Sec: Incoming.Sr.IIT_CO.

SC Date: 07-06-20
Time: 3HRS Max. Marks: 180

Name of the Student: ___________________ H.T. NO:

07-06-20_CO SUPER CHAINA_Jee-Adv_WAT-47_SYLLABUS

PHYSICS: PRESENT WEEK(80%): MODERN PHYSICS: Bhor's model
,Atomic Physics (Excluding X-rays, Moseley's law, problems
based on photo electric effect, Matter waves - Debroglie's
wavelength, Davisson - Germer experiment )
PREVIOUS WEEK(20%): ALTERNATE CURRENT : Definition of
Mean and RMS values, AC measuring devices, Complete AC
including transformers and Generator
CHEMISTRY: PRESENT WEEK(80%): d-Block elements: General
Characteristics, Oxidation states, size, ionisation energies,
electrode potentials, Oxidation states, size, ionisation energies,
electrode potentials, Colour, Magnetic properties.
PREVIOUS WEEK(20%): Group-17 : General characteristics,
Chlorine – preparation, properties, uses, Preparation &
properties of hydrides & oxides, Preparation & properties of
oxoacids & bleaching powder, Inter halogens & pseudo halogens
MATHEMATICS: PRESENT WEEK(80%): De-Moivre's theorem, nth roots of
unity, Miscellaneous problems in Complex Numbers
PREVIOUS WEEK(20%): Rotation - Coni's Theorem, Rotation
form, Geometrical interpretation, Cube roots of unity
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 31 – 40) Questions with Integer Answer Type 3 0 10 30
Total 20 60

MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 51 – 60) Questions with Integer Answer Type 3 0 10 30
Total 20 60
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
PHYSICS Max Marks : 60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct
1. The photon radiated from hydrogen corresponding to 2nd line of Lyman series is
absorbed by a hydrogen like atom ‘X’ in 2nd excited state. As a result, the hydrogen
like atom ‘X’ excites to nth orbit. Then,
A) X  He , n  4 B) X  Li  , n  6 C) X He , n 6 D*) X Li , n 9
2. The electron in a hydrogen atom jump back from an excited state to ground state, by
16
emitting a photon of wavelength  0  , where R is Rydberg constant, In place of
15R
emitting one photon, the electron can come back to ground state by
1 1 1 15 R
A*)emitting three photons of wavelengths 1 ,  2 , 3 such that   
1  2  3 16

1 1 15 R
B*)emitting two photons of wavelengths 1 ,& 2 such that  
1  2 16

16
C)emitting two photons of wavelengths 1 ,& 2 such that 1   2 
15R
16
D)emitting three photons of wavelengths 1 ,  2 ,&3 such that 1   2  3 
15R
3. A neutron collides head-on with a stationary hydrogen atom in ground state. Which of
the following statements are correct? (Assume that the hydrogen atom and neutron has
same mass):
A*)If kinetic energy of the neutron is less than 20.4 eV collision must be elastic.
B)If kinetic energy of the neutron is less than 20.4 eV collision must be inelastic.
C*)Inelastic collision may be take place only when initial kinetic energy of the neutron
is greater than or equal to 20.4 eV.
D) Perfectly inelastic collision can not take place.
4. A He  ion and Li 2 ion both are in second excited state. Let aHe and aLi are the
acceleration of electron in their orbits and THe and TLi are the time periods of electron in
their respective orbits. Then choose the correct option(s).
A*) aLi  aHe B) aLi  aHe C) TLi  THe D*) TLi  THe
 Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
5. A neutron of kinetic energy 65 e.V collides inelastically with a singly ionized Helium
atom at rest. The neutron is scattered at an angle 900 with respect to its incident
direction. The allowed value(s) of energy of neutron after the collision is / are___
A*) 0.28 e.V B) 0.64 e.V C) 5.2 e.V D*) 6.36 e.V
6. An imaginary particle has a charge equal to the charge of electron but mass of
imaginary particle is 50 times the mass of electron. Now, consider that imaginary
particle moves in circular orbit around a nucleus. The charge of nucleus is +4e, and
nucleus is assumed to be at rest. Assume mass of nucleus is very large as compared to
the mass of imaginary particle moving around it and Bohr theory is applicable.
Choose the correct option(s).
n 2 h 2 0
A*) The radius of nth orbit is200 , where m is mass of electron, h is Planck
 me2
constant, e is charge of electron.

B*) If all atoms are at 16th excited state then during de-excitation till 10th excited state
the total maximum number of possible wavelengths emitted is 21.
C*) The wavelength of photon emitted when transition takes place from third excited
state to ground state is 1.21 A0 .
D) Since mass of imaginary particle is different from the mass of electron so the
velocity of imaginary particle and the electron (if revolves around the same nucleus
instead of the imaginary particle) in nth orbit will be different.
7. An electron is excited from a lower energy state to a higher energy state in a hydrogen
atom. Which of the following quantities decrease as a result of excitation?
A*)potential energy B*) angular speed C*) kinetic energy D) angular momentum.
7. The wavelengths and frequencies of photons in transition 1, 2 and 3 for a hydrogen
like atom are (v1, v2 v3) and (1 ,2 ,3), respectively. Then

vv 1 2
A) v3 = v1 + v2 B*) v3  v 1 v2 C*) 3 = 1 + 2 D)  3  .
1 2 1   2
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
9. Assume that a sample of Hydrogen atoms is in energy state n1. It absorbs radiation of
wavelength 0 and consequently emit radiations of 6 different wavelengths of which
only two wavelengths are longer than 0.
A*)The final excited state of the atoms is n = 4
B*)The initial state of the atoms may be n1 = 2
C)The initial state of the atoms may be n1 = 3
D*)There are three wavelengths belonging to Lyman series in emitted radiation.
10. A single electron orbits a stationary nucleus of charge +Ze, where Z is a constant and e
is the magnitude of electronic charge. It requires 47.2 eV to excite the electron from the
second Bohr orbit to third Bohr orbit.
A)The value of Z is 6.
B*)The energy required to excite the electron from 3rd to 4th Bohr orbit is 16.53 eV.
C*)The smallest wavelength of lymann series of this atom is 36.5 Å.
D)The value of Z is 3
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
11. In a hypothetical system a particle of mass m and charge -3q is moving around a very
heavy particle having charge q. Assuming Bohr’s model to be true to this system, the
xq 2
orbital speed of mass m when it is nearest to heavy particle is . If x is an integer,
2 0 h
• 3
its value is__________ : (Neglect gravitational force)
12. A hydrogen like atom (atomic number Z) is in a higher excited state of quantum
number n. The excited atom can make a transition to the first excited state by
successively emitting two photons of energy 10.2e.V and 17.0 eV respectively.
Alternately, the atom from the same excited state can make a transition to the second
excited state by successively emitting two photons of energies 4.25 eV and 5.95 eV
respectively. Determine the value of ‘n’. (Ionization energy of H-atom 13.6eV ) • 6

13. A neutron is moving with speed ‘v’ towards a hydrogen atom which is in ground state.
If the hydrogen atom is also moving towards neutron with same speed, then minimum
• 5
KE of each so that an inelastic collision may occur will be …............. eV.
(Approx your answer to nearest integer)(Take masses of both are almost equal)
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
14. When an electron de-excites from an orbit say n1 to n 2 in Li++ ion, it gives rise to a
spectral line which has the same wavelength as some spectral line in the hydrogen
atom then n1 and n 2 must be multiples of • 3

15. A neutron strikes a hydrogen atom which is initially at rest and free to move. The
initial speed of the neutron is v0 . After the collision both neutron and the H atom move
making 30° angle with the initial velocity of the neutron. Also the H atom is found to
get excited to first excited state. If the initial KE of neutron is ‘x’ times first excitation
energy of the H atom, find the value of ‘x’ (assume mass of neutron = mass of H
atom) • 3

16. Hydrogen atoms in a gas chamber in ground states are excited by monochromatic
radiation of wavelength 975 Å. The number of lines in the resulting spectrum will be • 6

17. A moving hydrogen atom makes a head-on collision with another stationary hydrogen
atom. Before collision both atoms are in their ground states, and after collision they
move together. The minimum value of the kinetic energy of the moving hydrogen
atom is 13.6  a   e.V. where a and b are positive integers. find a+b.
1 • 4
 b

18. Consider a sample of hydrogen like atom in nth excited state . When these excited
atoms make a transition to ground state, the most energetic photons have energy
Emax = 51 eV and the least energetic photons have energy Emin = 2.6 eV. The atomic
number of atom is z. find the value of z+n. • 5

19. A hydrogen like atom of atomic number Z is in an excited state of quantum number 2n.
It can emit a maximum energy photon of 204 eV. If it makes a transition to quantum
state n, a photon of energy 40.8 eV is emitted. Ground state energy of hydrogen atom
• 4
is –13.6 Ev. The value of atomic number Z of this atom is__________
20. The binding energy of an electron in ground state of He atom is equal to 25.6 e.V. if
the energy required to remove both the electrons one after the other from the atom is
• 8
10x e.V. the value of x is________
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
CHEMISTRY Max Marks : 60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct
21. In which compound does vanadium have on oxidation number of +4?

A) NH 4VO2 B) K 4 V  CN 6  C) VSO4 D*) VOSO 4

22. Which is/are correct

A)Cr(VI) is more stable then Mo((VI) and W(VI)

B*)Sc does not exhibit variable oxidation states.

C*)The transition metal ions containing empty d-orbital’s e.g Sc3 and Ti 4 ions or

completely filled d-orbital’s e.g Cu  , Ag  , Zn 2 , Cd 2 , Hg 2 etc  in dry state are colourless

D*) ECu0 2
/ Cu
is +ve among EM0 2
/M
of 3d series elements as energy required to transform

Cu  s   cu 2  g  is not balanced by hydration enthalply.

23. Which of the following are paramagnetic?

A*) Cu 2 B*) Fe2 C*) Fe3 D*) Cr 3

24. The correct statements about some of the ions of 3d-series in aqueous solution

A*)Cr 2 is better reducing agent than Fe2

B*)Co3 is better oxidizing agent than Fe3

C*)When Fe3 is used as oxidizing agent, it attains 3d 6 electronic configuration

D*) Cu is the only metal in 3d series, which is not having ability to displace hydrogen

as H 2 from acid

25. Transition elements show magnetic moment due to spin and orbital motion of
electrons. Which of the following metallic ions have almost same spin only magnetic
moment?
A*) Co2 B) Cr 2 C) Mn 2 D*) Cr3

Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
26. In the form of dichromate, Cr(VI) is a strong oxidizing agent in acidic medium but
Mo(VI) in MoO and W (VI) in WO are not because

A)Cr (VI) is more stable than Mo VI andW VI .

B*)Mo(VI) and W(VI) are more stable than Cr(VI).

C*)Higher oxidation states of heavier members of group-6 of transition series are more
stable.
D)Lower oxidation states of heavier members of group-6 of transition series are more
stable.
27. Transition elements form binary compounds with halogens. Which of the following
elements will forms MF type compounds?

A) Cr B) Co C) Cu D) Ni

28. Which of the following will not act as oxidizing agents?

A) CrO3 B)* MoO3 * WO

C) 3 D) CrO42

29. Which of the following is/are true?

A) All halogens exist as diatomic gaseous molecules at ordinary temperature

B) Bromine dissolves in chloroform imparting blue colour

C) Chlorine monoxide is evolved when KClO3 is treated with conc. H 2 SO4

D*) Chloride ion is confirmed by chromyl chloride test

30. The state of hybridization in the anionic part of solid Cl2O6 is

A) sp 3d 2 B) sp 3d C*) sp3 D) sp 2

SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. An ion ' M n ' , (at no:26) has paramagnetic moment of 4.8 BM. Then the value of ‘n’
• 2
is_______________________

32. How many of the following are pseudohalogens?

{Azidocarbondisulphide, Isocyanide ion, Fulminate ion, Tellurocyanante ion,
Oxycyanogen, Selenocyanogen.} • 3
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
33. What is the oxidation number of Cl2 in final product formed due to oxidation in it
when Cl2 reacts with hot and concentratedNaOH? • 5

34. Select the number of correct matches for the outermost electronic configuration for d-
• 7
block elements.____________

Nb 5s1 4d 4 (group-5) W  6s 2 5d 4 (group-6)

V 4s2 3d 3 (group-5) Ru  5s1 4d 7 (group-8)

Rh 5s1 4d 8 (group-9) Pd  5s 0 4d 10 (group-10)

Pt  6s1 5d 9 (group-10)

35. Given the species: Mn3 , Co3 , Ti 2 ,V 2 , Cr 2 , Fe 2

(a) Number of species which are strong oxidizing agent =X

(b) Number of species which are strong reducing agents and will liberate hydrogen
from dilute acid=Y

Hence, find the value of 3X-Y. • 2

36. Find the number of colourless species among the following:

Sc 3 , Ti 4 ,V 3 , Zn 2 , Mn 2 , Fe3 , Ni 2 , Cu 2 , Cr 3 • 3

37. The number of species which are paramagnetic

Ti 3 ,V 3 , Cu  , Sc 3 , Mn 2 , Fe3 , Co 2 • 5

38. Number of ions which gives blue colour in aqueous state:

V 4 , Ni 2 , Ti 3 , Co 2 , Fe 3 , Cu 2 • 2

39. Find the number of species from the following which has magnetic moment value of
1.73 B.M. Fe2 , Cu 2 , Ni 2 , Sc 2 . • 2

40. How many unpaired electrons are present in Cu  ? • 0

Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
MATHEMATICS Max Marks : 60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct
z  z 1
41. z  x  iy;   z ; x, y,   R, then which of the following option(s) is/are correct ?
zz2
A*)Range of "" is (1 , ),as "z" varies

B) Range of "" for which more than one value of z is possible is 1,  )

C) "z" must be a real number

D)Range of "" for which exactly one value of z is possible is (1, 1

42. If z1 , z 2 , z3 are complex non-zero numbers satisfying z12  z 22  z32  z1 z 2  z 2 z3  z3z1  0

and z1 z 2  z3  z 2 z3  z1  z3 z 2  z1  0, then which of the following can be true ?
1
A*) z1  1  z 2  1  z3  1 B*) z1  1  z 2  1   z3  1
2
C*) z1  z 2  z3 D*) arg ( z 2  z1   arg  z3  z1   0
1 1 1 1
43. If     22  a, b, c, d  R  "  " is a non-real cube root of unity, then
a  b c d
which of the following statement(s) is/are true ?
1 1 1 1
A*) a  1  b  1  c  1  d  1  2

1 1 1 1
B*)     2 if defined
a 1 b 1 c 1 d 1
1 1 1 1 2
C)     if defined
a  b  c  d b  a  c  d c  a  b  d d  b  c  a abcd
1 1 1 1 2
D*) a  abcd  b  abcd  c  abcd  d  abcd  abcd if defined

44. If z  cis is a root of a 0 x n  a1x n 1  ......  a n  0, then which of the following must be
true? "a i "  R, i 

A) a 0  a1 sin   a 2 sin 2  .........  a n sin n   0

B*) a 0  a1 cos   a 2 cos 2  .........  a n cos n   0

C*) a 0 cosn   a1 cos  n  1   a 2 cos  n  2    .....  a n  0

D) a 0 sin n   a1 sin  n  1   a 2 sin  n  2    ...........  a n  0

Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P

45. If x r  cis  r 
for 1  r  n  r, n  N , then which of the following option(s) is/are true ?
2 
(where Re(z) and Im(z) denotes real and imaginary part of a complex number )
 n
  n 
A*) Lim Re   x r   1 B) Lim Re   x r   0
n  n 
 r 1   r 1 

 n   n

C) Lim Im   x r   1 D*) Lim Im   x r   0
n  n 
 r 1   r 1 

46. If 1 ,  2 ,......, 10 are the 10 non-real roots of the equation x11  1  0 , then which of the
following options are correct ?
A) 1   2  .....  10  0 B*) 1   2  .....  10  1
1 1 1 1 1 1 11
C*) 1    1    ........  1    5 D) 
1  1 1   2
 ........  
1  10 2
1 2 10

47. Let “n” be a positive integer and a complex number with unit modulus is a solution of
the equation z n  z  1  0 , then the value of n can be
A*) 62 B*) 2021 C*) 221 D) 2020
48. Let z1 , z 2 , z3 ,......, z n be all the distinct non-real complex numbers which satisfies z6  1
(or)  z  1  1 , then which of the following statement(s) must be correct ?
6

2 2
A*) 0  zi  z j  7 for i  j B) 3  zi  z j  7 for i  j
2 2
C*) 0  zi  z j  9 for i  j D) 1  zi  z j  9 for i  j

49. If cos   cos   cos   0  sin   sin   sin , then which of the following option(s) is/are
correct ?
* cos  2       cos  2       cos  2       3
A)
*
B) sin  2       sin  2       sin  2       0

C) cos  23    cos  23    cos  23   

3
2

D*) sin 2   sin 2   sin 2   3

2

2k 2k 
If S    sin
10
50.  i cos  then
k 1  11 11 
__
1
A*) S S = 0 B*) SS =1 C*) S 1  i  D) S S= 0
2
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
51. Sum of absolute values of the real parts of the common roots of x12  1  0 and
• 2
x 4 x 2 1 0 is _____________

Number of complex numbers satisfying the equation z 2  3z   z   z is __________

2
52. • 1

53. • 8
Number of distinct complex numbers “z” satisfying z6 z is_______________

54. If principal argument of a complex number lies in  ,, the principal argument of
6  6   • 9
the complex number "2sin  i  2  2 cos  " is " " then  ______________
5  5  10

55. Number of purely imaginary roots of the equation, x8  28x 6  70x 4  28x 2  1  0 is • 8

56. Number of common roots of the equations z3  1  i  z 2  1  i  z  i  0 and z 2019  1  0 is

• 2

x
 
x
57. The least positive integral value of “x” for which 3 i  sin  2 x  1 is "  " then
48

 • 4
=________________
6

58. If the expression z5  32 can be factorised into linear and quadratic factors over real
coefficients as z5 32  z 2z2 pz 4z2 qz 4 , where p q , then the value of
• 8
p2 2q is______________

59. Area of the quadrilateral formed by the roots of the equation x 4  2x 2  4  0 in argand
• 3
plane is  , then   = _________ ([.] denotes G.I.F )

2015
1 2  1 
60. Let '  ' be the non real cube root of unity and   b      b2   where
4 2  4 2
• 1
b  R , then maximum value of  b   ----------------- ([.] denotes G.I.F )
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
SOLUTIONS
PHYSICS
1 1  1 1
1. 13.6  2  2   13.6  z 2  2  2 
1 3  3 h 
2. E14  E1 2  E23  E3 4
1  1 
  
 0 1  2 3
 1
3. KE Lost = 13.6 1    10.2
 4
Z3 n3
4. a , T 
n4 Z2
5. Use conservation of linear momentum and energy
m0v 2 1 ze 2
6.  (Where m0  50m ) ……. (i)
rn 4 0 rn2
n h
m0vrn  ……. (ii)
2
n h 0
2 2
rn 
200 me 2
13.6 z 2
En   50eV
n2
E4  680 eV
E1  10880 eV
 E  E4  E1  10,200 eV
1240
  1.21 A
E
1
7. U (with negative sign)
n2
1
K 2
n
1
v
n
and L  n
Therefore, as n is increased U (P.E.) and L (angular momentum) increase while K
(K.E.) and v (linear speed) decreases.
Further linear speed is decreasing and radius is increasing. Therefore angular speed (
= v/r) will also decrease.
8. E3 = E1 + E2
 hv3 = hv1 + hv2
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
or v3 = v1 + v2
hc hc hc
Further  
 3 1  2
1 1 1
 
 3 1  2
1 2
or 3  .
1   2
n(n  1)
9. 6  n4
2
If the initial state were n = 3, in the emission spectrum, no wavelengths longer than 0
would have occurred. This is possible if initial state were n = 2
n=4
3
2

 (A), (B) and (D) 1

 1 1
10. 47.2  13.6 Z2  2  2 
2 3 
Z = 5.
also E  13.6  (5) 2 
1 1 
 2   16.53eV
3 4 
2

hC
and  13.6Z2

  = 36.5 Å.

h kq  3q  mv 2
11. mVr  ; 
2 r2 r
1 1  1 1  3
12. Z 2   2   2; Z 2   2  
4 n  9 n  4
13. k  k  10.2eV k  5.1eV  5 eV
1  1  
14. For Li++,  z 2  2  2  with z 2  9
  n1 n 2 
1  1    1 1  1 1 1 1
For hydrogen atom,   2  2  if 9  2  2   2  2  
  n3 n 4   n1 n 2  n 3 n 4  n1 / 3   n 2 / 3 
2 2

which implies n1 and n 2 should multiples of 3.

Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
15.
u1

m 
v0 Rest m 
m
before after
v1

3
mv0 = 2mv ' ---------------(1)
2
Loss in KE = First excitation energy
1 2 1
mv0   2m v  2  E
2 2
2
1 2 1 v
mv0  2m 0  E
2 2 3
1 2 2 
mv0 1  3  E
2  
1 2
mv0  3E
2
z2
16. E n  13.6
n2
With given wave length
Particle will jump to 4th orbit
So, number of lines will be 4C2 = 6.
17. Conceptual
1 1
18. Given 51= 13.6  2  2  Z 2
1 n 
 1 1
2.6 = 13.6   2 Z 2
 (n  1) n 
2

Z=2, N=4 this corresponds to 3rd excited state

 1 1 
19. E n 2  n1    1 3 .6 eV  Z 2  2  2 
 n2 n1 
 1 
So, 2 0 4   1 3 .6 Z 2
  1
 4n 
2

2 1 1 
and 40.8 = 13.6 Z  2  2 
 4n n 
taking the ratio , n  2, Putting in above equation Z= 4
 1 1
Emin  13.6eV  42  2  2   10.58eV
4 3 
20. Conceptual
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
CHEMISTRY
2 2
21. VOSO4  VO  SO 4

So oxidation state of V is +4.

24. 0
ECr 3
/ Cr 2
 EFe
0
3
/ Fe2
 ECo
0
3
/ Co 2

29. The first statement is false because F2 and Cl2 gases, Br2 is liquid while I 2 is a solid.
Bromine dissolves in chloroform imparting reddish-brown colour. Chlorine dioxide is
evolved when KClO3 is treated with conc. H 2 SO4
30. Fact
32. Azidocarbondisulphide  SCSN3 2 , Oxyeyanogen  OCN 2 and Selenocyanogen  SeCN 2
33. 3Cl2  6 NaOH 
hot
 5 NaCl  NaClO3  3H 2O

35. X  2 : Mn3 , Co3

Y  4; Ti 2 ,V 2 , Cr 2 , Fe 2

36. Sc 3 , Ti 4  d 0  , Zn 2  d 10  .

37. Ti 3 ,V 3 , Mn 2 , Fe3 , Co 2

38. V 4 , Cu 2

39. Cu 2 , Fe 2

MATHS
1
41. If   0  complex number is   i 
2
2x  1 2x  1
If   0   x  
2 2x
    1,   and if   0  infinite complex No’s
  1  2 real No’s
42. z1 , z1 , z3 can be all equal (or) can form an equilateral triangle with centroid as origin
A & C) z1  z1  z3 D) z1 1; z 2   ; z3  2
B)

If z3  z1  z1  1  z3  1 and if z 2  r  0  i 
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
1
1  r   1 r2  r
2
9
 r 2  3r   r 2  r  1
4
5
r
16
1 1 1 1 2
43. If  is a root for    
ax bx cx dx x
  is also a root
2

 2x 4  x 3  a  b  c  d   x  abc  bcd  acd  abd   2abcd  0

 Put x  
 a  b  c  d  2abcd & 2  abc  bcd  acd  abd
 1 is also a root & product of the roots is -abcd
 , 2 ,1,  abcd are the roots
44. z  e1   a r sin r    a n r  sin r  0
&  a r cos r    a n r  cos r  0
 a1 sin   a 2 sin 2  .....  a n sin n   0
& a 0 sin n   a1 sin  n  1   .....  a n 1 sin   0
n
1 1 1 
45.  x r  cis  2  4  ......  2n  = cis  1 as n  
r 1

46. x n 1

 x n 2  ......  1   x  1  x   2  ......  x   n 

 
log x n 1  x n 2  ......  1  log  x  1   log  x   2  ......  x   n 


 n  1   n  2   .....  1  1  1  .......  1
1  1  1  ....  1 1  1 1   2 1 n


11  1  1  1  .......  1  5
2 1  1 1   2 1  10
47. z  1  1  z   or 2
 n  3k  2
48.

 3 3i 
 zi  z j  1 & zi  z j  7   &  
 2 2 
 z i  z j  0 for z i   & z j  
3 3i
zi  z j  3 for zi  zj  
2 2
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s
49. ei   ei   ei   0 & ei   ei   ei   0
3
 cos8  cos8  cos8  0 & cos 2  cos 2  cos 2  0  sin 2   sin 2   sin 2  
2
e
i  
e 
i  
e 
i  
0
i  
e3i x  e3i   ei   3e
 e
i 2  
e
i 2 
e
i 2  
3
 2k 
10
50. S  i cis    i  1
k 1  11 
 S  i, S  i
51. x 4

 x2  1 x2 1  x6 1 
2 4  2    4  
 cis , cis , cis   , cis   are the roots
6 6  6   6 
52. x 2  y2  2ixy  3x  3iy  x 2  y2  2ixy  x 2  y2
 4ixy  3x  3iy  x 2  y 2
3x  x 2  y 2  x  0 & 4xy  3y  0  y  0 or 4x  3  0X
 3x  x
 x0
53. z  0  or  1 if z  0  z  0 } 1 root
If z  1 z 7  1 } 7 roots
6  3  3  3 3 
54. sin  i  2 cos 2   2 cos  sin  i cos 
5  5  5  5 5 
3        
 2 cos  cos    i sin  
5   10   10  
3
but cos 0
5
   9
 arg  
16 10
1
55. x 2  t & t   m and solve it
t
(or)
1  x 8  1  x 8  0
8
 1   1   2k   
    1   cis   ; k  0,1, 2, , 7
 1   1   8 
cis  1 
  i tan
cis  1 2
56.
 
x
57. 3 i must be real  x  6k
x
 sin  1 if x is multiple of 24
48
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Key & Sol’s

 
x
 3i  2 x  x  24, 48, 72,.......
 24 is the least possible value
 2k   2 8 
58. z5  32  2cis    p  2 cos  cos 
 5   5 5
 4 6 
q  2  cos  cos 
 5 5 
2 4
p  4cos ; q  4cos
5 5
p  16 cos 70 ; q  4 cos 360
2 2 2

 
2
p2  5 1 ; q   5 1
 p 2  2q  6  2 5  2 5  2  8
i i i i  i 
59. x 
2
2e 3 x 2e 6 ,  2e 6 , 2e 6 ,  2e 6
1 3
Area  4   2  2 3
2 2 
1 
1   4b  1   4b  2    1
2 2
60.
32  
3  61
32b 2  24b  6  32  b 
8
32b  24b  26  0
2