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SEC:SR_*CO-SC(MODEL-A&B) Date: 21-03-24


Time: 3 Hrs Max. Marks: 180
21-03-24_SR.IIT_STAR CO
CO-SC(MODEL-A&B) _JEE ADV_RPTA
PTA-1_SYLLABUS

MATHEMATICS: Vectors+3D
Vectors+3D,Sets & Relations

PHYSICS: Ray & wave Optics

CHEMISTRY: Gaseous state & Nomenclature


Nomenclature, Chemical bonding,
bonding Atomic
structure
यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19 – 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 33-36) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

:CHEMISTRY
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N:37 – 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec –III(Q.N : 51-54) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

SR.IIT_*CO SC Page No:2


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
MATHEMATICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. Let a1 , a 2 , a 3  R  0 and a1  a 2 cos 2x  a 3 sin 2 x  0 for all x  R then which of the
following is(are) correct?

A) Vectors a  a1i  a 2 j  a 3 k and b  4i  2j  k are perpendicular to each other.

B) Vector a  a1i  a 2 j  a 3 k and b  i  j  2k are parallel to each other.

C) If vector a  a1i  a 2 j  a 3 k is of length 6 units then one of the ordered triplets


 a1 , a 2 , a 3   1, 1, 2 

D) If 2a1  3a 2  6a 3  26 then a1i  a 2 j  a 3 k is 2 6

3 7
2. Let x, y, z be unit vectors such that x  y  z  a, x   y  z   b,  x  y   z  c, a.x  , a.y 
2 2

and a  2 . Then which of the following is(are) true?

3a  4b  8c
A) x  B) y  4c
3

4 3a  4b  8c
C) z 
3

cb  D) x  y 
3

3. A tetrahedron has three of its vertices at A,B and C where


OA  3i  2j, OB  i  3j  k,
 OC  2j . The fourth vertex D is such that DA.AB  0  DA.AC .

The volume of the tetrahedron is 3 2 cubic units and D lies on origin side of the plane
ABC. Which of the following statement(s) is(are) true?

SR.IIT_*CO SC Page No:3


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P

A) The unit vector perpendicular to the face ABC is


2

1  
j k 
B) The vector equation of the line AD is r   3i  2j    j  k     R 

C) The coordinates of D are  3, 3 2  2, 3 2 

D) The coordinates of D are  3,3 2  2,3 2 

x 1 y  3 z 1
4. Consider a plane P Containing the line L :   . If Q (1,10,1) be a point in
1 2 3
space then
A) Equation of plane P located at maximum distance from Q is x  5y  3z  11  0
B) Equation of plane P located at minimum distance from Q is 3x-z = 2
C) Image of Q with respect to L is (3,0,7)
D) Orthogonal projection of Q on L is (2,5,4)
5. Let P be the plane 3x  2y  3z  16 and let S= { i  j   k :  2  2   2  1 and the
7   
distance of  , ,   from the plane P is }. Let u, v and w be three distinct vectors in S
2
     
such that u  v  v  w  w  u . Let V be the volume of the parallelepiped determined
   32
by vectors u, v and w . Then the value of V is divisible by
3

A) 3 B) 15 C) 6 D) 9

6. P1 : 2x  y  z  5, P2 : x  y  4z  7, P3 : 7x  5y  6z  17 be three planes and let 'Si ' be the


set of points lying on "Pi "  i  1, 2,3 . Then which of the following options is(are)
correct?
A) Number of real values of  for which atleast 2 points exist in S1  S2  S3 is 2
B) Number of real values of  for which atleast 3 points exist in S1  S2  S3 is 1
C) Sum of positive integrals values of   10 for which S1  S2  S3 is a singleton
set is 43.
D) Distance from origin to P2 is less than distance from origin to P1 and P3 when
P1 , P2 , P3 are three planes which have more than one common point.

SR.IIT_*CO SC Page No:4


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. The minimum distance of the point (1,1,1) from the plane x  y  z  1 measured
x  x1 y  y1 z  z1
perpendicular to the line   is k where 3k 2 is equal to
1 2 3

8. If A,B,C,D are four points in space such that AB  CD  2i  j  k,


 BC  AD  3i  j  2k,

CA  BD  2i  k then area of the triangle formed by the points A,B,C (in sq units) is k,

then value of 4k 2 is

9. If a  3, b  4, c  5, d  6 then the sum of minimum and maximum values of a  b  c  d

is

10. If a 2  b 2  c 2  1 then the greatest value of  5b  4c    5a  3c    4a  3b  is ___


2 2 2

11. Let p    x  y    y  z     y  z    z  x     z  x    x  y  and 8         p.

 x  y  y  z  z  x  for positive numbers , ,  then the volume of the parallelepiped

whose coterminus edges are x, y, z is ____

12. If the equation of a plane passing through the point of intersection of lines
x 1 y  2 z  3 x  3 y 1 z  2
  and   and at greatest distance from origin is
3 1 2 1 2 3
4x  ay  bz  c then the value of a  b  c is

13. Number of real values of a for which the planes r. i  j  k   1, r.i  2a j  k   2 and r .

 ai  a j  k   3 intersect in a line is


2

14. If the lattice point (x,y,z) where x, y, z  I (set of integers) with the largest value of z
such that the point ‘p’ lies on the planes 7x  6y  2z  272 and x  y  z  16 ( Given
xyz
x, y, z  0 ) then the value of is equal to
11

SR.IIT_*CO SC Page No:5


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 15 to 16:
A ray of light emanicipating from the point P 1, 3, 2  and travelling parallel to the line
x2 y z2
  is incident on the plane x  y  3z  0 at the point Q. After reflecting
1 3 2
from the plane the ray travels along the line QR. It is also known that the incident ray
reflected ray and the normal to the plane at the point of incidence are in the same plane.
15. The equation of line QR is
x  12 y  22 z  4 x  3 y  15 z  6
A)   B)  
15 37 10 3 7 2
x 3 y  6 z 3 x 3 y6 z3
C)   D)  
15 37 10 3 7 2
16. The equation of plane PQR is

A) 5x  2y  z  3  0 B) 11x  5y  2z  30

C) 5x  y  z  6 D) x  y  z  6

Paragraph for Question Nos. 17 to 18:


The vertices of triangle ABC are A(3,1,3), B(0,2,2) and C(2,-1,5). Points D and E
divide AB, CA in the ratio 1:2 respectively. P is a point in space such that the
perpendicular from it to the plane of ABC meets at F where F is the point of
intersection of CD and BE. Also the distance of P from the plane of ABC is 2 (P lies
on non-origin side of the plane ABC)

17. The vector FP is

A) 7i  7j  7k B)


2

7  
j k  C) 7j  7k D) j  k

18. The volume of tetrahedron PABC is (incubic units)

4 7 7
A) B) 7 C) D)
7 3 4

SR.IIT_*CO SC Page No:6


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
19. In a young’s double – slit experiment, the separation between the two slits is d and
wavelength of light is  . The intensity of light falling on slit 1 is four times the
intensity of light falling on slit 2. Find the correct choices:

A) If d   , the screen will contain one maximum

B) If   d  2 , at least one more maximum (besides the central maximum)

C) If the intensity of light falling on slit 1 is reduced so that it becomes equal to that of
slit 2, the intensities of the observed minima will decrease

D) If the intensity of light falling off on slit 2 is increased so that it becomes equal to
that of slit 1, the intensities of the observed minima will decrease

20. Two coherent point light sources are placed at x = -d/2 and x = d/2. These sources are
surrounded by a spherical screen having equation x 2  y2  z 2  R 2  R  d  . The sources
emit monochromatic light at wavelength   d / 3

A) The number of maxima produced on the screen are 7

2R 5
B)The shape and length of second order maxima is circle,
3

C) If radius of screen is doubled the intensity of maxima will become one fourth

D) All maxima are equally spaced along x-axis

SR.IIT_*CO SC Page No:7


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
21. In an interference experiment similar to Young’s double slit experiment, the silts
S1 and S2 are illuminated with coherent microwave sources, each of frequency of 106 Hz .

The sources are synchronized to have zero phase difference. The slits are separated by
a distance d  150.0 m . The intensity I    is measured as a function of  , where  is
defined as shown.

If I0 is the maximum intensity, then I    for 0    900 is given by

I0 I0
A) I     for   300 B) I     for   900
2 4

C) I     I0 for   00 D) I    is constant for all

22. For an isosceles prism of angle A and refractive index  , it is found that the angle of
minimum deviation m  A . Which of the following options is/are correct?

A) For the angle of incidence i1  A, the ray inside the prism is parallel to the base of
the prism

B) For this prism, the refractive index  and the angle of prism A are related as
1 
A  cos 1  
2 2

C) At minimum deviation, the incident angle i1 and the refracting angle r1 at the first
i
refracting surface are related by r1   1 
2

D) For the prism, the emergent ray at the second surface will be tangential to the
surface when the angle of incidence at the first surface is
 A 
i1  sin sin A 4 cos 2  1  cos A 
 2 

SR.IIT_*CO SC Page No:8


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
23. A transparent slab of thickness d has a refractive index n(z) that increases with z. Here
z is the vertical distance inside the slab, measured from the top. The slab is placed
between two media with uniform refractive indices n1 and n 2   n1  , as shown in the
figure. A ray of light is incident with angle i from medium 1 and emerges in medium
2 with refraction angle f with a lateral displacement  .

Which of the following statement(s) is (are) true?


A) n1 sin i  n 2 sin f B) n1 sin i   n 2  n1  sin f

C)  is independent of n 2 D)  is dependent of n(z)


24. A plane polarized blue light ray is incident on a prism such that there is no reflection
from the surface of the prism. The angle of deviation of the emergent ray is   600 (see
Figure-1). The angle of minimum deviation for red light from the same prism is
min  300 (see Figure-2). The refractive index of the prism material for blue light is 3 .
Which of the following statement(s) is(are) correct?

A) The blue light is polarized in the plane of incidence.


B) The angle of the prism is 450 .
C) The refractive index of the material of the prism for red light is 2

D) The angle of refraction for blue light in air at the exit plane of the prism is 600

SR.IIT_*CO SC Page No:9


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. Consider a concave mirror and a convex lens (refractive index = 1.5) of focal length 10
cm each, separated by a distance of 50 cm in air (refractive index = 1) as shown in the
figure. An object is placed at a distance of 15 cm from the mirror. It’s erect image
formed by this combination has magnification M1 . When the set-up is kept in a medium
7 M
of refractive index , the magnification becomes M 2 . The magnitude 2 is.
6 M1

26. A monochromatic beam of light is incident at 60° on one face of an equilateral prism of
refractive index n and emerges from the opposite face making an angle   n  with the
d
normal (see the figure). For n  3 the value of  is 600 and  m . The value of m is.
dn

SR.IIT_*CO SC Page No:10


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
27. The point S is monochromatic source of light emitting light of wavelength  . At the
point P at a distance x from the mirror as shown in the figure, interference takes place
between two light rays one directly coming from source S and another after reflection
from the mirror such that a maxima is formed. The value of x may be______  .

3
28. A thin convex lens is prepared from glass of refractive index g  . The two convex
2
surfaces have equal radii of 20 cm each. One of the surfaces is silvered from outside to
5
make it reflecting. The lens now is placed in a large medium of refractive index 1  .
3
It’s effective focal length will be_____cm.
29. At a point on the screen in YDSE experiment 3rd maxima is observed at time t  0 sec .
Now screen is slowly moved with constant speed away from the slits in such a way that
the centre of slits and centre of screen lie on the same line always and at t  1 sec the
intensity at that point is observed (3/4)th of maximum intensity in between 2nd and 3rd
maxima.
(Here D = separation between the screen and slits. d = separation between the slits,
0
d  D,   5000 A ) The speed of the screen is________D.

30. A light ray (AB) is incident parallel to principal axis (XY) at a distance of R/2 (R is
radius of curvature of the concave mirror) from principal axis as shown. BCD is the
reflected ray which intersects principal axis at C. If O is centre of curvature and P is the
pole of the mirror, the value of x is _____ R

SR.IIT_*CO SC Page No:11


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
31. An equi-convex lens of focal length 10cm in air and refractive index  g  1.5  is placed
1 
in a liquid whose refractive index varies with time as   t   1.0  t , (t in sec). Lens
 10 
will acts as concave lens of focal length 20 cm t = 5n (in sec). Find n.
32. A converging lens (focal length f) is broken into two equal pieces as shown in the
figure and the two pieces are placed 60 cm apart as shown along with the object. It is
found that real images are formed at the same place and ratio of image heights is 9:1, if
1
the value of f is  20   cm, then value of x is_____.
 x

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 33 to 34:
Light guidance in an optical fiber can be understood by considering a structure
comprising of thin solid glass cylinder of refractive index n1 surrounded by a medium
of lower refractive index n 2 . The light guidance in the structure takes place due to
successive total internal reflections at the interface of the media n1 and n 2 as shown in
the figure. All rays with the angle of incidence i less than a particular value i m are
confined in the medium of refractive index n1 . The numerical aperture (NA) of the
structure is defined as sin i m .

SR.IIT_*CO SC Page No:12


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
33. For two structures namely S1 with n1  45 / 4 and n 2  3 / 2 and
S2 and n1  8 / 5 and n 2  7 / 5 and taking the refractive index of water to be 4/3 and that of
air to be 1, the correct option(s) is (are)
A) NA of S1 immersed in water is the same as that of S2 immersed in a liquid of
16
refractive index
15
6
B) NA of S1 immersed in liquid of refractive index is the same as that of S2
15
immersed in water
C) NA of S1 placed in air is the same as that of S2 immersed in liquid of refractive
4
index
15

D) NA of S1 placed in air is the same as that of S2 placed in water.


34. If two structures of same cross-sectional area, but different numerical apertures NA1
and NA 2  NA 2  NA1  are joined longitudinally, the numerical aperture of the combined
structure is
NA1NA 2
A) B) NA1  NA 2 C) NA1 D) NA 2
NA1  NA 2

Paragraph for Question Nos. 35 to 36:


Most materials have the refractive index, n > 1. So, when a light ray from air enters a
sin 1 n 2
naturally occurring material, then by Snell’s law,  , it is understand that the
sin 2 n1
refracted ray bends towards the normal. But it never emerges on the same side of the
normal as the incident ray. According to electromagnetism, the refractive index of the
c
medium is given by the relation n       r  r , where c is the speed of
v
electromagnetic waves in vacuum, v its speed in the medium r and r are positive,
implying positive n for the medium. When both r and r are negative, on must choose
the negative root of n. Such negative refractive index materials can now be artificially
prepared and are called meta-materials. They exhibit significantly different optical
behavior, without violating any physical laws. Since n is negative, it results in a change
in the direction of propagation of the refracted light. However, similar to normal
materials, the frequency of light remains unchanged upon refraction even in meta-
materials.

SR.IIT_*CO SC Page No:13


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
35. For light incident from air on a meta-material, the appropriate my diagram is:

A) B)

C) D)

36. Choose the correct statement

A) The speed of light in the meta-material is v  c n

c
B) The speed of light in the meta-material is v 
n

C) The speed of light in the meta-material is v = c

D) The wavelength of the light in the meta-material   m  is given by  m  air n , where


 air is the wavelength of the light in air.

SR.IIT_*CO SC Page No:14


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
CHEMISTRY MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
37. The van der Walls constants (a and b) of two gases A and B are
a /dm6atm mol 2 b /dm3 mol1
A: 1.360 0.0318
B: 3.592 0.0426

The critical parameters Pc:Vc:Tc are related as


A) Pc (A) < Pc (B) B) Vc (A) < Vc(B)
C) Tc (A) < Tc(B) D) Tc ( A )  Tc (B )
38. Which of the following samples of reducing agents is /are
chemically equivalent to 25ml of 0.04M KMnO4 to be reduced to Mn2

A)25ml of 0.1M SnCl2 to be oxidized to Sn 4

B)50ml of 0.1M H 3 AsO3 to be oxidized to H 3 AsO4

C)25ml of 0.1M H 2O2 to be oxidized to O2

D)25ml of 0.2M FeSO4 to be oxidized to Fe3

39. For a gas which of the following statements are correct?

A) Inversion temperature is double than Boyle temperature

B) Boyle temperature is double than inversion temperature

C) Critical temperature is less than inversion and Boyle temperatures

D) Inversion temperature is more than Boyle temperature and critical temperature

SR.IIT_*CO SC Page No:15


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
40. Which is correct IUPAC name among the following?

A) Styrene is phenyl ethene

B) Mesitylene is 2,4,6-trimethyl benzene

C) Acetophenone is phenyl ethanone

D) Salicylic acid is 2-hydroxy benzoic acid

41. The IUPAC name(s) of the following compound is (are)

A)1-chloro – 4 - methylbenzene

B)4 – chlorotoluene

C)4 – methylchlorobenzene

D)1 – methyl – 4 -chlorobenzene

42. Choose the correct statement among the following.

 
A) Radial distribution function  2 . 4 r 2 dr gives probability at a particular distance

along one chosen direction.

B) The number of radial nodes for a 2s orbital is two.

C) For s – orbital, the wave function  nlm (r , ,  ) depends only on ‘r’ and is independent
of  and  .

D) '2 p ' orbital with quantum numbers, n  2, l  1 and m  0 also shows angular
dependence.

SR.IIT_*CO SC Page No:16


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
43. How many of the following statements are incorrect?

I. LiCl has lower melting point than NaCl .

II. LiCl dissolves more in organic solvents whereas NaCl does not.

III. An ionic compound A B  is most likely to be formed when the ionization energy
of A is high and electron affinity of B is low.

IV. Among calcium halides, CaF2 is the most ionic.

44. In how many of the following pairs, both the species are isostructural?

(I) [ NF3 and BF3 ] (II) [ BF4 and NH 4 ]

(III) [ BCl3 and PCl3 ] (IV) [ NH 3 and NO3 ]

45. In how many of the following molecules, the central atom carries two or more lone
pairs?

PCl3 , SO2 , ClF3 , H 2O, PCl5 , XeF2 , XeF6 , IF5 , BCl3

46. In the preparation of iron from hematite ( Fe2O3 ) by the reaction

with carbon Fe2O3  C  Fe  CO2 ,how many kg of 80% pure iron could be
produced from 120kg of 90% pure Fe2O3 ?
47. For a gas obeying P V  b   RT a graph is plotted between volume (V lit.) on Y-axis
and temperature (K) on X-axis at a constant pressure of 0.04105 atm. Find the slope of
the line.

SR.IIT_*CO SC Page No:17


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
48. 0.144 g of pure FeC2O4 was dissolved in dilute H 2 SO4 and the solution was diluted to
100 ml. What volume in ml. of 0.1 M KMnO4 will be needed to oxidise FeC2O4
solution?

49. A Li 2 ion is in a higher excited state of quantum number ' n ' . This excited ion can
make a transition to the first excited state by successively emitting two photons of
energies 10.2 eV and 17.0 eV respectively. The value of ' n ' is __________

50. On a metal with work function 2.0 eV, light of wavelength 400 nm falls. Then
maximum velocity of ejected photoelectrons is x  105 m / s . Hence x is _______

(Given h  6.625 1034 J .s ; c  3 108 m / s ; 1eV  1.6 1019 J and mass of e-  9.11031 kg )

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 51 to 52:
The process of the addition of the standard solution of intermediate solution of a
reactant, i.e., titrant from the burette to the measured volume of solution of the
substance to be estimated until the reaction between the two is just complete, i.e., till
the 2nd substance is completely used up, (i.e., upto the end point) is termed as titration
or volumetric estimation. Titration is classified in following two categories :

a) Acid-base titrations, b) Redox tritrations

The acid-base titrations are further classified in following three categories:

a) Simple titration, b) Back titration, c) Double titration

In simple titration, we can find the concnetration of substance with the help of the
standard solution of another substance which can react with it. Back titration is usually
used to calculate % purity of a sample.

In double titration two indicators, phenolphthalein (HPh) and methyl orange (MeOH)
respectively are used namely.

SR.IIT_*CO SC Page No:18


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
51. A solution contained Na2CO3 and NaHCO3 . 15 mL of the solution required 5 mL of N/10
HCl for neutralization using phenolphthalein as an indicator. Addition of methyl
orange after I end point required a further 15 mL of the acid for neutralization. The
amount of Na2CO3 present in one litre of the solution is:

A) 21.2 g B) 3.53 g C) 0.212 g D) 4.24 g

52. The volume of 0.1 N HCl required to neutralize completely 2 g of equimolar mixture of
Na2CO3 and NaHCO3 is:

A) 316 mL B) 158 mL C) 632 mL D) 237 mL

Paragraph for Question Nos. 53 to 54:


Ideal gas equation is represented as PV = nRT. Gases present in universe were found
ideal in the Boyle’s temperature range only and deviated more from ideal gas behavior
at high pressure and low temperature. The deviations are explained in terms of
PV
compressibility factor Z. For ideal behavior Z   1 . The main cause to show
nRT
deviations were due to wrong assumptions made about forces of attractions (which
becomes significant at high pressure) and volume (V) occupied by molecules in PV =
nRT is supposed to be volume of gas or the volume of container in which gas is placed
by assuming that gaseous molecules do not have appreciable volume. Actually volume
of the gas is that volume in which each molecule of a gas can move freely. If volume
occupied by gaseous molecule is not negligible, then the term V should be replaced by
the ideal volume which is available for free motion of each molecule of gas in 1 mole
gas.

Vactual = volume of container – volume occupied by molecules

V b

Where, b represents the effective volume of co-volume or excluded volume occupied


by molecules present in one mole of gas.

Similarly for n mole gas Vactual  V  nb

SR.IIT_*CO SC Page No:19


यश TG~ @bohring_bot
Narayana IIT Academy 21-03-24_SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_RPTA-1_Q’P
53. Which of the following statements are correct?

Tc
I) Larger is the value of for a gas larger would be its excluded volume.
Pc

II) Larger is the excluded volume of gas, more will be its critical volume.

R 
III) The slope for an isochore obtained for a gas showing P V  b   RT is  .
V  b 

IV) The excluded volume for He is more than that for H 2 .

A) I, II, III B) I, II, IV C) II, III, IV D) III, IV

54. Assuming the molecules of gas as hard spheres, each of radius 2.0  1010 m, the fraction
of volume occupied by the molecules to the total volume of a given amount of gas at
27 0 C and at 1 atm pressure and 10 atm pressure respectively are:

A) 99.9%, 99% B) 0.082%, 0.82% C) 99%, 90% D)1%, 10%

SR.IIT_*CO SC Page No:20

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