bonding: Formation of ionic bonds, factors affecting the
formation of ionic bonds; calculation of lattice enthalpy, Fajan's rules,
Applications of Fajan's rules- solubilty , thermal stability, melting
points, VSEPR
MATHEMATICS: PRESENTWEEK (80%): Pair of Straight Line: Pair of straight lines
passing through the origin, Homogenisation, General Pair of straight
lines, Miscellaneous Problems
PREVIOUS WEEK (20%): Location of origin (or a point) w.r.t two lines,
Angle Bisectors, Family of lines, Concurrency of three or more lines,
System of linear equations in two variable
Narayana IIT Academy 05-09-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-18_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
CHEMISTRY:
+Ve - Ve
Marks Marks
Sec – I(Q.N :19 – 24) +4 -2 6 24
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N : 33-36) +3 -1 4 12
Total 18 60
MATHEMATICS:
+Ve - Ve
Marks Marks
Sec – I(Q.N:37 – 42) +4 -2 6 24
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec –III(Q.N : 51-54) +3 -1 4 12
Total 18 60
Jr.IIT_CO SC Page 2
PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. The net external torque on a system of particles about an axis is zero. Which of the
following are compatible with it?
A) The forces may be acting radially from a point on the axis
B) The forces may be acting on the axis of rotation
C) The forces may be acting parallel to the axis of rotation
D) The torque caused by some forces may be equal and opposite to that caused by
other forces.
2. A massless spool of inner radius r, outer radius R is placed against vertical wall and
tilted split floor as shown. A light inextensible thread is tightly wound around the
spool through which a mass m is hanging. There exists no friction at point A, while
the coefficient of friction between spool and point B is  . The angle between two
surfaces is  .
Jr.IIT_CO SC Page 3
A) the magnitude of force on the spool at B in order to maintain equilibrium is
2 2
r  r 1
mg     1  
 R   R  tan 
2
B) the magnitude of force on the spool at B in order to maintain equilibrium is

 r 1
mg 1  
 R  tan 
cot 
C) the minimum value of  for the system to remain in equilibrium is
 R / r  1
tan 
D) the minimum value of  for the system in equilibrium is
 R / r  1
3. In the figure shown, the rod is uniform and has a mass m, length L. The horizontal
thread is connected to the rod at a point at a distance L/3 along the rod from lower end
angle between rod and wall 60
A) In equilibrium, tension in the thread is 3mg / 2 .
B) In equilibrium, tension in the thread is 3 3mg / 2

C) The minimum value of friction coefficient between the lower end of rod and the
vertical wall for the rod be in equilibrium is 2 / 3 3
D) The maximum value of friction coefficient between the lower end of rod and the
vertical wall for the rod be in equilibrium is 2 / 3 3
4. A ball projected with speed 10 m/s at angle of projection   300 with horizontal. If
coefficient of restitution e  1 / 3 between ball and ground then  g  10 m / s 2 
 65 3 
A) Displacement of ball up to third collision is  m
 9 
B) Maximum height attain after first collision is 0.14 m.
C) Total energy of ball remain conserved
D) Total energy of ball not remain conserved
Jr.IIT_CO SC Page 4
5. A car of mass m0 starts moving to the right due to a constant horizontal force F. At the
same time sand starts falling into the car from a stationary hopper.
The rate of loading is constant and equal to  kgs 1 .
Ft
A) Velocity of the car at time t is
 m0  t 
Ft
B) Velocity of the car at time t is
2  m0  t 
Fm0
C) acceleration of the care at time t is
2  m0  t 
2
Fm0
D) acceleration of the car at time t is
 m0  t 
2
6. A ball A collides elastically with an another identical ball B with velocity 10 m/s at an
angle of 300 from the line joining their centres C1 and C2 . Select the correct
alternative(s)-
A) Velocity of ball A after collision is 5 m/s
B) Velocity of ball B after collision is 5 3 m / s
C) Both the balls move at right angles after collision
D) Kinetic energy will not be conserved here, because collision is not head on
Jr.IIT_CO SC Page 5
SECTION - II
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. A smooth ring is fixed horizontally on a smooth horizontal surface. From a point A of
the ring, a particle is projected at an angle  to the radius vector at A. If the coefficient
of restitution between the ring and the particle is 0.5 and the particle returns to the
point of projection A after two reflections, then cot 2  is equal to
8. Two vertical walls are separated by a distance of 2 meters. Wall ‘A’ is smooth while
wall B is rough with a coefficient of friction   0.5 A uniform rod is probed between
them. The length of the longest rod in meters that can be probed between the walls is
equal to
9. A rigid massless beam is balanced by a particle of mass 4m in left hand side and a
pulley particle system in right hand side. The value of x/y is
Jr.IIT_CO SC Page 6
10. Calculate the force ‘F’ in Newton that is applied horizontally at the center of the wheel
which is necessary to raise the wheel over the obstacle of height 0.4m. Radius of the
wheel is 1m and its mass is 10kg  g  10ms 2 
11. A L shaped, uniform rod has its two arms of length l and 2 l . It is placed on a rough
horizontal table and a string is tied at the bend. The string is pulled horizontally so that
the rod slides with constant speed. The angel  that the longer side makes with the
string is given by    tan 1  N  . The value of N is (Assume that the rod exerts
uniform pressure at all points on the table.)
12. A uniform hemispherical shell in equilibrium is on rough incline on the verge of

sliding. The angle  in degree that the circular base of the hemisphere makes with the
 1 
horizontal is  sin   
 2 2
Jr.IIT_CO SC Page 7
13. The ladder in equilibrium is shown in figure has negligible mass and rests on a
frictionless floor. The crossbar connects the two legs of the ladder at the middle. The
angle between the two legs in 600 . The fat person sitting on the ladder has a mass of 80
Newton. The value of X is  g  10m / s 2 

80
kg. Tension in the crossbar is
X
14. An oblique projectile of mass 1 kg is projected at an angle 300 with the horizontal with
velocity of 20 m / s . After 1.5 sec of projection the magnitude of torque on it
(in SI ) is (ignore air resistance)  g  10 m / s 2 
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases
Paragraph for Question Nos. 15 to 16:
A uniform metal sheet of mass M has been folded to give it L shape and it is placed on
a rough floor as shown in figure. Wind is blowing horizontally and hits the vertical
face of the sheet as shown. The speed of air varies linearly from zero at floor level to
v0 at height L from the floor. Density of air is  . Assume that air particles striking the
sheet come to rest after collision, and that the friction is large enough to prevent the
sheet from sliding
Jr.IIT_CO SC Page 8
15. The torque of wind about y-axis as shown in figure is
1 2 3 3 2 3  v02 3
A)  v02 L3 B)  v0 L C)  v0 L D) L
2 2 4
16. The sheet will not topple if
Mg 2Mg 3Mg Mg
A) v0  B) v0  C) v0  D) v0 
 L2  L2  L2 3 L2

A uniform circular disc of radius R and mass M is rotating about an axis passing
through its center and perpendicular to its plane. It is gently placed on a rough
horizontal surface with its plane in contact with the surface. The coefficient of friction
between the surfaces is  .
17. The frictional torque on the disc is
1 2 3
A)  MgR B)  MgR C)  MgR D)  MgR
3 3 2
18. If the initial angular speed of the disc is 20 rad / s and friction offers an angular
deceleration of  rad / s 2 then the number of rotations made by the disc before coming
to rest is
A) 50 B) 100 C) 150 D) 200
Jr.IIT_CO SC Page 9
CHEMISTRY MAX.MARKS: 60
SECTION- I
option.
19. Among the following correct order is/are
A) Melting point order: LiCl  NaCl  KCl  RbCl  CsCl
B) Melting point order: LiF  LiCl  LiBr  LiI
C) Thermal stability: BeCO3  MgCO3  CaCO3  SrCO3  BaCO3
D) Solubility in water: BeCO3  MgCO3  CaCO3  SrCO3  BaCO3
20. When Z-axis is internuclear axis, which of the following causes zero overlapping
A) px  p y B) px  s C) p y  s D) p y  p y
21. In which of the following molecules, different bond lengths present?

A) BrF5 B) ClF3 C) SF4 D) IF7
22. In which of following cases, d x2  y 2 orbital used in hybridization
A) d 3 s (tetrahedral) B) sp 3d 3
C) sp 3d (square pyramidal) D) dsp 2
23. Among the following polar molecule with non-polar covalent bond is/are
A) O3 B) PCl3 C) SF4 D) XeF4
A) Bond energy:  3 p 3 p   1s 3 p   1s 1s
B) Bond energy:  2 p 2 p   3 p 3 p   4 p 4 p   5 p 5 p
C) Bond energy:  3 p 3 p   3 p 3d   3d 3d
D) Bond energy: Bond formed with hybrid orbitals > Bond formed with corresponding
atomic orbitals.
Jr.IIT_CO SC Page 10
SECTION - II
 N 0 A  Z   Z   e 2  1 
25. Born-Lande equation for lattice energy is U   1   , where
r  n
N 0  Avogadro’s number, A  Madelung’s constant, Z  , Z   Charge of cation, anion,
e  Charge of electron, r  Distance between cation and anion, n  Born exponent.
‘n’ valued depends on the electronic configuration of cation and anion. ‘n’ value for
NaCl is
26. In how many of the following molecules, central atom undergo no hybridization
(satisfy Drago’s rule).
NH 3 , PH 3 , AsH 3 , SbH 3 , H 2O, H 2 S , H 2 Se, H 2Te, CH 4 , SiH 4 , CCl4 , SCl2 ,
Cl2O, PCl3 , SO2 , NCl3 , Br2O, PH 4 , AsH 4 , SCl4
27. In IF5 number of 900 bond angles are

28. Among the following how many statement(s) is/are correct about ethene  C2 H 4 
molecule (z-axis is internuclear axis,   bond is  py   py )
a) Ground state electronic configuration of carbon is used to explain bonding

b) The ratio of hybrid orbitals and pure atomic orbitals involved in the bonding is 1:1
c)xz-plane is molecular plane
d)xz-plane is nodel plane for   bond.
e) 2 s,2 px ,2 p y orbitals of carbon involved in the hybridization
f) Sigma electron cloud is in xz-plane

g) It is planar molecule
29. In water molecule bond angle is 1040 281 , percentage of p-character of hybrid orbital
 1
involved in the bonding is  cos1040 281   
 4
30. The dipole moment of H 2 S is 0.95D. Bond angle in H 2 S is 970 . H-S bond length is
1.32A0 , percentage of ionic character of H-S bond is ( cos970  0.925,

cos 48.50  0.662 )
(I) N  N bond length: N 2 H 4  N 2 F4
(II) C  Cl bond length: CH 3Cl  CF3Cl
1 2 3 4 5 6 7 8 9 10 11
(III) H 2 C  C H  C  C  C H 2  C H  C H  C H  C H  C H 2  C H 3
C – C bond length: C10  C11  C9  C10  C7  C8  C2  C3
(IV) X  P  X : POF3  POCl3  POBr3 ; where X-halogen
(V) In HCHO, HCO  HCH
(VI) Bond angle: NO2  NO2  NO2
(VII) Bond angle: NH 3  PH 3  AsH 3
(VIII) Bond angle at Oxygen:  CH 3 2 O   SiH 3 2 O
(IX) Bond angle at Nitrogen: CH 3 NCO  SiH 3 NCO
(X) Bond angle: NH 3  NH 4
(XI) Bond angle: H 2O  H 3O 

32. Total number of non-bonding electron pairs in the molecule ClF3 is/are
SECTION – III
(COMPREHENSIN TYPE)
Lewis dot structures, in general, do not represent the actual shapes of the molecules. In
case of polyatomic ions, the net charge is possessed by the ion as a whole and not by a
particular atom. It is, however, feasible to assign a formal charge on each atom. The
formal charge of an atom in a polyatomic molecule or ion may be defined as the
difference between the number of valence electrons of that atom in an isolated or free
state and the number of electrons assigned to that atom in the Lewis structure.
The counting is based on the assumption that the atom in the molecule owns one
electron of each shared pair and both the electrons of a lone pair.
Formal charges help in the selection of the lowest energy structure from a number of
possible Lewis structures for a given species. Generally the lowest energy structure is
the one with the smallest formal charges on the atoms. The formal charge is a factor
based on a pure covalent view of bonding in which electron pairs are shared equally
by neighbouring atoms.
For SCN  three Lewis dot structures are possible
S  C  N   S  C  N   S  C  N 
  
I   II   III 
(l.p. at the atoms not given)
15. Correct statement among the following is
A) Formal charge of an atom will not change from one structure to other structure
B) Sum of formal charges of all atoms  C , S , N  in SCN  is zero
C) Formal charge of sulphur in the structure-I, II and III is 0, -1 and -1 respectively
D) Formal charge of nitrogen in the structure-I, II and III is -1, 0 and -2 respectively.
16. Most stable structure of SCN  is
A) I B) II C) III D) All are equally stable
Dipole moment a molecule is the vector sum of dipole moments of all the bonds in it.
Dipole moment of C-H, C  Cl and C  O are XD, YD and ZD. (Assume that no
deviation is observed in the bond angles)
17. Dipole moment of CH 3Cl and
O
CH 3  C  CH 3 are
A)  3 X  Y  D,  6Y  Z  D B)  X  Y  D,  X  Z  D
C)  3 X  Y  D,  6Y  Z  D D)  X  Y  D,  X  Z  D
18. Among the following dipole moment highest for
Cl
Cl Cl Cl
Cl Cl
A) B) C) D)
Cl Cl
Cl
Cl
MATHEMATICS MAX.MARKS: 60
SECTION- I
option.
37. Equation x 3  10x 2 y  xy 2  4y3  0 represented three straight lines, out of these
three, two lines makes equal angle with y = x and   0 , then the value of  is
A) 7 B) -8 C) 8 D) 9
38. If the line y = mx bisects one of the angles between the lines x 2  4xy  2y 2  0 then
'm' can be equal to
5 1 5 1 1
A) B) -2 C) D)
2 2 2
39. The lines 3x 2  8xy  3y 2  0 and the line 3x 2  8xy  3y 2  2x  4y  1  0 forms a
quadrilateral ABCD. Which of the following is/are true for the formed quadrilateral ?
A) The quadrilateral is a square
B) From a quadrilateral whose one of the diagonal has the equation as 2x  4y  1  0
 3 1 
C) One of the vertex of the quadrilateral can be  , 
 10 10 
D) Form a quadrilateral whose one of the sides, has the equation as 3x  y  1  0
40. Two adjacent vertices of a parallelogram are (-1, 3) and ( -2, 4). If the area of the
parallelogram be 12 square unit and the point of intersection of diagonals lies on
positive side of X-axis, then the coordinates of one of vertices are
A)  7,  3 B) 17,  3 C) 18,  4  D)  6, 4 
41. Two straight lines u = 0 and v = 0 passes through the origin and angle between them is
tan 1  7 / 9  . If the ratio of the slope of v = 0 and u = 0 is 9/2, then their equations are
A) y  3x and3y  2x B) 2y  3x and3y  x
C) 3x  y  0 and 2y  3x  0 D) 3x  2y  0 and 3y  x  0
42. If AOB is isosceles where O is origin and OA, OB are equal sides which are

represented by the pair of equations 7x 2  8xy  y 2  0 then the equation of AB can
be
A) x  2y  7  0 B) x  2y  3  0
C) 2x  y  5  0 D) 2x  y  6  0
SECTION - II
43. If the equation ax 2  2hxy  by 2  2gx  2fy  c  0 represents two straight lines which
 af   ch 
intersect each other on the X-axis then the value of      is, ...........
 gh   fg 
44. If the pairs of the lines x 2  2xy  y 2  0 and x 2  2xy  y 2  0 have exactly one
line in common, then joint equation of the other two lines is given by
ax 2  2hxy  by 2  0 ,
( where a, b, h are positive integers such that HCF(a, h)=1), then the value of
(a-b+h-1) is...............
45. The pair of lines joining the origin to the points of intersection of the curve
9x 2  16y 2  144 by the line 2x  2y    0 are coincident(   0 ), then  is equal to
46. The area bounded by y  x  1, y   x  1 is .............
47. The number of lines that can be drawn through the point (4, -5) at a distance of 10
units from the point (1, 3) is.............
48. If the pair of straight lines xy - x- y + 1 = 0 and the line ax+ 2y - 3 = 0 are concurrent
then a = ..............
49. If x 2  y 2  2 y  a 2 represents a pair of perpendicular lines, then  / a  ..........
The distance between the parallel lines given by  x  7y   4 2  x  7y   42  0

2
50.
SECTION – III
(COMPREHENSIN TYPE)
If L, M are feet of perpendiculars from (c, 0) on the pair of lines ax 2  2hxy  by 2  0 .
Then

51. Slope of the line LM is
ba ab ba ab

A) B) C) D)
h h 2h 2h

52. Equation of the line LM is
A)  a  b  x  hy  bc  0 B)  b  a  x  hy  bc  0
C)  a  b  x  2hy  bc  0 D)  a  b  x  2hy  bc  0

Consider the equation of a pair of straight lines as xy  8x  9y  12  0
53. The value of  is
A) 0 B) 2 C) 4 D) 6
54. The point of intersection of lines is  ,   , then the equation whose roots are ,  is
A) 4x 2  x  8  0 B) 6x 2  x  12  0
C) 4x 2  x  8  0 D) 6x 2  x  12  0

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SEC: JR_*CO-SC Date: 05-09-21

Time: 3 Hrs Max. Marks: 180

A) The forces may be acting radially from a point on the axis

B) The forces may be acting on the axis of rotation

C) The forces may be acting parallel to the axis of rotation

B) the magnitude of force on the spool at B in order to maintain equilibrium is

A) In equilibrium, tension in the thread is 3mg / 2 .

B) In equilibrium, tension in the thread is 3 3mg / 2

D) Total energy of ball not remain conserved

The rate of loading is constant and equal to  kgs 1 .

A) Velocity of ball A after collision is 5 m/s

B) Velocity of ball B after collision is 5 3 m / s

C) Both the balls move at right angles after collision

point of projection A after two reflections, then cot 2  is equal to

pulley particle system in right hand side. The value of x/y is

12. A uniform hemispherical shell in equilibrium is on rough incline on the verge of

Newton. The value of X is  g  10m / s 2 

(in SI ) is (ignore air resistance)  g  10 m / s 2 

16. The sheet will not topple if

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17. The frictional torque on the disc is

A) 50 B) 100 C) 150 D) 200

21. In which of the following molecules, different bond lengths present?

C) Bond energy:  3 p 3 p   3 p 3d   3d 3d

Cl2O, PCl3 , SO2 , NCl3 , Br2O, PH 4 , AsH 4 , SCl4

27. In IF5 number of 900 bond angles are

a) Ground state electronic configuration of carbon is used to explain bonding

f) Sigma electron cloud is in xz-plane

1.32A0 , percentage of ionic character of H-S bond is ( cos970  0.925,

(IX) Bond angle at Nitrogen: CH 3 NCO  SiH 3 NCO

(X) Bond angle: NH 3  NH 4

(XI) Bond angle: H 2O  H 3O 

46. The area bounded by y  x  1, y   x  1 is .............

49. If x 2  y 2  2 y  a 2 represents a pair of perpendicular lines, then  / a  ..........

The distance between the parallel lines given by  x  7y   4 2  x  7y   42  0

ba ab ba ab

Paragraph for Question Nos. 53 to 54:

53. The value of  is

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