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2021_PAPER-I
07-01-2024_Jr.Super60_NUCLEUS BT_ Jee-Adv
(2021-P1)_CTA-23_Syllabus
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 30 – 35) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 49 – 54) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60
S1 S2
k1 k2
F
m
LIST I LIST II
Choose the most appropriate answer from the options given below
(A) A-(i), B-(iii), C-(ii), D-(iv) (B) A-(ii), B- (iii) C-(i), D-(iv)
(C) A-(iii), B-(ii), C(i), D-(iv) (D) A-(ii), 8-(iii), C-(iv), D-(i)
10 V 20 V
1 9
8 Chamber 2
30 V 40 V
A) 25 s B) 50 s C) 75 s D) 100 s
1
1 1 1 1
1 1 1
1
9V 9V 9V 9V
Power delivered by the cell enclosed in boundary to the circuit is
A) 9 W B) 18 W C) 27 W D) Zero
4
2 G
12
A B
D
L
L L 2L 3L
A) B) C) D)
2 3 3 4
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks:0 in all other cases
Question Stem for Question Nos. 5 and 6
Question Stem
Analyze the circuit shown.
3
3
3
6
6
24 V 6
5. Find power dissipated by any of 6 resistance (in W)
6. Find power delivered by battery (in W)
Sec: Jr.Super60_NUCLEUS BT Space for rough work Page 5
Sri Chaitanya IIT Academy 07-01-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2021-P1)_CTA-23_Q.P
Question Stem for Question Nos. 7 and 8
Question Stem
A small block of mass m is fixed at upper end of a massless vertical spring of spring
4mg
constant k and natural length 10 L. The lower end of spring is free and is at a
L
height L from fixed horizontal floor as shown. The spring is initially unstressed and the
spring-block system is released from rest in the shown position.
m
10L
Horizontal
floor
7. As the block is coming down, the maximum speed attained by the block is x gL .
Find x .
8. At the instant of maximum speed, force exerted by ground on spring is xmg . Find x .
Question Stem for Question Nos. 9 and 10
Question Stem
A uniform hemisphere of mass 2m and radius R is placed at rest on a smooth horizontal
surface. A small insect of mass m is at rest at a point P of the hemisphere near ground as
shown. Now, the insect begins to climbing up (without slipping). Hemisphere with
constant speed V with respect to the hemisphere. Consider motion of the insect from P
to another shown point Q on the hemisphere. Centre C of the hemisphere, P and Q lie in
same vertical plane.
Q
R
600 P
C
xR
9. Displacement of the hemispherical bowl is .Find x .
3
xV 2
10. Acceleration of the hemisphere at the instant, the insect is at Q, is . Find x .
2R
Sec: Jr.Super60_NUCLEUS BT Space for rough work Page 6
Sri Chaitanya IIT Academy 07-01-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2021-P1)_CTA-23_Q.P
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
11. Choose the correct alternative (s) for the circuit shown.
A
3 6
18V
6 3
A) A is at higher potential.
B) Between A and B, the circuit can be replaced by an equivalent cell of emf 6V and
internal resistance 4 .
C) Short circuit current between A and B is 2A.
D) Maximum power that can be drawn between points A and B is 2.25W.
12. A bead is connected with a fixed disc’s periphery of radius R by an inextensible
R
massless string of length l in a smooth horizontal plane. If the bead is pushed with
2
a velocity v0 perpendicular to the string, the bead moves in a horizontal curve and
consequently collapses on the disc after a time t. Then,
A) Work done by the string on the bead is mv02
l2
B) time taken by bead to strike the disc is t
2 Rv0
C) average speed of the bead during its motion before is strikes the disc is v0
D) kinetic energy of the bead increases gradually
Sec: Jr.Super60_NUCLEUS BT Space for rough work Page 7
Sri Chaitanya IIT Academy 07-01-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2021-P1)_CTA-23_Q.P
13. The figure here shows a heavy box sliding freely on fixed smooth very long incline. A
smooth rigid wire PQ is fixed to the box as shown. A bead R (of mass 1 kg) attached to
a spring of natural length 3 1 m can slide freely along the wire. Initially at the
instant shown, the spring is relaxed and oriented perpendicular to the incline while the
bead is at rest w.r.t wire. During subsequent motion, the beads comes to rest w.r.t wire
when spring has rotated by 30 0 . Taking, g 10m / s 2 ,choose the correct alternative(s).
Q
Heavy
box 300
R
P
Smooth 600
fixed
incline
A) Normal force on the bead by the wire when the bead is at rest again w.r.t wire is
5 3 1N.
4
B) Maximum displacement of the bead w.r.t wire is 3 1 m.
M
smooth
M'
M cot M tan
A) M ' B) M '
1 cot 1 tan
Mg Mg
C) Tension in string is D) Tension in string is
tan cot
16. The ring on a fixed rod as shown in figure is given a constant horizontal
acceleration (ag g / 3) . Maximum deflection of the string from the vertical is
0 , then
m ring
smooth horizontal rail
B) 0 60o
C) At maximum deflection, tension in string is equal to mg
2mg
D) At maximum deflection, tension in string is equal to
3
SECTION-IV
(INTEGER ANSWER TYPE)
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
17. Three identical uniform planks A, B and C of mass m = 1 kg each and length L=
2 m are placed on a smooth fixed horizontal surface as shown in the figure. There
is friction between A and B (friction coefficient being ) while there is no
friction between A and C. At the instant shown, that is at t = 0 the block A has
horizontal velocity of magnitude v = 6 m/s towards right, whereas speed of B
and C is Zero. At the instant, block A has covered a distance L relative to block
B velocity of all blocks are same. If heat dissipated due to friction in the system
H
is H, find value of in joule.
2
A L
B C
300 B
19. A vertical hollow cylinder is fixed on the ground. A uniform rod can be balanced
partly in and partly out of the cylinder with the lower end of the rod resting
against the vertical wall of the cylinder, as shown in the figure. The angle made
by rod with the vertical in equilibrium is . Maximum and minimum possible
value of are 530 and 37 0 , respectively. Coefficient of friction between road and
1 37
cylinder is tan tan 1 .Find the value of n.
2 28n
*M CO M * CO
C O M C O
M
A. B.
M * CO M * CO
C O M C O
M
C. D.
3
22. Calculated spin only magnetic moments of central metal ion of Mn CN 6 and
tetrahedral MnBr42 ions are respectively
A. 2.82 BM and 5.9 BM B. 0 BM and 5.9 BM
C. 1.73 BM and 2.82 BM D. 2.82 BM and 2.82 BM
23. In Ni CO 4 , metal act as:
A. donar acceptor B. donar acceptor
C. donar acceptor D. donar acceptor
x
Arrangement
in a hypothetical Arrangement in
symmetrical ield. actual ield
oƒ ligand
Process coordinate
If the energy of the arrangement in a hypothetical symmetrical field = x
And the crystal field splitting energy = 0
26. If energy of eg & t2 g orbitals are in the given diagram x 0 , y 0 respectively then
x y is ________
Crystal field stabilization energy for Fe CN 6 is (consider no change in energy on
4
27.
pairing) is x. 0 . The value of x is ________
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
30. The correct statement(s) among the following is/are
3 2
A. The complexes Co NH 3 6 and Fe NH 3 6 have same geometry
3 2
B. The complexes Co NH 3 6 and Fe NH 3 6 differ in their magnetic properties
2
C. The complexes Pt CN 4 and CuCl4
2
differ in their geometry
2 3
D. The complexes Ni NH 3 6 and Cr NH 3 6 differ in their primary valency
31. Which of the following statements are correct
A. Ag NH 3 2 is less stable than Ag CN 2
B. Ag NH 3 2 is more stable than Ag en
2
C. Pt CN 4 is a tetrahedral complex
36. The crystal field stabilization energy of Co NH 3 6 Cl3 is x 0 then 10x is AB . Sum
of A B is
37. M II NH 3 2 Py 2 NO2 2
NH 3
Py
M II NH 3 3 Py NO2 2 (M-central metal atom/
ion) (ignore linkage isomer). Difference between the total geometrical isomers of
reactant and product is:
38. How many of the following are tetrahedral complex
2 2 2
i. Ni CN 4 ii. Zn NH 3 4 iii. Cd H 2O 4 iv. PtCl4
2
9
70 f 8 80 , Then the least values of f x is
2
STATEMENT: 2
If 5x 2 2kx 1 0 has exactly one integral solution which is ‘1’ . Then sum of all
Positive integral values of k is 9
A) Both ( S1 ) and ( S 2 ) are true B) Only ( S1 ) is true
C) Only ( S 2 ) is true D) Both ( S1 ) and ( S 2 ) are false
40. If the quadratic equation x 2 tan x 1 tan 0 has two integral roots,
2
Then sum of all possible values of in interval 0, 2 is k .Then the value of k is.
A) 2 B) 3 C) 1 D) 4
41. A monic quadratic trinomial P(x) is such that P(x) = 0 and P P P x = 0 have a
Common root, then
A) P 0 . P 1 0 B) P 0 . P 1 0
C) P 0 . P 1 0 D) None of these
42. Consider the following statements:
STATEMENT: 1
Let A (0, 2), B and C are points on parabola y2 x 4 and such that CBA , then the
2
range of ordinate of C is (,0] [4, )
STATEMENT: 2
m1 , m2 , m3 are the slope of normals (m1 m2 m3 ) drawn through the point (9, 6) to the
parabola y 2 4x . A [aij ] is a square matrix of order 3 such that aij 1 if i j and aij mi
if i j . Then detA = 8
A) Both ( S1 ) and ( S 2 ) are true B) Only ( S1 ) is true
C) Only ( S 2 ) is true D) Both ( S1 ) and ( S 2 ) are false
Sec: Jr.Super60_NUCLEUS BT Space for rough work Page 16
Sri Chaitanya IIT Academy 07-01-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2021-P1)_CTA-23_Q.P
SECTION-II
(PARAGRAPH WITH NUMERICAL VALUE TYPE)
This section contains THREE (03) questions stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 43 and 44
Question Stem
Consider the parabola y 4x . Let A 1,0 and B 0,1 . F is the focus of the parabola.
2
44. If L 4,3 and Q a, b is a point on the parabola such that FQ QL is least then
4 a b
Question Stem for Question Nos. 45 and 46
Question Stem
A parabola is drawn through two given points A (1, 0) and B (-1, 0) such that its directrix
always touches the circle x y 4 Then
2 2
x2 y 2
45. The locus of focus of the parabola is 1 then a - b =
a b
46. The maximum possible length of semi latus rectum is k 3 then k 1
Question Stem for Question Nos. 47 and 48
Question Stem
The chord AC of the parabola y 4ax subtends an angle of 9 0 0 at points B and D on
2
47. Value of 2 t2 t4
t1 t3
48. The y-coordinate of the midpoint of the points of intersection of the tangents at A,C and
B,D is __
SECTION-III
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
Sec: Jr.Super60_NUCLEUS BT Space for rough work Page 17
Sri Chaitanya IIT Academy 07-01-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2021-P1)_CTA-23_Q.P
For each question, choose the option(s) corresponding to (all) the correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen,
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks: -2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
49.
3 psinx – p sinx p 2 – psinx sin 2 x 1 has a solution for x, then p
can be ____________
A) -2 B) -1 C) 0 D) 1
50. If two of the three quadratic equations with positive coefficients ( p q r)
orthocenter of le ABC is focus S of the parabola then (none of the vertices of the
triangle is vertex of the parabola)
1 1 1
A) t1t2 t3t2 t3t1 5 B) 1
t1t2 t2t3 t3t1
C) If t1 1thent2 t3 0 D) 1 t1 1 t2 1 t3 4
SECTION-IV
(INTEGER ANSWER TYPE)
This section contains THREE (03) question.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
55. All possible values of real parameter ' a ' for which the equation x 4 2ax 2 x a 2 a 0
has all real Solutions, is given by , where m and n are relatively prime positive
m
n
integers, then the value of m n is equal to
56. Consider the following statements:
STATEMENT: 1
If sin x
x 2x 9x
when the number of solutions in the interval
2 5 10
(30, 40) is (where [.] is GIF) is 2
STATEMENT: 2
If (x2 + x + 2)2 – (a - 3) (x2 + x + 1) (x2 + x + 2) + (a - 4) (x2 + x + 1)2 = 0 has at least one
real root, then the complete set of values of a is 5,
19
3
STATEMENT: 3
Tangent and normal at the ends A and C of focal chord AC of parabola y2 = 4x intersect
at B and D, then minimum area of ABCD is 8
The number of correct statements is
57. A line L : y mx 3 meets y – axis at A 0,3 and the arc of the parabola
y 2 16 x, 0 y 6 at the point B , . The tangent to the parabola at B intersects the y
– axis at C 0, then the numerical value of slope m of the line L such that the area of
the ABC has a local maximum is _____