20 08 2023 SR Elite C 120, C IPL & IPL IC Jee Adv 2022 P2 RPTA 01

Sri Chaitanya IIT Academy., India.
 A.P  T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
Sec: Sr. Elite(C-120, C-IPL & IPL-IC) Jee Adv – 2022-P2 Date: 20-08-2023
Time: 02.30Pm to 05.30Pm RPTA-01 Max. Marks: 180
MATHEMATICS : Sets & Relations, Functions

PHYSICS : Thermal physics-1, Thermometry, Thermal expansion,
Calorimetry, KTG
CHEMISTRY : Atomic Structure, General Organic Chemistry
(Nomenclature, Isomerism, intermediates)
Name of the Student: ___________________ H.T. NO:

SRI CHAITANYA IIT Academy, India 20-08-2023_ Sr.Elite (C-120, C-IPL & IPL-IC)_Jee Adv (2022-P2)_RPTA-01_Q.Paper
JEE-ADVANCE-2022-P2-Model
Time: 3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct
Sec – II(Q.N : 9 – 14) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60
PHYSICS:
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 27 – 32) +4 -2 6 24
Total 18 60
CHEMISTRY:
Sec – I(Q.N : 37 – 44 Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 45 – 50) +4 -2 6 24
Total 18 60
Sec: Sr. Elite(C-120, C-IPL & IPL-IC) Space for rough work Page 2
MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtualNumeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks:+3 If ONLY the correct integer is entered;
Zero Marks:0 If the question is unanswered;
Negative Marks:-1 In all other cases
01. If f  x  is odd function, f 1  3 and f  x  2   f  x   f  2  then f  3  ___
 1
1
 hn .Pn  x   1  2hx  h2  2 , x  1, h 

02. Let Pn  x  be function satisfying value of P3  0  
n 1 3
_____
x   x
03. Let f  x  
1  x   x
x  R. If range of f  x  is  a, b  then b  where . is GIF
x 1
04. Then function f  x   can be expressed as sum of even function g  x  and odd
x3  1
function h  x  . The value of g  0   __
05. If A   x, y  / x 2  y 2  25 & B   x, y  / x 2  9 y 2  144 then n  A  B   __
If f  x  is continuous and has property f  f  x   1  x the value of f    f   is ___

1 3
06.
4 4    
 tan1 x 
 2  4   x 2  14 x  40 

07. The number of integral values of x for which   0
x !  x  1 !
08. Let A1, 2,3,4. A relation is R on A is defined by R   x, y  / x  y , x 2  y 2  9 x, y  A,
number of elements in R is____
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks:+4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four optionsare correct but ONLY three options are
chosen;
Partial Marks:+2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks:+1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks:0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
09. Which of the following functions have graph symmetrical about origin?
 x y 
A) f  x  is given f  x   f  y   f  
 1  xy 

B) f  x  is given by f  x   f  y   f x 1  y 2  y 1  x 2 

C) f  x  is given by f  x   f  y   f xy  1  x 2 1  y 2 
D) f  x  is given by f  x  y   f  x   f  y  x  R
10. Consider real value function satisfying 2 f  sin x   f  cos x   x they
A) Domain of f  x   R B) Domain of f  x    1,1
2  
C) Range f  x    , D) range is R
 3 3 
11. If a relation R is defined on Z as R   a, b  / 2 a 2  3b 2  35, a, b  zthen
A) Domain  1, 2 B) domain  2, 4
C) Range  0, 1, 2, 4, 9 D) Range  1, 3
12. Let f be a real value function satisfy
1

3
 5

f  x  k   1   2  5 f  x   10 f  x   10 f  x   5  f  x   f  x   x  R for positive value k
2 4

5
then period of f  x  is
1
 k  1   k  1 
2 2 log 2k
A) k B) 2k C) 
D) 10 10
xa
13. f  x  : R  b  R  1 Be defined by f  x    a  b  then
xb
A) f is one –one B) f is on to C) f is bijective D) f 1  2   a  2b
2x
14. Let f  x   2  x and g  x   this
x 1
2
A) Domain  f  g  2    1,   B) Domain  f  g  2    0,  
C) Range f  range  g  2    2,3 D) Range f  Range  g  2   1,  
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
Let f :  1,1  B bc a function defined by f  x   Tan 1 

2x 
15. 2 
. If f is bijection then B 
1 x 
       
A)  0,  B) 0,  C)  ,  D)  ,
 2  2  2 2  2 2 
16. Range of log 2  sin x  cos x  is
B) 0,  C)   , 0
1 1
A)  1, 0 D) 0,1
 2  2 
17. If f  x   x 3  x and g  x   sin 2 x then
A) g  f  x    2sin 2 B) g  f 1   1   
C) f g  12 
3
8
D) f  f 1   2
18. Let A and B are non-empty set if f : A  B be a function defined as f  A   f  x  / . x  A ,
f 1  B   x  A / f  x   B then
A) f  f 1B   B B) f  f 1  B    B C) f 1  f  A   A D) f 1  f  A   A
PHYSICS Max Marks: 60
SECTION-I
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
19. Calculate the pressure exerted by a mixture of 8 g of oxygen, 14g of nitrogen and 22g of
carbon dioxide in a container of 10L at a temperature of 270 C [in 105 N / m2 and to the
nearest integer]_______ 105
20. A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300K.
Find the ratio of average rotational kinetic energies per O2 molecules to per N 2
molecules.
21. 2kg of ice at 150 C is mixed with 2.5kg of water at 250 C in an insulated container. If the
specific heat capacities of ice and water are 0.5cal / g 0C and 1 cal / g 0C , find the amount
of water present in the container? (in kg nearest integer)
22. An ideal gas I filled in a closed rigid and thermally insulated container. A coil of 100 
resistor carrying current 1A for 5 minutes supplies heat to the gas. The change in internal
energy of the gas is___ 103 J
23. The average translational kinetic of O2 (Molar mass 32) molecules at a particular
temperature is 0.048 eV. The translational kinetic energy of N 2 (Molar mass 28)
molecules in eV at the same temperature is 6 x 103 . The value of x is
24. The amount of heat supplied to decrease the volume of an ice water mixture by 1cm 3
without any change in temperature is 80x cal . The value of x is
 ice  0.9, water , Lice  80cal / gm 
25. An iron rod of length 50 cm is joined at an end to an Aluminum rod of length 100 cm. All
measurements refer to 200 C. The coefficient of linear expansion of iron and Aluminum
are 12  106 / 0C and 24  106 / 0C , respectively. The average coefficient of composition
system is x  106 / 0C find x value.
26. Select the correct alternative, a vessel contains 1 mole of O2 gas (molar mass 32) at a
temperature T. The pressure of the gas is P. An identical vessel containing one mole of
He gas (molare mass 4) at a temperature 2T has a pressure of xP then x value.
SECTION – II
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
27. Due to thermal expansion with rise in temperature:
A) Metallic scales reading becomes lesser than true value
B) Pendulum clock becomes slow
C) A floating body sinks a little more
D) The weight of a body in a liquid increase
28. When the temperature of a copper coin is raised by 800 C , its diameter increase by 0.2%
A) Percentage rise in the area of a face is 0.4%
B) Percentage rise in the thickness is 0.4%
C) Percentage rise in the volume is 06%
D) Coefficient of linear expansion of copper is 0.25  104 / 0C
29. During the melting of a slab of ice at 273 K at atmospheric pressure:
A) Positive work is done by the ice-water system on the atmosphere.
B) Positive work is done on the ice-water system by the atmosphere:
C) The internal energy of the ice-water system increases
D) The internal energy of ice-water system decreases.
30. Reading of temperature may be same on
A) Celsius and Kelvin scale B) Fahrenheit and Kelvin scale
C) Celsius and Fahrenheit scale D) All the three scales
31. A vessel is party filled with liquid. When the vessel is cooled to a lower temperature, the
space in the vessel unoccupied by the liquid remains constant .Then the volume of the
liquid VL  volume of the vessel VV  , the coefficient of cubical expansion of the material
of the vessel  V  and of the solid  L  are related as

 L Vv  V VL
A)  L   V B)  L   V C)  D) 
 V VL  L VV
32. Let Vav Vrms and V p respectively denote mean speed, root mean square speed and the most
1
probable speed of the molecule in an ideal monoatomic gas at absolute temperature T.

The mass of a molecules is m then:
A) No molecule can have speed greater then 2Vrms
B) No molecule can have sped less than VP / 2

C) V p  Vav  Vrms
D) The average kinetic energy of a molecules is 3/4 mvP2

SECTION – III
33. The average translational energy and the rms speed of molecules in a sample of oxygen
gas at 300 K are 6.21  1021 J & 484 m / s respectively. The corresponding values at 600 K
are nearly (assuming ideal gas behavior)
A) 12.42  1021 J ,968m / s B) 8.78  1021 J ,684m / s
C) 6.21  1021 J ,968m / s D) 12.42  1021 J ,684m / s
34. A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300 K.
The ratio of the average rotational kinetic energy per O2 molecule to that per N 2
molecules is
A) 1:1 B) 1:2 C) 2:1 D) 2:1
35. The mean free path of a gas molecule is λ1 at temperature T. The pressure and
temperature, of both the gas, are made two times their original value. The new mean free
path was found to be λ2. Then λ1:λ2 is -
A) 1:2 B) 2:1 C) 1:1 D) 1:4
36. A real gas behaves like an ideal gas if its
A) Pressure and temperature are both high
B) Pressure and temperature are both low
C) Pressure is high and temperature is low
D) Pressure is low and temperature is high
CHEMISTRY Max Marks: 60
SECTION-I
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
37. Electromagnetic radiation of wavelength 663nm is just sufficient to ionize the atom of
x
metal A. The ionization energy of metal A in kJ mol 1 is . What is x ….. (Rounded off
60
to nearest integer)  h  6.63  1034 J  s, c  3.00  108 ms 1 , N A  6.02  mol 1 
38. If the wavelength for an electron emitted from H-atom is 3.3  1010 m, then energy
absorbed by the electron in its ground state compared to minimum energy required for its
x
escape from the atom, is times what is x (Nearest integer) {Given, h  6.626  1034 Js }
5
[Mass of electron  9.1  1031 kg ]
39. A ball weighing 10g is moving with a velocity of 90ms 1. If the uncertainty in its velocity
is 5%, then the uncertainty in its position is ……… 1033 m (Rounded off to the nearest
integer) [Given, h  6.63  1034 J  s ](Rounded off to nearest integer)
 h  6.63  1034 J  s, c  3.00  108 ms 1 , N A  6.02  mol 1 
40. A proton and a Li 3 nucleus are accelerated by the same potential. If Li and P denote the
Li
de-Broglie wavelengths of Li 3 and proton respectively, then the value of is x  101. the
p
value of x is…….. (Rounded off to the nearest integer) (Mass of Li 3  8.3 mass of proton)
41. The work function of sodium metal is 4.41  1019 J . If photons of wavelength 300nm are
incident on the metal, the kinetic energy of the ejected electrons will be
 h  6.63  10 34
J s; c  3  108 m / s  …………….. 1019 J
42. Total number of possible stereoisomers of dimethyl cyclopentane is……. (neglecting

optical isomers)
43. The number of stereoisomers possible for 1, 2- dimethyl cyclo propane is
44. The number of acyclic structural isomers (including geometrical isomers) for pentene
are…….
SECTION – II
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
45. Which of the following about an electron occupying the 1s-orbital in a hydrogen atom are
correct (The Bhor radius is represented by a0 )
A) The electron can be found at a distance 2a0 from the nucleus.

B) The magnitude of the potential energy is double that of its kinetic energy on an
Average.
C) The probability density of finding the electron is maximum at the nucleus.
D) The total energy of the electron is maximum when it is at a distance a0 from the
Nucleus.
46. Which of the following statements are correct?
A) The electronic configuration of Cr is  Ar  3d 5 4 s1
B) The magnetic quantum number may have a negative value
C) In the ground state of an atom, the orbitals are filled order of their increasing
Energies.
D) The total number of nodes are given by n  2 .
 1 1
47. For the Balmer series in the spectrum of H atom, v  RH  2
 2  , the correct statements
 n1 n2 
among (a) to (d) are:

A. As wavelength decreases, the lines in the series converge
B. The integer n1 is equal to 2
C. The lines of longest wavelength corresponds to n3  3
D. The ionization energy of hydrogen can be calculated from wave number of these
Lines
48. Which of the following will not show geometrical isomerism?
A) Ph  N  N  Ph B) 2,4  Di nitro phenyl hydrazone of acetone
C) Oxime of formaldehyde D) Cyclo hexan 1,2  diol
49. Which of the following methods are used for resolution?
A) Biological methods by using special enzymes
B) By making their diastereomers
C) Chromatographic method using special adsorbents
D) Azetortopic distillation
50. In which of the following strength G decreases. If there can be some intramolecular
rearrangement
Me
 Me
A) C H2 B ) Me

Me
Me 
C) 
C H2
C H2 D)
Me
SECTION – III
51. The correct order of nucleophilicity is
.. ..
A) F 1  OH  B) H 2 O  OH  C) R O H  RO  D) NH 2  NH 3
.. ..
52. Arrange the following carbocations in decreasing order of stability

a) CH 3 b) C2 H 5 c)  CH 3 3 C 
A) a  c  b B) a  b  c C) c  b  a D) c  a  b
53. If the de-Broglie wavelength of the electron in nth Bohr orbit in a hydrogen atom is equal
to 1.5 a0 ( a0 is Bohr radius), then the value of n/Z is
A) 1.0 B) 0.75 C) 0.40 D) 1.50
54. The number of subshells associated with n  4 and m  2 quantum numbers is
A) 8 B) 2 C) 16 D) 4

20 08 2023 SR Elite C 120, C IPL & IPL IC Jee Adv 2022 P2 RPTA 01

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20 08 2023 SR Elite C 120, C IPL & IPL IC Jee Adv 2022 P2 RPTA 01

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Sri Chaitanya IIT Academy., India.

 A.P  T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI

MATHEMATICS : Sets & Relations, Functions

Name of the Student: ___________________ H.T. NO:

function h  x  . The value of g  0   __

05. If A   x, y  / x 2  y 2  25 & B   x, y  / x 2  9 y 2  144 then n  A  B   __

If f  x  is continuous and has property f  f  x   1  x the value of f    f   is ___

08. Let A1, 2,3,4. A relation is R on A is defined by R   x, y  / x  y , x 2  y 2  9 x, y  A,

number of elements in R is____

10. Consider real value function satisfying 2 f  sin x   f  cos x   x they

A) Domain of f  x   R B) Domain of f  x    1,1

11. If a relation R is defined on Z as R   a, b  / 2 a 2  3b 2  35, a, b  zthen

A) Domain  1, 2 B) domain  2, 4

C) Range  0, 1, 2, 4, 9 D) Range  1, 3

A) f is one –one B) f is on to C) f is bijective D) f 1  2   a  2b

A) Domain  f  g  2    1,   B) Domain  f  g  2    0,  

C) Range f  range  g  2    2,3 D) Range f  Range  g  2   1,  

Let f :  1,1  B bc a function defined by f  x   Tan 1 

17. If f  x   x 3  x and g  x   sin 2 x then

18. Let A and B are non-empty set if f : A  B be a function defined as f  A   f  x  / . x  A ,

nearest integer]_______ 105

of water present in the container? (in kg nearest integer)

energy of the gas is___ 103 J

of the vessel  V  and of the solid  L  are related as

probable speed of the molecule in an ideal monoatomic gas at absolute temperature T.

B) No molecule can have sped less than VP / 2

D) The average kinetic energy of a molecules is 3/4 mvP2

to nearest integer)  h  6.63  1034 J  s, c  3.00  108 ms 1 , N A  6.02  mol 1 

42. Total number of possible stereoisomers of dimethyl cyclopentane is……. (neglecting

correct (The Bhor radius is represented by a0 )

A) The electron can be found at a distance 2a0 from the nucleus.

among (a) to (d) are:

52. Arrange the following carbocations in decreasing order of stability

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