You are on page 1of 23

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -1(Adv-2023-P1-Model) Date: 08-02-2024
Time: 09.00Am to 12.00Pm GTA-14 Max. Marks: 180
08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Syllabus

MATHEMATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:


Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

JEE-ADVANCE-2023-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 3) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 4 – 7) +3 -1 4 12
Choice
Sec – III(Q.N : 8 – 13) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 18 – 20) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 21 – 24) +3 -1 4 12
Choice
Sec – III(Q.N : 25 – 30) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 31 – 34) Matching Type +3 -1 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 35 – 37) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 38 – 41) +3 -1 4 12
Choice
Sec – III(Q.N : 42 – 47) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 48 – 51) Matching Type +3 -1 4 12
Total 17 60

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 2
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

MATHEMATICS
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

1. The complete set of values of real parameter ' m ' for which the equation

m sin 2 x  (m  1) sin x  (m  2)  0 has

 2 
A) No real roots is (,1)  1  , 
 3 

B) 5 roots in [0, 2 ] is {2}

 3  2
C) 4 roots in [0, 2 ] is (1,2)   2, 
 3 

 3  2 
D) 2 roots in [0, 2 ] is  1, 1, 
 3 

2. If P1P2 and Q1Q2 , two focal chords of a parabola are at right angles, then:
A) area of the quadrilateral P1Q1P2Q2 is minimum when the chords are inclined at an

angle to the axis of the parabola
4
B) minimum area is twice the area of the square on the latus rectum of the parabola
C) minimum area of P1Q1P2Q2 cannot be found
D) minimum area is thrice the area of the square on the latus rectum of the parabola
Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 3
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
1
p cos x  xe x
3. If lim  0 , then which of the following is/are incorrect about p, q ?
x 0 1
1  sin x  q cos x  e x
A) p  0, q  R B) p  4, q  2
C) p  2, q  R D) p  0, q  2
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
100
3 100   
4. If 2(1  x )    ar xr  cos  2 ( x  r )   , then the value of a0  a2  a4  .  a100
r 0
is equal to:
A) 2100 B) 2101 C) 2100  50 D) 2100  50
5. Let and be two complex numbers such that | z |  1,| w |  1 and | z  iw |  | z  iw |  2 ,
then z equals
A) 1 or i B) i or i C) 1 or 1 D) i or 1
6. A square OABC is formed by line pairs xy  0 and xy  1  x  y where ' O ' is the origin.
A circle with centre C1 inside the square is drawn to touch the line pair xy  0 and
another circle with centre C2 and radius twice that of C1 , is drawn to touch the circle C1
and the other line pair. The radius of the circle with centre C1 is:
2 2 2 2 2 1
A) B) C) D)
3( 2  1) 3( 2  1) 3( 2  1) 3 2
 
2010
e  
1 1  ln x 
7. The value of the definite integral  1 dx , equals:
x  x 
e  ln x ln  
  ln x  
A) 2009  ln(2010  ln2010) B) 2010  ln(2009  ln2009)
C) 2009  ln(2010  ln2009) D) 2010  ln(2010  ln2010)

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 4
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
 Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

32 52 7 2 2
8. The sum upto infinite terms of the series 1      is equal to
2 2 2 23
9. If all the letters of the word 'MATHEMATICS' are arranged arbitrarily. The probability
1
that C comes before E, E before H, H before I and I before S is , then N is equal to
N
10. An isosceles  ABC is inscribed in the circle x 2  y 2  16, A  (0,4) . From points A, B
x2 y 2
and C three ordinates are drawn which cut the ellipse   1 at the points P, Q and
16 9
R respectively such that A and P are on the opposite sides, Q and B are on the same side
and C and R are on the same side of the major axis. If PQR is right angled at P and 
is the smallest angle of the  ABC , then find the value of 16 tan 2  8tan   9 .
x2 y 2
11. A normal to the hyperbola   1 , has equal intercepts on positive and -axes. If
4 1
x2 y2 9 2
this normal touches the ellipse
a2

b2
 1 , then find
25

a  b2 . 
x
12. Let f ( x)   3t (3t  4)( x  t )dt ( x  0) . If x  a is the point where f ( x) attains its local
0
minimum value then find the value of 3a .
 1
13. Let y  f ( x) be a curve C1 passing through (2,2) and  8,  and satisfying a differential
 2
 d2y  2
 dy 
equation y    2   . Curve C2 is the director circle of the circle x 2  y 2  2 . If
 dx 
2  dx 
 
the shortest distance between the curves C1 and C2 is ( p  q ) where p, q  N , then

find the value of ( p 2  q ) .


Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 5
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
 Negative Marks: –1 In all other cases.

2cos t if i  j

14. Let A(t )   aij  is a matrix of order 3  3 given by aij   1 if | i  j | 1, then
 0 otherwise

Column-I Column-II
The number of t ininterval [2π , 4π ] such that | A(t ) |  4 is
P 1 0
equal to

π   4π 
Q A   A   is equal to 2 1
 17   17 

R The maximumvalue of | A(t ) |  | A(2t ) |,  t  R is equal to 3 4


π
S  | A(t)  A(4t) | dt is equal to 4 6
0

5 8
A) P -5; Q -4; R -3; S -1 B) P -3; Q -4; R -5; S -1
C)P -3; Q -2; R -5; S -1 D) P -1; Q -2; R -3; S -4
15. Let A  {1,2,3, 4}, B  {1,2,3, 4,5,6,7,8}
Column-I Column-II
The number of functions f : B  A, suchthat
P if x1  x2 , then f  x1   f  x2   x1 , x2  B 1 7
is N.Thenthe sumof digits of N is

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 6
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

The number of onto functions f : B  A


Q suchthat if x1  x2 , then f  x1   f  x2  2 8
 x1, x2  B is N.Thenthe sum of digits of N is
The numbers of one  one function f : A  B
R suchthat f ( x )  x  x  A is N. 3 9
Then the sumof digits of N is
The number of one  one function f : A  B
suchthat there are exactly two, x,
S 4 10
x  A for which f ( x)  x is N. Thenthe
sum of digits of N is

5 12
Code:
A) P -5; Q -2; R -1;S -3 B) P -4; Q -1; R -5; S -2
C) P -4; Q -2; R -3; S -2 D) P -1; Q -2; R -3; S -4
16. Match the Column I with Column II
Column-I Column-II
Let f : R  R and f n  x   f ( f n 1( x))
 n  2, n  N , the roots of equation
P 1 1
f3 ( x) f 2 ( x ) f ( x )  25 f 2 ( x) f ( x)  175 f ( x)  375 .
Which also satisfy equation f ( x )  x will be

Let f :[5,10] onto [4,17] , the integers in the range


Q 2 5
of y  f ( f ( f ( x ))) is/are

Let f  x   8 cot 1  cot x  


5sin 1(sinx)  4tan 1(tanx)
R 3 10
1
 sin(sin x) , then possible integral values which
f ( x) can take

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 7
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

Let '  ' denotes the roots of equation


 2 
cos (cos1x)  sin  1 sin  1  x   2sec  1 (sec x ) then
S  2  4 15
 
possible values of [|10 |] where [] denotes the
greatest integer function will be
5 12
Code:

A) P -1, 2; Q -1, 3; R -2, 3, 4; S -1, 3


B) P -2, 4 ; Q -2, 3, 4, 5; R -1, 2, 3, 4, 5; S -1, 3
C) P -2, 3, 4; Q -1, 2; R -1, 3, 4; S-1, 3
D) P -2, 3; Q -1, 2; R 1, 2, 3, 4; S -1, 2
17. Match the Column I with Column II
Column-I Column-II
The coordinates of a point on the line
P x  4 y  5, z  3 y  6 at a distance 3 from the point 1 (1, 2,0)
(5, 3,  6) is/are

The plane containing the lines


x2 y 3 z 5
Q   and parallel to iˆ  4 ˆj  7 kˆ has 2 (5,0, 6)
3 5 7
the point
A line passes through two points A(2, 3, 1) and
B (8, 1, 2) . The coordinates of a point on this line (2,5,7)
R 3
nearer to the origin and at a distance of 14 units from
A is/are
The coordinates of the foot of the perpendicular from
x y 2 z 3
S the point (3, 1,11) on the line   4 (10, 7, 7)
2 3 4
is/are
Code:
A) P -1; Q -3; R -4; S -2 B) P -2; Q -1; R -1; S -3
C) P -1; Q -2; R -3; S -4 D) P -2; Q -1; R- 4; S -3

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 8
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
PHYSICS Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

18. Work function of a metal X equals the ionization energy of Li 2  ion in second excited

state. Work function of another metal Y equals the ionization energy of He  ion with
electron in n  4 . Now photons of energy E fall separately on both the metals such that
maximum kinetic energy of photoelectron emitted from metal X is half that of
photoelectron emitted from metal Y. Choose the correct statement (E0  Potential energy
of electron in ground state of hydrogen atom)
A) E  3.5 E0
7 E0
B) E 
8
C) If E is increased, difference in maximum kinetic energies of photo electrons emitted
from X and increases
D) If E is increased, difference in maximum kinetic energies of photo electrons emitted
from X and Y remains constant
19. A particle is moving along a vertical circle of radius R  20 m with a constant speed

v  31.4 ms1 as shown in Fig. Straight line ABC is horizontal and passes through the
centre of the circle. A shell is fired from point A at the instant when particle is at C .
If distance AB is 20 3 m and shell collides with the particle at B, (    and

g  10m/s 2 )

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 9
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

A) Smallest possible value of the angle  of projection, will be 30


B) velocity u of projections should be 20 m/s

C) Smallest value of  must be 45


D) Velocity of projectile will be 30 m/s
20. A solid metallic cylinder of mass m  1 kg and radius R  20 cm is free to roll (without
sliding) over the inclined surface of a wooden wedge of mass  0.28 kg . Surface of wedge

is inclined at 37 with the horizontal and the wedge lies on a smooth horizontal floor.

g (10m/s 2 )
When the system is released from rest,

A) Acceleration of the wedge is 3.75 m/s 2

B) angular acceleration of the cylinder 30 rad/s 2


C) force of interaction between cylinder and the wedge 5.75 N
D) Friction between cylinder and the wedge will be 3 N
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 10
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
21. On an imaginary planet the acceleration due to gravity is same as that on Earth but there
is also a downward electric field that is uniform close to the planet's surface. A ball of
mass m carrying a charge q is thrown upward at a speed v and hits the ground after an
interval t. What is the magnitude of potential difference between the starting point and
the top point of the trajectory?
mv  gt  mv  gt  mv 2mv
A) v   B) v   C)  v  gt  D) (v  gt )
2q  2 q  2 2q q

22.
In the given circuit the resistance R can be varied. Battery having emf 18 volt is having
internal resistance 3Ω . The value of R is selected such that power dissipated in it is
maximum. Now 6Ω resistance is replaced by an inductor having inductance L  6 mH
so circuit will appear like the circuit shown in diagram given below

Find time constant for above circuit in milliseconds.


A) 5 B) 4 C) 3 D) None of these
23. The space between two concentric conducting spherical shells of radius a and 2a is
filled with a dielectic medium having dielectric constant K and resistivity  . The inner
sphere is given a charge Q at t  0 and outer is earthed then

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 11
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
t

0K
A) Charge on inner sphere as a function of time is Qe
2t

e0 K 
B) charge on inner sphere as a function of time is Qe

C) resistance is
8a

D) resistance is
4a
24. An AC source of angular frequency  is fed across a resistor R and a capacitor C in
series. The current registered is I. If now the frequency of source is changed to  / 3 (but
maintaining the same voltage), the current in the circuit is found to be halved. The ratio
of reactance to resistance at the original frequency  will be :
3 5 3 5
A) B) C) D)
5 3 5 3
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
 Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. In the system shown in Fig pulleys are massless and frictionless. Thread is inextensible.
mg sin 
Neglecting friction, acceleration of the right wedge is given by a 
M  x m( y  cos 
find x 2  y 2

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 12
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
26. A small sphere of mass m  0.5 kg carrying a positive charge q  110  C is connected
with a light, flexible and inextensible string of length r  60 cm and whirled in a vertical
circle. If a vertically upward electric field of strength E  105 NC 1 exists in the space,
calculate minimum velocity of sphere required at highest point so that it may just
complete the circle. ( g  10 ms2 )
27. Two small particles, each of mass m carrying positive charge q each are attached to the
ends of a non-conducting light thread of length 2l. A third particle of mass 2m is
attached at mid-point of the thread. The whole system is placed on a smooth horizontal
floor and the particle of mass 2m is given a velocity as shown in Fig. minimum
distance between the two charged particles during the process of motion is expressed as
 a. qb  
  find a  b  c  d  e to nearest integer
 c d  mV 2  q e 
 0 

28. A coil of radius R carries current I . Another concentric coil of radius r (r  R ) carries
current i . Planes of two coils are mutually perpendicular and both the coils are free to
rotate about common diameter. Maximum kinetic energy of smaller coil when both the
x 0 M R r 2 I i
coils are released, masses of coils are M and m respectively is . Find
y ( M R 2  mr 2 )
x y
29. Conductor of length l has shape of a semi-cylinder of radius R ( ) . Cross section of
the conductor is shown in Fig. Thickness of the conductor is t ( R) and conductivity of
its material varies with angle  only, according to the law    0 cos . If a battery of
emf V and of negligible internal resistance is connected across its end faces, calculate
0 0bV ct d
magnetic induction at mid point O of the axis of the semi-cylinder is find
a 
a 2  b2  c2  d 2

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 13
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

30. A copper rod is bent into a semi-circle of radius a and at ends straight parts are bent along
diameter of the semi-circle and are passed through fixed, smooth and conducting rings O
and O' as shown in Fig. A capacitor having capacitance C is connected to the rings. The
system is located in a uniform magnetic field of induction B such that axis of rotation
OO' is perpendicular to the field direction. At initial moment of time (t  0) , plane of
semi-circle was normal to the field direction and the semi-circle is set in rotation with
constant angular velocity  . Neglecting resistance and inductance of the circuit, if
x
calculate current I flowing through the circuit at time t is found to be   c a d cB cos  t .
y
x 
Find 2   cd 
y 

SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
 Negative Marks: –1 In all other cases.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 14
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
31. A potentiometer experiment setup is shown in the given diagram. R is the point when
there is no deflection in the galvanometer. E1 is the source. Match the following.

Column-I Column-II
P If only emf of battery E1 is increased 1 point R will shift to left
If only resistance offered by rheostat is
Q 2 point R will shift to right
increased
If resistance box (RB) is connected and point R will remain
R 3
resistance of RB is increased. unchanged point R
If an identical battery is connected in parallel may shift to left or right
S 4
to E .
Code:
A) P -1; Q -2; R -4; S -4 B) P -2; Q -2; R -4; S -2
C) P -1; Q -2; R -2; S -4 D) P -1; Q -2; R -4; S -2
32. Column-I gives certain situations regarding a point object and its image formed by an
optical instrument. The possible optical instruments are diverging and converging mirrors
or lenses as given in Column-II. Same side of principal axis means both image and object
should either be above the principal axis or both should be below the principal axis as
shown in figure. Same side of optical instrument means both image and abject should be
either left of the optical instrument or both should be on right of the optical instrument as
shown in figure. Match the statements in column-I with the corresponding statements in
column-II.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 15
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

Column-I Column-II
If point object and its image are on same side of
P principal axis and opposite sides of the optical 1 Concave mirror
instrument then the optical instrument is
If point object and its image are on opposite side of
Q principal axis and same sides of the optical instrument 2 Convex mirror
then the optical instrument is
If point object and its image are on same side of
R principal axis and same sides of the optical instrument 3 Diverging lens
then the optical instrument is
If point object and its image are on opposite side of
S principal axis and opposite sides of the optical 4 Converging lens
instrument then the optical instrument is
Code:
A) P -1, 2; Q -2; R -3, 4; S-3 B) P -1; Q -1, 2; R -4; S-3
C) P -2; Q -1; R -3; S-3, 4 D) P -1, 2; Q -1,2; R -3, 4; S-3, 4
33. Capillary rise and shape of droplets on a plate due to surface tension are shown in
column-II. Match the following.
Column-I Column-II

Adhesive force is greater than


P 1
cohesive force.

Cohesive forces is greater than


Q 2
adhesive forces.

A mercury drop is pressed between two


R Pressure at A > pressure at B 3 parallel glass plates.

S Pressure at B > pressure at A 4

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 16
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
Code:
A) P -1; Q -2;R -1, 3; S -2 B) P -1; Q -2, 3, 4; R -1, 3, 4; S-2

C) P -2; Q -2, 3, 4; R -1, 3, 4; S-3 D) P -1; Q -4; R -3; S-2

34. Match the following graphs (in column–II) between position of object (u) and position of
image (v). Take positive sign in the direction of ray.

Column-I Column-II

P Concave mirror 1

Q Convex mirror 2

R Convex lens 3

S Concave lens 4

Code:
A) P -1; Q - 4; R -2; S -3 B) P -1; Q -2; R -3; S-4

C) P -1; Q -4; R -3; S-2 D) P -2; Q -3; R -4; S-1


Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 17
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
CHEMISTRY Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
 choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option
(i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

35. Which of the following statement(s) is/are false?


A) Azurite is a sulphide ore
B) Slag is more dense than molten metal
C) Cinnabar is an ore of iron
D) Cupellation process is used for purification of Ag
36. In the given reaction

3 Hg 2
2 2 7 (1) CH MgX K Cr O /H 
CH  CH (X) 
(Y)   (Z)
dil. H 2SO4 (2) H 2O room temp

Y is CH3  CH  CH3

A) X is CH3CHO B) OH

Z is CH3  C  CH3

C) O D) Z is CH3COOH

37. Select the correct statements:


3
A) For CsCl unit cell (edge-length  a ), rc  ra  a , rc  radius of cation, ra  radius
2
of anion

B) For NaCl unit cell (edge-length   ), rc  ra 
2
C) The void space in bcc unit cell is 0.68
D) The void space % in a face centred unit cell is 26%
Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 18
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : −1 In all other cases
38. The density of neon will be highest at:
A) S.T.P. B) 0  C, 2 atm C) 273 C,1atm D) 273 C, 2 atm
39. O-xylene on ozonolysis may give
A) B)

C) D)

40. At room temperature following reaction goes to completion 2AB(g)  B2 (g)  2AB2 (s)
AB2 is solid with negligible vapour pressure below 0 C . At 300 K , the AB in the
smaller flask exerts a pressure of 3 atm and in the larger flask B2 exerts a pressure of
at 400 K when they are separated out by a close valve. The gases are mixed by
opening the stop cock and after the end of the reaction the flask are cooled to 250 K

The final pressure is:


A) 0.156 atm B) 0.3125 atm C) 0.625 atm D) 3.2 atm
41. Which of the following substrates will give rearranged product in hydration reaction?
CH3  CH  CH  CH 2

A) CH3 B) CH 3  CH 2  CH  CH 2
Ph CH3

C  CH  C  CH 3

C) CH 3  CH  CH 2 D) Ph CH3

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 19
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
 Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

42. The sum of the bond order of following species, C22 ,B2 , NO,O 2 ,O 2 ,Cl2 ,S2 is x.
Find 2x.
43. A first order reaction has a rate constant 5  102 s 1 . The time required (in sec) for the
reaction to reduce 20 gram of the reactant to 2g is ………..(Round off to nearest
integer).
44. What is (t  u  v  w  x  y )

45. All possible carbonyl compounds with molecular formula  C8H8O  which has a benzene

ring in its structure and gives positive Tollen's test, when reacted with hydroxylamine
how many organic products will be possible with difference in melting point?

46. A complex of Fe 2 has magnetic moment value of 4.89 B.M. The number of electrons in
the t2g level of Fe 2 is ___________
47. The ion Co(en)Cl2 Br2 is expected to have x isomers. The value of x is ____________
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
 Negative Marks: –1 In all other cases.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 20
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
48. Column-I contains some cations and Column-II contains some anions which produce
white ppt with corresponding cation. Match Column-I with a Column-II and select
correct code for your answer.

Column I Column II

P Ag  1 Cl

Q Zn 2  2 S2

R Mg 2  3 CO32

S Ba 2  4 SO 24

Code:
A) P-2; Q -3 R -1; S -4 B) P-4; Q -3; R- 2; S -1
C) P-1; Q -4; R -3; S -2 D) P-1; Q -2; R -3; S -4

49. Match the Column I with Column II


Column I Column II
NaOH / CaO
P Schimdt reaction 1 RCOOH 
 RH

Re d P / X
2  R  CH  COOH
R  CH 2COOH 
Q Curtius reaction 2 

(i ) NaN
3  RNH
R Decarboxylation 3 RCOCl 
 2
(ii ) H 3O , 

3  RNHN H
S HVZ reaction 4 RCOOH  2

Code:
A) P -4; Q -3; R -1; S -2 B) P -2; Q -1; R -3; S -4
C) P -3; Q -4; R -1; S -2 D) P -2; Q -4; R -3; S -1
Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 21
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P
50. Match the solution in Column I with its nature in Column II.
Column I Column II
P Benzene  Toluene 1 Non-ideal solution
Q Ethanol  Water 2 Ideal solution
R Benzene  Ethanol 3 ΔH mix  0

S Acetone  Chloroform 4 ΔH mix  0


Code:
A) P-1,3; Q -2,4;R-3; S -2, 3 B) P-2; Q -1,3; R -2; S-2, 4
C) P-3, 4; Q -1,2; R -3; S-2, 4 D) P-2; Q -1, 3; R -1, 3; S-1, 4
51. Match the Column-I with Column-II
Column - I Column - II
Molecular species Properties

P H 2O 1 ΔHof  0

Q H 2O 2 2 sp3 hybridized central atom

R HO 2 3 Paramagnetic

S O2 4 Polar

T O3 5 sp 2 hybridized central atom

Code:
A) P-1, 4, 5; Q -3, 4, 5; R -1, 3, 5 ; S -1, 3;T-2, 3, 4

B) P -2, 4; Q -2, 4; R-2, 3, 4; S -1, 3; T-4, 5

C) P -1, 2, 4; Q -2, 3, 4; R -2, 3, 4; S -1, 3; T-3, 4, 5

D) P -3, 4, 5; Q -1, 4, 5 ; R -1, 3, 5; S-1, 3; T-2, 3, 4

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 22
Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-14_Q.P

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 23

You might also like