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Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAM ILNADU  M AHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -1 (Adv-2022-P1-M odel) D ate: 07-04-2024
T i me: 09.00Am to 12.00Pm GT A-22/20 M ax. M ar k s: 180
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20_Syllabus

M ATHEM ATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEM ISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:


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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

JEE-ADVANCE-2022-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180

MATHEMATICS:
+ Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 1 – 8) +3 0 8 24
Answer Type
Questions with Multiple Correct
Sec – II(Q.N : 9 – 14) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 15 – 18) Matching Type +3 -1 4 12

Total 18 60

PHYSICS:
+ Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 19 – 26) +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Sec – III(Q.N : 33 – 36) Matching Type +3 -1 4 12

Total 18 60

CHEMISTRY:
+ Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 37 – 44 +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Sec – III(Q.N : 51 – 54) Matching Type +3 -1 4 12

Total 18 60

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MATHEMATICS
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.

tdx

1. The number of solution(s) of the equation e

0 xx  
2025  x  1 
x

t
  xe t
2  x2
dx is R, then the
0

value of R 2  42 R  1000 is equal to _______


  2x  
  1  2cos  k 
3 
2. If f  x      , then number of points where
k 1
3 
 
 
 xf
  x   xf  x    x 1 x 2  3x  2 is non-differentiable in x  0,14  is equal to
(where [.] denotes greatest integer function)
          
3. If        and tan   tan   tan    1 , the value of
 4   4   4 
1  cos   cos   cos   is  R  7 , then R is equal to _______
4. In the given figure AB and BC are adjacent sides of square ABCD; M is the midpoint of
AB; N is the midpoint of BC; and AN and CM intersect at O. The ratio of the area of
AOCD to the area of ABCD is m : n (GCD (m, n) = 1) then the value of 2m + 3n is equal
to ________
D C

N
O

B
A M

5. If the standard deviation of 10 observations x1, x2 ,....., x10 is 10 and that of another set of

 
10 observations y1, y2 ,....... y10 is 4 and also X i  xi  x yi  y . Given that x is mean 
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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
10
of all xi ’s and y is mean all yi ’s.  X i  320 . The variance of observations
i 1
x1  y1, x2  y2 ,......, x10  y10 is equal to ________
6. Let C1 and C2 be two circles intersecting at points P and Q. The tangent line closer to Q
touches C1 and C2 at M and N respectively. If PQ = 3, QN = 2, and MN = PN, The value
of QM 2 is equal to ________
7. Let (1, 0) be the vertex and x + y – 7 = 0 be the equation of the latus rectum of a parabola
and if the equation of parabola is x 2  y 2  2 xy  px  qy  r  0 , then
p  q  r is equal to ________
8. The number of solutions of equation
9cos12 x  cos2 2 x  1  6cos6 x cos 2 x  6cos 6 x  2cos 2 x in 0, 4  are ________
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.

9. For x  0 , let f  x represent the real root of the equation y 3  26 xy  27 .


1
 f  x log e f  x dx  52  243loge 3  R  , then R is divisible by
2 1
If
0
A) 3 B) 4 C) 7 D) 16
10. e
tan x
sec x  tan x  2sec x  1 sec x.dx  e tan x f  x   C , then which of the following
option(s) is(are) FALSE ? (C is constant of integration)

A) f  0  2 B) f    4 3  8
 3
   2
C) f   / 4  4  2 6 D) f    4 3 
 6  3

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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

Let f :  0,1  R be a continuous function. If f (x) is differentiable on (0, 1) and


1
 f  x dx  0 , then which option(s) is(are) CORRECT?
0
c
A)  f  x  dx  f c  , for at least one c in (0, 1)
0
c
f c 
B)  f  x dx  , for at least one c in (0, 1)
2c
0
c
1  c 
f  x dx  
  c   
C) f c , for at least one c in (0, 1)
0
c
1  c 
f  xdx  
 c   
D)  f c , for at least one c  0,1
0

9 27 3 219
12. The value(s) of x satisfying the equation x9  x 6  x  x  0 is
8 64 512
1  13 1
A) B)
4 2
1  13
C) D) more than two real and distinct values
4
13. Assume that  ,  ,  satisfy 0        2 , If
cos  x     cos  x     cos  x     0
for all x  R , then which of the following option(s) is(are) CORRECT ?
2 2  
A)     B)    C)    D)    
3 3 3 3

Sec: Sr.Super6 0 _Elite, Target & LIIT-BTs Space for rough w ork Page 5
14.
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Sri Chaitanya IIT Academy

 
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

Let f x be a twice differentiable non-decreasing function such that


3
1  
x x
  f t  dt  2   f  t  dt  x  R   0 and f 1  1 , then which of the following
3

0 x  0


option(s) is(are) CORRECT?


A) Number of solutions of f  x   x 2  x is 1
B) Number of solutions of f  x   log e x3 is 1
C) Number of solutions of f  x   x11  x7 is 1
D) Number of solutions of f  x   2 x12  x 24  x36 is 2
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
15. Let A and B are non singular square matrices of order 3  3 such that B is adjoint of A
and A1 AT  A B 1 . Match List-I with List-II and select the correct answer using the
code given below the list.
LIST-I LIST-II
A) A is equal to P) 1
B) B is equal to Q) A=I
C) If A is symmetric matrix then R) A3  I
D) If A is orthogonal matrix then S) B=I
B3  I T)
U) –1
Where X denotes determinant of matrix X and I is identity matrix.
A) A–P, B–U, C–Q,S, D–R,T B) A–U, B–U, C–S,T, D–Q,R
C) A–U, B–U, C–Q,R, D–S,T D) A–P, B–P, C–Q,R,S,T, D–R,T

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16.
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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
Match List-I with List-II and select the correct answer using the code given below the
list.
COLUMN-I COLUMN-II
A) If the length of any edge of a regular tetrahedron is P) 1
1 unit then the distance (in units) of any vertex 3
from the opposite face is
B) If the length of any edge of a regular tetrahedron is Q) 1
1 unit and  is the angle between any edge and a 2 2

face not containing that edge then cos  is equal to


C) The edges of a parallelepiped are of unit length R) 1
and are parallel to non-coplanar unit vectors 2
     1
a, b, c such that a.b  b.c  c.a  . Then the
2
volume of the parallelepiped (in cubic units) is
D) If  is the acute angle between the lines x = 2t – 2, S) 1
y = 3 – 4t, z = t – 4 and x = – 2 – t, y = 3 + 2t, z = 6
3t – 4 then cos  is equal to
T) 2
3
A) A–T, B–P, C–R, D–S B) A–R, B–Q, C–P, D–S
C) A–R, B–P, C–Q, D–S D) A–R, B–P, C–R, D–T
17. Two absent minded room-mates A and B forget their umbrella’s in some way or another.
A always takes his umbrella when he goes out of his home, while B forgets to take his
1
umbrella with probability . Each of them forgets his umbrella at a shop with probability
2
1
. After visiting three shops they return home. Probability that
4

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COLUMN-I
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
COLUMN-II
A) Both umbrellas, are in the home P) 4366
8192
B) Only one umbrella, in the home Q) 2457
8192
C) B has lost his umbrella given that there is only one, R) 999
umbrella in the home 4366
D) A has lost his umbrella given that there is only one S) 3367
umbrella, in the home 4366
T) 1367
8192
U) 5735
8192
A) A–Q, B–P, C–R, D–S B) A–S, B–P, C–R, D–Q
C) A–P, B–Q, C–R, D–S D) A–Q, B–R, C–P, D–S
18. Match List-I with List-II and select the correct answer using the code given below the
list.
COLUMN-I COLUMN-II
A) Let  ,  ,  ,  be the roots of the equation x4  x3  2x2  x  1  0 , P) 0

  
then the value of  3  1  3  1  3  1  3  1 is 
B) 2180 179 Q) 4
The value of 
45 k 1
sin k 0 is

C) If complex numbers z1, z3 and z3 are the vertices of an isosceles R) 8


right angled triangle, right angled at the vertex z2 , then

 z1  z2  2   z3  z2 2 equals
D)
Let Z 
1
2
 
3  i . If the least positive integer value of ‘n’ such
S) 16

 
106 2
that z101  i109  z n is ‘k’ then k is
5
A) A–Q, B–R, C–P, D–S B) A–S, B–P, C–R, D–Q
C) A–S, B–R, C–P, D–Q D) A–Q, B–P, C–R, D–S

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PHYSICS
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.
19. A rectangular hole of dimensions a b is cut in horizontal bottom of large vessel. To
close the hole, a cuboidal block of dimensions b  c  c is put on it in such a way that the
square faces and a diagonal plane remain vertical as shown in the figure. Now a liquid of
density  is slowly poured in the vessel. The mass m of the block be so that the hole
always remains closed irrespective of the level of liquid in the vessel is
 y
 a 
m  b c   . Find x + y?
 x 

20. A small body starts falling onto the sun from a distance equal to radius of the earth’s
orbit. Find approximate time of fall onto the surface of the sun. (in days) (round it off to
nearest integer)
21. Small identical balls with equal charges are fixed at vertices of regular 2004–gon with
side a. At a certain instant, one of the balls is released and a sufficiently long time
interval later, the ball adjacent to the first released ball is freed. The kinetic energies of
the released balls are found to differ by K at a sufficiently long distance from the
polygon. The charge q of each part is x0aK . Find x?
22. A thin uniform conducting disc of radius r and mass m rests on a horizontal tabletop
where a uniform magnetic field of induction B pointing vertically upwards exists.
Coefficient of friction between the disc and the tabletop is  . Two points P1 and P2 on
the rim of the disc are connected with two flexible wires, which facilitate a current to
flow through the disc. The contact points P1 and P2 subtend an angle  at the centre of
the disc. Minimum current must flow through the disc so that it begins to slide
mg
is . Find x + y? Acceleration of free fall is g.
xBr sin  / y 

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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

23. In a region of space, a radial magnetic field is established, flux density B of which varies
with distance r from the origin of a coordinate system according to the law B   / r 2 .
Here  is a positive constant. A small conducting ring of radius a and resistance R is
placed parallel to the y – z plane with its centre at point (x,0,0). The force that must be
p 2a 4 2v
applied on the ring to move it with a constant velocity vi is . Find
 
n
R xq x2  a 2
pq n?
24. Two identical inductors each of inductance L are connected in series and then a capacitor
of capacitance C is connected in parallel to one of the inductors.
This combination is connected across a series combination of an incandescent lamp and a
variable frequency alternating voltage source as shown in the figure. It has been observed
that the lamp glows with minimum brightness at an angular frequency  . Angular
frequency that will make the lamp glow with maximum brightness is x  . Find x?

R
25. A transparent sphere of radius R has a cavity of radius as shown in figure. The
2
a b
refractive index of the sphere is   . If a parallel beam of light falling on left
c
surface focuses at point P, find the value of [bc – a]

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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
Some identical thin convex lenses are arranged at edge of a full circle of radius R,
according to the picture below. The lenses have equal angle spacing of    1 . Each
lens has aperture length of D.

Longest focus distance, f , of the lenses so that it is possible to trap a ray of light inside
D
the circle is x . Find x?

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
27. Mark the CORRECT statement(s):-
A) When two waves of different frequency f1 and f 2 are superimposed at a point, the
variation of intensity takes place with frequency f1  f 2 .
B) When an observer is moving, relative speed of the sound waves with respect to the
observer is changed, while due to motion of source, the sound wavelength of the wave
changes.
C) When a high pressure compression pulse reaches water surface in a resonance column,
it reflects as a low pressure rare fraction pulse due to a phase change of  .
D) When a tuning fork is struck by a hammer a transverse wave sets in the prong while a
longitudinal wave sets in the stem (handle) of tuning fork.
28. The figure shows the variation of photocurrent with anode potential for a photosensitive
surface for three different radiations. Let I a , I b and I c be the intensities f a , fb and f c be
the frequencies for the curves a, b and c respectively.
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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

A) f a  fb and I a  I b B) f a  f c and I a  I c
C) f a  fb and I a  I b D) f a  f c and I b  I c
29. A pulse of light of duration 100 ns is absorbed completely by a small object initially at
rest. Power of the pulse is 30 mW and the speed of light is 3108 ms1 . The final
momentum of the object is
A) 0.31017 kg  ms1 B) 1.0 1017 kg  ms1
C) 3.0 1017 kg  ms1 D) 9.0 1017 kg  ms1
30. An astronaut leaves his spaceship for some experiment and floats freely in space at rest
relative to his spaceship. His friend in the spaceship ignites a rocket installed on the
spaceship for a very short duration. Which of the following observations can you make
relative to a reference frame moving together with the astronaut outside the spaceship?
A) The spaceship has lesser kinetic energy than the ejected gases.
B) The spaceship and the ejected gases have equal kinetic energies.
C) The spaceship has greater kinetic energy than the ejected gases.
D) Magnitudes of momenta of spaceship and ejected gases are equal.
31. A small block rests on flat bottom of a deep bowl that is placed on a horizontal floor.
There is no friction between the block and the bowl as well as between the bowl and the
floor. Total mass of the bowl and the block is M. If the bowl is given a horizontal
velocity by a sharp hit, the block rises to a maximum height h sliding on the walls of the
bowl. Which of the following statements are CORRECT?

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A) Maximum kinetic energy of the bowl is Mgh.
B) If the bowl is lighter than the block, minimum kinetic energy of the bowl is zero.
C) To predict minimum kinetic energy of the bowl, we must know ratio of the masses.
D) To predict maximum as well as minimum kinetic energy of the bowl, we must know
ratio of the masses.
32. A sledge on which you are riding is given an initial push to slide on a straight level
frictionless track. Snow is falling vertically on the sledge in the frame of the track. You
have to adopt any one of the following three strategies to keep our sledge moving fastest.
I) You sweep the snow off the sledge so that it leaves the sledge perpendicular to the
track, as seen by you in the frame of the sledge.
II) You sweep the snow off the sledge so that it leaves the sledge perpendicular to the
track, as seen by someone in the frame of the track.
III) You do nothing.
Order the strategies from the best to the worst.
A) II, III and I B) III, II and I C) I, II and III D) II, I and III
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
33. Column-I shows two waves travelling in opposite direction (shown by the arrows) while
column-II describes the nature of resultant wave as a result of superposition of these two
waves.

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COLUMN-I
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
COLUMN-II
A) P)

Both waves have same amplitude time period T


B) Q)

Both waves have same amplitude, and


time period T
C) R)

Both waves have same amplitude, and time period T


D) S)

Wave 2 have double the amplitude as wave 1


but both waves have same time period T
T) Velocity of point with
minimum amplitude is zero
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A) A–PT, B–RT, C–QT, D–S


07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
B) A–PT, B–RT, C–S, D–QT
C) A– QT, B–RT, C– PT, D–S D) A–PT, B– S, C–QT, D–RT
34. The diagram shows a cuboidal container with a non–viscous liquid of nonuniform density
but a uniform refractive index 0 . The height of container is 0.4 SI units and the density
of liquid varies linearly according to the relation:
   0 1  4 y 

Where  0 is a constant and y is the vertical distance measured from the midplane

(ABPQ) of the container. (y is positive when measured upward, and negative when
measured downward).
There are two horizontal slits, covered with perfectly transparent films, in one of the
vertical faces as shown in the figure. A thin transparent strip of material having
superficial dimensions equal to the slits and thickness equal to d (volume V0 ) is released
from rest from an initial depths below the mid–plane (ABPQ) (i.e., from
y = – s) close to the slits. The strip has a constant density  0 , uniform refractive index
 0  and it move due to buoyancy keeping its plane parallel to the plane of the slits;
always remaining very close to the plane of the slits).
Monochromatic plane wavefronts (of light) parallel to the plane of the slits enter into the
liquid through the face opposite the double–slit. The intensity of light is observed on the
screen placed outside the container parallel to the plane of the slits.

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COLUMN-I
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
COLUMN-II
A) s = 2d and 0 < t < 1 sec P) Central bright fringe is always at C
B) s = 3d and 0 < t < 2 sec Q) Central bright fringe is below C four times
C) s = d/4 and 0 < t < 6 sec R) Central bright fringe is above C twice
D) s = d and 0 < t < 3/4 sec S) Central bright fringe is above C four times
T) Central bright fringe is below C twice
A) A–RS, B–QR, C–P, D–R B) A–RT, B–QS, C–PQ, D–RS
C) A–RP, B–QT, C–P, D–R D) A–RT, B–QS, C–P, D–R
35. Four identical conducting places are kept parallel to each other. Area of each plate is
A and d is separation between successive plates. Column–I represent arrangement of
plates. Column–II represent equivalent capacity of arrangement between 1 and 2.
COLUMN-I COLUMN-II
P) 1) 0 A
2d

Q) 2) 30 A
1 2 d

R) 3) 2 0 A
3 d

S) 1 4) 20 A
d
2

A) P–3, Q–4, R–1, S–2 B) P–3, Q–4, R–2, S–1


C) P–2, Q–4, R–3, S–1 D) P–4, Q–3, R–2, S–1

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36.
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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
A particle of unit mass is moving along the x–axis under the influence of a force and its
total energy is conserved. Four possible forms of the potential energy of the particle are
given in Column–I (a and U 0 are constant). Match the potential energies in Column–I to
the corresponding statement(s) in Column–II.
COLUMN-I COLUMN-II
A)  22 P) The force acting on the particle is zero at
U 0   x  
U1  x   1 
2   a  
x = a.
 
B) U 0  x 
2 Q) The force acting on the particle is zero at
U 2  x   
2  a  x = 0.

C) 2   2  R) The force acting on the particle is zero at


U 0  x   x  
U 3  x    exp   a  
2  a    x = – a.

D)  3 S) The particle experiences an attractive


U 0  x 1  x  
U 4  x    
2  a 3  a   force towards x = 0 in the region x  a .
 
T) U0
The particle with total energy can
4
oscillate about the point x = – a.
A) A–PT, B–QT, C–PS, D–PQ
B) A–PQRT, B–QS, C–PQRS, D–PRT
C) A–PQRT, B–QST, C–PRS, D–PR
D) A–PQRT, B–QRS, C–PQRS, D–PT

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CHEMISTRY
07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.
37. In the following sequence of reactions the overall % yield of ‘O’
92% yield 78% yield 85% yield
is L 
 M 
 N 
O
38. Catalytic hydrogenation of the following compound produces saturated hydrocarbons.
The number of stereo isomers formed is.
Me Me

Me

Me

39. The coordination number of Al in crystalline AlCl3 is P and in liquid AlCl3 is Q. Then
P + Q is
i ) NH OH .HCl
40. Benzophenone 
2  Major What is the molecular wt of ‘S’
ii ) H 2 SO4 .H 2O.heat
iii )1eq Br2 / FeBr3 S
(At. wt: C = 12, H = 1, O = 16, N = 14, Br = 80)
41. The number of S-S bonds present in tetrathionate ion is
42. An irreversible reaction A  B  products is monitored in buffered aqueous solution
under conditions where  B    A by measuring the concentration of A as a function of
time. The decay of A is found to be first order under these conditions, with the half-life
for its disappearance varying as shown.
 B pH Half-life for disappearance of A

0.100 M 1.00 120 s


0.200 M 1.00 60 s
0.200 M 1.50 190 s

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Sri Chaitanya IIT Academy 07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P
What is the half-life (in minutes) of disappearance of B if buffered aqueous solution
under conditions where [A] >> [B] by measuring the concentration of A as a function of

time at [A] = 0.20 at POH  12.50 [To report your answer nearest integer]
43. Boiling point of a solution containing 1.28 gram of naphthalene in 100 gram CC 4 is
350.5K. An unknown compound of mass 2.16 grams in 200 gram CC 4 yields a solution

with boiling point of 350.6K. If the molar mass of unknown compound is xgmol1 , then
x
the value of is (Boiling point of CC 4 is 350 K)
10
44. 2 mole of ideal gas undergoes a state change from 2 atm to 20 atm at constant
temperature of 300 K. What is the change in Gibb’s free energy for this state change in

kJ? (Use R  8 JK 1mol1 and n10  2.3 ) rounding to nearest integer


SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.

45.  
The metal in M 2 in the following reaction

M 2  S 2  Black ppt White ppt


hot
conc.HNO3

A) Mn2 B) Fe 2 C) Cd 2 D) Zn 2
46. Identify the reagents in the following conversion to get the product in maximum yield.

R S
P COOH

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(Where R and S are reagents and P is intermediate product)
A) R = Hydroboration - Oxidation B) S = Jones oxidation
C) R  PdCl2 / CuCl2 D) S = Haloform reaction
47. In the following reaction, the major products E and F are
OH

 CH3CO 2 O
 E 
i ) NaOH / CO F
2
ii ) H 3O 

OCOCH3

OH

COO COCH3

A) COOH B)
OH O COCH3

COOH COOH

C) D)
48. Among the following the species having see-saw shape is/are

A) SF4 B) XeF4 C) ClF4 D) ClF4


49. Purification of colloidal solution performed by
A) Removing all the electrolytes from dispersion medium.
B) Removing all the electrolytes from surface of colloidal particles.
C) Electrodialysis.
D) Electrophoresis.
50. The amount of ion discharged during electrolysis is dependent on
A) Conductance B) time
C) Electric current D) Electrochemical equivalent
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SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
51. Match the following.
COLUMN-I COLUMN-II
A) Br
P) P  SN 2
NaSH


excess
Br

B) Br Q) Q  E2
NaSH
 
excess
Br

NO2

C) C H O  Na  R) R  S N Ar

2 5 

Br

D) Br C H O  Na  S) S  E1

2 5

A) A – R, B – P, C – Q, D – P B) A – P, B – P, C – Q, D – S
C) A – P, B – R, C – Q, D – P D) A – Q, B – R, C – S, D – P
52. Match the following.
COLUMN-I COLUMN-II
A) Na Co  NO   P) sp3
3 2 6
B)  NiCl  PPh   Q) dsp 2
 2 3 2
C) Co  H O   Cl R) sp3d 2
 2 6 2
D) H 2  AuCl4  S) d 2sp3
A) A – R, B – P, C – S, D – Q B) A – R, B – P, C – R, D – Q
C) A – S, B – P, C – R, D – Q D) A – S, B – P, C – S, D – P
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53.
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Sri Chaitanya IIT Academy

Match the following.


07-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-22/ 20 _ Q.P

COLUMN-I COLUMN-II
A) HOCl P) Strongest acid
B) HClO2 Q) Strongest oxidising agent
C) HClO3 R) The shape of the conjugate base of the
acid does not depend on the presence of
lone pair of electrons.
D) HClO4 S) Two/One d   p bonds are present
A) A – P, B – R, C – S, D – Q B) A – Q, B – S, C – S, D – P
C) A – Q, B – S, C – P, D – P D) A – R, B – S, C – S, D – Q
54. The van der Walls constants a and b of a real gas are 3.6L2atm mol 2 and
0.05L mol 1 respectively. If 200g of gas (molecular mass 40) is placed in 10L vessel at
300K. Choose the correct matching in the context of real gas exactly following van der
walls equation.
COLUMN-I COLUMN-II
A) Pressure correction (atm) P) 0.25
B) Free space for the molecules to move in vessel (L) Q) 0.0125
C) Actual volume of the gas molecules per mole (L) R) 0.9
D) Effective volume occupied by total gas molecules (L) S) 9.75
T) Dependent on
volume of the vessel
A) A – R, B – ST, C – Q, D – P B) A – ST, B – R, C – Q, D – P
C) A – RT, B – ST, C – P, D – Q D) A – ST, B – RT, C – P, D – Q

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