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Yashpatil TG~ @bohring_bot

Sec: SR.IIT_*CO-SC Date: 17-03-24


Time: 3HRS Max. Marks: 186

Name of the Student: ___________________ H.T. NO:

17-03-24_SR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-1(P2)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
Time: 3 Hrs
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
IMPORTANT INSTRUCTIONS Max Marks: 186
MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 1 – 6) 3 -1 6 18
Choice
Questions with Multiple Correct
Sec – II(Q.N : 7 – 14) 4 -2 8 32
Choice (Partial Marking +1)
Questions with Comprehension
Sec – III(Q.N : 15 – 18) Type 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 19 – 24) 3 -1 6 18
Choice
Questions with Multiple Correct
Sec – II(Q.N : 25 – 32) 4 -2 8 32
Choice (Partial Marking +1)
Questions with Comprehension
Sec – III(Q.N : 33 – 36) Type 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 37 – 42) 3 -1 6 18
Choice
Questions with Multiple Correct
Sec – II(Q.N : 43 – 50) 4 -2 8 32
Choice (Partial Marking +1)
Questions with Comprehension
Sec – III(Q.N : 51 – 54) Type 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62

SR.IIT_*CO-SC Page. No. 2


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
MATHEMATICS
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Max. Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
2 1
n k 
2 an 2
1. If  then
k 1 4
1 bn 2  cn  1
k 
4
A) a  b  c  6 B) a  2b  3c  6 C) 3a  2b  c  6 D) a 2  b2  c 2  6
2 3
 3x 2
3
 3x  5 
2. If I   x dx and J   ln  x  2 dx , then e
I J
equals ………..
ln  x  1
1 2

A) 2 B) 3 C) 4 D) 5
3. Position vector of a point A is  aiˆ  bjˆ  ckˆ  and a2  b2  c 2  4; and position vector of

another point B is piˆ  qjˆ  rkˆ  and p 2


 q2  r 2  9 . Given AOB  2 cos1 1 , where O is origin.
5

If AQ is perpendicular to angle bisector of AOB i.e. line OQD where D lies on AB, then
value of QD =?
1 2 3 4
A) B) C) D)
25 25 25 25

4. An ellipse with axes parallel to OX and OY, cuts the parabola y2 = 4x at (1, -2) and
touches it at (4, 4), the coordinates of the other points of intersection is
A) (9, -6) B) (9, 6) C) (4, -4) D) (1, -2)
5. One of the asymptote (negative slope) of a hyperbola passes through (2,0) whose
transverse axis is given by x  3 y  2  0 . Find equation of hyperbola if it is given that
y  7 x  11 can intersect hyperbola at (2,3) only.

A) 7 x 2  6 xy  y 2  8 x  4 y  3  0 B) 7 x 2  6 xy  y 2  20 x  8 y  3  0
C) 7 x 2  6 xy  y 2  20 x  4 y  3  0 D) 7 x 2  8 xy  y 2  20 x  4 y  3  0
6. Find the minimum distance of the point (1, 1, 1) from the plane x + y + z = 1, measured
x a y b zc
perpendicular to the lines  
1 2 3

7 7 14 28
A) B) C) D)
3 3 3 3

SR.IIT_*CO-SC Page. No. 3


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
SECTION-II
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P

(Multiple Correct Answer Type)


This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
7. Let P be any point on the director circle of an ellipse E, with centre at O. Tangents are
drawn from point P to the ellipse to touch it at A and B. The semi major axis of the
ellipse is 4 and the product of the lengths of perpendiculars drawn from P and O to the
line AB is 5.

16 6
A) The radius of director circle is B) The eccentricity of the ellipse is
1 11

40 10
C) The latus rectum of the ellipse is D) The latus rectum of the ellipse is
11 11

8. Which of the following is/are true:

π π
(i) If O < A < then A sec A <
6 3 3

π π
(ii) if O < A, B < , then A cosec A+B cosec B <
4 2

π π
(iii) If O < A, B, C < , then A cot A + B cot B + C cot C <
3 3

A) (i) B) (ii) C) (i) and (ii) D) (i) and (iii)

9. The isogonal trajectories of the family of circles x 2  y 2  a2 which intersect at 450.

y y
A) tan -1 + log x 2 + y 2 = C B) tan -1 - log x 2 + y 2 = C
x x

x x
C) tan -1 - log x 2 + y2 = C D) tan -1 + log x 2 + y2 = C
y y

10. Let a(n) = nn – nC1 (n – 1)n + nC2. (n–2)n – …………………+ (–1)n–1. nCn–1 . 1n ; n  N :

A) a (2023) = 2023 ! B) a (2023) < 2023 !

C) a (2023) < 2024! D) a(2023) = 2024!

SR.IIT_*CO-SC Page. No. 4


Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
11. Let f(x + y) = f(x) + f(y) + 2xy – 1  x, y  R, f(0) = 1, f’(0) = 1 and g : R  R such
that g (x – g (y)) = g (g (y)) + x.g(y) + g(x) – 1  x, y  R.

A) Number of real solution of equation f(x) = g(x) is 2

B) Range of function h : R  R, h(x) = f(x) + g(x) is  3 ,  


2 

1 1
C) If  is a root of equation f(x) = 0 then 2
  1    2 is equal to 1
 

1 1
D) If  is a root of equation g(x) = 0 then   1  2   4 is equal to 31/4
4 2

12. If 4 sin x  cosec x  K has m distinct roots for 0 x, then

A) If K > 5, then m = 2 B) If K = 5, then m = 3

C) If 4 < K < 5, then m = 4 D) If K = 4, then m = 2

13. Let f(x) be a differentiable function which satisfy the relation f (x + y) = exf (y) + eyf (x),
x y z
x, y R and f(0) = 2. If the straight line   intersect the plane
f(0) f(1)  1
f 
 2

 1
f(0) f(1) f 
2
x+y+ e z  3e at (x1, y1, z1) and the value of determinant x1 y1 z1  , then ‘  ’ is
f  x1  f  y1  f  z1 

A) zero B) a positive rational number

C) a negative rational number D) an irrational number

14. If the probability that two queens, placed at random on a chess board, do not take on
k
each other be then k is
k  13

A) a prime number

B) not a prime number

C) a twin prime number

D) not a twin prime number

SR.IIT_*CO-SC Page. No. 5


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
SECTION-III
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P

(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 15 and 16:
Given that the equation

f(x) = x 3  3x  1 and g(x) = 3x 2 ,then

15. The number of distinct real roots of f  f  x  0 is

A) 9 B) 7 C) 5 D) 6

16. If the equation f(x) = g(x) has its roots , ,  , then equation whose roots is   ,   ,   

is

A) f  x  3   g  x  3  B) f  3  x   g  x  3 

C) f  x  3   g  x  3  D) f  x  3   g  x  3 

Paragraph for Questions 17 and 18:

Let the line 3x + 4y =12 intersects xaxis and y-axis at points A and B respectively.
Circles are drawn touching the lines OA, OB and circum circle of triangle OAB (where
O is origin) further let ‘R’ be set of radii of such circles, N = sum of elements in R.

17. Tangents are drawn from a point ‘P’ lying on the circle (x  1)2  (y  3)2  r 2

N
(where r  2 ), touching the circle x2 + y2 – 2x – 6y – 88 = 0 at A, B, then locus of
2

orthocenter of PAB is

A) x 2  y 2  2x  6y  186  0 B) x 2  y 2  2x  6y  98  0

C) x 2  y 2  2x  6y  176  0 D) none of these

18. Locus of the centre of circle which cuts the circumcircle of OAB orthogonally and
radius equal to ‘N – 10’ is

A) x2+y24x3y-196 = 0 B) x2 + y2 + 4x + 3y196 = 0

C) x2+y24x 3y14 = 0 D) none of these

SR.IIT_*CO-SC Page. No. 6


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
PHYSICS
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Max. Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
19. Find the minimum value of F so that all blocks move together with the same acceleration
string
m

2m 4m

6m F

 0
 0

91 mg 52 mg
A) B) 7 mg C) D) 6 mg
7 7

20. Consider the shown network, the capacitor C1   6 F  has an initial charge
30e
q0  C , C2  4 F and R  80 Initially C2 is uncharged. At t = 0, the switch S is
e 1
closed. Then the charge on C2 at t = 192 μs is

S R

C1

C2

A) 12 C B) 6 C C) 3 C D) 1.5 C

21. Three metal rods of the same length and area of cross–section form an equilateral
triangle as shown in figure. D is the mid–point of side BC. If AD is independent for
small change in temperature, then (1 is the coefficient of linear expansion for rod BC
and 2 for rods AB and AC)
A

B C
D

2
A) 1  2  2 B) 1  C)  2  1 D) 1  4  2
2
SR.IIT_*CO-SC Page. No. 7
Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
22. There are n number of radioactive nuclei in a sample at a time t. If n ' number of 
particles are emitted in the next two seconds from the sample, then the half life of the
sample is (thalf life >>2 sec):

n' 2n 2n  n
A) B) 0.693    C) 0.693  ln   D) 0.693   
2  n'   n'   n'

23. Three coherent sonic sources emitting sound of single wavelength ‘  ’ are placed on the
x-axis at points   11 / 6, 0  ,  0, 0  ,   11 / 6, 0  . The intensity reaching a point  0, 5 / 6 

from each source has the same value I 0 . Then the resultant intensity at this point due to
the interference of the three waves will be :

A) 9I 0 B) 7I 0 C) 4I 0 D) 5I 0

24. Two instruments A and B are used to measure diameter of a rod. A large number of
readings are taken by both the instruments. Frequency of measurement f(d) is defined as
the number of times diameter of the rod measured as ‘d’ Consider the following graphs
for f(d) vs d for both the instruments.

f d  A

dA dB d

A) A is more accurate than B

B) B is more accurate than A

C) A is more precise than B

D) B is more precise than A

SR.IIT_*CO-SC Page. No. 8


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
SECTION-II
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P

(Multiple Correct Answer Type)


This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
25. In a decay process A decays to B , A  B .

Where B is stable. Initially no. of nuclei of A is N 0 and that of B is zero. Two graphs of
number of nuclei of A and B versus time is given then

NA NB

NO NO
9 NO
10
NO/5
NO/8
O t(sec) O t2 t(sec)
t1 6

A) t2  t1  4sec B) t2  t1  2sec C) t1  2 log 2 5sec D) t 2  log 2 100sec

26. A rat of mass m falls from a height h onto the end of a platform, as shown in the figure.
The spring is initially unstretched and the mass of the platform can be neglected.
Assuming that there is no loss of energy the maximum elongation of the spring is (The
plat form can rotate about the hinge shown)(x>>h)

mg  m 2 g 2  2mghk mg  m 2 g 2  2mghk
A) B)
k 2k

k m 2 g 2  2mghk
C) D)
m2 g 2  2mghk k

SR.IIT_*CO-SC Page. No. 9


Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
27. Two equal uniform rods P and Q each of length  move with the same velocity v as
shown in the figure. The second rod has an angular velocity  ( 6v / l and clockwise)
about its centre of gravity G1 in addition to v.

A) If the ends A and A ' are suddenly fixed simultaneously, both the rods will start to
rotate with the same angular velocity.
B) If the ends A and A ' are suddenly fixed simultaneously, the rod Q will start to rotate
with greater angular velocity.
C) If the ends B and B ' are suddenly fixed simultaneously, both rods will start to rotate
with the same angular velocity.
D) If the ends B and B ' are suddenly fixed simultaneously, the rod P will start to rotate
with greater angular velocity.
28. Consider on imaginary sphere of radius R as shown with centre at O. Mark the correct
option(s)

O P Q

A) If a point charge q is placed at point Q  OQ  r  R  then average electric field on the


1 q
surface of the sphere is in magnitude
4 0 r 2
B) If a point charge q is placed at point P  OP  r  R  then average electric field over the
surface of the sphere is zero
C) If a point charge q is placed at point P  OP  r  R  then average electric field over the
1 qr
entire volume of the sphere is
4 0 R 3
D) If a point charge Q is placed at point P  OP  r  R  then the average electrostatic field
1 q
over the surface of the sphere is
4 0 r 2

SR.IIT_*CO-SC Page. No. 10


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
29.
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
A container having a hole at the bottom is free to move on a horizontal smooth surface.
As the liquid comes out, container moves in backward direction with an acceleration 
and finally acquired velocity v (when all liquid drains out) Neglect the mass of
container. Cross-sectional area of open surface of container is A and that of hole is a
(a<<A).

The correct options are


A

h
a
v

A)  is independent of height of liquid in vessel.

B)  depends only A and a and g.

C) v depends upon  and h

D) v independent of 

30. The magnetic field lines due to a semi infinite solenoid is shown in the figure. Mark the
CORRECT option(s)

SR.IIT_*CO-SC Page. No. 11


Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
A) In the semi-infinite solenoid shown Fig. (b), the filed line FGH, which passes through
the very end of the winding, is a straight line from G out to infinity.

B) The flux of B through the end face of the semi-infinite solenoid is just half the flux
through the coil at a large distance back in the interior,

C) Any filed line that is a distance r0 from the axis far back in the interior of the coil exits
from the end of the coil at a radius r1  2 r0 , (assuming that r0  (solenoid radius)/ 2 ))

r0
D) Any field line at a radial distance greater than inside the solenoid exit the
2

solenoid before reaching the open end of the solenoid through the side walls

31. In the displacement method, the distance between object and screen is 96 cm. The ratio
of length of two images formed by a convex lens placed between them is 4.84

A) ratio of length of object and length of shorter image is 11/5

B) distance between two positions of lens is 36 cm

C) focal length of lens is 22.5 cm

D) distance of the lens from the shorter image is 30 cm.

32. A small solid cylinder of mass M and radius R slides down a smooth fixed curve of
height ‘h’ from rest and gets onto the plank of mass M which is resting on a smooth
surface as shown in the figure. Take  as the coefficient of friction between plank and
the cylinder. The disc lands on the plank with speed V0 in pure translational motion. For
this situation mark out the correct statement(s).[plank is free to move]

SR.IIT_*CO-SC Page. No. 12


Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
A) The cylinder is performing impure rolling motion initially on the plank and finally
performs pure rolling motion

B) The direction of frictional force on the cylinder while rolling on plank is initially in
backward direction and finally it attains zero value.

C) The velocity of the centre of mass of the plank + cylinder systems, after the cylinder
starts pure rolling, is V0/2

D) The minimum length of the plank required for pure rolling of the cylinder over the
plank 3V0 2 / 16g . Where V0  2 gh

SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 33 and 34:
A plane pressure pulse, triangular in shape, approaches a rigid wall along normal at a
speed of 400m/s. At time t = 0, situation is shown in the figure. The peak pressure is
100Pa. The pulse gets reflected by the wall and pressure near the wall gets doubled.
Height of the wall is 2 m and width is also 2m. A detector on the wall records a
minimum excess pressure of 16 Pascal.

33. For how much time the detector will record the pulse?

A) 37.5  10 2 s B) 34.5  10 2 s C) 31.5  10 2 s D) 21 10 2 s

34. Total impulse imparted by the pulse on the wall will be

A) 300 Ns B) 150Ns C) 750 Ns D) 75Ns

SR.IIT_*CO-SC Page. No. 13


Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Paragraph for Questions 35 and 36:

Fifteen metal rods each of thermal resistance 50 C / W and their lateral surfaces are

thermally insulated are connected in the form. Regular hexagon as shown in figure

E D

F C

A B

If the corners A, B are maintained at the steady state 400 C , 150 C . Then

35. What is the steady temperature at the corner E?

A) 350 C B) 250 C C) 27.50 C D) 300 C

36. What is the rate of heat flow through rod ED?

A) 5W B) 10W C) 2.5W D) Zero

SR.IIT_*CO-SC Page. No. 14


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
CHEMISTRY
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Max. Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

37. The pKa values of –COOH, -SH and  NH3 groups present in the amino acid cysteine are
1.8, 8.2 and 10.8 respectively. The structure of cysteine at a pH=5 will be?

COOH
HS
NH2

-
COOH COO
HS HS
+ +
A) NH3 B) NH3

- -
COO - COO
-
S S
+
C) NH3 D) NH2

38. Column - 1 - gives a reactant, Column - 2 gives the reagent it is treated with, Column - 3
gives the significance of the reaction itself or one of the significant compounds which
can be derived from the product

Column 1 Column 2 Column 3

1. Aliphatic Aldehydes A. HCN P. Distinguishing Test

2. Ketones B. NaHSO3 Q. Pinacol formation

3. Aromatic Aldehydes C. 2.4 DNP R. White ppt

4. Carbonyl compounds D. 1) Mg / ether S. Amino Acid


2) H 2 O

Which of the following is a correct combination ?

A) 3AS B) 1BR C) 2BQ D) 4CS

SR.IIT_*CO-SC Page. No. 15


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
39.
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Three bulbs (I), (II) and (III) of volume V litres, 2V litres and 3V litres are connected by
tubes of negligible volume fitted by stopping valve (as shown in fig). The bulb I is at 1
atm containing 0.3 moles of H 2 gas at 1270 C . Bulb (III) contains O2 gas at 770 C and 2
atm. Bulb (II) is vacuum and maintained at 270 C

The valve (b) is opened first and then closed after some time. Then the valve (a) is
opened and closed after same time as for valve (b). The number of moles of O2 diffused
into bulb (II) is 0.1 mole

Based on above discussion, the pressure (in atm) observed in bulb (III) after diffusion is?

A) 0.5 B) 2.7 C) 0.3 D) 1.9

40. White phosphorus is a tetra atomic solid  P4  s  at room temperature and on strong

heating in absence of oxygen, it polymerizes into red phosphorus as

The enthalpy of sublimation  P4  s   P4  g   white is 59 KJ/mol and enthalpy of

atomization is 316.25 KJ/mol of P  g  . The average P – P bond enthalpy in P4 molecule


is?

A) 220 KJ B) 201 KJ C) 110 KJ D) 210 KJ

41. At 298 K, the limiting molar conductivity of a weak monobasic acid is 4 102 S cm2 mol 1 .
At 298 K, for an aqueous solution of the acid the degree of dissociation is  and the
molar conductivity is y 102 S cm2 mol 1 . At 298 K, upon 20 times dilution with water, the
molar conductivity of the solution becomes 3 y 102 S cm2 mol 1 the value of  is?

A) 0.11 B) 0.22 C) 0.33 D) 0.77


SR.IIT_*CO-SC Page. No. 16
Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
42. For a reaction A  P, the energy of activation is 15.8 Kcal at 298 K. Calculate the
number of activated molecules if we start with 1 mole of A, considering Arrhenius
equation to be valid (Given: e  26.51  3.067 1012 )

A) 1.031 1021 B) 1.847 1012 C) 5.85 1023 D) 3.067 1012

SECTION-II
(Multiple Correct Answer Type)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
43. Which one of the following reactions is/are correct?

44. Which of the following statements is/are correct?

A) When lead nitrate is heated to at 4000 C only brown coloured gas is released.

B) Complete Hydrolysis of PCl5 gives H 3 PO4 and HCl

C) N 2O5  g   2 NaOH  aq.  2 NaNO3  H 2O

D) CCl4 cannot be hydrolysed but hydrolysis of SiCl4 conform H 4 SiO4  HCl

45. Which of the following pairs of metals liberate NO gas with 20% dil HNO3?

A) Cu, Fe B) Sn, Zn C) Hg, Pb D) Ag, Au

SR.IIT_*CO-SC Page. No. 17


Yashpatil TG~ @bohring_bot
Narayana IIT Academy
46.
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P

A) The numner of p  d bonds in the structure of gas E is 1

B) The sum of oxidation numbers of 2 metals present in yellow ppt, G is 8

C) D is one of the strongest oxiding agents known

D) B is a gas which has oxidising properties

47.

A) V is less basic than aniline but it gives carbyl amine reaction

B) V is more basic than pyridine but doesn’t give Mustard oil reaction

C) S will not give coloured ppt with 2,4-DNP but gives Fehling’s test

D) S on reduction with H2/Ni gives a product which gives Lucas test

SR.IIT_*CO-SC Page. No. 18


48.
Yashpatil TG~ @bohring_bot
Narayana IIT Academy
Choose the correct options according to MOT
17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P

A) Bond order for C2 molecule is 2

B) molecular orbitals are polycentric

C) Bond length order B2 > F2

D) Bond energy order B2 > F2

49. Which of the following pair(s) of compounds is expected to exhibit same colour in
aqueous solution?

A) FeCl2, CuCl2 B) CoCl2, CuCl2 C) NiCl2, FeCl2 D) FeCl2, MnCl2

50. Identify the element(s) which give a product with highest oxidation number possible for
that element on reaction with hot and conc. NaOH?

A) S8 B) P4 (white) C) Cl2 (g) D) Si

SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 51 and 52:
On addition of 0.25 mole of a non-volatile solute HA (mono basic acid) in 5 moles of
benzene solute gets partially dimersied and the pressure of solution measured is 581.11
mm Hg.
 PBenzene
0
 600 mm Hg 
 0 
 PH 2O  23.76 mm Hg 

2HA   HA 2

51. Degree of association of solute   in solution is?


A) 0.9 B) 0.7 C) 0.6 D) 0.4
52. How many mL of 1.25M NaOH will be required for complete neutralization of the
aqueous acid?
A) 200 B) 70 C) 160 D) 400

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Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-1(P2)_Q’P
Paragraph for Questions 53 and 54:

A mixture of NaCl & NaBr weighing 4gm was dissolved and treated with excess of
AgNO3 to precipitate all of the chlorides & bromides as AgCl and AgBr. The washed ppt
was treated with KCN to dissolve the precipitates. The resulting solution was
electrolyzed, the weight of Ag deposited is 6.0 gm.

K  Ag  CN 2   KOH 
electrolysis
 Ag  KCN  O2  H 2O

(M.W. of NaCl , NaBr and Ag are 58.5,103,108 g/mol)

53. Wight percent of NaCl in the original mixture is?

A) 23.4 B) 56.6 C) 36.8 D) 68.4

54. The volume (at STP, in ltr) of O2 produced during electrolysis is?

A) 0.47 B) 0.16 C) 0.31 D) 0.78

SR.IIT_*CO-SC Page. No. 20

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