24-12-23 - JR - Iit - Star Co-Sc (Model-B) - Jee Adv - 2020 (P-I) - Wat-33 - QP

Sec: JR.
IIT _*CO-SC(MODEL-B) Date: 24-12-23

Time: 3 Hrs Max. Marks: 198
24-12-23_JR.IIT_STAR CO-SC(MODEL-B) _JEE ADV_WAT-33_SYLLABUS
MATHEMATICS: PRESENT WEEK (80%): Equation of Plane, Distance of point from
plane, angle between two planes, Family of Planes, Unsymmetrical form of line, Image
of point and line with respect to plane
PREVIOUS WEEK (20%) 3D-GEOMETRY: Introduction of 3-D,

Direction Ratios and Direction Cosines, Equation of straight line in Space, Angle
between two lines and interesection of two lines, Skew lines and shortest distance
between them
PHYSICS: PRESENT WEEK (80%): Electric flux, Gauss' Law, Applications of
Gauss' Law, Electric field due to spherical, cylindrical and infinite sheet like charge
distribution.(Exclude: Electric potential and potential energy, Relation between field
and potential, Conservation of energy, Potential due to various charge distributions,
Complete electric dipole, Conductors and their properties, Electrostatic pressure,
Electrostatic self-energy)
PREVIOUS WEEK (20%) ELECTROSTATICS: Electric Charge and

their properties, Coulomb's law, Electric field due to a point charge and distributed
charge (limited to collection of distcrete charges, line, ring, disc of charge), Concept of
electric field lines. (Exclude: Electric field due to spherical, cylindrical and infinite
sheet like charge distribution, Gauss law, Electric potential and potential energy,
Relation between field and potential, Conservation of energy, Potential due to various
charge distributions, Complete electric dipole, Conductors and their properties,
Electrostatic pressure, Electrostatic self- energy.)
CHEMISTRY: PRESENT WEEK (80%): Reactions of alkenes: Addition of hydrogen halide,

halogen, halogen/water, halogen/alochol, NOCl, RCl, RCOCl, addition of water,
oxymercuration- demercuration, hydroboration – oxidation, Hydroxylation
reactions, ozonolysis, oxidation by KMnO4 and reduction of alkenes (Exclude:
KMnO4/NaIO4, OsO4/NaIO4,reaction with carbenes, Simon-Smith reaction,
woodward, prevost)
PREVIOUS WEEK (20%): Alkenes: Preparation of alkenes: Mechanism of
Elimination reactions (E1,E2, E1,CB),Dehydrohalogenation, Mechanism of Elimination
reactions (E1, E2, E1CB) ,dehydrohalogenation, dehlogenation, dehydration of
alcohols, Hoffman elimination and pyrolysis of ester, Hydrogenation of alkynes and
birch reduction
Narayana IIT Academy 24-12-23_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-33_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 25 – 30) +4 -2 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
MATHEMATICS
Sec – II (Q.N : 43 – 48) +4 -2 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
JR.IIT_*CO-SC Page. No. 2

MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. Number of planes which are equidistant from 4 non coplanar points?
A) 4 B) 5 C) 7 D) 2
2. The image of the point P(3, 5, 7) in the plane 2x+y+z = 0 is
A)  9,1, 1 B)  9, 1,1 C)  9,1, 1 D)  9, 1, 1
3. Angle between the two faces of a regular tetrahedren is?

1 2 1 1
A) Cos 1 B) Cos 1 C) Cos 1 D) Cos 1
6 3 3 3
4. A plane makes intercepts OA, OB , OC whose measures are a, b, c on the axes OX , OY , OZ .

The area of the triangle ABC is
A) a 4  b 4  c 4  a 2b   b 2c2  c 2 a 2 B) a 2  b 2  c 2  bc  ca  ab
1 2  1
C) a b  b 2c 2  c 2 a 2 D)  a  b  c  b  c  a  c  a  b  a  b  c 
2 4
5. The plane lx  my  0 is rotate about its line of interaction with the plane z  0 through an
angle  . The equation of the plane in its new position is
A) lx  my  z l 2  m 2 sin   0 B) lx  my  z l 2  m 2 tan   0
C) lx  my  z l 2  m 2 cot   0 D) None of these

x 1 y   z  3 x  3 y 1 z  2
6. If the lines L1 :   and L2 :   are coplanar, then the equation
3 1 2 1 2 3
of the plane passing through the point of intersection of L1 and L2 which is at a maximum
distance from the origin is
A) 4 x  3 y  5 z  50  0 B) 4 x  3 y  5 z  50  0
C) 4 x  3 y  5 z  50  0 D) 4 x  3 y  5 z  50  0

SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. A rod of length 2 units whose one end is (1, 0, -1) and other end touches the plane x-
2y+2z+4 = 0, then
A) The rod sweeps the figure whose volume is  cubic units.
B) The area of the region which the rod traces on the plane is 2
C) The length of the projection of the rod on the plane is 3 units.
D) The centre of the region which the rod traces on the plane is (10 / 3,  2 / 3,1 / 3) .
8. Consider a pyramid OPQRS located in the first octant ( x  0, y  0, z  0) with “O” as origin,
and OP and OR along the X-axis and Y-axis respectively. The base OPQR of the pyramid
is a square with OP=3. The point S is directly above the mid-point, T of diagonal OQ
such that TS=3 Then
A) The acute angle between OQ and OS is  / 3
B) The equation of the plane containing the triangle OQS is x-y=0
3
C) The length of the perpendicular from P to the plane containing the triangle OQS is
2
units.
15
D) The perpendicular distance from ”O” to the straight line containing RS is units.
2
9. Let P1  x  y  2 z  3 and P2  x  2 y  z  4 be two planes. Let A  2, 4,5  , B  4,3,8  be two
points in space. The equation of plane P3 through the line of intersection of P1 and P2 such
that the length of the projection upon it of the line segment AB is the least, is-
A) 2 x  y  3 z  7 B) 2 x  y  3 z  7
7
C) The perpendicular distance from origin to the plane P3 is units
2
D) The DR’s of normal of the plane P3 is  2, 1,3
x 1 y z 1 x 1 y z 1
10. Let L1 and L2 be the following straight lines L1 :   and L2 :  
1 1 3 3 1 1
x   y 1 z  
Suppose L    lies in the plane containing L1 and L2 , and passes through
l m 2
the point of intersection of L1 & L2 . If the line L bisects the acute angle between the lines
L1 and L2 , then which of the following statements is/are True?
A)     3 B) l  m  2
C)     1 D) l  m  0
11. Let S be the reflection of a point Q with respect to the plane given by,
      
r    t  p  i  tj  1  p  k , where t , p  R and i , j , k are the unit vectors along the three
  
positive coordinate axes. If the position vector of Q and S are 10i  15 j  20k and
  
 i   j   k respectively, then which of the following is/are true?
A) 3      101 B) 3       71
C) 3      86 D) 3        121
12. Let P1 and P2 be two planes given by P1 :10 x  15 y  12 z  60  0, P2 :  2 x  5 y  4 z  20  0

which of the following straight lines can be edge of some tetrahedron whose two faces lie
on P1 and P2 ?
x  1 y 1 z 1 x6 y z
A)   B)  
0 0 5 5 2 3
x y4 z x y4 z
C)   D)  
2 5 4 1 2 3

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
x 3 y 5 z 7 x  2 y  2 z 1
13. The nearest line of the lines   and   to the plane
1 2 1 7 6 1
2 x  3 y  4 z  1  0 meets xy plane at P ( ,  ,  ) then      equals

14. A plane passing through (1, 1, 1) cuts positive direction of co-ordinate axes at A, B and C
k
the volume tetrahedron OABC satisfies V  l , then (k  l ) equals. (Where h.c.f of  k , l  =1)
15. If the line x  y  z intersects the line

x sin A  y sin B  z sin C  18  0  x sin 2 A  y sin 2 B  z sin 2C  9, where A, B, C are the angles of
A B C
triangle ABC, then 80  sin sin sin  is equal to_______
 2 2 2
16. The distance of the point 1, 2,3 from the plane x  y  z  5, measured parallel to the line
x y z
  is k , then the value of k is
2 3 6
17. A point P  x, y, z  moves such that x  a  2b  3, y  3a  b  1, 2 z  a  5b  2 where a and b
are parameters. The minimum distance of P from the origin, is k, find  k  where
. represents greatest integer function.

18. The number of values of ‘k’ for which planes x  3 z  kx, 5 x  4 y  ky, 3x  2 y  5 z  kz
have same line of intersection is________

PHYSICS MAX.MARKS: 66
19. In figure +Q charge is located at one of the edges of the cube as shown in figure. Then
electric flux through cube due to +Q charge is given as
Q Q Q Q
(A). (B) (C) (D)
0 2 0 4 0 8 0
20. A sphere of radius R carries charge density proportional to the square of the distance
from the center given as   Ar 2 , where A is a positive constant. At a distance of R/2
from the center, the magnitude of the electric field is:
A) A /(4 0 ) (B) AR3 /(40 0 ) (C) AR3 /(24 0 ) (D) AR3 /(5 0 )
21. ABC is an equilateral triangle of side L. A positive charge +q is kept at A. As we move
from B to C the magnitude of change in electric intensity is
1 q 1 3q 1 q
A) B) C) D) zero
4 o L2 4 o L2 4 o 3L2
22. In the figure C is the center of a hemispherical surface of radius R and P is a point
vertically below the center C at a distance R. A positive charge +q is kept at P. The
electric flux that enters the hemispherical surface is

( 2  1)q ( 2  1)q
A) B)
2 2 o 2 o
q
C) D) zero
2 o
23. In a regular polygon of n sides, each corner is at a distance a from the centre. Identical
point charges of magnitude q each are placed at  n  1 corners. The electric field at
the centre is
q q  n  q  n 1  q
(A) (B)  n  1 (C)   (D)  
4 0 a 2 4 0 a 2  n  1  4 0 a 2  n  4 0 a 2
24. Figure shows an imaginary cube of side a. A uniformly charged rod of length a moves
towards right at a constant speed  . At t=0, the right end of the rod just touches the left
face of the cube. Plot a graph between electric flux passing through the cube versus time.
A) B)
C) D)

correct options.
option.
25. An electrostatic field converges at the origin whose magnitude is given by the
expression E  106 r N / C where r is the distance from the origin
A) Total charge contained in any spherical volume with its centre at origin is positive
B) Total charge contained in any spherical volume, irrespective of the location of its
centre is negative
C) Total charge contained in a spherical volume of radius 3 cm with its center at origin
has magnitude 3  10 3 C
D) Total charge contained in a spherical volume of radius 3 cm with its centre at origin
has magnitude 3  10 9 C
26. A small point charge (q) is placed on one of the vertex of cube as shown in the figure
Then
q
A) Flux through the shaded face of cube is
6 0
q
B) Flux through the shaded face of cube is
24 0

q q
C) Flux through complete cube is D) Flux through complete cube is
8 0 0
27. A closed surface with dimensions a=b=0.4m and c=0.6m is located as in figure. The left
edge of the closed surface is located at position x  a . The electric field throughout the
region is non-uniform and given by E  (3  2 x 2 ) NC 1 where x is in meter.
A) Flux through the closed surface = 2.69 Nm 2 / C
B) Flux through the closed surface = 0.269 Nm 2 / C

C) Net charge inside closed surface = 2.38 pC
D) Net charge inside closed surface = 8.85 pC
28. A particle having specific charge s starts from rest in a region where the electric field
has constant direction but magnitude varying with time t as E  E0t. In time t , it is
observed that the particle acquires a velocity  after covering a distance x, then
(Assume that only force due to the given electric field is acting on the charge)
1 1 1
(A) x   E0 s  t 3 (B) x   E0 s  t 3 (C)    E0 s  t 2 (D)    E0 s  t 2
2 6 2
29. A few electric field lines for a system of two charges Q1 and Q2 fixed at two different
points on the x - axis are shown in the figure. With the figure what information about
charges and electric field we are getting.
(A) Q1  Q2 (B) Q1  Q2
(C) At a distance to the left of Q1 the electric field is zero

(D) At a finite distance to the right of Q2 the electric field is zero

30. Charges Q1 and Q2 lie inside and outside respectively of a closed surface S. Let E be the
field at any point on S and  be the flux of E over S:
(A) If Q1 changes , both E and  will change
(B) If Q2 changes, E will change but  will not change
(C) If Q1 =0 and Q2  0 then E  0 but   0
D) If Q1 =0 and Q2  0 then E  0 but   0

31. Two charged particles shown in figure are in limiting equilibrium, the coefficient
friction   ___
32. A rectangular parallelepiped has length breadth and thickness in the ratio 3 : 2 : 1.
Imagine a uniform charge distribution along a straight line of  coulombs per meter. The
straight line passes through the centre of the rectangular parallelepiped. The ratio of the
1
minimum and maximum electric flux associated with it is then x =
x
33. A point charge of magnitude 106.2 pC is placed along the axis of a disc of radius 3 R
at a distance R from its centre. Flux of electric field linked with the area of the disc is
(in SI)
34. The number of field lines that move out from a positive charge of one nano coulomb is
(In nearest integer)

35. In a region of space, the electric field is given by E  8i  4 j  3k . The electric flux
n
through a surface of area 300 units in the x y plane is  30  . Find the value of n

36. Two free particles carrying charges +q and +4q are placed apart at a distance l . The
mq
third charge which makes the system equilibrium is then m  n 
n
CHEMISTRY MAX.MARKS: 66
37. When (1R,2R)-1,2-Dibromo-1,2-diphenyl ethane is heated with Zn, the product would
be
A) Cis -1,2-diphenyl ethane
B) A mixture of cis, trans alkenyl bromide
C) Cis-alkenyl bromide
D) Trans -1,2-diphenyl ethane
1). Hg ( OAC )2

2). NaBH 4

38.
Product (A) of the above reaction is:
A) B) C) D)
39. The major product of the given reaction is:
H 3C
1) BH3.THF
H 3C CH3 2) H2O2 / NaOH
H 3C OH H 3C H 3C OH HO
CH3
H 3C CH3 H 3C OH CH3 H 3C CH3 H 3C CH3
A) B) C) D)

40. The suitable reactant of the given reaction is:
1. H 2 SO4 , heat
? 
2.O3thenZn / H 2O
A) B) C) D)
41. The reaction of propene with HBr in the presence of ROOR (peroxide) proceeds
through which of the following most stable intermediates?
 
A) CH 3  C H  CH 3 B) CH 3  C H  CH 2 Br
Br
|  
C) CH 3  CH  C H 2 D) CH 3  CH 2  C H 2
42.
The structure of Q is
A) B) C) D)

correct options.
option.
43.
Which is/are correct statements about the product:
A) is a saytzeff’s product, obtained as minor
B) is a Hoffmann product, obtained as minor
C) is a Hoffmann product, obtained as major
D) is a saytzeff’s product, obtained as major
44. In the following given reaction the product(s) obtained is (are)

H 3C
HBr
CH2
CH3
H3C Br Br CH3 H3C CH3
Br
CH3 Br
A) B) C) D)

45.
OH
CH2
A) B)
OH
C) D)
46. Which of the following reactions are correctly represented with respective to their major
product?
A) CH 3  CH  CH 2  HCl  CH 3  CH (Cl ) CH 3
RO
B) CH 3  CH  CH 2  HI 
hv
 CH 3  CH 2  CH 2  I
2 2
RO
C) CH 3  CH  CH 2  HBr 
hv
 CH 3  CH 2  CH 2  Br
2 2
RO
D) CH 3  CH  CH 2  HI 
hv
 CH 3  CH ( I ) CH 2
2 2
47.
CH2
H2
Ni
CH3
Correct statement(s) about the above reaction is

A) Pair of enantiomers obtained
B) Pair of diastereomers obtained
C) Syn addition takes place
D) Carbocation intermediate is reported

48. The correct order for the given property for following compounds is (are)
H 3C CH3 H 3C H
<
H H H CH3
A) Stability :
H 3C H H 3C CH3
<
H CH3 H 3C H
B) Number of hyper conjugations:
H3C H H3C CH3

<
H CH3 H H
C) Dipole moment:
H3C CH3 H3C H

<
H H H CH3
D) Melting point :
49. Examine the structural formulas of the following compounds and find how many
compounds will produce CO2 on Hot alkaline KMnO4
, , ,
, H 3C  CH  CH 2 , Ph  CH  CH 2

50.
Sum of X and Y is
51. How many of the following addition reactions are syn addition reaction?
H 3C CH 3
Br2

CCl4

C C
H
a) H
b)
H , pd  BaSO
c) H 3C  C  C  CH 3  2
 4
Na , Liq . NH
d) H 3C  C  C  CH 3  3
BH 3 ,THF

H 2O2 ,OH

e)
Cold KMnO4
 
f)
Br2
H2 O
g)

52. The number of Alkenes which can produce 2-Methylbutan-2-ol upon hydration with
dil. H2SO4 as a major product
53. Number of different products formed by the reductive ozonolysis of 1-3-Butadiene is
54. Minimum number of carbon atoms for an acyclic alkene, that shows both
Geometrical and optical isomerism is [not consider the isotopes]

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Sec: JR.

IIT _*CO-SC(MODEL-B) Date: 24-12-23

PREVIOUS WEEK (20%) 3D-GEOMETRY: Introduction of 3-D,

PREVIOUS WEEK (20%) ELECTROSTATICS: Electric Charge and

CHEMISTRY: PRESENT WEEK (80%): Reactions of alkenes: Addition of hydrogen halide,

TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198

JR.IIT_*CO-SC Page. No. 2

3. Angle between the two faces of a regular tetrahedren is?

4. A plane makes intercepts OA, OB , OC whose measures are a, b, c on the axes OX , OY , OZ .

C) lx  my  z l 2  m 2 cot   0 D) None of these

JR.IIT_*CO-SC Page. No. 3

9. Let P1  x  y  2 z  3 and P2  x  2 y  z  4 be two planes. Let A  2, 4,5  , B  4,3,8  be two

12. Let P1 and P2 be two planes given by P1 :10 x  15 y  12 z  60  0, P2 :  2 x  5 y  4 z  20  0

SECTION - 3 (Maximum Marks : 24)

JR.IIT_*CO-SC Page. No. 5

15. If the line x  y  z intersects the line

17. A point P  x, y, z  moves such that x  a  2b  3, y  3a  b  1, 2 z  a  5b  2 where a and b

. represents greatest integer function.

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A) Flux through the closed surface = 2.69 Nm 2 / C

B) Flux through the closed surface = 0.269 Nm 2 / C

(C) At a distance to the left of Q1 the electric field is zero

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SECTION - 3 (Maximum Marks : 24)

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H 3C CH3 2) H2O2 / NaOH

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A) is a saytzeff’s product, obtained as minor

B) is a Hoffmann product, obtained as minor

C) is a Hoffmann product, obtained as major

D) is a saytzeff’s product, obtained as major

44. In the following given reaction the product(s) obtained is (are)

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Correct statement(s) about the above reaction is

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H3C H H3C CH3

H3C CH3 H3C H

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