07.05.23 - Osr - Star Co-Sc - Jee-Adv - 2019 - P2 - Gta-6 (P2) - QP

Sec: OSR.
IIT_*CO-SC Date: 07-05-23

Time: 3HRS Max. Marks: 186
Name of the Student: ___________________ H.T. NO:
07-05-23_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-6(P2)_SYLLABUS
PHYSICS: TOTAL SYLLABUS
CHEMISTRY: TOTAL SYLLABUS
MATHEMATICS: TOTAL SYLLABUS

Narayana IIT Academy 07-05-23_OSR.IIT_*CO-SC_JEE-Adv_GTA-6(P2)_Q’P
TIME:3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 1 – 8) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 9 – 14) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Matrix Matching Type
Sec – III (Q.N : 15 – 18) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
CHEMISTRY
Sec – I (Q.N : 19 – 26) +4 -1 8 32
Sec – II (Q.N : 27 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
+3 -1 4 12
Total 18 62
MATHEMATICS
Sec – I (Q.N : 37 – 44) +4 -1 8 32
Sec – II (Q.N : 45 – 50) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
+3 -1 4 12
Total 18 62
OSR.IIT_*CO-SC Page. No. 2

PHYSICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
1. A solid sphere of mass m and radius r initially lies over a wedge (mass M, lying on
smooth ground) as shown. The curved surface AB is rough (coeff of friction is  ), but
the surface BC is smooth. The system is released from rest at t  0 (consider r  R ), and
coefficient of friction between sphere and surface AB is rough enough to ensure pure
rolling of sphere when it descends from A to B for the first time. (consider m  M ).
Choose the correct statement/s
t  t 
A) 
t 0
Ndt    M  m  gdt
t 0
(N = normal reaction on wedge from the smooth
ground.)
4
B) Max m height reached by the sphere on the surface BC, for the first time is R (height
9
is measured from a horizontal surface passing through point-B)
C) Just after the sphere crosses point B for the second time, the instantaneous power lost
116 5
by the system due to friction is  mg gR
9 9
D) Just after the sphere crosses point B for the second time, the instantaneous power
87 5
lost by the system due to friction is  mg gR
9 9
2. A neutral conducting ring of radius R is kept in x  z plane, with its centre at the origin.
 3 R 
If a point charge ' q ' is kept at   R , , 0  , then.
 2 2 


A) E at point A  0, R, 0  due to charge induced on the ring is along a plane parallel to
x  z plane.
 q
B) The component of net E at point A  0, R, 0  along y-axis is
24 0 R 2
C) The electric potential difference between point A  0, R, 0  and the origin is

q  1 
 1 
4 0 R  3
 R 3 
D) The point on y-axis with maximum electric potential is  0, , 0 
 2 
3. A thin wire of cross section area ‘s’ and length 2 R is made of two materials of
resistivity p and 2 p as shown. It is bent into shape of a ring WXYZ  of radius R
through which magnetic filed (into the paper) B varies with time as B  t (‘  ’ is a
positive constant).
XYZ is semi-circular wire of resistivity p , and ZWX is semi-circular wire of resistivity
2p .
Choose the correct statement(s).
 Rs
A) Current through the ring is in anticlock wise manner
3p
0  Rs
B) Charge accumulated at the junction ' x ' is
3
0  Rs
C) Charge accumulated at the junction ' x ' is 
3
   
D) D)  E.dl   E. dl
Z Y  X X W  Z
L.H.S is line integral of net Electric field over the semi circle Z  Y  X .
R.H.S. is line integral of net Electric field over the semi circle X  W  Z ).

4. On a frictionless surface, two blocks of mass ' m ' and ' M ' are connected with a non-
extensible string of length x0 and a spring of unscratched length l   x0  is compressed
and adjusted between the blocks. The spring is just in contact and not attached with any
blocks. The system is given a horizontal velocity U 0 along the x-axis as shown. If the
string is burnt mid-way, then
1
Given that E0  k  l  x0 
2
 2mME U 2 Em 
A) Change in kinetic energy of mass M is  0 0
 0 
 mM mM 
 
 2mME U 2 EM 
B) Change in kinetic energy of mass M is  0 0
 0 
 mM mM 
 
C) for a given value of M , if equal amount of kinetic energy increases for both blocks
M 8MU 02
then  1 .
m E0
D) For given value of M , if equal amount of kinetic energy increases for both blocks
M
then 1.
m
5. Three observers O1 , O2 and O3 are stationary along ' y ' axis. A source ' S ' moving with
a constant speed of 110 m / s towards the origin O from ' x ' axis continuously emits a
sound of frequency 600 H Z . The observers O1 , O2 and O3 , hears sound of frequency f1 , f 2
and f3 respectively exactly at the moment when source passes the origin. If OO1  660 m .
O1O2  O2O3  330 m . Speed of sound  330 m / s . Then, correct option is__
A) f1  f 2  f3 B) f1  f 2  f3 C) f1  f 2  f3 D) f1  f3  2 f 2
6. A solid glass cylinder of radius R and refractive index   2 is cut and a quarter
portion is carved and kept in vaccum as shown. A horizontal ray of light falls normally
on the vertical surface as shown.


A) For   , TIR takes place on curved surface.
4
B) If a ray suffers TIR from the curved surface ' n ' times before hitting the corner
n
B  R, O  , then  for the ray follows  
2n  1
2R
C) For very small value of  , the ray intersects the x-axis at x  .
2 1
R
D) For very small value of  , the ray intersects the x-axis at x  .
2 1
7. On x  y plane, the potential energy of a particle of mass ' m ' varies with r as U  kmr 2
where k  a positive constant, r  distance from the origin, m  mass of particle
Two particles A and B of mass ' m ' and ' 2m ' respectively, rotate about the origin in
concentric circular path of radius R and 2R . Time taken by them to complete one round
about the origin is TA and TB .
While the particles are rotating, they are given a very small push radially outward. They
start oscillating (radially inward and outward) about their original circular path with
time period  A and  B respectively.
Choose the correct:
A) TA  TB B)  A   B C) 2 TA  TB D) 2 A   B
8. In the shown circuit initially, the switch is open, and the circuit is in steady state. Then:
A) The charge on 3μF capacitor in steady state before closing the switch is 20μC
B) The current through the battery in steady state before closing the switch is zero.
C) The charge on 2μF in steady state after closing the switch is 8μC
D) The current through the battery in steady state after closing the switch is 2 ampere.

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
9. Calculate the ratio of moment of inertia of a thin uniform disc about axis 1 and 2 marked
in the figure. O is the centre of the disc. If the ratio is m / n , where m and n are co-
primes then report answer as m  n .
10. From a thin, uniform circular disc of radius 2R and mass per unit area  0 , a smaller
concentric disc of radius R is cut out. Now a disc of radius R and mass per unit area 2 0
is fixed inside the space created, resulting in the composite disc shown in the figure. if
the composite disc is rotated about a diameter with angular velocity  , its kinetic energy
is
X
8
  0 R 4 2  . The value of X is____.
11. An insulated expandable container which requires negligible energy to expand is filled
with 2 moles of helium gas at 300k. Amount heat input required to increases its
temperature to 310k, is xR . Then x is ( R  gas constant).
12. The amount of heat generated in the circuit shown after the switch SW is shifted from
position 1 to position 2 is X  Joule. Find X . [Given the C  C0  1 F ,   6V ]

13. A proton is fired from very far away towards a nucleus with charge Q = 120e, where e is
the electronic charge. It makes a closed approach of 10fm to the nucleus. The de Broglie
wavelength (in units of fm) of the proton at the start is: (take the proton mass,
m p   5 / 3  1027 kg ; h / e  4.2 1015 Js / C : 1/ 4 0  9 109 m / F : fm  1015 m )
14. The circuit consists of three identical resistors each of resistance R  100  across which
three ideal voltmeters are connected. The impedance of pure inductor and capacitors are
X L and X C respectively. If reading of all three voltmeter are same and X L  X C and
R  100  . Then the rms current through the inductor will be (in amp)
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.15 and Q.16 by appropriately matching the lists based on the information
given in the paragraph.
A musical instrument is made using four different metal strings, 1, 2, 3 and 4 with mass
per unit length  , 2 ,3 and 4 respectively. The instrument is played by vibrating the
strings by varying the free length in
between the range L0 and 2L0 . It is found that in string-1    at free length L0 and
tension T0 the fundamental mode frequency is f 0 . List –I gives the above four strings
while list –II lists the magnitude of some quantity.

LIST- I LIST – II
I String-1    P 1
II String-2  2  Q 1/ 2
III String-3  3  R 1/ 2
IV String-4  4  S 1/ 3
T 3 /16
U 1/16
15. If the tension in each string is T0 , the correct match for the highest fundamental
frequency in f 0 units will be,
A) I  P, II  R, III  S , IV  Q B) I  Q, II  S , III  R, IV  P
C) I  P, II  Q, III  T , IV  S D) I  Q, II  P, III  R, IV  T
3L0 5 L0 7L
16. The length of the string 1,2,3 and 4 are kept fixed at L0 , , and 0 , respectively.
2 4 4
String 1, 2, 3 and 4 are vibrated at their 1st , 3rd , 5th and 14th harmonics, respectively
such that all the strings have same frequency. The correct match for the tension in the
four strings in the units of T0 will be,
A) I  P, II  Q, III  T , IV  U B) I  P, II  Q, III  R, IV  T
C) I  P, II  R, III  T , IV  U D) I  T , II  Q, III  R, IV  U
Answer the following by appropriately matching the list based on the information given in the
paragraph. In a thermodynamic process on an ideal monatomic gas, the infinitesimal
heat absorbed by the gas is given by T X , where T is temperature of the system and X
is the infinitesimal change in a thermodynamic quantity X of the system. For a mole of
3 T  V 
monatomic ideal gas X  R ln    R ln   . Here, R is gas constant, V is volume of
2  TA   VA 
gas. TA and VA are constants.
Constant, V is volume of gas. TA and VA are constants.
The List-I below gives some quantities involved in a process and List-II gives some
possible values of these quantities.

LIST- I LIST – II
I Work done by the system in process 1  2  3 P 1
RT0 ln 2
3
II Change in internal energy in process 1  2  3 Q 1
RT0
3
III Heat absorbed by the system in process 1  2  3 R RT0
IV Heat absorbed by the system in process 1  2 S 4
RT0
3
T 4
RT0  3  ln 2 
3
U 5
RT0
6
17. If the process carried out on one mole of monatomic ideal gas is as shown in figure in
1
0 0 
the PV-diagram with PV RT0 , the correct match is,
3
A) I  Q, II  R, III  S , IV  U B) I  Q, II  S , III  R, IV  U
C) I  Q, II  R, III  P, IV  U D) I  S , II  R, III  Q, IV  T
18. If the process on one mole of monatomic ideal gas is as shown in the TV-diagram with
1
0 0 
PV RT0 , the correct match is,
3
A) I  P, II  T , III  Q, IV  T B) I  S , II  T , III  Q, IV  U
C) I  P, II  R, III  T , IV  S D) I  P, II  R, III  T , IV  P

CHEMISTRY Max.Marks:62
SECTION – I
19. Which of the following statements are true ?
A) In metal carbonyl complexes d C  O bond length is more compared to that in CO

molecule.
B) In metal carbonyls CO molecule acts as both Lewis acid as well as Lewis base.
C) Cis – platin effectively inhibit the growth of tumours.
D) In metal carbonyls metal atom acts as both Lewis acid as well as Lewis base.
20. According to Molecular Orbital theory,
A) C2 molecule is expected to contain two  bonds between carbon atoms.
B) O2 is expected to have a longer bond length than O2 .
C) N 2 and N 2 have same bond energy.
D) N 2 and O2 have same bond order.
21. In an evacuated vessel of capacity 49.2 litres, 4 moles of Argon gas and 5 moles of
PCl5  g  were introduced and the temperature is maintained at 240 K (assume the at this
temperature decomposition of PCl5 take place). At equilibrium, the total pressure of the
mixture was found to be 4.8 atm. (Given R  0.082 atmLmol 1K 1 )
Correct statement(s) is/are
A) The degree of dissociation PCl5  g  into PCl3  g  and Cl2  g  is 0.6.
B) K p for the reaction PCl5  g   Cl3  g   Cl2  g  is 2.7 atm.
C) At equilibrium total moles of gases are 12
D) On removing Ar  g  from the equilibrium mixture at constant pressure and
temperature, the extent of dissociation of PCl5 will increase.

22. When a mixture of salt ‘X’ and K 2Cr2O7 is strongly heated with conc. H 2 SO4 , deep red
orange coloured vapours are evolved. These vapours when passed into NaOH solution
gives yellow solution. The salt ‘X could not be,
A) HgCl2 B) AgCl C) KCl D) SnCl4
23. Consider the following reactions and pick the correct statements
A) More than four mole of HI is required in (ii)
B) More than three mole of HI is required in (i)
C) One mole of HI is required in (iii)
D) Methanol is produced in (i) only
24. Choose the correct option(s) for the following reaction:
Cl
HCl
+
Cl
(I) (II)
A) II is 1,2-addition product
B) I is 1,4-addition product
C) I is kinetically controlled product (KCP)
D) II is thermodynamically controlled product (TCP)

25. In which chemical reaction(s) visible change takes place?
A)
B)
C)
D)
26.
In the above reaction sequence, identify correct statement with respect to formation of D
A)
B)

C)
D)
SECTION – II
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
27. Complex spin-only magnetic moment (in BM)

 Fe  CO 4  C2 O 4   a
 FeCl4 

b
3
 Co  C 2 O 4 3  c
2
Cu  NH3 4  d
(Given: 3  1.7 ; 2  1.4 ; 5  2.2; 15  3.8; 35  5.9; 6  2.4 )
Then  a  b  c  d  =__________
28. In a quality control analysis for Sulphur impurity, 1.32 grams of steel sample was burnt
in a stream of oxygen and Sulphur was converted in to SO2 gas. The SO2 gas was then
oxidized to sulphate by using H 2O2 solution to which had been added 30 ml of 0. 4M
NaOH. The equation for the reaction is,
SO2  H 2O2 (aq )  2OH  (aq)  SO42 (aq)  2 H 2O(l )
22.5 ml of 0.24M HCl was required to neutralize the base remaining after oxidation
reaction. The % (by mass) of Sulphur in the given sample is
29. The atomic masses of He and Ne are 4 and 20 a.m.u., respectively. The value of the de
Broglie wavelength of He gas at 730 C is “M” times that of the de Broglie wavelength
of Ne at 7270 C . Then, M is
E  F   CaC2  CO ; CaC 2   D  E (E is obtained in elemental form)

0
2000 C N2
30. 
CaC 2 
H2O
 A  B
; B 
Excess CO 2 gas
G
G 
Dilute HCl
 H  I   H 2O ;
The number of correct statements about the above compounds are
(i) Compound ‘G’ cannot be obtained in solid form
(ii) Compound ‘F’ is used as a drying agent
(iii) Compound ‘D’ is can be used as a fertilizer
(iv) Compound ‘D’ is calcium nitride
(v) Solution of compound ‘G’ on boiling give a white ppt.
(vi) Compound ‘B’ is less soluble in water than ‘G’
(vii) Hydrolysis of ‘D’ gives a gas in which central atom undergoes sp hybridization
(viii) The gas ‘A’ can decolourise Baeyer’s agent.
(ix) Sodium continues to burn in the atmosphere of gas ‘I’.
31. How many compounds (including stereoisomers) of formula C4 H11 N give positive
carbylamines reaction or test?

32. A student is asked to select some compounds from the following
(I) CH 3CHO (II) (III) H-C-H (IV)

OH
CH3-C-CH2-CH3
(V) CH3 (VI) PhCHO (VII) CH 3CH 2CHO (VIII) PhCOCH 3

(IX) EtOEt
Only those compounds can be selected which give atleast two positive test/reaction from
following list
(i) Positive Tollens test
(ii) Positive 2,4-DNP test
(iii) Immediate turbidity with lucas reagent
(iv) Positiveiodoform test
(v) Cannizzaro reaction
How many compounds can be selected by student?
SECTION-III
Answer the following questions based on the following data.
Column –I Column–II
(I) (P) U  0

(II) (Q) Work done  0
(III) (R) W   Pext (V2  V1 )
(IV) (S) Q  U
(T) Isobaric process

(U) Isochoric process
33. Which of the following options has the incorrect combination consider List – I and
List – II?
A) (I), (Q), (U) B) (II), (Q) C) (III), (R), (T) D) (IV), (Q)
34. Which of the following options has the correct combination for isothermal process ?
A) (I), (Q) B) (IV), (P) C) (II), (R) D) (III), (S)

List-I includes starting materials and reagents of selected chemical reactions. List-II
gives structures if compounds that may be formed as intermediate products and or final
products from the reactions of List-I
List –I List–II
(I) (P)
(II) (Q)

(III) (R)
(IV) (S)
(T)
(U) O
O
35. Which of the following options has correct combination considering List – I and
List – II?
A) (I), (Q), (T), (U) B) (II), (P),(S),(T) C) (II), (P),(S), (U) D) (I), (S), (Q), (R)
36. Which of the following options has the correct combination considering List – I and List
– II?
A) (III), (S), (R) B) (IV), (Q), (U) C) (III), (T), (U) D) (IV), (Q), (R)

MATHEMATICS Max.Marks:62
SECTION – I
37. Let f ( x)  x  x 2  1
A) The number of points at which f is not differentiable is 7
B) The absolute difference between the number of points of local minima and local
maxima is 1
C) f ( x)  k will have 8 distinct real roots if k  (0,1)
D) f ( x)  k will have 8 distinct real roots if k  (1, )
t
38. If the maximum area enclosed between curve x  2 cos 2 ; y 2  2  cos t , y  axis and line
2
y  mx is A , then which of the following can be true?
1 1 6 3 5
A) m  B) m   C) A  4 3 D) A 
2 2 3
e
39. I    nx  e x dx then
1
ee 1 ee 1 ee 1  ee e e 1  e e
A) I  B) I  C) I  D) I 
2  2e 2  2e 2 2
40. If a, b, c are positive numbers where a  2b  4 and b  2c  5 , then
27 27
A) maximum value of ab3 is B) maximum value of b 2c3 is
8 4
4 2 9 2
C) minimum value of  is 4 D) minimum value of  is 6
a b b c
41. Given p ,q  0,1, 2,3, 4,......,19, 20 . Consider the system of equations
x  y  z  4 , 2x  y  3z  6 , x  2y  pz  q
A) The number of ordered pairs  p ,q  so that the system of equations has unique
solution is 420
B) The number of ordered pairs  p ,q  so that the system of equations has no solution is
20
C) The number of ordered pairs  p ,q  so that system of equations has infinite solutions
is 1.
D) The number of ordered pairs  p ,q  so that system of equations has infinite solutions
is 6.

42. If A  z1  is a variable point in argand plane such that z1 z1  5, 0  arg  z1    . Also,
B  z2  & C  z3  are two fixed points in argand plane satisfying
z 4  6 z 2  25  0 &   arg z  0 .
A) Internal angle bisector of A of ABC will always pass through a fixed point.
B) Circumcentre of ABC is origin
C) Orthocentre  z4  of ABC satisfies z4  2i  5.  i  1 
D) Orthocentre  z4  of ABC satisfies z4  2i  5.  i  1 
43. The equation of the sides of the triangle having (3, 1) as a vertex and x  4 y  10  0 and
6 x  10 y  59  0 as angle bisector and as median respectively drawn from different
vertices, are:
A) 6 x  7 y  13  0 B) 2 x  9 y  65  0 C) 18 x  13 y  41  0 D) 6 x  7 y  11  0
44. The tangent at point P(1,1) on the curve C : y  x3  x  1 cuts the curve at Q. The tangent at
Q on the curve cuts the curve at R. Then
A) (1, 0) and centroid of PQR lies on the opposite side of curve C
B) The abscissae of P, Q and R are in G.P.
C) The ordinates of P, Q and R are in G.P.
D) Length of subnormal at Q is less than 100.
SECTION – II
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
1 100  2 2  
k

100  
45. Find the absolute value of 1  tan  100   .
2 k 1   2 1 
1.2 2.22 3.23

46. If Sn     ..... up to n terms and  is the sum of infinite terms of Sn , then the
3 4 5
  2
value of ‘m’ if the roots of equation  x 4     2    4  x3  140   x  120 x  m  0
2
   1 
form a geometric sequence is ………

47. If  ,  are two distinct real roots of the equation ax3  x  1  a  0 ,  a  1, 0  , none of
(1  a ) x3  x 2  a al  k   
which is equal to unity, then the value of lim1 is . Find the value
x

 e  1  x  1
1 x

of kl .
   
48. Let a  2i  j  2k , b  i  j, c is a vector such that a.c  c , c  a  2 2 and angle between
      
 
a  b and c is .If a  b  c is equal to
3
6 3

, then the value of '  ' is
49. Tangent is drawn at any point ( x1 , y1 ) on the parabola y 2  4ax . Now tangents are drawn
from any point on this tangent to the circle x 2  y 2  a 2 such that all the chords of contact
2
x  y 
pass through a fixed point ( x2 , y2 ) , then 4  1    1   ……..
 x2   y2 
50. Let A  {1, 2,3,5,8,9} . Then the number of possible functions f : A  A such that
f (m.n)  f (m). f (n) for every m, n  A with m . n  A is equal to …….
SECTION-III
Triangle is formed by joining the vertices of a cube
LIST – I LIST – II
Probability that the triangle is isosceles or 3
a) p)
equilateral is greater than 14
Probability that the triangle is isosceles but 2
b) q)
not equilateral is smaller than 7
Probability that the triangle is scalene is 3
c) r)
greater than 7
Probability that the triangle is right angled is 4
d) s)
greater than or equal to 7
6
t)
7

51. Which of the following is the only CORRECT combination?
A) a  s B) a  q C) b  p D) c  t
52. Which of the following is the only INCORRECT combination?
A) a  p B) d  p C) c  s D) c  q
Let the circles C1 : x 2  y 2  9 and C2 : ( x  3) 2  ( y  4) 2  16 intersect at the points X and Y.
Suppose that another circle C3 : ( x  h) 2  ( y  k ) 2  r 2 satisfies the following conditions:
i) centre of C3 is collinear with the centres of C1 and C2 .
ii) C1 and C2 both lies inside C3 and
iii) C3 touches C1 at M and C2 at N
A line through X and Y intersect C3 at Z and W, and let a common tangent of C1 and C3
be a tangent to the parabola x 2  8 y
There are some expressions given in the List-I whose values are given in List-II below
LIST – I LIST – II
I) 2h  k p) 6
length of ZW
II) q) 6
length of XY
Area of  MZN 5
III) Area of  ZMW
r)
4
21
IV)  s)
5
t) 2 6
10
u)
3
53. Which of the following is the only CORRECT combination?
A) I  s B) I  u C) III  r D) II  t
54. Which of the following is the only INCORRECT combination?
A) I  p B) II  q C) IV  t D) IV  u



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Sec: OSR.

IIT_*CO-SC Date: 07-05-23

Name of the Student: ___________________ H.T. NO:

07-05-23_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-6(P2)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

OSR.IIT_*CO-SC Page. No. 2

OSR.IIT_*CO-SC Page. No. 3

C) The electric potential difference between point A  0, R, 0  and the origin is

Choose the correct statement(s).

OSR.IIT_*CO-SC Page. No. 4

OSR.IIT_*CO-SC Page. No. 5

Choose the correct:

OSR.IIT_*CO-SC Page. No. 6

OSR.IIT_*CO-SC Page. No. 7

OSR.IIT_*CO-SC Page. No. 8

OSR.IIT_*CO-SC Page. No. 9

OSR.IIT_*CO-SC Page. No. 10

A) In metal carbonyl complexes d C  O bond length is more compared to that in CO

C) Cis – platin effectively inhibit the growth of tumours.

20. According to Molecular Orbital theory,

A) C2 molecule is expected to contain two  bonds between carbon atoms.

B) O2 is expected to have a longer bond length than O2 .

C) N 2 and N 2 have same bond energy.

D) N 2 and O2 have same bond order.

mixture was found to be 4.8 atm. (Given R  0.082 atmLmol 1K 1 )

Correct statement(s) is/are

A) The degree of dissociation PCl5  g  into PCl3  g  and Cl2  g  is 0.6.

B) K p for the reaction PCl5  g   Cl3  g   Cl2  g  is 2.7 atm.

C) At equilibrium total moles of gases are 12

D) On removing Ar  g  from the equilibrium mixture at constant pressure and

temperature, the extent of dissociation of PCl5 will increase.

OSR.IIT_*CO-SC Page. No. 11

A) HgCl2 B) AgCl C) KCl D) SnCl4

A) More than four mole of HI is required in (ii)

B) More than three mole of HI is required in (i)

C) One mole of HI is required in (iii)

D) Methanol is produced in (i) only

24. Choose the correct option(s) for the following reaction:

OSR.IIT_*CO-SC Page. No. 12

OSR.IIT_*CO-SC Page. No. 13

(Given: 3  1.7 ; 2  1.4 ; 5  2.2; 15  3.8; 35  5.9; 6  2.4 )

SO2  H 2O2 (aq )  2OH  (aq)  SO42 (aq)  2 H 2O(l )

E  F   CaC2  CO ; CaC 2   D  E (E is obtained in elemental form)

The number of correct statements about the above compounds are

(i) Compound ‘G’ cannot be obtained in solid form

(ii) Compound ‘F’ is used as a drying agent

(iii) Compound ‘D’ is can be used as a fertilizer

(iv) Compound ‘D’ is calcium nitride

(v) Solution of compound ‘G’ on boiling give a white ppt.

(vi) Compound ‘B’ is less soluble in water than ‘G’

(viii) The gas ‘A’ can decolourise Baeyer’s agent.

(ix) Sodium continues to burn in the atmosphere of gas ‘I’.

carbylamines reaction or test?

OSR.IIT_*CO-SC Page. No. 15

(I) CH 3CHO (II) (III) H-C-H (IV)

(V) CH3 (VI) PhCHO (VII) CH 3CH 2CHO (VIII) PhCOCH 3

OSR.IIT_*CO-SC Page. No. 16

(II) (Q) Work done  0

(III) (R) W   Pext (V2  V1 )

(T) Isobaric process