02-08-20 - Incoming - JR.IIT - STAR CO-SC - Jee-Adv - CAT-3 - 2017 - P-II - QP

Sec: Incoming.Jr.IIT_*CO.
SC Date: 02-07-20
Time: 3HRS Max. Marks: 240
02-08-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-3_SYLLABUS
PHYSICS: PRESENT WEEK (50%):Spring problems, problems related to
types of equilibria
PREVIOUS WEEK (25%):Work, Power, Energy : Work, Kinetic
energy,work - enegry theorem,conservative and non conservative
forces,potential energy,conservation of energy, EXCLUDE: Spring
problems, problems related to power, Problems related to types of
equilibria,Also exclude vertical circular motion
CUMULATIVE(25%): Horizontal Circular Motion
CHEMISTRY: PRESENT WEEK (50%):Geometrical Isomerism, E-Z nomenclature,
structural Isomerism
PREVIOUS WEEK (25%):Effect of temperature on enthalpy-
Kirchoff equation,Enthalpy of atomisation, Neutrlisation,
hydrogenation, bond enthalpy, resonance enthalpy
Thermodynamics-II: Limitations of first law of thermodynamics;
Second law of Thermodynamics; Carnot cycle, efficiency of
thermodynamic system, Entropy -physical significance ,
expressions in all types of processes, Gibb's free energy - physical
significance, spontneity of processes
CUMULATIVE(25%):
1. Chain and position isomers Functional and metamers
2. Polarity of molecules & dipole moment 3. Real gase3s
MATHEMATICS: PRESENT WEEK (50%):Equation of Straight Line: General form,
Slope Form, Intercept Form, Normal form, Two Point Form,
Parametric Form, Angle between two lines, Intersection of two lines,
Position of Two Points w.r.t a line, Length of perpendicular distance
of a point from a line, Distance between parallel lines, Reflection of
a point w.r.t a line
PREVIOUS WEEK (25%):2-D GEOMETRY : Introduction of Co-
ordinate Geometry, Distance Formula, Section formula, Finding
various Centres with given vertices of a triangle, Area of Triangle,
Collinearity of Points, Locus(Simple problems), Translation and
Rotation of axes
CUMULATIVE(25%): MATRICES & DETERMINANTS
Narayana IIT Academy 02-08-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-3_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 183
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61
CHEMISTRY
Sec – II (Q.N : 26 – 32) +4 -2 7 28
Sec – III (Q.N : 33 – 36) +3 0 4 12
Total 18 61
MATHEMATICS
Sec – II (Q.N : 44 – 50) +4 -2 7 28
Sec – III (Q.N : 51 – 54) +3 0 4 12
Total 18 61
PHYSICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. Two Particle A and B are moving with uniform velocities of 20m/sec and 10m/sec as
shown in the shown in the figure.The Magnitude of angular velocity of A with respect
to B.when their separation (AB) is 10 meter is.
A) 3  1 rad / s B) 3  1 rad / s C) 1 rad / s D) None of these

2 2
2. A Uniform chain of mass M and Length L lies on a horizontal table such that one third
of its length hangs from the edge of the table.The work done is pulling the hanging
part on the table will be
A) MgL B)MgL C) MgL D) MgL

3 9 18
3. A Particle is moving in a circle of radius R in such a way that at any instant the total
acceleration makes an angle of 4 5 0 with radius .Initial speed of particle is 0 .The time
taken to complete the first revolution is
R 2R 2R 2x R
A) B) C) e D) (1  e2x )
0 0 0 0
4. A smooth wire is bent into a vertical circle of radius a. A bead Pcan slide smoothly on
the wire.The circle is rotated about diameter AB as axis with a speed  as shown in
figure.The bead P is at rest with respect to the circular ring in the position shown. The
Value of 2 is equal to
2g g 3 2a
A) 2 g B) C) D)
a a 3 a g 3
5. Consider the following two statements A and B and identify the correct choice in the
given choices
(A) Centripetal force, centrifugal force are equal in magnitude and opposite in
direction but they are not force of action and force of reaction respectively because
both act on same body.
(B) Centrifugal force is a pseudo force in both inertial frame of reference andnon
inertial frame of reference
A) A is true and B is true B)A is true and B is false
C) A is false and B is true D) A is false and B is false
6. The average acceleration vector for a particle having a uniform circular motion in a
complete revolution (symbols have usual meaning)
2
A) a constant vector of magnitude
r
2
B) in magnitude and perpendicular to the plane of circle
r
C)equal to the instantaneous acceleration vector at the start of the motion
D)a null vector
7. The two blocks are placed over each other as shown in figure. There is friction
between two block but there is no friction between M and ground. A horizontal force
is F applied on lower block. So that both the block move together and friction between
A and B is static in nature.For this situation mark the incorrect statement.
A)The work done by friction force on A is positive as observed from ground frame
B)The work done by friction force on A is zero as observed from ground frame
C)The work done by friction force on A is zero as observed from a frame fixed to B
D)The work done by friction force on B is zero as observed from a frame fixed to A
SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
8. In the pulley block system shown in figure strings are light. Pulleys are massless and
smooth.System is released from rest. In 0.3 second:
A)Work done on 2 kg block by gravity is 6J
B)Work done on 2 kg block by string is -2J
C)Work done on 1 kg block by gravity is -1.5J
D)Work done on 1 kg block by string is 2J
9. A sledge moving over a smooth horizontal surface of ice at a velocity 0 drives out on
a horizontal road and comes to a halt as shown. The sledge has a length ‘ l ’, mass m
and friction between sledge and road is μ
A)No work is done by the friction to switch the sledge from ice to the road.
B)A work of 1 mgl is done against friction while sledge switches completely on to
2
road.
C) The distance covered by the sledge on the road (after it is completely on the road)
0 2 
is (  )
2g 2
0 2 
D) Total distance moved by the sledge before stopping is (  )
2g 2
10. A particle of mass 5 kg moving in the x-y Plane has its potential energy given by
U=(-7x+24y) J, where x and y are in metre. The Particle is initially at origin and has a
 ˆ 1 .
velocity u  (14.4iˆ  4.2j)ms
A) The particle has a speed of 25 ms1 at t=4s
B) The particle has an acceleration of 5 m s 2
C) The acceleration of the particle is perpendicular to its initial velocity

D) None of the above is correct
11. The figure shows a potential energy function. In the region 0  r  R , U(r) is parabolic .
In the region r  R ,U(r) is an inversely proportional function.
Identity the correct conservation force function F(r) Plot.
12. A block of mass 5 kg is sliding on a rough inclined plane as shown in figure.The

Spring constant of spring is k = 408N/m.(g=10 m / s 2 )
A) The maximum deformation of the spring will be 1 m

B) Maximum velocity will be attained by the block when compression will be 0.083m
C) Maximum spring force will be 408 N.
D) As the block just touches the spring, velocity of block will be maximum.
13. A rod is fixed between a vertical wall and a horizontal surface.A smooth ring of mass
1 kg is released from rest which can move along the rod as shown.At the release point
spring is vertical and relaxed. The natural length of the spring is ( 3 1)m .Rod makes
an angle of 3 0 0 with the horizontal. Ring again comes to rest when spring makes an
angle of 3 0 0 with the vertical. (g=10 m / s 2 )
A)Force constant of the spring is 5 ( 3  1) N/ m

2
2
B) Maximum displacement of ring is m
3 1
C)Maximum extension in the spring is ( 3 1)m
D)Normal reaction on ring due to rod when it again comes to rest is 5 ( 3  1) N

3
14. In the figure shown P is the peak of a mountain. From the ground point G;a block of
mass m and 2m are lifted slowly to the peak via path I and II respectively. Both paths
have same co-efficient of friction. If the work done be respectively wI and w II ;
Choose the correct options

A) 2wI = w II
B) wI = w II
C)Loss of energy due to friction is same for both and paths
D) w1I = w1II ;(where w1I and w1II are work done per unit mass)
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 15 and 16:
The figure shows the variation of potential energy of a particle as a function of x, the
X-coordinate of the region. It has been assumed that potential energy depends only on
x. For all other values of x, U is zero, i.e., for x  10 and x  15 , U=0. Based on above
information answer the questions the following
15. If total mechanical energy of the particle is 25J, then it can be found in region.
A) 10  x  5 and 6  x  15 B) 10  x  0 and 6  x  10

C) 5  x  6 D) 10  x  10
16. If total mechanical energy of the particle is -40J, then it can be found in region.
A) x  10 and x  15 B) 10  x  5 and 6  x  15
C) 10  x  15 D)It is not possible.

The Potential energy of a particle that is bound to a certain point at a distance r from
the centre of the force is given by U(r) = A2  B . Where A and B are positive
r r
constants. Answer the following questions;
17. The equilibrium distance is given by:
A) A B) 2A C) 3A D) B
B B B 2A
18. The work required to move the particle from equilibrium distance to infinity is :
B2 4B2
A) B B) 4 B C) D)
4A A 4A A
CHEMISTRY Max. Marks: 61
SECTION – I
19. Identify the correct match ?
A) & ( Position Isomers )
B)
D D
C) & ( Geometrical isomers )
H H
Me Me
H Me
D) &
( Geometrical isomers )
Me H
20.
A) Positional isomers B) Geometrical isomers

C) Identical D) Chain isomers
21. Which of the following is an ‘E’ isomer?
Cl H3CO
CH3 C2H5
A) C=C B) C=C
H3C H H3C CH3
O2N Cl O2N Cl
C) C=C D) C=C
Br Br
CH3 CH3
22. Which of the following cannot show geometrical isomerism?
A) 1 – phenyl – 2- butene B) 1, 2 – dichloroethene
C) Cyclopropylethene D) Hex – 2- ene
23. The difference between heat of reaction at constant pressure and constant volume for
the reaction given below at 25°C in kJ is
2C6H6(l) + 15O2(g) 12CO2(g) + 6H2O (l)
A) –7.43 B) +3.72 C) –3.72 D) 7.43
24. Under the same conditions how many ml of 1M KOH and 0.5 M H2SO4 solutions,
respectively when mixed for a total volume of 100 ml produce the highest rise in the
temperature
A) 67 : 33 B) 33 : 67 C) 40 : 60 D) 50 : 50

25. A diatomic molecule has a dipole moment of 1.2 D, if its bond distance is 1.0 A . What
fraction of an electronic charge e exists on each atom?
A) 20% of e B) 21% of e C) 19% of e D) 25% of e
SECTION-II
26. Which of the following do not exhibit geometrical isomerism(cis-Trans)
H Cl
C
A) H Cl B) CH 3  CH  CCl2
H Cl
Cl Cl
C) H Cl D) H Br
27. Which of the following are correctly matched ?
Compounds Number of geometrical isomers
A) CH3  CH  CH  CH  CH  Ph 4
B) CH3   CH  CH 4  CH3 2
C) CH3  CH  CH  CH3 10
D) CH3   CH  CH 5  CH3 20
28. Which of the following pair of compounds represent correct matching
A)
CH3 CH2 C C H and CH3 C C CH3

B)
(Position Isomers )
CH3 CH2 CH2 NH2 and CH3 CH CH3

C)
NH2
( Metaners )
CH3 CH CH2 ,
D)
(Ring Chain Isome rs)
29. Mark out the correct Match

Br Br
H H
and are geometrical isomers
(A) are geometrical isomers
CH3 C2H5 H5C2 CH3
Br OH OH
H H
and are geometrical isomers
CH3 CH3
are geometrical isomers
(B) Br
o o
(C) CH3  CH 2  C  O  CH 3 and H-C-O-CH2CH 2CH3 are metamers
are metamers
H
(D) O and CH3 OH are functional isomers
CH3
are functional isomers
30. Which of the following statement(s) is/are correct?
A) B and C has zero dipole moment
B) A, H and F has non – zero dipole moment
C) D and E has zero dipole moment
D) G and I has zero dipole moment
31. Which of the following statements are true?
A) all spontaneous reactions has  Ssystem positive
B) allnon spontaneous process have  G positive.
C)  Ssystem + ∆Ssurroundingsis positive for spontaneous process.
qsystem
D) ∆Ssurroundings = 
T
32. Which of the following statement is incorrect?

A) For every process that has T  0 , ∆U = 0
B) The entropy of an isolated system must remain constant
C) For reversible process in a closed system  Ssystem is zero
D) For every cyclic process, the final state of the surrounding is the same as the initial
state of the surrounding
SECTION – III
(PARAGRAPH TYPE)
3
One mole of an ideal gas for which Cv  R is heated at a constant pressure of 1 atm
2
from 250 C to 1000 C . On the basis of above write up, answer the following questions.
33. What will be amount of work done in process?
A) 149.025 cal B) 62.32 cal
C) 36.16 cal D) 298.5 cal
34. What will be change in entropy for above isobaric process? log1.2517  0.0975 
A) 1.115 calK 1mol1 B) 3.734 calK 1mol1
C) 2.92 calK 1mol1 D) 8.78 calK 1mol1

A real gas is supposed to obey the gas equation P(V – nb) = nRT at STP. If one mole of
a gas occupies 25 dm3 volume at STP.
35. Calculate the diameter (in cm) of each gas molecule
A)1.27 x 10-9 B) 3.81 x 10-9 C)1.27 x 10-8 D)3.81 x 10-10
36. Calculate compressibility factor for gas
A) 1.115 B) 1.011 C) 0.012 D) 0.331

MATHEMATICS Max. Marks: 61
SECTION – I
37. At what inclination with the positive direction of x axis, a line be drawn through the
6
point (1, 2) so that its point of intersection with the line x + y = 4 is at a distance
3
from the given point
(A) 75º (B) 60º (C) 45º (D) 30º
 cos  sin  
38. If A=  , then which of following statement is true -
 sin  cos  
 sin n  
(A) A.A= A & (A)n =  cos n
n
n 
 sin  cos  
 cos n sin n 
(B) A.A = A & (A)n =  
 sin n cos n 
 sin n  
(C) A.A = A & (A)n =  cos n
n
n 
 sin  cos  
 cos n sin n 
(D) A.A= A & (A)n =  
 sin n cos n 
39. The solution of the system of equations a2x + ay + z = – a3, b2x + by + z = – b3, c2x +
cy + z = – c3 is
(A) x = – (a + b + c), y = ab + bc + ca, z = – abc
(B) x = (a + b + c), y = ab + bc + ca, z = – abc
(C) x = – (a – b – c), y = ab + bc + ca, z = – abc
(D) None of these
40. The set of lines represented by the equation (cos + sin)x + (cos – sin)y – 3(3 cos
+ sin) = 0 always pass through a fixed point M for all real values of . The reflection
of M in the line x – y = 0, is-
(A) (6, 3) (B) (3, 6) (C) (–6, 3) (D) (3, –6)

41. A triangle ABC is formed by the lines 2x – 3y – 6 = 0; 3x – y + 3 = 0 and
3x + 4y – 12 = 0. If the points P(,0) and Q(0,) always lie on or inside the ABC,
then the set of exhaustive values for and re
(A) [–1,2] and [–2,3] (B) [–1,3] and [–2,4]
(C) [–2,4] and [–3,4] (D) [–1,3] and [–2,3]
42. A ray of light passing through the point A(1,2) is reflected at a point B on the x-axis
and then passes through (5,3). Then the equation of AB is
(A) 5x + 4y = 13 (B) 5x – 4y = –3 (C) 4x + 5y = 14 (D) 4x – 5y = –6
43. The area of the rhombus ABCD is 24. The equation of the diagonal BD is 4x+3y+2=0
and A  (3, 2) . The length of the side of the rhombus is
(A) 7 (B) 5 (C) 4 (D) 3
SECTION-II
44. If the points (2,1), (3, 4), (a 2 , a) lie on the same side of the straight line 6 x  7 y  3  0 then
a can be any number in the interval
6 
(A) (0,1) (B)  ,  (C) (2, 4) (D) (1,1)
5 5 
45. (3, 2), (-4, 1) and (-5, 8) are vertices of triangle then select the CORRECT alternative/s
(A) orthocentre is (4, 1) (B) orthocentre is (-4, 1)
(C) circumcentre is (-1,5) (D) circumcentre is (3, 2)
46. An equation of a line passing through (2,3) and making an intercept of 2 units between
the lines y  2 x  5 and y  2 x  3 is
(A) 5 x  4 y  2  0 (B) 3 x  4 y  18 (C) x = 2 (D) y = 3

47. A piece of cheese is located at (12, 10) in a coordinate plane. A mouse is at
(4, –2) and is running up the line y = –5x + 18. At the point (a, b), the mouse starts
getting farther from the cheese rather than closer to it. Then which of the following is
CORRECT?
(A) b=2 (B) a=2 (C) b=8 (D) a=8
48. An equilateral triangle has its centroid at origin and one side is x  y  1 . The equations
of the others sides are
(A) y  1   2  3   x  1 (B) y  1   2  3   x  1
(C) y  1   2  3   x  1 (D) x  1   2  3   y  1
49. Which of the following statements are FALSE?
(A) If A and B are square matrices of the same order such that ABAB = 0, it follows
that BABA = 0
(B) Let A and B be different n  n matrices with real numbers. If A3 = B3 and
A2B = B2A, then A2 + B2 is invertible
1  1
(C) If A is a square, non-singular and symmetric matrix, then  A 1

  

is skew
symmetric
(D) The matrix of the product of two invertible square matrices of the same order is also
invertible
50. System of equation x + 3y + 2z = 6
x  y  2z  7
x + 3y + 2z =  has
(A) Unique solution if   2,   6 (B) infinitely many solution if   4,   6
(C) no solution if   5,   7 (D) no solution if   3,   5

SECTION – III
(PARAGRAPH TYPE)
Let ABC be an acute angled triangle and AD, BE and CF are its medians, where E and
F are the points E(3, 4) and F(1, 2) respectively and centroid of ABC is G(3, 2), then
On the basis of above passage, answer the following questions:
51. The equation of side AB is
(A) 2x + y = 4 (B) x + y – 3 = 0 (C) 4x – 2y = 0 (D) None of these
52. Co-ordinate of D are
(A) (7, –4) (B) (5, 0) (C) (7, 4) (D) (–3, 0)

A (x1, y1), B(x2, y2), (y1 < y2) are two points on the line x + y = 4 from which
perpendicular AQ and BP are drawn on line 4x + 3y = 10 where P and Q are the feet
of perpendiculars such that AQ = BP = 1. Now considering AB as diameter, a circle is
drawn which meets the line 4x + 3y = 10 at C and D such that C is closer to P.
On the basis of above passage, answer the following questions
53. The length PQ is equal to-
(A) 3 14 (B) 4 5 (C)14 (D) None of these
54. Length QD is equal to
(A) 3 2  17 (B) 3 2 – 17 (C) 4 2  17 (D) 5 2 –7

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A) 3  1 rad / s B) 3  1 rad / s C) 1 rad / s D) None of these

A) MgL B)MgL C) MgL D) MgL

A) A is true and B is true B)A is true and B is false

C) A is false and B is true D) A is false and B is false

A)Work done on 2 kg block by gravity is 6J

B)Work done on 2 kg block by string is -2J

C)Work done on 1 kg block by gravity is -1.5J

D)Work done on 1 kg block by string is 2J

C) The acceleration of the particle is perpendicular to its initial velocity

12. A block of mass 5 kg is sliding on a rough inclined plane as shown in figure.The

A) The maximum deformation of the spring will be 1 m

A)Force constant of the spring is 5 ( 3  1) N/ m

C)Maximum extension in the spring is ( 3 1)m

D)Normal reaction on ring due to rod when it again comes to rest is 5 ( 3  1) N

Choose the correct options

A) 10  x  5 and 6  x  15 B) 10  x  0 and 6  x  10

A) x  10 and x  15 B) 10  x  5 and 6  x  15

C) 10  x  15 D)It is not possible.

Paragraph For Questions 17 and 18:

constants. Answer the following questions;

17. The equilibrium distance is given by:

A) & ( Position Isomers )

C) & ( Geometrical isomers )

A) Positional isomers B) Geometrical isomers

A) 1 – phenyl – 2- butene B) 1, 2 – dichloroethene

C) Cyclopropylethene D) Hex – 2- ene

2C6H6(l) + 15O2(g) 12CO2(g) + 6H2O (l)

A) –7.43 B) +3.72 C) –3.72 D) 7.43

A) 20% of e B) 21% of e C) 19% of e D) 25% of e

Compounds Number of geometrical isomers

28. Which of the following pair of compounds represent correct matching

CH3 CH2 C C H and CH3 C C CH3

CH3 CH2 CH2 NH2 and CH3 CH CH3

29. Mark out the correct Match

A) B and C has zero dipole moment

B) A, H and F has non – zero dipole moment

C) D and E has zero dipole moment

D) G and I has zero dipole moment

31. Which of the following statements are true?

A) all spontaneous reactions has  Ssystem positive

B) allnon spontaneous process have  G positive.

C)  Ssystem + ∆Ssurroundingsis positive for spontaneous process.

32. Which of the following statement is incorrect?

33. What will be amount of work done in process?

A) 149.025 cal B) 62.32 cal

C) 36.16 cal D) 298.5 cal

A) 1.115 calK 1mol1 B) 3.734 calK 1mol1

C) 2.92 calK 1mol1 D) 8.78 calK 1mol1

Paragraph For Questions 35 and 36:

a gas occupies 25 dm3 volume at STP.

35. Calculate the diameter (in cm) of each gas molecule

A)1.27 x 10-9 B) 3.81 x 10-9 C)1.27 x 10-8 D)3.81 x 10-10

36. Calculate compressibility factor for gas

A) 1.115 B) 1.011 C) 0.012 D) 0.331

from the given point

(A) 75º (B) 60º (C) 45º (D) 30º

(A) x = – (a + b + c), y = ab + bc + ca, z = – abc

(B) x = (a + b + c), y = ab + bc + ca, z = – abc

(C) x = – (a – b – c), y = ab + bc + ca, z = – abc

(D) None of these

(A) (6, 3) (B) (3, 6) (C) (–6, 3) (D) (3, –6)

(A) [–1,2] and [–2,3] (B) [–1,3] and [–2,4]