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A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS&ALL_BT’S JEE-ADVANCE‐2021-P2 Date:19-04-2023
Time: 02.00Pm to 05.00Pm GTA-16 Max. Marks: 180
19-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P2)_GTA-16_Syllabus
JEE‐ADVANCE‐2021‐P2‐Model
Time: 3:00Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 7 – 12) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 13 – 16) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 17 – 19) +4 0 3 12
Value Type
Total 19 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 20 – 25) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 26 – 31) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 32 – 35) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 39 – 44) +4 -2 6 24
with Partial mark
Paragraph Questions with Numerical
Sec – II(Q.N : 45 – 50) +2 0 6 12
Value Answer Type
Paragraph Questions with Single
Sec – III(Q.N : 51 – 54) +3 -1 4 12
Answer Type
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60
O
X
inverted and just placed above the surface of a liquid of uniform volume mass
density 2 as shown in fig. When left free, its maximum displacement is equal to h and it
gets submerged just completely. Assume that liquid body is large enough, that level of
liquid doesn’t change when paraboloid enters the liquid (Neglect viscosity and if any
dissipative forces of liquid). Then which of the following are correct?
2
A) 3
1
B) It oscillates between extremes simple harmonically.
C) It oscillates between these extremes, but Oscillations are not SHM.
h 4 gh
D) Submerged depth at equilibrium = , Maximum speed in the oscillation = V
3 3 3
3. Friction between the wedge shown and horizontal floor is sufficient to prevent the wedge
from slipping. The mass of the wedge is M and its angle of inclination is . A small block
of mass m is just placed near the top of the wedge and released. Coefficient of friction
between wedge and block is .
m
B O B
Where B0 , and are positive constants and z and r are vertical and radial position
coordinates, respectively. Initially plane of the ring is horizontal and the ring has no
current flowing in it. When released, it starts to move downwards with its axis still in
vertical direction. In the given diagram, point O is on the axis and slightly above the
solenoid having vertical and radial position coordinates as (0,0). Ring has mass m, radius
r0 and self-inductance L. Assume, the acceleration due to gravity as g.
1
A) The magnitude of current in the ring is B0 r02 z
L
2 B02 2r04 z
B) The force(magnitude) acting on the ring is .
L
mgL
C) Vertical coordinate z for equilibrium position of the ring is .
2 B02 2r04
1 2mL
D) The time period of ring’s motion is .
B0r0 2
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 5
Sri Chaitanya IIT Academy 19-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P2)_GTA-16_Q.P
5. A weight less piston divides thermally insulated cylindrical vessel into two equal parts.
One contains one mole of an ideal gas with adiabatic exponent , the other is evaccuated.
The initial gas temperature is T0 . The piston is released, the gas fills the whole volume of
the container. The piston is slowly displaced back to the initial position. Like internal
energy U, entropy is another state function of a gas whose change can be calculated
as S dQ , where dQ = Quantity energy in the form of heat which may be either absorbed
T
or ejected by the gas at temperature T. If U1, S1 denote change in internal energy, change
in entropy in the free expansion, and U 2 , S2 changes in internal energy, change in
entropy in the slow compression respectively, then which of the following are correct.
A) U1 0, S1 0 B) U 2 0, S 2 0
C) U1 U 2 0, S1 S2 0 D) S1 0, S2 0
6. Two identical solid spheres A and B of mass m and radius r each have short light identical
dipoles embedded at their respective centers. B is in equilibrium on an incline of
inclination as shown such that its dipole moment is parallel to the incline. Sphere A is
released, in the position shown, on a rough horizontal surface. Both A and B are located in
electric field of a uniform infinite sheet of surface charge density . If friction between A
and horizontal surface is sufficient to prevent slipping, (neglect mutual interaction
between A and B).
+ B
+ A P
+
+ P
+
Uniform +
non-conducting
plane sheet +
+
+
+
+
+
+
5g
A) its acceleration is , just after its release.
7
2mg
B) friction acting on it is , just after its release.
7
10 P
C) its angular speed at the instant, when it has angularly displaced by is .
2 2
7 mr 0
D) friction acting on it, when the dipole becomes parallel to horizontal surface is zero.
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 6
Sri Chaitanya IIT Academy 19-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P2)_GTA-16_Q.P
SECTION-2(Maximum Marks: 12)
Paragraph with Numerical
This section contains THREE (03) question stems.
There are TWO (02) questions corresponding to each question stem.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-
screen virtual numeric keypad.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Q
R
60 P
C
R
9. Magnitude of Displacement of the hemispherical bowl is . The value of k is
k
v2
10. Acceleration of the hemisphere at the instant, the insect reaches Q is , where n =
nR
Question Stem for Question Nos. 11 and 12
Question Stem
Four metallic plates are placed as shown in the figure. Plate 2 is given a charge Q whereas
all other plates are uncharged. Plates 1 and 4 are joined together. The area of each plate is
same.
1 2 3 4
d 2d d
Q
11. The charge appearing on the right face of plate 3 is: n , where n=
4
Qd
12. The potential difference between plates 1 and 2 is: k , where k=
4 0 A
SECTION-3(Maximum Marks: 12)
Paragraph with Single Answer Type
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
R R
O
d
13. The electric field E in the overlap region is:
A) Non uniform B) zero C) d D) r
3 0 3 0
14. The potential difference V between the centers of the two spheres for d = R is:
2 2 2 2
A) d B) d C) zero D) d
3 0 0 0
Paragraph-II
Passage: A particle P moving parallel to X-axis in the XY-plane with a constant speed V,
starting from position (0, l ) at time t=0. Another particle Q starts from origin (0,0) and
chases P with same uniform speed V, simultaneously.
15. Radius of curvature of Q in the frame of P at the start of motion is
l
A) l B) C) 2l D) 2 2l
2
16. Minimum radius of curvature of Q, in the process of chasing will be
4l 4l 4l l
A) B) C) D)
3 3 3 3 3 3
phase difference between the wavelets from the opposite edges of the slit is K Where
2
K=?
18. A radioactive element is being produced at a constant rate k. The element has decay
of the element after one half life of the element is xN0. Find x.
CH3C H-C-CH3
D) OH is oxidized by HIO4 .2 H 2O
21. The correct statement(s) among the following is/are
A) Number of B-O-B bonds in borax is 5.
B) Formula of borax is Na2 B4O5 OH 4 8H 2O
C) BF3 is a stronger Lewis acid than BI3
D) B OH 3 behaves as a strong acid in the presence of glycerol
22. Identify correct statements
A) Sucralose has three chlorine atoms per molecule
B) Sucralose in unstable at cooking temperature
C) Butylated hydroxytoluene and butylated hydroxy anisole are anti oxidatns
D) Sodium rosinate, sodium silicate, borax are fillers in laundry soaps
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 11
Sri Chaitanya IIT Academy 19-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P2)_GTA-16_Q.P
23.
Identify correct statement for above reaction sequence?
A) ‘Z’ product is sweet smelling substance
HO
O
OH OH H LAH H hemi ketal product
Reaction of 'X'
B)
C) ‘Y’ product liberate CO2 gas with aqueous NaHCO3 and also soluble in aqueous
NaOH
D) ‘Z’ product is resolvable
24.
Column I Column II
(A) H N NH Cl (P) Sodium fusion extract of the compound gives
2 3
Prussian blue colour with FeSO 4
(B) (Q) Gives positive FeCl3 test
PCl5 g
PCl3 g Cl2 g
K2
C
disappearance of A is1.4 104 sec1 . The rate constant ( k1 ) for the formation of B is
x 105 sec1 and the rate constant ( k2 ) for the formation of C is y 104 sec1 .
28. The value of x is______________.
29. The value of y is_____________.
Question Stem for Question Nos. 30 and 31
Question Stem
A solid metal oxide ( M 2O3 ) crystallizes as HCP for O 2 ions and the metal ions ( M 3 )
occupy only octahedral voids in ideal crystal. The metal may exhibit +3 and+4 oxidation
states. The composition of a real metal oxide crystal is found to be M0.60O1.00 . The
percentage of metal atoms missing in the crystal is x% and the ratio of numbers of M 3
and M 4 ions in the crystal is y:1
y
30. The value of is_________.
x
31. The fraction of M 3 ions in real crystal is___________.
Paragraph-1:
Ideal gas equation PV=RT is not followed by real gases. Real gases follow Van-der-waal
an 2
equations in which pressure is substituted as P and volume term is substituted by
2
V
an2
( V nb ). i.e., P V nb nRT where ‘a’ and ‘b’ are called Van-der-waal
2
V
constant. By the help of ‘a’ and ‘b’ we can study critical phenomenon of gases.
dV
32. The ratio of coefficient of thermal expansion / V and the isothermal
dT P
dV
compressibility K / V for an ideal gas is.
dP T
P P TT
A) B) C) D)
T T PP
8
33. Q: For BF3 g van-der-waal equation can be written as P V 0.1 2 RT
V2
critical volume of BF3 gas will be:
A) 0.15 litre B) 0.3 litre C) 24 litre D) 0.4 litre
Paragraph-2:
The following column I, II, III represent the different type of observations based on CFT
in complex compounds. Answer the questions that follow
Column-I- Crystal field stabilization energy (CFSE) (neglecting PE in all cases)
Column-II- Electronic configuration
Column-III- Type of complex
Column – I Column – II Column-III
CFSE Electronic Type of Complex
(neglecting PE in all cases) Configuration
(I) 0.4 0 (i) t25g , eg0 (P) High spin & paramagnetic
(II) 2.0 0 (ii) t24g , eg0 (Q) Low spin & paramagnetic
36. PCl5 g is taken in a flask at 1.0atm, sealed and allowed to attain the
following equilibrium:
The equilibrium mixture was then allowed to pass through a pin hole and the gases
coming out of pin hole initially, was collected, analyzed and mole fraction of Cl 2 was
found to be 0.53. What is the value of K P for the dissociation of PCl5 g ? (in bar)
38. The compound among following which can give 2,4-DNP test (2,4-
dinitrophenylhydrazine test)
O
NH2
H
O
O
k 2 4k 3
1
39. If cos ec k2 k
, then which of the following option(s) is/are
k 1
CORRECT? (where [.] denotes the greatest integer function)
d 1 2 x 3 2
A) sin at x tan is
2 4 3
dx 1 x
tan 1 2
B) 0 2 tan x dx tan 1 2
2
x
C) lim
3
1 sin x 2 tan x
2 e 2
x tan
4
3
tan 2
4 tan 1 x dx 2 tan1
D)
0
40. Let a line parallel to the axis of the parabola y 2 4 x be drawn through
on SQ and directrix respectively from point T. (S is focus), then which of the following
5 2 6
n n
42. If En 5 2 6 , n N then which of the following statement(s) is/are
INCORRECT?
A) En 1 10 En En 1 B) En1 10 En En 1
C) En is divisible by 4 D) En is divisible by 2n n N
43. Let a class have 20 students. The average marks of these students in the mathematics
examination is 62 and their variance is 30. A student fails in the examination if he/she gets
less than 40 marks, then the number of students that may fail is
A) 1 B) 0 C) 2 D) 3
44. Which of the following statement(s) is/are CORRECT?
A) The line of intersection of planes r.n1 q1, r.n2 q2 and
r.n3 q3 , r.n4 q4 are perpendicular if n1.n3 n2 .n4 n1.n4 n2 .n3
B) If three distinct planes r.n1 q1, r.n2 q2 ; r.n3 q3 intersect in a line which is contained
by the plane r.n4 q4 ;then n1 n2 n4 n3 n1 n2 n3 n4
C) If a plane contains line of intersection of planes r.n1 q1, r.n2 q2 and is parallel to
line of intersection of planes r.n3 q3 , r.n4 q4 then n1 n2 n4 n3 n1 n2 n3 n4
D) Given three non-parallel planes r .a 1, r .b 4, r .c 5 where a , b , c are mutually
perpendicular vectors, then the position vector of point of intersection of planes is
a 4b 5c
r
a b c
f 20
47. The value of
100
f n
48. The value of lim
n n3
n2 , then n1 n2 is equal to
A) 7 B) 8 C) 6 D) 9
SECTION-4(Maximum Marks: 12)
Non-Negative Integer Answer Type
This section contains THREE (03) questions.
The answer to each question is a NON-NEGATIVE INTEGER.
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
55. Federer, Nadal, Djokovic and Murray are the four players left in a singles tennis
tournament. They are randomly assigned opponents in the semi final matches, and the
winners of those matches play each other in the final match to determine the winner of the
2
tournament. When Federer plays Nadal, Federer will win the match with probability .
3
When either Federer or Nadal plays either Djokovic or Murray, Federer or Nadal will win
3
the match with probability . Assume that outcomes of different matches are independent.
4
p
The probability that Nadal will win the tournament is , where p and q are relatively
q
prime positive integers. Find units digit of p + q.
56. If the sum of all the elements of the set : 1,2,3,......100 and HCF ,24 1 is N,
then the units digit of N is
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 21
Sri Chaitanya IIT Academy 19-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P2)_GTA-16_Q.P
57. Given eight distinguishable rings, let N be the number of possible five-ring arrangements
on the four fingers (not the thumb) of one hand. The order of rings on each finger is
significant, but it is not required that each finger have a ring. The number of distinct digits
in N are