06-09-20 - SR - Co-Super Chaina - Jee-Adv - Rta-1 (P-Ii) - Syllabus

Sec: Incoming.Sr.
IIT_CO-SC Date: 06-09-20

Time: 3HRS Max. Marks:183
Name of the Student: ___________________ H.T. NO:
06-09-20_INCOMING.SR.CO-SUPER CHAINA_Jee-Adv_RTA-1(P-II)_SYLLABUS
PHYSICS: PT-1 TO PT-4 SYLLABUS ONLY
CHEMISTRY: PT-1 TO PT-4 SYLLABUS ONLY
MATHEMATICS: PT-1 TO PT-4 SYLLABUS ONLY

Narayana IIT Academy 06-09-20_Incoming.Sr.IIT_CO-SC_JEE-Adv_RTA-1(P-II)_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 183
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61
CHEMISTRY
Sec – II (Q.N : 26 – 32) +4 -2 7 28
Sec – III (Q.N : 33 – 36) +3 0 4 12
Total 18 61
MATHEMATICS
Sec – II (Q.N : 44 – 50) +4 -2 7 28
Sec – III (Q.N : 51 – 54) +3 0 4 12
Total 18 61
SR.IIT_CO-SC Page. No. 2
Education consists mainly of what we have unlearned.

PHYSICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. A cubical region of side ‘a’ has its center at the origin. It encloses three fixed point
charges, -q at (0,-a/4, 0), +3q at (0, 0, 0) and –q at (0, +a/4, 0). Choose the Incorrect
option(s) ?
A) The net electric flux crossing the plane x=+a/2 is equal to the net electric flux
crossing the plane x= -a/2
B) The net electric flux crossing the plane y=+a/2 is more than the net electric flux
crossing the plane y=-a/2
q
C) The net electric flux crossing the entire region is
o
D) The net electric flux crossing the plane z=+a/2 is equal to the net electric flux
crossing the plane x=-a/2
2. A grounded metallic ball of radius r is placed on the center of a uniformly charged thin
insulating disc of radius R,( R  r ). If total charge on the disc is Q , the force of
electrostatic interaction between the ball and the disc is
Q2r 2Q 2 r 2Q 2 r  Q2r
A) B) C) D)
 o R 3  o R 3  o R4  o R4

3. There is a sample of air at standard conditions in the vertical cylinder shown in the fig.
The piston moves without friction and its mass is same as that of the pan on the other
side of the massless and smooth fixed pulley. Some fixed amount of sand is slowly
poured either onto the top of the piston or into the pan. The temperature remains the
same. Then:
A) Displacement of the piston will be greater if sand is poured in the pan

B) Displacement of the piston will be greater if sand is poured on to the top of the
piston.
C) Displacement of piston will be same in both cases.
D) Displacement of piston is greater or lesser in any case, will depend on the initial
volume and pressure of the gas.
4. Water at temperature 400C flows from a tap T into a heated container C. The container
has a heating element (a resistor R) which is generating heat at the rate of P, that may be
1000
varied. The rate of water inflow from tap V  liter / min . The heat generated is
7
sufficient so that the water in the container is boiling and getting converted into steam at
a steady rate. What is power P that must be generated as heat in the steady state in
resistor R so that the amount of liquid water in the container neither increases nor
decreases with time? (Neglect other losses of heat, such as conduction from the
container to the air and heat capacity of container) For water, specific heat c=4.2 KJ kg-
1
K-1, latent heat of vaporization Lvap  2.268MJ kg 1 , density   1000kg m 3

A) 6 102W B) 6 104W C) 6 105W D) 6 106W
5. The side of a cube is measured by Vernier callipers (10 divisions of Vernier scale
coincide with 9 divisions of main scale , where 1 div of main scale is 1mm). The main
scale reads 10mm and first division of Vernier scale coincides with main scale. Mass of
the cube is 2.736g. Find the density of the cube in appropriate significant figures ( in gm
cm-3)
A) 1 B) 2 C) 3 D) 4
6. A small sphere is charged uniformly and placed at A  u, v  so that at point B  8, 7  electric


field strength is E  54i  72 j NC 1 and potential is + 900V
A) The magnitude of charge is 2C
B) The coordinates of point A is (2, 1)
C) If dielectric strength of air is 3 106Vm1 , the minimum radius of the sphere is
5.48cm(nearly)
D) The magnitude of charge is 2C
7. A non-standard verniercallipers has 10 V.S.D coinciding with 7 M.S.D, with each
M.S.D equal to 1 mm. The scale has a maximum measurable length of 100 MSD. If 14th
M.S.D. is found to coincide with 4th V.S.D, where does the zero of vernier lie? Assume
no zero error.
A) Between 10th and 11th M.S.D. B) Between 11th and 12th M.S.D.
C) Between 9th and 10th M.S.D. D) Exactly on the 10th MSD


SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
8. A metal cylinder of mass 0.5kg is heated electrically by a 12W heater in a room at 15oC.
The cylinder temperature rises to 25oC in 5 min and finally becomes constant at 45oC.
Assuming that rate of heat loss is proportional to the excess temperature over the
surroundings, which of the following statements is/are correct.
A) the rate of loss of heat of the cylinder to surrounding at 20oC is 2W
B) the rate of loss of heat of the cylinder to surroundings at 45oC is 12W
240
C) specific heat capacity of metal is Jkg 1 oC 1
3
ln  
2
240
D) specific heat capacity of metal is Jkg 1 oC 1
ln 2
9. ‘n’ mole of Helium gas undergoes a thermodynamic process in which the molar heat
capacity C of the gas can be described as a function of the absolute temperature
3RT
C , where R is gas constant and T0 is the initial temperature of the Helium gas:
4T0
( Vo is the initial volume)
A) Volume of gas as a function of temperature is given by V  V0   exp  

 T 
3/2
 3 T  T0  

0
T   4T0 
B) Volume of gas as a function of temperature is given by V  V0  T0  e xp  2 T  T0  

1/2
T   3T0 
C) Work done on the system until the point at which the Helium gas reaches the minimal
3
volume is nRT0
8
D) Work done on the system until the point at which the Helium gas reaches the minimal
3
volume is  nRT0
8

10. Two insulating hemispherical shells are placed very close to each other with their
centres almost coincident, as shown in figure -a and figure-b. Both of them are
uniformly charged, one with total electric chargeQ and the other with total charge q.
A) The magnitude of the net electric force exerted by the two bodies on each other is F =
Qq
in case of fig-a
8 o R 2
B) The magnitude of the net electric force exerted by the two bodies on each other is
Qq
F= in case of fig-b
8 o R 2
Qq
C) The magnitude of the net electric force is F  even if they are tilted by an
8 o R 2
angle 
D) the direction of force is paralle to the axis of symmetry of larger hemispherical shell

11. In a uniform electric field, equipotential surface must
A) be plane surfaces
B) be normal to the direction of the field
C) be spaced such that surfaces having equal differences in potential are separated by
equal distances
D) have decreasing potential in the direction of the field
12. Choose correct statement(s)
A) the number of significant figures in 0.31103 is two
B) The length, breadth and thickness of a rectangular sheet of metal measured with same
instrument are 4.234 m, 1.00 m and 2.01 cm
C) When 97.52 is divided by 2.54, the result is 38.393700000.
D) When 0.2 J is subtracted from 7.26 J, the result with correct number of significant
figures is 7.1 J.
uv
13. In an experiment to find ‘f’ using a formula f  , where u and v are measured
uv
quantities as follows.
u  (8.0  0.2) 101 m
v  (4.0  0.2) 101 m
A) Order of magnitude of ‘u’ in meter is zero
B) Number of significant digits in ‘ v ’ when measured in ‘cm’ will be 3
10
C) Percentage error in (u  v) is %
3
65
D) Percentage error in f is % (nearly)
6

14. A student uses a simple pendulum of length 1m to determine acceleration due to gravity
g. He uses a stop watch with least count of 0.5 s for this and records 40 s for 20
oscillations. For this observation, which of the following statements is/are true? Least
count of scale used for measurement of length is 1cm.
A) Percentage error in measurement of time period is 5 / 4 %
B) Percentage error in measurement of time period is 5 / 2 %

C) Percentage error in determination of g 2.5%
D) Percentage error in determination of g 3.5%
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 15 and 16:
A point charge is placed at a distance d>R from the centre of an equally charged,
isolated ,conducting sphere of radius R. Lets call the point charge q .The charged ,
isolated sphere may be replaced by two image charges. One image charge, of charge
R R2
q1   q at radius r1  , is needed to make the potential equal at all points on the
d d
sphere. The second image charge, of charge q2  q  q1 at the centre of the sphere, is
necessary to recreate the effect of the additional charge on the sphere (the additional
charge is the extra charge on the sphere left over after you substract the surface charge
density induced by the point charge q )the force on the point charge is the sum of the
forces from the two image charges:
 
   
F
1  qq1 qq2 
 2 
q2   dR 
d 2  dR 
4 o   R 2 2
 d 4 o  d 2  R2  2 d4 
 d
 
   
  d  
15. Identify the correct answer from the following options

A) as d  R , over all force is attractive
B) as d   , over all force is repulsive
C) both A and B are correct
D) cannot be concluded whether option A , B correct or wrong with this data given

16. What is the limiting value of magnitude of force of attraction when the point charge is
located at distance a  d  R from the surface of the sphere (if a  R )
q2 q2
A) F  B) F 
16 o a 2  o a 2
q2
C) F  D) information is not sufficient to find
4 o a 2

A cylindrical vessel made of thermally insulating material is fitted with a horizontal
insulated piston P of mass m and area A. The piston is also made by thermally insulating
material. There is no friction between inner surface of the cylinder and the piston. Above
the piston, a liquid of density  is filled up to the brim of the cylinder. The piston is
supported at the position shown due to pressure of an ideal gas filled in the lower portion
of the cylinder. When the gas is heated by the heater H, it expands and pushes the piston
up, spilling the entire liquid out of the cylinder. Number of moles of the gas is n and
atmospheric pressure is P0 and initial temperature is T0
17. Work done by the gas is:
A)  gh 2 A  mgh B) P0 hA   gh 2 A  mgh
C) P0 hA  0.5  gh 2 A  mgh D) P0 hA   gh 2 A  0.5mgh
18. Final temperature of the gas is:

 P A   ghA   P0 A 
A) 2T0  0  B) 2T0  
 P0 A   P0 A   ghA 
 P A   ghA  mg   P0 A  mg 
C) 2T0  0  D) 2T0  
 P0 A  mg   P0 A   ghA  mg 

CHEMISTRY Max. Marks: 61
SECTION – I
19.
1)a.Sia 2BH,THF

b.NaOH,H 2O 2
2)Hg  OAC 2 ,H 2O
  major product 

3) NaBH 4 / OH
Find the correct structure of major product

OH
OH
OH
A) OH B)
OH
OH
OH OH
C) D)
20. How many products having 12 carbons are obtained in the following reaction?

Na
Cl
  C14carbon 
A) 3 B) 4 C) 10 D) 12
21. The correct order of rate of wurtz reaction
I) II)
Na / Ether
Na / Ether
CH2  F   CH 2  Cl  
III) IV)
Na / Ether
CH 2  Br Na
/  CH2  I  
Ether
 
A) I  II  II  IV B) II  I  III  IV
C) IV  III  II  I D) In all rate of wurtz reaction is same

22. Total number of stereoisomers possible for the given compound is
A) 2 B) 3 C) 4 D) 5
23. Damascenones are possible for the smell of roses. When damascenones is treated with
NaOD in D2O for long time, then find maximum number of D atom present in
damascenones.
A) 6 B) 8 C) 9 D) 10
24. Find out major product in the following reaction is
H 3C 3 C  Br2
A) B)
C) D)

25.
OCH 3
Li H O / 
 Q  major product 
P 
3
liq.NH 3 , EtOH
The correct structure of Q is

O OH
OH O
A) B) C) D)
SECTION-II
26. Which of the following compounds undergo decarboxylation when treated with sodalime
A) B)
C) D)
27. Which among the following compound is/are not used in Gattermann Koch formylation
OH NMe 2 CH3 OH OH
A) B) C) D) OH

28. In which reaction major product formation takes place by Hoffmann rule
OAC
 CH 3 3 COK /  |

A) CH3  CH 2  CHBr  CH 3 
 B) CH 3  CH 2  C  CH 3  

CH3  CH 2  CH  CH 3   Br
|
| CH 3ONa / 
C) D) CH 3  CH 2  C H  CH 3  
H O N  CH 3 3
 
29.
Cl CN
O2 N O2 N
KCN
NO2 NO2
Which statement is / are true about this reaction?
A) Mechanism during reaction is SNAr 2
B) Mechanism during reaction is benzyne

C) Reaction rate does not depends upon concentration of C N
D) Reactivity will be high if F is present in place of Cl
30. O
||
Ph  C  CH 3 
Re agent
 Ph  CH 2  CH 3
reagent can be
A) NH 2 NH 2 , glycol / OH /  B) Zn – Hg | conc. HCl
CH 2  CH 2 ; Raney Ni  H 2
| |
C) Red P / HI D) SH SH

31. Select the reactions with correct major products
OH OH
CF3 CF3
Br2
CS 2 ,  5 0 C
CH 3  Cl
AlCl3
Br CH 3
A)  major  B)  major 
N N NH 2 NH 2
CH 3 CH 3
NaNO 2 , HCl conc.HNO 3
conc.H 2SO 4
NO NO 2
C)   D)
major  major 
32. Which of the following statements is / are not true?

A) All ortho-para directing groups activates the ring
B) All ortho-para directing groups except halogens activate the ring
C) All meta-directing groups have  - bond on the atom directly attached to the ring.
D) All meta-directing groups are deactivating
SECTION – III
(PARAGRAPH TYPE)
Grignard reagent is usually prepared by
R  X  Mg 
Et2O
 RMgX
Ar  X  Mg 
Et2O
 ArMgX
Grignard reagent acts as strong base, Grignard reagent carry out nucleophilic attack in
absence of acidic hydrogen. Grignard reagent forms, complex with ethers solvent.
Complex formation with molecule of ether is an important factor in the formation and
stability of Grignard reagent

33. Find out major product in the following reaction
Br
1) Mg; ether
major product 
2) Ph  CHO
N
H 3) H3 O
A) B)
C) D)
34. How many moles of Grignard reagent will consume when it reacts with following
compounds
A) 6 B) 8 C) 9 D) 10

E2 reaction – Elimination biomolecular in the general mechanism of the E2 reaction a
strong base abstract a proton on a carbon atom adjacent to the one of the leaving group.
As the base abstracts a proton a double bond forms and the leaving group leaves
35.
Ph Ph
H 3C H H 3C H
alc.KOH alc.KOH
X  Y 
H 3C Br Br CH 3
Ph Ph
Products X and Y are
A) X  CiS alkene Y  CiS alkene B) X  Trans alkene Y  CiS alkene
C) X  Trans alkene Y  Trans alkene D) X  CiS alkene Y  Trans alkene
36.
Cl Cl
C6 H 5 H C6 H 5 H
NaOEt / EtOH NaOEt / EtOH
P Q 
C6 H 5 H H C6 H 5
CH 3 CH 3
Products Q and R are
A) P  Z alkene Q  Z alkene B) P  E alkene Q  Z alkene
C) P  E alkene Q  E alkene D) P  Z alkene Q  E alkene

MATHEMATICS Max. Marks: 61
SECTION – I
 x  sin x x  1,  

x   0,1
37. If f  x   
lnx
,
 ln   x  x   1, 0 
  x  sin x
 x   , 1
then f  x  is
1) even 2) odd 3) Neither even nor odd 4) Periodic function
, n  N in the interval 
1 1 1 
38. Total number of value of x, of the form , such that
n  2049 2020 
 x  2 x  3x  ........  2019 x  2039190 x, where . denote fractional part function then
the value of   ______
A) 35 B) 36 C) 30 D) 29
 x  3 x 2  5 x  6 ; x0

39. If f  x     x  1  x  ; 0  x  2 then number of values of x where f  x  is

  x  1 x  3
1/3
; x2
continuous but not differentiable is / are (where . represent G.I.F)

A) 3 B) 4 C) 5 D) 2
 x2 
4 
x2  1  2 ae 2
40. If the value of lim x  2   e is equal to (where a and b are positive integer
x   x  1  b
 
 
and co – prime) then the value of a 2  b 2 is
A) 3 B) 5 C) 7 D) 10
41. If a function f :  2,    R is such that f  x   x 2  4 x  x 2  4 , then range of f  x  is
A)  ,   B)  6,12 C)  6,   D)  6, 4

3 x  sin x  cos x  3  sin x 
2 3
42. If  dx  f  x   C , where lim f  x   1 and C is the constant of integration,

x4 x 0
 x

  tf  t  dt   2 x
2
then the value of 2 lim  0  is…

x 0 1  cos x
A) 3 B)-3 C)6 D) -6
cos ec x  2016
2
43.  cos 2016 x
dx 
cot x tan x cot x tan x

A) c B) c C)  c D)  c
cos 2016 x cos 2016 x cos 2016 x cos 2016 x
SECTION-II
44. Let f be a polynomial function satisfying f  x 2   xf  x   x 4  x 2  1 x  R  . Then, which of
the following is correct ?
A) f is an even function B) f is an odd function
f  x
C) lim 1
x  x3
 f  x 
D) lim  2
 x  exist and is equal to a non – zero quantity
x 
 x 
45. Suppose that f  x  is defined on R, satisfying f  0   0 , and for any
x  R . f  x  2   f  x   3  2 x , f  x  6   f  x   63  2 x then which of the following is / are
CORRECT?
A) f  2   3 B) f  4   15 C) f  6   63 D) f  4   17
46. Consider two functions f  x   

    
 3x /2  3 x /2 7 sin cos x3 , x  R  x x  n, n  I

and
 1n 3  2  1n 5  7 ,
    
x   x x  n, n  I 
   
 5 x / 3  5 x / 3 5 cos sin x3 , x  R  I

g  x   where . is greatest integer function, then ……
  1 2 3
  2 sin x  2  , xI
A) f is even function B) g is an odd function

C) f is neither even nor odd function D) g is neither even nor odd function

x  2 x 1
47. Let f  x   x then
x 1 1
A) Domain of f  x  is 1, 2    2,   B) Range of f  x  is  2, 1   2,  
C) f '  2   k , where k is non zero D) f ' 1.7   1
48. Let f be a differentiable function satisfying f  x  y   f  x   f  y    e x  1 e y  1 , x, y  R
and if f 1  0   2 then which of following statement(s) is / are true

1
A) Number of solution of f  x   0 is 1 B) Lt  f  x   cos x  e x 1  e2
x 0

C) If f     2 then tan 1   tan 1    
1
 2
f  x
D) Lt 2
x 0 x
 x3  sgn  x    x  : 0  x  2
49. If f  x    , where . , 
. and sgn . represents the greatest
 cos x  x  2 ; 2 x
integer, the fractional part and signum function respectively

A) f  x  is differentiable at x  1
B) f  x  is continuous but non – differentiable at x  1
C) f  x  is discontinuous at x  2
D) f  x  is non – differentiable at x  2
50. Let
 tan 1  x 1 1
  x  1
2017
e sin 2 if x  1
f  x    x  1
 x 1
 1 if
 10 
and   lim  n  f 1    n  k  then,
4
k
n  k 1  n k 1 
A) f  x  is continuous but non – derivable at x = 1
B) f  x  is differentiable at x =1
C) 55 f ' 1    0
D)  is divisible by 11

SECTION – III
(PARAGRAPH TYPE)
1  1

1  ax   exists, and it is finite and has the value equal to
Consider the limit lim  
 1  x 1  bx 
x 0 x 3
l (where a, b are real constants), then,
51. ab 
3 1
A) B) C) 1 D) 0
4 2
b
52. 
l
A) 38 B) 16 C) 72 D) 24

There exist llinear polynomials f  x  , g  x  and h  x  such that for all x, they satisfy
 1 if x  1

f  x   g  x   h  x    3x  2 if 1  x  0
2 x  2 if x0

53. The value of f  3 can be
A) 6 B) 9 C) 12 D) 15
54. The value of g  3 .h  2  can be
43 45 53 41
A) B) C)  D)
4 4 4 4

Sec: INC.SR.IIT_CO-SC RTA-1 Date: 06-09-20
Time: 3HRS 2017_P2 Max. Marks: 180
KEY SHEET
PHYSICS
1 B 2 A 3 A 4 D 5 C
6 C 7 B 8 ABC 9 AC 10 ABC
11 ABCD 12 AD 13 AC 14 AD 15 C
16 A 17 C 18 D
CHEMISTRY
19 D 20 C 21 C 22 B 23 D
24 A 25 C 26 ABCD 27 ABD 28 ABC
29 AD 30 ABCD 31 A,D 32 ABC 33 C
34 B 35 B 36 D
MATHEMATICS
37 C 38 C 39 A 40 B 41 C
42 D 43 C 44 C 45 ABC 46 AD
47 ABD 48 ABCD 49 ACD 50 BCD 51 C
52 D 53 A 54 B
Narayana IIT Academy 06-09-20_Inc.Sr.IIT_CO-SC _JEE-Adv_RTA-1(P-II)_KEY&SOL
SOLUTIONS
PHYSICS
1. APPLICATION OF GAUSS LAW
2. POTENTIAL IS ZERO
R q1
 0
2 o 4 o r
q1  2 Rr
Since R>>r so mostly this charge q1 is in a uniform electric field of disc
 1 Q2r
F q 
2 o  R 3 o
3. when sand is poured pressure decreases and hence volume increases in side
4. conceptual
5. previous IIT question
6. Magnitude of Electric field is 90 V/m

Potential is 900 V
V 900
  10
E 90
(8  u ) 2  (7  v) 2  10 from the above equation
7  v 72 4
  from the vector equation of E
8  u 54 3
(u,v)=(2,-1)
1 q
 900  q  106 C
4 o 10
1 q
 3  106
4 o R 2
SR.IIT_CO-SC Page 2

7. 10VSD  7MSD
1VSD  0.7MSD
4VSD  2.8MSD
SO zero of Vernier scale lies in between 11th and 12th MSD
8.
9. PdV 3RT
CV  
ndT 4T0
RTdV 3RT
CV  
VdT 4T0
dV  3 3 
   dT
V  4To 2T 
dV  3 3 
 V    4To  2T  dT
 V  3(T  To ) 3 T 
log e    log e  
 Vo  4 To 2  To 
3
 V   T  2 3(T  To )
log e     
 Vo   To  4To
3
 T 2  3(T  To ) 
V  Vo  o  exp  
T   4To 
10. It’s a simple mathematical process, follow from a to g
SR.IIT_CO-SC Page 3

This combination is same as interaction of hemispherical shell with a point charge q placed at the
 1 Qq
centre F  q
4 o 8 o R 2
Note in this case the radius of small shell is not in to account so fig-a and fig-b gives the same result.
11. Uniform field lines and equipotential surfaces are perpendicular to each other
12. Powers of 10 are not significant so option A will have only two significant figures, in case of option
2 least count is different for all the three measurement so B is wrong, in option C the answer must
have 3 significant figures, D is correct
T t 0.5 5
14. 100  100  x100  % option A is correct and B is wrong
T t 40 4
g L T
100  100  2 100  1  2.5  3.5% option C is wrong and D is correct
g L T
15&16:
17 & 18:
Work done against atmosphere = Po hA
Work done against gravity in lifting the piston= mgh
 hAgh  gAh 2
Work done in expelling the liquid = 
2 2
Summing up all gives the total work done
mg
Also final pressure of the gas is Pf  Po 
A
mg
Initial pressure of the gas is Pi  Po    gh
A
Initial volume is hA , final volume is 2hA
mg mg
( Po    gh)(hA) ( Po  )(2hA)
Use Ideal gas equation A  A
T0 T
SR.IIT_CO-SC Page 4

CHEMISTRY
19. Conceptual
20.
   3 isomers 
 3 isomers 
 
  4 isomers 

3  3  4  10  total isomers 
21. Conceptual
22.
23.
24. Conceptual
25.
SR.IIT_CO-SC Page 5

26. Conceptual
27. Strongly activated aromatics are not used in Gattermann Koch formylation
28. Conceptual
29. Conceptual
30. A) Wolff-Kishner reduction
B) Clemmensen reduction
D) Mozingo reduction
31. B) No reaction (deactivated ring)
C) No reaction ( Due to SIR present)
32. Conceptual
33.
34. Conceptual
35. E2 Anti Elimination
36. E2 Anti Elimination
SR.IIT_CO-SC Page 6

MATHS
37. x  1 not there in domain
38.  x    2 x   ............   2019 x 
 1 1 
x ,
 2049 2019 
39. x  2, 3, 1 not differential
40.
41.
42. Sol : Put cos x  t
 e  f  t    f '  t  dt  e f  t   c
t t
43.
1
GI   cos 2016 x cos ec 2 xdx  2016 2016
dx
cos x
1
 cos 2016 x   cot x    2016 cos 2017 x   sin x   cot x  dx  2016 2016
dx
cos x
cot x
 c
cos 2016 x
SR.IIT_CO-SC Page 7

44.    
f x 2 xf  x   x 4 x 2  1
 xf  x   x f  x   x . x   x   x 2 
2
2 2 3 2
 
f  x  f  x
2
 x   x
2
 2
 2 2
x x
f  x
  x 2  k  f  x   x3  kx
x
45. From the given relations we get
f  x  2  f  x   3 2x
46. f   x   f  x   x  R  even
g x  g  x x  R odd
 x if x  1, 2 

47. f x   x if x   2,  


48.

f 1  x  y   f 1  x   e x e y  1  
  f x  e  k  f 1  x  k  ex
1 x
1 1 y

f  x  y   f  y   e e  1 x

But f  0   0, f  0   2
1
 f x  ex  x  1
f 1  x   ex  1 0  f is increasing
f    
f    
No of solutions of f  x   0 is 1
 f  x  cos x  1 
Also Lt  f  x   cos x  e x 1 1   e
1
Lt
 x o
x 0  e x 1 
49.
SR.IIT_CO-SC Page 8

50.
53,54.
SR.IIT_CO-SC Page 9

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Sec: Incoming.Sr.

IIT_CO-SC Date: 06-09-20

Name of the Student: ___________________ H.T. NO:

PHYSICS: PT-1 TO PT-4 SYLLABUS ONLY

CHEMISTRY: PT-1 TO PT-4 SYLLABUS ONLY

MATHEMATICS: PT-1 TO PT-4 SYLLABUS ONLY

SR.IIT_CO-SC Page. No. 2

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 3

Education consists mainly of what we have unlearned.

A) Displacement of the piston will be greater if sand is poured in the pan

SR.IIT_CO-SC Page. No. 4

Education consists mainly of what we have unlearned.

A) 6 102W B) 6 104W C) 6 105W D) 6 106W

6. A small sphere is charged uniformly and placed at A  u, v  so that at point B  8, 7  electric

C) Between 9th and 10th M.S.D. D) Exactly on the 10th MSD

Education consists mainly of what we have unlearned.

A) the rate of loss of heat of the cylinder to surrounding at 20oC is 2W

B) the rate of loss of heat of the cylinder to surroundings at 45oC is 12W

A) Volume of gas as a function of temperature is given by V  V0   exp  

B) Volume of gas as a function of temperature is given by V  V0  T0  e xp  2 T  T0  

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 7

Education consists mainly of what we have unlearned.

B) be normal to the direction of the field

D) have decreasing potential in the direction of the field

12. Choose correct statement(s)

A) the number of significant figures in 0.31103 is two

C) When 97.52 is divided by 2.54, the result is 38.393700000.

u  (8.0  0.2) 101 m

v  (4.0  0.2) 101 m

A) Order of magnitude of ‘u’ in meter is zero

B) Number of significant digits in ‘ v ’ when measured in ‘cm’ will be 3

SR.IIT_CO-SC Page. No. 8

Education consists mainly of what we have unlearned.

B) Percentage error in measurement of time period is 5 / 2 %

15. Identify the correct answer from the following options

SR.IIT_CO-SC Page. No. 9

Education consists mainly of what we have unlearned.

Paragraph For Questions 17 and 18:

17. Work done by the gas is:

C) P0 hA  0.5  gh 2 A  mgh D) P0 hA   gh 2 A  0.5mgh

18. Final temperature of the gas is:

SR.IIT_CO-SC Page. No. 10

Education consists mainly of what we have unlearned.

Find the correct structure of major product

SR.IIT_CO-SC Page. No. 11

Education consists mainly of what we have unlearned.

24. Find out major product in the following reaction is

SR.IIT_CO-SC Page. No. 12

Education consists mainly of what we have unlearned.

The correct structure of Q is

SR.IIT_CO-SC Page. No. 13

Education consists mainly of what we have unlearned.

Which statement is / are true about this reaction?

A) Mechanism during reaction is SNAr 2

B) Mechanism during reaction is benzyne

D) Reactivity will be high if F is present in place of Cl

A) NH 2 NH 2 , glycol / OH /  B) Zn – Hg | conc. HCl

SR.IIT_CO-SC Page. No. 14

Education consists mainly of what we have unlearned.

NaNO 2 , HCl conc.HNO 3

32. Which of the following statements is / are not true?