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MATHEMATICS: Vectors+3D
Vectors+3D,Sets & Relations
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19 – 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 33-36) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
:CHEMISTRY
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N:37 – 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec –III(Q.N : 51-54) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
3 7
2. Let x, y, z be unit vectors such that x y z a, x y z b, x y z c, a.x , a.y
2 2
3a 4b 8c
A) x B) y 4c
3
4 3a 4b 8c
C) z
3
cb D) x y
3
The volume of the tetrahedron is 3 2 cubic units and D lies on origin side of the plane
ABC. Which of the following statement(s) is(are) true?
x 1 y 3 z 1
4. Consider a plane P Containing the line L : . If Q (1,10,1) be a point in
1 2 3
space then
A) Equation of plane P located at maximum distance from Q is x 5y 3z 11 0
B) Equation of plane P located at minimum distance from Q is 3x-z = 2
C) Image of Q with respect to L is (3,0,7)
D) Orthogonal projection of Q on L is (2,5,4)
5. Let P be the plane 3x 2y 3z 16 and let S= { i j k : 2 2 2 1 and the
7
distance of , , from the plane P is }. Let u, v and w be three distinct vectors in S
2
such that u v v w w u . Let V be the volume of the parallelepiped determined
32
by vectors u, v and w . Then the value of V is divisible by
3
A) 3 B) 15 C) 6 D) 9
CA BD 2i k then area of the triangle formed by the points A,B,C (in sq units) is k,
then value of 4k 2 is
is
12. If the equation of a plane passing through the point of intersection of lines
x 1 y 2 z 3 x 3 y 1 z 2
and and at greatest distance from origin is
3 1 2 1 2 3
4x ay bz c then the value of a b c is
13. Number of real values of a for which the planes r. i j k 1, r.i 2a j k 2 and r .
14. If the lattice point (x,y,z) where x, y, z I (set of integers) with the largest value of z
such that the point ‘p’ lies on the planes 7x 6y 2z 272 and x y z 16 ( Given
xyz
x, y, z 0 ) then the value of is equal to
11
A) 5x 2y z 3 0 B) 11x 5y 2z 30
C) 5x y z 6 D) x y z 6
4 7 7
A) B) 7 C) D)
7 3 4
C) If the intensity of light falling on slit 1 is reduced so that it becomes equal to that of
slit 2, the intensities of the observed minima will decrease
D) If the intensity of light falling off on slit 2 is increased so that it becomes equal to
that of slit 1, the intensities of the observed minima will decrease
20. Two coherent point light sources are placed at x = -d/2 and x = d/2. These sources are
surrounded by a spherical screen having equation x 2 y2 z 2 R 2 R d . The sources
emit monochromatic light at wavelength d / 3
2R 5
B)The shape and length of second order maxima is circle,
3
C) If radius of screen is doubled the intensity of maxima will become one fourth
The sources are synchronized to have zero phase difference. The slits are separated by
a distance d 150.0 m . The intensity I is measured as a function of , where is
defined as shown.
I0 I0
A) I for 300 B) I for 900
2 4
22. For an isosceles prism of angle A and refractive index , it is found that the angle of
minimum deviation m A . Which of the following options is/are correct?
A) For the angle of incidence i1 A, the ray inside the prism is parallel to the base of
the prism
B) For this prism, the refractive index and the angle of prism A are related as
1
A cos 1
2 2
C) At minimum deviation, the incident angle i1 and the refracting angle r1 at the first
i
refracting surface are related by r1 1
2
D) For the prism, the emergent ray at the second surface will be tangential to the
surface when the angle of incidence at the first surface is
A
i1 sin sin A 4 cos 2 1 cos A
2
D) The angle of refraction for blue light in air at the exit plane of the prism is 600
26. A monochromatic beam of light is incident at 60° on one face of an equilateral prism of
refractive index n and emerges from the opposite face making an angle n with the
d
normal (see the figure). For n 3 the value of is 600 and m . The value of m is.
dn
3
28. A thin convex lens is prepared from glass of refractive index g . The two convex
2
surfaces have equal radii of 20 cm each. One of the surfaces is silvered from outside to
5
make it reflecting. The lens now is placed in a large medium of refractive index 1 .
3
It’s effective focal length will be_____cm.
29. At a point on the screen in YDSE experiment 3rd maxima is observed at time t 0 sec .
Now screen is slowly moved with constant speed away from the slits in such a way that
the centre of slits and centre of screen lie on the same line always and at t 1 sec the
intensity at that point is observed (3/4)th of maximum intensity in between 2nd and 3rd
maxima.
(Here D = separation between the screen and slits. d = separation between the slits,
0
d D, 5000 A ) The speed of the screen is________D.
30. A light ray (AB) is incident parallel to principal axis (XY) at a distance of R/2 (R is
radius of curvature of the concave mirror) from principal axis as shown. BCD is the
reflected ray which intersects principal axis at C. If O is centre of curvature and P is the
pole of the mirror, the value of x is _____ R
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 33 to 34:
Light guidance in an optical fiber can be understood by considering a structure
comprising of thin solid glass cylinder of refractive index n1 surrounded by a medium
of lower refractive index n 2 . The light guidance in the structure takes place due to
successive total internal reflections at the interface of the media n1 and n 2 as shown in
the figure. All rays with the angle of incidence i less than a particular value i m are
confined in the medium of refractive index n1 . The numerical aperture (NA) of the
structure is defined as sin i m .
A) B)
C) D)
c
B) The speed of light in the meta-material is v
n
A)1-chloro – 4 - methylbenzene
B)4 – chlorotoluene
C)4 – methylchlorobenzene
A) Radial distribution function 2 . 4 r 2 dr gives probability at a particular distance
C) For s – orbital, the wave function nlm (r , , ) depends only on ‘r’ and is independent
of and .
D) '2 p ' orbital with quantum numbers, n 2, l 1 and m 0 also shows angular
dependence.
II. LiCl dissolves more in organic solvents whereas NaCl does not.
III. An ionic compound A B is most likely to be formed when the ionization energy
of A is high and electron affinity of B is low.
44. In how many of the following pairs, both the species are isostructural?
45. In how many of the following molecules, the central atom carries two or more lone
pairs?
with carbon Fe2O3 C Fe CO2 ,how many kg of 80% pure iron could be
produced from 120kg of 90% pure Fe2O3 ?
47. For a gas obeying P V b RT a graph is plotted between volume (V lit.) on Y-axis
and temperature (K) on X-axis at a constant pressure of 0.04105 atm. Find the slope of
the line.
49. A Li 2 ion is in a higher excited state of quantum number ' n ' . This excited ion can
make a transition to the first excited state by successively emitting two photons of
energies 10.2 eV and 17.0 eV respectively. The value of ' n ' is __________
50. On a metal with work function 2.0 eV, light of wavelength 400 nm falls. Then
maximum velocity of ejected photoelectrons is x 105 m / s . Hence x is _______
(Given h 6.625 1034 J .s ; c 3 108 m / s ; 1eV 1.6 1019 J and mass of e- 9.11031 kg )
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 51 to 52:
The process of the addition of the standard solution of intermediate solution of a
reactant, i.e., titrant from the burette to the measured volume of solution of the
substance to be estimated until the reaction between the two is just complete, i.e., till
the 2nd substance is completely used up, (i.e., upto the end point) is termed as titration
or volumetric estimation. Titration is classified in following two categories :
In simple titration, we can find the concnetration of substance with the help of the
standard solution of another substance which can react with it. Back titration is usually
used to calculate % purity of a sample.
In double titration two indicators, phenolphthalein (HPh) and methyl orange (MeOH)
respectively are used namely.
52. The volume of 0.1 N HCl required to neutralize completely 2 g of equimolar mixture of
Na2CO3 and NaHCO3 is:
V b
Tc
I) Larger is the value of for a gas larger would be its excluded volume.
Pc
II) Larger is the excluded volume of gas, more will be its critical volume.
R
III) The slope for an isochore obtained for a gas showing P V b RT is .
V b
54. Assuming the molecules of gas as hard spheres, each of radius 2.0 1010 m, the fraction
of volume occupied by the molecules to the total volume of a given amount of gas at
27 0 C and at 1 atm pressure and 10 atm pressure respectively are: