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SEC: SR_*CO-SC(MODEL-A) Date: 23-07-2023

Time: 3 Hrs WAT-48 Max. Marks: 183

23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_ TEST SYLLABUS


MATHS:
PRESENTWEEK (80%):
Binomial theorem: Binomial theorem for a positive integral index, Constant term,
Numerically greatest term, Properties of the Binomial coefficients, Multinomial Theorem
PREVIOUS WEEK (20%):
Differential equations:
Formation of ordinary differential equations, solving differential equation ( Variable &
separable, Homogeneous, linear differential equation of first order ),
Differential equations which are reducible to linear form of first order
PHYSICS: OPTICS-III 80%: Refraction at curved surface ,Lenses and combination of
lenses,
MAINS EXPERIMENTS: The focal length of Convex lens, using the parallax method.
ADVANCED EXPERIMENTS: focal length of a concave mirror and a convex lens using u-
v method
OPTICS-II 20% : Refraction at plane surface, TIR and Prism, dispersion and deviation in
thin prism, MAINS EXPERIMENTS: The plot of the angle of deviation vs angle of
incidence for a triangular prism. Refractive index of a glass slab using a travelling
microscope.
CHEMISTRY:
PRESENTWEEK (80%): bonding in metal carbonyls, structures of mononuclear &
dinuclear metal carbonyles (NCERT), CFT (octahedral and tetrahedral fields)],
spectrochemical series, Stability, importance and applications of complexes, isomerism in
complexes
PREVIOUS WEEK (20%):
CO-Ordination Compounds: Introduction, Definition of important terms related to co-
ordination compound, types of ligands, IUPAC rules, Nomenclature, Werner theroy
and Sidgwick theory, VBT - hybridization and geometries (linear, tetrahedral, square
planar and octahedral)
Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P

2017-P2 MODEL
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 183

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 25) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 26 – 32) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 33 – 36) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 43) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 44 – 50) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 51 – 54) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61

Please mark/bubble/bolden your answer against the corresponding question


No.(ignore the subjects mentioned on OMR sheet, if found any difference).

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MATHEMATICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. The sum of the coefficients of those terms in the expansion of  x1  x2  x3  x4 8 which
contain x3 but not x4 is ____
A) 48 B) 28 C) 38 D) 38  28
n  1   1 1 
2. If   nC    , then the value of
    nCi  nC j  is equal to
r 0 r 0i jn

2 n n 2
A) n  B) C) n D)
2 2
n n
ar  100
3. If 1  xn   ar xr and S r  1  and  Sr  101 , then the value of ‘n’ is equal to
r 0 ar1 r 1 100
A) 99 B) 100 C) 101 D) 102
th
4. If 1 ,  2 , 3 ,...... n are the n roots of unity, then C1.1  C2 . 2  .......  n Cn . n is equal to
n n

 2i(k 1)  
 
(where  k  e  n 
)
1 1
A)
2
B)
2
 2n
 1   2   1 
 

C) 1 1   2 n  1
2
 
D) 2 1   2 2n  1
1

2020
(1)K 1 2020
5. 
K 1 K
CK 

1 1 1 1 1 1 1
A) 1    .....   B) 1    ..... 
2 3 2019 2020 2 3 2020
1 1 1 1 1 1
C) 1    .....  D) 1    ..... 
2 3 2019 2 3 2019
6. A differentiable function f : R  R satisfying the differential equation
 x f 2 t  
 
f  x   1  x 1   2
2 
dt  then f  2   ______

 0 1 t 
17 17 15
A) 0 B) C)  D)
15 15 17

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P

xdx  ydy y3
7. 
xdx  ydy x3

The solution of this differential equation is


3 3 3
3 y x 2  y2  y 2
A) log    log 3
 tan 1    c  0
2 x x
x2

3 3 3
2 y x 2  y2 1  y 
B) log    log
2
3
 tan   c 0
3 x 2 x
x

 32 
2 y x  y 1  y
C)    log  
  tan  3
c0

3 x  x   x2 
 

 32 
1 3 3 1  y c  0
D) log x  y  tan  3 
2  x2 
 
SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.

n
8. If  7+2 11  =I+f , where n, I  N  n  2017  , 0  f  1 ,then which of the following is / are

correct?
A) I is even integer B) I is odd integer
C) (I + f )f = 5n D) (I + f )(1 – f ) = 5n
10
9. If 1+2x+3x 2  =a 0 +a1x+a 2 x 2 +..............a 20 x 20 , then

A) a1 =20 B) a 2 =210 C) a19 =20.39 D) a 20 =22 .37 .7


25
10. The largest coefficient in the expansion of  4+3x  is
14 11
4 3
A) 25 C11 325   B) 25 C11 425   C) 25 C14 414 311 D) 25
C14 411 314
 3 4

11. Sum of the products of the binomial coefficients of (1 + x)n taken two at a time is
1 2n 1 1 n
A) 2n - 2n
Cn B) 22n-1 -
2
 C n  C)  2n -
2
2n
Cn  D)
2
4 - 2n
Cn 

12. For r = 0, 1, ………, 10 let A r , Br and Cr denote, respectively, the coefficient of x r in


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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
10
10 20 30
the expansion of 1+x  , 1+x  and 1+x  , then  A B
r=1
r 10 Br -C10 A r  is equal to

A) C10 - B10 B) 0 C) A10  B102 - C10 A10  D) B10 - C10

13. The value of 12 C 2 +13C3 +14C 4 +.........+999C989 is


1000 1000 999 1000
A) C11 - 12 B) C11 + 12 C) C11 - 12 D) C989
n
14. If 1+x  = a 0 +a1x+a 2 x 2 +.......+a n x n in which a n-3 , a n-2 , a n-1 are in A.P, then

A) a1 ,a 2 ,a 3 are in G.P B) a1 ,a 2 ,a 3 are in H.P C) n = 7 D) n = 14

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.

Paragraph For Questions 15 and 16:


A rabbit moving in xy-plane starts at origin and runs up y-axis with uniform speed “a”
m/s . At the same time a dog, running with speed “b” m/s , starts at the point (1,0) and
approaches the rabbit. Assuming the path of dog is a curve y= f(x) in xy plane (you may
use the formula; differential arc length of a curve ds  (dx)2  (dy ) 2 . Answer the
following
dy
15. At any moment of time t, measured from the instant both started =
dx
y  at x
a) y  at b) c) ( y  at ) x d)
x y  at

16. Differential equation governing the path of the dog is


2 2
dy dy
a) bxy "  a 1    b) xy '  ab 1   
 dx   dx 

c) xy "  ab 1  y 2 d) xy "  ab 1  x 2
Paragraph For Questions 17 and 18:
50 50  r
Cr  2r  1 50
2
100
r 2
Let P =  50
Cr  50  r 
, Q    50
Cr  and R =   1  100
Cr 
r 1 r 0 r0

17. The value of P – Q is equal to

A) 1 B) - 1 C) 250 D) 2100
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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
18. The value of P – R is equal to

A) 1 B) - 1 C) 250 D) 2100

PHYSICS Max. Marks: 61


SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
19. A spherical aquarium, filled with water, is placed in front of a flat vertical mirror. The
radius of the aquarium is R, and the distance between its center and the mirror is 3R.
A small fish, which is initially at the point nearest to the mirror, starts to move with
velocity v along the wall. An observer looks at the fish from a very large distance along
a horizontal line passing through the center of the aquarium. What is the relative
velocity vrel at which the two images of the fish seen by the observer will move apart?
Express your answer in terms of v. Assume that: The wall of the aquarium is made of a
4
very thin glass. The index of refraction of water is n  .
3
8 4 8 2
A) v B) v C) v D) v
5 3 3 3

20. A prism of angle A and refractive index 2 is surrounded by medium of refractive


index 3 . A ray is incident on side PQ at an angle of incidence i  0  i  900  as shown

. The refracted ray is then incident on side PR of prism. The minimum angle A of prism
for which ray incident on side PQ does not emerge out of prism from side PR ( for any
value of i ) is

A) 300 B) 450 C) 600 D) 1200


21. In the realm of optical phenomena, let us contemplate the phenomenon of swiftness
exhibited by the radiant beams traversing through a medium known as the glass lens,

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
wherein its velocity manifests as 2 × 108 meters per second. Engage your intellectual
faculties to partake in the analysis of a plano-convex lens, endowed with an aperture
diameter measuring 10 centimeters, while its thickness at the central region gracefully
stretches to 2 millimeters. From the array of alternatives laid before you, kindly select
the ONE BEST option that aligns harmoniously with the discerned truth.
A) Imbibe the notion that the refractive index of this lens obtains a value of 1.5.
B) Ponder upon the proposition that the radius of curvature adorning the convex
surface of this lens approximates a magnitude of 62.5 centimeters.
C) Reflect upon the hypothesis that the focal length encompassed by this lens
gracefully approaches the vicinity of 125 centimeters.
D) Adhere to the belief that all the aforementioned options converge to the path of
correctness, permeating this inquiry with the virtue of truthfulness.
22. A thin lens of focal length f and its aperture has a diameter d . It forms an image of
intensity I .Now the central part of the aperture up to diameter (d/2) is blocked by an
opaque paper . The focal length and image intensity would change to
(assuming the paraxial ray approximation)
f I I 3f I 3I
A) , B) f , c) , D) f,
2 2 4 4 2 4
23. A vertical pencil of rays comes from bottom of a tank filled with a liquid. When it is
accelerated horizontally with an acceleration of 7.5 m/s2, the ray is seen to be totally
reflected by liquid surface. What is minimum possible refractive index of liquid ?
4 5
A) slightly greater than B) slightly greater than
3 3
C) slightly greater than 1.5 D) slightly greater than 1.75
24. A vessel of depth H is filled with non-homogeneous liquid whose refractive index
y
varies with depth y as   1  . What is the apparent depth as seen by an observer
H
from above ?
H H
A) H B) H In2 C) D)
2 In2

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P

25. Imagine a scenario where two plane mirrors are placed perpendicular to each other.
These mirrors are not stationary; they are actually moving with constant velocities in
their respective directions. Meanwhile, there exists an object, denoted as O, which
remains still amidst this dynamic environment. Our task is to determine the speed at
which the image, labeled as I, moves after undergoing two reflections—one from each
mirror. To find the answer, we need to understand the principles of reflection and
motion. By examining the interplay between light and the moving mirrors, calculate the
speed at which the image I travels through space.

A) 7 m/s B) 2m/s C) 5 m/s D) zero

SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
26. A luminous point object is placed at O, whose image is formed at I as shown in figure.
Line AB is optical axis. Which of the following statement is/are correct ?

A) If a lens is used to obtain the image , then it must be a converging lens and its
optical centre will be the intersection point of line AB and OI .
B) If a lens is used to obtain the image , then it must be a diverging lens and its optical
centre will be the intersection point of line AB and OI .
C) If a mirror is used to obtain the image then the mirror must be concave and object
and image subtend equal angles at the pole of the mirror
D) I is a real image .

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
27. The angle of deviation (  ) vs angle of incidence (i) is plotted for a prism . Pick up the
correct statements.

A) The angle of prism is 600


B) The refractive index of prism is n  3
C) For deviation to be 650 the angle of incidence i1  550
D) The curve of '  ' vas 'i' is parabolic
28. In the realm of optical phenomena, we find ourselves immersed in a scenario involving
an object positioned upon the principal axis of a concave lens, with a focal length of
1.0 meter. Precisely situated at a distance of 3 meters from the lens, the object
commences its motion at time t = 0. With velocity components unveiled, wherein the
object ventures forth with a speed of 1 meter per second along the principal axis,
drawing nearer to the lens(this direction being chosen as positive x-axis), and
concurrently moves with a transverse velocity of 1 meter per second perpendicular to
the principal axis(this direction being chosen as positive y-axis). Our pursuit is to
discern the nature of the image's motion, which, in this optical tapestry, meanders
parallel to a line delineated by the equation ax + by = c, where a, b, and c stand as
relatively prime integers, while x and y denote spatial coordinates in meters. Traverse
the expanse of possibilities and identify the option(s) that align harmoniously with the
veracity of this situation.
A) Contemplate the possibility that the axial component of the image's velocity at time
t = 0 materializes as 1/16 meter per second.
B) Reflect upon the proposition that the transverse component of the image's velocity
at time t = 0 reveals itself to be 1/4 meter per second.

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
C) Engage in the notion that the value of parameter "a" within the aforementioned
equation finds itself equal to 4 for scenario when "b" is positive.
D) Ponder upon the hypothesis that the numerical value ascribed to parameter "c" must
stand at 3.
29. In the figure is depicted the path of a ray of light BC after refraction in a double convex
lens L of principal focus F and of principal axis OO’. Identify the only correct figure
for the incident ray under paraxial approximation.

A) B)

C) D)
30. A convex lens forms an image of an object on a screen. The height of the image is 9cm.
The lens is now displaced until an image is again obtained on the screen . The height of
this image is 4 cm. The distance between the object and the screen is 90 cm.
A) The distance between the two positions of the lens is 30 cm
B) The distance of the object from the lens in the first position is 36 cm
C) The height of the object is 6 cm
D) The focal length of the lens is 21.6 cm

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
31. In the given figure 'O' is a point object kept on the principal axis of a glass equiconvex
lens of radius of curvature 10 cm. An isosceles glass prism of angle 1.8° lies in
between the object and the lens. Light falling on the prism (at a small angle of
incidence) get refracted through prism and then fall on the lens. Refractive index of
glass is 3/2. Select the correct options (s).


A) The distance between the two images formed by the prism is cm
10

B) The distance between the two images formed by the lens is cm
20
C) The distance between the plane of images (drawn  to axis of the lens) formed by
the prism and the plane (drawn  to axis of the lens)of images formed by the lens is
45 cm

D) the deviation produced by the prism is rad
200
32 A plano convex lens of refractive index 1.5 is silvered on plane surface and it behaves
like a concave mirror of focal length 30cm, then select the correct option (s).
A) the radius of curvature of the curved surface is 30 cm
B) If the curved surface is silvered the focal length would become 10cm
C) The lens can behave like a converging lens even when the medium around it
changes.
D) all of the above are correct.

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 33 and 34:
A equiconvex lens of focal length 10cm is shown in the figure. A circular disc of
diameter 1cm is placed on the principle axis of the lens with its plane perpendicular to
the principal axis at a distance 15 cm from the optical centre of lens . The radius of disc
starts increasing according to the law r   0.5  0.1t  cm / sec where t is time in second

33. The image formed by the lens will be in the shape of a


A) Circular disc
B) Elliptical disc with major axis horizontal
C) Elliptical disc with major axis vertical
D) Distorted disc
34. In the above question, the area of image of the disc at t = 1 second is
A) 1.2 cm 2 B) 1.44cm 2 C) 1.52cm 2 D) None of this
Paragraph for Questions 35 and 36:
All objects referred to the subsequent problems lie on the principal axis

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
35. If light is incident on surface 1 from left , the image formed after the first refraction is
definitely
A) Real for a real object B) Real for a virtual object
C) Virtual for a real object D) Virtual for a virtual object
36. If light is incident on surface 2 from right then which of the following is true for image
formed after a single refraction
A) Virtual object will result in a Real image
B) Real object will result in a real image
C) Virtual object will result in a virtual image
D) Real object will result in a virtual image

CHEMISTRY Max.Marks:61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.

37. The correct order of molar conductance of following formula of complexes


CoCl3 . 4 NH 3 CoCl3 . 3NH 3 CoCl3 . 6 NH 3 CoCl3 . 5 NH 3
(i ) (ii) (iii ) (iv)

A) iii > iv > ii > i B) ii > iv > iii > i


C) i > iv > iii > ii D) iii > iv > i > ii
38. Number of bridged ligands in Co2 (CO )8 are ‘X’
Number of Mn-Mn metal bonds in Mn2 (CO )10 are ‘Y’
3
Number of unpaired electrons in Cr  H 2O 6  are ‘Z’, value of (X+Z-Y) is

A) 5 B) 4 C) 3 D) 6
39. Among the following complexes the one which shows zero crystal field stabilisation
energy is
3 2 3 3
A) Co( H 2O )6  B) Co( H 2O )6  C)  Mn( H 2O )6  D)  Fe( H 2O )6 

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
40. Which one of the following complex and name are incorrectly matched?
A) Cr ( NH 3 )3 ( H 2O)3  Cl3 : triamminetriaquachromium(III) chloride

B) Co  H 2 NCH 2CH 2 NH 2 3  2  SO4 3 : tris(ethane-1,2–diamine)cobalt(III) sulphate

C)  Ag  NH 3 2   Ag (CN ) 2  : diamminesilver(I) dicyanidoargentate(I)

D) Co  NH 3 4  H 2O  Cl  Cl2 : Tetraamminechlorideaquacobalt(III) chloride

41. The geometries of the ammonia complexes of Ni 2 , Pt 2 and Zn 2 , respectively, are


A) octahedral, square planar and tetrahedral B) tetrahedral,
octahedral and square planar
C) tetrahedral, square planar and octahedral D) octahedral,
tetrahedral and square planar
42. Which of the following complex can exhibit optical isomerism
3 3
A) Co  NH 3 6  B)  Pt  NH 3 2 Cl2  C)  Pd ( gly) 2  D) Co(en)3 

43. Which of the following is correct ?


A) correct order of field strength of ligands :
CO  CN   NH 3  NCS   C2 O42  F   SCN   S 2  I 

B) hexacyano ferrate(ll) ion has less crystal field stabilization energy than pairing
energy
C) The hexaquo manganese(II) ion contains five unpaired electrons, while the
Hexacyanoion contains only one unpaired electron
2
D) In  Fe  H 2O 6  iron has t2 g 2eg 4 configuration

SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
44. Which of the following is/are inner orbital complex(es)?
2 3 3 3
A)  Ni  NH 3 6  B) Cr  NH 3 6  C)  Fe  CN 6  D) Co  NH 3 6 

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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
45 Which of the following is/are correct.
A) Hardness of water is estimated by simple titration with Na2 EDTA .
B) In black and white photography,the developed film is fixed by washing with hypo
2
solution which dissolves the undecomposed AgBr to form a complex ion  Ag  S2O3 2 

C) EDTA is used in the treatment of lead poisoning.


D) chlorophyll is a coordination compound of magnesium.
46. Which of the following is/are correct.
3
A) Ti  H 2O 6  has violet in colour.
2
B) Yellow light is observed by the complex CoCl  NH 3 5  it appears red

C) correct order of observed wavelength of light is


3 3 3 2
Co  CN  6   Co  NH 3 6   Co  NH 3 5 H 2O   CoCl  NH 3 5 

3 3
D)  Fe  H 2O 6  is a strongly paramagnetic where as  Fe  CN 6  is a weakly

Paramagnetic
47. In an experiment, grams of a compound X (liquid/solid) taken in a container is
loaded in a balance as shown in figure I below. In the presence of a magnetic field, the
pan with X is either deflected upwards (figure II), or deflected downwards (figure III),
depending on the compound X. Identify the correct statement(s).

A) If X is Co  NH 3 6  Cl3 , deflection of the pan is upwards.


B) If X is K3  Fe(CN )6  , deflection of the pan is downwards.
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Narayana IIT Academy 23-07-2023_SR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-48_Q’P
C) If X is Cr  H 2O 6  Cl3 , deflection of the pan is upwards.
D) If X is  Pt  NH 3 2 Cl2  , deflection of the pan is upwards.

48. Choose the correct statement(s) among the following:


2
A)  Ni  CN 4  has square planar geometry.

B)  Pt  NH 3 2 Cl2  has 2 geometrical isomers.


3
C) Fe in  Fe  CN 6  has t2 g 5eg 0 electronic configuration.

D) The bond order of CO in V (CO )6  is more than bond order of CO in Cr (CO)6 

49. The correct option(s) regarding the complex Co( gly ) 2 ( NH 3 )2  ( gly  NH 2CH 2COO  ) is

(are)
A) It has five geometrical isomers
B) It will have three geometrical isomers if one bidentate ‘gly’ is replaced by one
chloride ion and one NH 3 ligands
C) It will have two geometrical isomers if two bidentate ‘gly’ are replaced by two
chloride ions and two NH 3 ligands

D) It absorbs light at longer wavelength as compared to Co ( gly )2  H O 2 

50. Choose the correct statement(s) among the following:


A) Ni 2 ion does not form inner orbital octahedral complexes.
2
B) The complex  Mn Cl2 Br2  has two geometrical isomers.
3 3 3 3
C) Co(en)3   Co(en)2 ( NH 3 ) 2   Co(en) ( NH 3 ) 4   Co( NH 3 )6 

(Stability order of complexes)


2  
D)  Fe  CO 6    Mn  CO 6   Cr  CO 6   V  CO 6  (CO stretching frequency order)

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SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 51 and 52
Complex compounds can exhibit isomerism like structural and stereo. The complexes
containing coordination number 1, 2, 3 cannot exhibit geometrical and optical
isomerism. Geometrical and optical isomerism are common in the complexes having
coordination number 4 and 6.
51. Number of geometrical isomers possible for the following complex are  Pt ( gly)2 FCl 

A) 8 B) 9 C) 6 D) 5
52. Which of the following complex is not a coordination isomer of Co( NH 3 )6  CrCl6 

A) Co( NH 3 ) 4 Cl2  Cr ( NH 3 ) 2 Cl4  B) Co( NH 3 ) 2 Cl4  Cr ( NH 3 ) 4 Cl2 

C) Co( NH 3 )3 Cl3  Cr ( NH 3 )3 Cl3  D) Co( NH 3 )5 Cl  Cr ( NH 3 )Cl5 

Paragraph For Questions 53 and 54


A complex compound(X) of cobalt contains four NH 3 molecules, one nitro group and
two chloride ions for one Co atom. One mole of this compound produces two mole
ions in aq. solution. One mole reacting with excess of AgNO3 solution, one mole of
AgCl get precipitated.
53. The formula of the complex compound (X) is
A) Co( NH 3 )4 ( NO2 ) Cl   NH 3  Cl B) Co  NH 3 5 Cl  Cl  NO2 

C) Co  NH 3 4 NO3 Cl  Cl D) Co  NH 3 4 NO2 Cl  Cl

54. The structural isomer of the ‘X’ is


A) Co  NH 3 4 (ONO) Cl   NH 3  Cl B) Co  NH 3 5 Cl  Cl  NO3 

C) Co  NH 3 4 (ONO2 ) Cl  Cl D) Co  NH 3 4 ONO Cl  Cl

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