21-06-20 - Jee-Adv - CAT-44 - QP - KEY

Sec: Incoming.Sr.IIT_CO.
SC Date: 21-06-20
Time: 3HRS Max. Marks: 240
Name of the Student: ___________________ H.T. NO:
21-06-20_CO SUPER CHAINA_Jee-Adv_CAT-44_SYLLABUS

PHYSICS: PRESENT WEEK (50%):Characterstic and continuous X-rays, Bragg's
Law, Moseley's law, Atomic nucleus and its properties, Binding energy
and its calculation (Exclude: Nuclear Reactions, Law of radioactive
decay; Decay constant; Half-life and mean life; α, β and γ radiations;
Energy calculation in these processes Fission and fusion processes.)
PREVIOUS WEEK (25%):Photo Electric Effect,radiation,Hertz and
Lenard's observations,radiation pressure, Matter waves: Debroglie's
wavelength, Davisson - Germer experiment (Excluding: X-Rays)
CUMULATIVE (25%): EMI
CHEMISTRY: PRESENT WEEK (50%):bonding in metal carbonyls, structures of
mononuclear & dinuclear metal carbonyles, CFT & stability of
complexes, isomerism in complexes
PREVIOUS WEEK (25%): CO-Ordination Compounds : Introduction,
Definition of important terms related to co-ordination compound,types
of ligands, IUPAC rules, Nomenclature, Werner theroy and Sidgwick
theory, VBT
CUMULATIVE (25%): 1) Pinacole-pinacolone reac. 2) Oxides of
nitrogen and phosphorus 3) Types of half cell & batteries
MATHEAMTICS : PRESENT WEEK (50%):P & C: Fundamental Principles of counting,
Linear permutations, circular permutations, Number of integral
divisors
PREVIOUS WEEK (25%):Binomial theorem for a positive integral
index, Constant term, Numerically greatest term, Properties of the
Binomial coefficients,
CUMULATIVE (25%): AREA
Narayana IIT Academy 21-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-44_Q’P
Time: 3:00 Hour’s IMPORTANT INSTRUCTIONS Max Marks: 240
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 16) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 17 – 20) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80
CHEMISTRY:
Sec – II(Q.N : 37 – 40) 4 -2 4 16
Total 20 80
MATHS:
Sec – II(Q.N : 57 – 60) 4 -2 4 16
Total 20 80
PHYSICS Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1. The path of photoelectrons emitted due to electromagnetic radiation incident on a
sample of material A, is found to have a maximum bending radius of 0.1m in a
magnetic field of  
2 / 3 104 T . When the radiation is incident normally on a double
slit having a slit separation of 0.1mm, it is observed that there are 10 fringes in a width
of 3.1cm on a screen placed at a distance of 1m from the double slit. Find the work
function of the material in eV?
0
Given that mass of the electron  0.5 MeV / c 2 , hc  12400 eV  A .
4 1
2. The wavelengths of k x-rays of two metals ‘A” and ‘B’ are and
1875R 675R
respectively, where ‘R’ is rydberg constant. The number of elements lying between‘A’
and ‘B’ excluding A & B according to their atomic numbers is
3. Photons of energy 5 eV are incident on the cathode. Electrons reaching the anode have
kinetic energies varying from 6eV to 8eV. Find the work function of the metal in eV.
4. An   particle and a proton are accelerated from rest by a potential difference of

100V. After this, their de Broglie wavelengths are  and  p , respectively. The ratio
p
is n , find ‘n’

5. A sliver sphere of radius 1cm and work function 4.7eV is suspended from an
insulating thread in free-space. It is under continuous illumination of 200 nm
wavelength light. As photoelectrons are emitted, the sphere gets charged and acquires
a potential. The maximum number of photoelectrons emitted from the sphere is A 10 z
0
(where 1  A  10 ). The value of ‘z’ is ( hc  12400 eV  A )
6. Two parallel conducting rails are connected to a source of emf E and internal
resistance r. Another conducting rod of length l having negligible resistance lies at rest
and can slide without friction over the rails. A uniform magnetic field B isapplied
perpendicular to the plane of the rails. At t=0, the rod is pulled along therails by
applying a variable force F. The velocity of the rod is observed to be V  V0 cos t  .
Then the average power (in watt) spent by the force over 1 cycle is4n. Find n. (Given:
B  2 Tesla, r  2  10 4 , v0  2m 1 , l  2m )
7. A proton is fired from very far away towards a nucleus with charge Q  120e , where ‘ e
’ is the electronic charge. It makes a closest approach of 10 fm to the nucleus. The de
Broglie wavelength (in units of fm) of the proton at its start is: (take the proton mass,
1
mp   5 / 3 1027 kg ; h / e  4.2  10 15 J .s / C ;  9  109 m / F ; 1 fm  1015 m )
4 0
8. The work functions of Silver and Sodium are 4.6 and 2.3 eV, respectively. The ratio of
the slope of the stopping potential versus frequency plot for Silver to that of Sodium is
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. A very long solenoid perpendicular to the page generates a downward magnetic field
whose magnitude increases with the time. A conducting wire loop around the solenoid
contains two identical bulbs A and B which are glowing. Two points diametrically
opposite on the wire loop are shorted with another wire lying to the right of bulb B in
the plane of the page as shown in fig. After the shorting wire is inserted
A) Bulb A goes out and bulb B dims

B) Bulb A goes out and bulb B gets brighter
C) Bulb B goes out and bulb A dims
D) Bulb B goes out and bulb A gets brighter
10. A circuit shown consists of two resistances R and 3R, two capacitors each of
capacitance C, two inductors each of inductance L, an ideal battery of electromotive
force ‘  ’, an ideal voltmeter and a switch. Initially the switch is closed and the circuit
is in steady state. Now the switch is opened.
A) The voltmeter reading immediately after the switch is opened is 2

L 2
B) The total heat dissipated in the resistor 3R after the switch is opened is 2
2R
C) The voltmeter reading immediately after the switch is opened is 4
L 2
D) The total heat dissipated in the resistor 3R after the switch is opened is
R2
11. Binding energy per nucleon verses mass number curve for nuclei is shown in the
figure. W, X, Y and Z are four nuclei indicated on the curve. The process that would
release energy is
A) Y  2 Z B) W  X  Z C) X  Y  Z D) W  2Y
12. Which of the following statement(s) is/are correct?
A) The rest mass of a stable nucleus is less than the sum of the rest masses of its
separated nucleons.
B) The rest mass of a stable nucleus is greater than the sum of the rest masses of its
separated nucleons.
C) In nuclear fission, energy is released by fusing two nuclei of medium mass
(approximately 100 amu)
D) In nuclear fission, energy is released by fragmentation of a very heavy nucleus
13. Assume that the nuclear binding energy per nucleon (B/A) versus mass number (A) is
as shown in the figure. Use this plot to choose the correct choice(s) given below
A) Fusion of two nuclei with mass numbers lying in the range of 1<A<50 will release
energy.
B) Fusion of two nuclei with mass numbers lying in the range of 51<A<100 will
release energy.
C) Fission of a nucleus lying in the mass range of 100<A<200 will release energy
when broken into two equal fragments.
D) Fission of a nucleus lying in the mass range of 200<A<260 will release energy
when broken into two equal fragments.
14. An X-ray tube is operating at 50kV and 20mA. The target material of the tube has
mass of 1kg and specific heat 495 J kg 1 0C 1 . One percent of applied electric power is
converted into X-rays and the remaining energy goes into heating the target. Then,
A) A suitable target material must have high melting temperature
B) A suitable target material must have low thermal conductivity
C) The average rate of rise of temperature of the target would be 2 0C s 1
D) The minimum wavelength of X-rays emitted is about 0.25 1010 m .
15. Which of the following statements are correct for an X-ray tube?
A) On increasing potential difference between the filament and target, photon flux of
X-rays increases
B) On increasing potential difference between the filament and target, frequency of X-

rays increases
C) On increasing filament current, cut-off wavelength increases
D) On increasing filament current, intensity of X-rays increases

16. A non-conducting ring of mass m and radius R has a charge Q uniformly distributed
over its circumference. The ring is placed on a rough horizontal surface such that the
plane of the ring is parallel to the surface. A vertical magnetic field B  B0t 2 tesla
perpendicular to plane of ring is switched on. After 2 second from switching on the
magnetic field the ring is just about to rotate about vertical axis through its centre and
perpendicular to its plane. Then
A)the induced electric field is quadratic in time ‘ t ’
B) the torque on the ring due to magnetic field is B0QR 2t
C) until 2 seconds, the friction force does not come into play
2B0 RQ
D) the friction coefficient between the ring and the surface is
mg
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.
Paragraph for Question Nos. 17 &18
The X-ray spectrum of a metallic target is as shown. Two characteristic X-ray spikes
shown has K X-ray and K  X-ray. (Given Rydberg constant R  1.09 107 m1 ,
0
hc  12400 eV  A )
17. Choose the correct statement(s)

A) Accelerating potential difference for bombarding electrons is 105 eV
B) Accelerating potential difference for bombarding electron cannot be determined
C) Wavelength of K X-ray is 0.230 A
D) Wavelength of K  X-ray is 0.180 A
18. The atomic number of target atom is
A) 74 B) 73 C) 72 D) 71
Paragraph for Question Nos. 19&20
Two capacitors of capacitance C and 3C are charged to potential difference V0 and 2V0
respectively and connected to an inductor of inductance ‘L’’ as shown in the figure.
Initially the current in the inductor is zero. Now the switch ‘S’ is closed
19. The maximum current in the inductor is

3V0 3C 3C 3C C
A) B) V0 C) 2V0 D) V0
2 L L L L
20. Potential difference across capacitor of capacitance ‘C’ when the current in the circuit
is maximum
V0 3V0 5V0 7V0
A) B) C) D)
4 4 4 4
CHEMISTRY: Max. Marks: 80

SECTION – I
(INTEGER ANSWER TYPE)
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. Find the sum of optically active isomers of both  Pt  gly 2 Cl 2  and  Co  en 2 Cl 2 
22. How many molecules in which dz 2 orbital involved in their hybridization of central
atom?
4
XeF2 , XeOF4 , BrCl3 ,  Ni  CN 4  ,  NiCl4  ,  Fe  CN 6 
2 2
23. Co forms binuclear complex with a sigma bond between two Co atoms. Consider that
metal carbonyls follows EAN rule. The complex can be written as CO 2 (CO) x . Find
the value of x ?
24.
How many products are obtained in the above reaction.
25.
In product P, functional group is attached to X numbered carbon, and degree of

unsaturation is Y. Then (Y-X) is
26. How many of the following statement(s) is/are correct?
(A) Colourless, diamagnetic N 2O 4 has a weak N-N bond that can readily dissociate to
give the brown paramagnetic NO 2
(B) N 2O5 has N-O-N bent bond in gaseous state and consists of NO 2 and NO3 ions in
the solid state.
(C) Nitric oxide is formed by the action of lightening on atmospheric N 2 and O 2 . This
NO after oxidized to NO 2 contribute to the problem of acid rain
(D) Ammonia is reacted with oxygen using a Platinum-Rhodium gauze catalyst to

form nitric oxide, however in absence of catalyst NH 3 can be oxidised to form N 2 , as
4NH 3  3O 2 
 2N 2  6H 2O
(E)Sodium on reaction with N2O5 forms a paramagnetic species
27. The CFSE for octahedral low spin complex for d 4 electronic configuration is 'x' cm-1,
x
the value of
700
[ Dq  2100 cm 1 , Pairing energy = 28,000 cm-1]

28. How many compounds show geometrical isomerism?
 
 Co  NH 3 4 Cl 2  ,  Pt  Cl  Br  H 2O   NH 3   ,  Cr  en 2 ClBr  ,  Co  NH 3 3 Cl3  ,
 
 Co  en 2 Cl 2  ,  Co  NH 3 4  H 2O  Br  
SECTION – II
29. Which of the following statement is correct?
A) Cr(CO) 6  Fe(CO)5  Ni(CO) 4 (Order of increasing CO bond strength)
B) [V(CO)6 ]  [Cr(CO) 6 ]  [Mn(CO) 6 ] (order of increasing M-C bond strength

where M is central metal atom/ion)
C) [V(CO)6 ]  [Cr(CO)6 ]  [Mn(CO) 6 ] (Effective atomic no)
D) [V(CO)6 ]  [Cr(CO) 6 ]  [Mn(CO) 6 ] (Order of increasing CO bond strength)
30. Which of the following IUPAC names are correct?
A) K 2 [OsCl5 N] : Potassium pentachlordonitridoosmate (VI)
B) [Fe(NH 4C5  C5H 4 N)3 ]Cl 2 : Tris(bipyridine)iron(II) chloride
C) [Fe(C5 H 5 ) 2 ] : bis( 5 -cyclopentadienyl)iron(II)
D) [Pt(py) 4 ][PtCl 4 ]: Tetrapyridineplatinum(II) tetrachloridoplatinate(II)
31. Which of the following statement is incorrect?
A) geometrical isomerism is not observed in complexes of co-ordination number 4

having tetrahedral geometry
B) square planar complexes do not show optical isomerism
C)the square planar complex of general formula Ma 3b or Mab3 exhibits cis-trans
isomerism
(where M is central metal and a and b are monodentate ligands)
D) the platinum glycinato complex [Pt(Gly) 2 ] doesn't show geometrical isomerism.
32. Identify the correct statement(s)
A) [NiCl4 ]2 as well as [Ni(CO) 4 ] are paramagnetic
B) CFSE for [Ti(H 2 O)6 ]3 is 0.4  0
C)  0 increasing order is [CrCl6 ]3  [Cr(NH 3 )63  [Cr(CN)6 ]3
D) In spectro chemical series, halide ions are arranged as I   Br   Cl  F
33. Which of the statement(s) is/are true?

A) In metal carbonyl complexes, C-O bond length increases compared to that in CO
molecule
B) The pair of compounds [Cr(H 2O) 6 ]Cl3 and [CrCl3 (H 2O)3 ].3H 2 O show hydrate
isomerism
C) d z2 orbital of central metal atom/ion is used in dsp 2 hybridization
D) Facial and meridional isomers associated with [Ma 3b3 ]n  type complex compound,
both are optically inactive
34. According to Valence Bond Theory, which complex has dsp2 hybridization and square
planar shape?
A) [Ni(CN)4]2- B) [Cu(NH3)4]2+ C) [PtCl4]2- D) Fe(CO)5
35. Which in true in case of [Ni(CO)4] complex

A)Hybridisation of Ni is sp3 B) Tetrahedral shape of the molecule
C) Diamagnetic D) Inner orbital complex
36. Which of the following statement(s) is/are correct with respect to below reaction?
A)The product P is a spiro compound

B)The product P is optically active
C)The product P contains two five membered rings
D)N2 gas is evolved in the reaction

SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice A), B), C) and D) for its answer, out of which ONE OR MORE is/are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 37 to 38:
In complexes of weak filed ligands,  0  P (pairing energy), the energy difference

between t 2g and eg sets is relatively less. Under the influence of strong field ligands
 0  P (pairing energy), the energy difference between t 2g and eg sets is relatively
high.
37. Which of the following is correct statement?
A) Complex [Co(H 2O)6 ]2 is more stable than [Co(H 2O)6 ]3
B) All complexes of Ni(II) are bound to be outer d-orbital complexes
C) Stability constant for [Ni(en)3 ]2 is greater than stability constant for [Ni(NH3 )6 ]2
D)  oct for [Cr(H 2O)6 ]3 is greater than  oct for [Cr(NH3 )6 ]3
38. Select the correct increasing order of 10 Dq. Value for chromium complexes:
(1) [Cr(en)3 ]3 (2) [Cr(ox)3 ]3 (3) [CrF6 ]3 (4) [Cr(H 2O)6 ]3
A) 4 < 3 < 1 < 2 B) 3 < 4 < 2 < 1 C) 4 < 3 < 2 < 1 D) 3 < 4 < 1 < 2
Paragraph for Question Nos.39 to 40

A white compound (A) on strong heating decomposes to produce two products (B)
and (C). (B) on reaction with white phosphorus produces (D), which is a strong
dehydrating agent. (D) on reaction with perchloric acid converts it to its anhydride.
39. The compound (A) is
A) NH 4 NO 2 B) NH 4ClO 4 C)  NH 4 2 Cr2O7 D) NH 4 NO3
40. The product/s obtained on hydrolysis of (D) is
A) Mixture of H 3PO3 and H 3PO 4 B) Only PH 3
C) Only H 3PO 4 D) mixture of H 3PO3 and H 3PO 2

MATHEMATICS Max. Marks: 80
SECTION – I
(INTEGER ANSWER TYPE)
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
41. Considering the rectangular hyperbola xy  15!, the number of points (, ) lying on
it, where ,  N and  divides  , is 12 then the value of  is _____.
42. Nine hundred distinct n-digit numbers are to be formed using only the 3 digits 2, 5, 7.
The smallest value of n for which this is possible is
43. The number of ways of arranging 11 objects A,B,C,D,E,F, , , , ,  so that every
 lies between two  (not necessarily adjacent) is , K  6! 11C5 , then K is (For e.g.
here the arrangement ABCEFD is valid but ABCEFD is not)
44. The number of numbers from 1 to 10 4 (both inclusive) in which there exist two
consecutive digits which are same is equal to n, then the highest digit in n is(For e.g.
1223 or 333 are two such numbers but 32 or 1232 are not)
If the sum of all the coefficients of the terms in the expansion of  x  y  z  w 

6
45.
which contain x but not y, is 95t then the value of t is
4
46. If tr is the numerically second largest term in the expansion of  3  2x 15 at x  , then r
3
Find natural number n so that area bounded by y  nx 2 ,

1 2
47. y nx and y2  4y  3  0 is
2
greatest.
48. A point P(x, y) moves is such a way that  x  y  1   x  (where [.] greatest integer
function) and x   0, 2 . Then the area representing all the possible positions of P
equals
SECTION – II
49. A contest consists of ranking 10 songs of which 6 are Indian classic and 4 are western
songs. Number of ways of ranking so that
A) There are exactly 3 Indian classic songs in top 5 is  5!

3
B) Top rank goes to Indian classic song is 6  9!
C) The ranks of all western songs are consecutive is 4! 7!

10
D) The 6 Indian classic songs are in a specified order is P4
50. Using the elements –3, –2, –1 0, 1, 2, 3
A) The number of 3  3 matrices having trace (Sum of principal diagonal elements)0

is 37  7 6 
B) The number of 3  3 matrices is 79
C) The number of 3  3 skew symmetric matrices is 7 3
D) The number of 3  3 symmetirc matrices is 7 6
51. The number of isosceles triangles with integer sides if no side exceeds 2008 is
A) 1004  if equal sides do not exceed 1004

2
B) 1004  if equal sides exceed 1004

2
C) 3 1004  if equal sides have any length  2008

2
D)  2008  if equal sides have any length  2008

2
52. Triangles are formed by joining vertices of an octagon then number of triangle
A) In which exactly one side common with the side of octagon is 32
B) In which atmost one side common with the side of polygon is 48
C) At least one side common with the side polygon 50
D) Total number of triangle 56

53. 11
C10 .9 C1 11 C9 .9 C2  ......... 11 C2 .9 C9 
A) 20
C11 B) 20
C8 C) 20
C9  1 D) 20
C9
n n
Cr 2r 1
Let for n  N, f (n)    1
r
54. then
r 0  r  1 r  2 
A) f  2n   f  2n  1 B) f  n   f  n  1
C) f  2n   f  2n  1 D) f  2011  f  2012 
55. A1 is the area between by y  log e x, y  log e  x  and y  0 containing negatively-axis. A2
is the area between y  loge x and y  0 containing the positive y axis. A3 is the area
between y  log e x , y  log e x containing the y-axis, then
A) A1  A2  A3  8 B) A1  A2  0
2 A1  4 A2  A3
C) 4 D) 5 A2  3 A1  A3  8
4
37
56. If area of the region bounded by the curve y  x 2  x & the lines y  mx, y nx is
6
 m  n, m, n  N then
A) m = 4 B) n = 2 C) m = 3 D) n = 3
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice A), B), C) and D) for its answer, out of which ONE OR MORE is/are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 57 to 58
50 50  r
Cr  2r  1
   1  100 Cr 
50 100
Let L    
2 2
 
50 r
; M C ; N
Cr  50  r 
50 r
r 1 r 0 r 0
57. The value of (L – M) is equal to

A) 1 B) –1 C) 250 D) 2100
58. The value of (M + N) is equal to
A) 2L + 1 B) 2L – 1 C) 2L + 2 D) 2L – 2
Paragraph for Question Nos. 59 to 60
Let x1 x2 x3 x4 x5 x6 be a six digit number. Find the number of such numbers such that
59. x1  x2  x3  x4  x5  x6 is
A) 9 C4 B) 9 C3 C) 10 C4 D) 10 C3
60. x1  x2  x3  x4  x5  x6 is
A) 11 C5 B) 11 C4 C) 210 C6 D) 10 C5
Sec: Incoming Sr.IIT SC-60 CAT-44 Date: 21-06-20
Time: 3HRS 2015-P2 Max.Marks:240
KEY SHEET
PHYSICS
1 2 2 4 3 2 4 8 5 7
6 4 7 7 8 1 9 D 10 AB
11 D 12 AC 13 BD 14 AC 15 BD
16 D 17 ACD 18 A 19 A 20 C
CHEMISRTY
21 8 22 4 23 8 24 2 25 9
26 5 27 8 28 6 29 CD 30 ABCD
31 CD 32 BCD 33 ABD 34 ABC 35 ABC
36 AD 37 C 38 B 39 D 40 C
MATHS
41 8 42 7 43 3 44 6 45 7
46 9 47 1 48 2 49 ABCD 50 ABCD
51 AC 52 ABD 53 C 54 CD 55 ABCD
56 BC 57 B 58 C 59 C 60 C
Narayana IIT Academy 21-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-44_Key & Sol’s
SOLUTIONS
PHYSICS
P 2 e2 B 2 R 2
1. KEmax  
2m 2m
D
Fringe width   ;10   3.1cm
d
hC
KEmax  W0 

W0  2eV
1 2  1 1
2. Using  R  z  1  2  2 
  n2 n1 
For ‘  ’ particle; n1  2, n2  1
1875 R 23
For metal A:  R  Z1  1    Z1  26
4 4
For metal B: 675R  R  Z 2  1  1  Z 2  31
2 3
4
Therefore, 4 elements lie between A and B
3. K max  5eV  8eV
K max  3eV ;W0  2eV
h 
4.  ; P  8
2mQV0 
5. Stopping potential, VS  1.5 volts
Q
Emission stops when,  Vs
2 0 R
But Q  ne; ‘n’ is no of electrons
50
Emitted, n   107 .
48
   Bvi  B l B 2 vl 2
6. F  B  l  ma  F   ma 
 r  r r
B lV 2 2 2
Bl v
 Power Fv  mav 
r r
B l 2 2
  power  
r
 v 2  (since other terms produce zero average)
 B l v0
2 2 2
2  22  104  22
2
   16 w
2r 2  2 104
P2 Qe h
7.  ;    7  1015 m
2m 4 0 r P
8. Conceptual.
9. Conceptual.
10. When switch is closed and at steady state, current through capacitors is zero. And also

through ideal voltmeter, i  .
R

Just after switch is open, inductors retain, i  hence drop across
R
Voltmeter is, 3iR  iR  2 .
1 2  1    
2
Heat dissipated  2  Li    L   
2   2  R  
11. Release of energy requires Binding energy of products to be greater binding energy of
reactants.
12. Conceptual.
13. Conceptual.
Q
14.  mS t ;
t
Q 99
  VI 
t 100
15. Conceptual.
r dB
16. ENC  ; Ring rotates  NC   Limiting friction .
2 dt
17&18.
hC
Cutoff wavelength, C 
eV0
1
C   1010 m V0 n 105 volts
8.06
Shorter wavelength corresponds to K  X-ray.
19&20.
di
When current is maximum, 0
dt
5CV0
From KVL: Q  
4
Q 5V0
P.d across C   C 
C 4
From energy conservation:
 5CV0  .
2
1 1 1 2
CV02   3C  2V0   Limax 
2
2 2 2 2  4C 
MATHS
41. The largest number whose perfect square can be made with 15! is 25 33 51 71
So that number of ways of selecting x will be
(1 + 5) (1 + 3) (1 + 1) (1 + 1) = 96.
42. 3n 900  n  7
43. There are three major ways  ,  and 
Each major way has six empty spaces. The number of ways of putting letters at these
empty spaces must be non-negative integer function of x1  x2  ...  x6  6  6 61C61  11C5
No.of arrangements is  3 11 C5  6!  K  3
45. The sum of coefficients of terms not containing y = 36
The sum of coefficients of terms not containing both x & y = 26
So the required number = 36 - 26 = 665.
3  2y y
47. Area      dy
1
 n n 
is greatest when n is least

48. If x  (0, 1)
Then – 1  x + y < 0
And if x  [1, 2)
0x+y<1
1 
Required area  4  .1. 2 sin   2 sq. units
2 4
1
1 2 3
0
–1
–1
x+y=1
x+y=0
x + y = –1
A) 6 C3 .4 C2 .5!.5!   5!
3
49.
B) 6C1.9!
C)  6  1!4!
D) 10 P4
50. A) a11  a22  a33  0 remaining ‘6’ elements can be filled in 76 ways
 3, 0,3 ,  2, 0, 2  , (1, 0,1) 

  3!.5  30
 3,1, 2  ,  3, 1, 2  
 2,1,1 2, 1, 1  3.2  6

1
 0, 0, 0  
37
B) Each of 9 elements can be filled in 7 ways
0   
C)  0   3 elements can be filled 73 ways
 0 
D) a 11 , a22 , a33 filled in 7 ways, also a12 filled in 7 ways then a21 filled in one way and
  
so on     6 elements can be filled 76 ways

  
51. If the sides are a, a, b then the triangle forms only when 2a  b .so for any a N , b can
change from 1 to 2a -1 when a  1004 then number of triangles= 1+3+5+..+(2(1004)-1)=
1004  and if 1005  a  2008, b cam take any value from 1to 2008. but a has 1004
2
possibilities hence number of triangles = 1004  2008=2 1004 

2
 Total number of isosceles triangles  3 1004 

2
52. Total number of triangle = 8C3 = 56

Number of triangle having exactly one side common with the polygon = 8×4 = 32
Number of triangle having exactly two side common with the polygon = 8
Number of triangle having no side common with the polygon = 16
1  x 
11
53. 11 C0 11 C1 x 11 C2 x 2   11 C11 x11 --(I)
1  x 
9
 9C0  9C1x  9C2 x 2    9C9 x9 --(II)
On multiply (I) & (II) and compare coefficient of x11 on both sides and put x  1
20
C11  11C119C0  11C109C1    11C29C9
20 C9  1  11C109C1    11C29C9

1 n
(1  2) n  2  1  2(n  2)
54. f(n) = 
2(n  1) (n  2) r 0
n2
Cr  2 (2) r  2 
2(n  1)(n  2)
 1
 n  2 if n  odd
= 
 1 if n  even
 n  1
55.
y  log e x and y  0 y  log e x and y  0
-1 0 1 -1 0 1
A1  1  1  2 sq, units A2  1  1  2 sq, units
A3  2  2  4 sq.units
56. Area of the region bold by y  x 2  x & y  mx is

m 1
Sm    x (x  (m  1))dx  (m  1)3 / 6
0

(  )3
 (x  ) (x  ) dx  (  )
 b
37
Area of the region  Sm  Sn 
6
 (m  1)3  (n  1)3  37
Let m + 1 = a, n + 1 = b  (a  b) (a 2  ab  b 2 )  37
Since 37 is a prime
a 2  ab  b 2  37, a – b = 1
 a 2  ab  b 2  1
 (a, b)  (4, 3)  (m, n)  (3, 2).

57&58:
50  r
Cr  2r  1 
T r   50  
Cr  50  r 
50  r
Cr  50  r  1 
50 1  
Cr  50  r 
50  r 50  r
C Cr  50  r  1 
Tr  50 r  50  
Cr Cr  50  r 
50  r
Cr  50  r  1 
Now 50  
Cr  50  r 

 50  r  150  r  !r ! 50  r  !  50  r  1 ! 50  r  1 !
r !50 !  50  r  .50 ! 50 !.50 !
50  r 1
Cr 1
 50
Cr 1
50  r 50  r 1
Cr Cr 1
T r   50
 50
Cr Cr 1
T r   v  r   v  r  1
50  r
Cr
Where v  r   50
Cr
100 50
50
C50 C0
S   T r   v  50   v  0   50
 50
r 1 C50 C0
L 100 C50  1
50
M    50 Cr  100 C50
2
r 0
100
 Cr    1 .  100 C50 
2
N    1
r 100 100
r 0
N 100 C 50
L – M = –1
L – N = –1
59. x1  x2  x3  x4  x5  x6  9C  9C  9C  9C  10C
6 4 3 4 4

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Sec: Incoming.Sr.IIT_CO.

Name of the Student: ___________________ H.T. NO:

21-06-20_CO SUPER CHAINA_Jee-Adv_CAT-44_SYLLABUS

4. An   particle and a proton are accelerated from rest by a potential difference of

A) Bulb A goes out and bulb B dims

A) The voltmeter reading immediately after the switch is opened is 2

A) A suitable target material must have high melting temperature

B) A suitable target material must have low thermal conductivity

C) The average rate of rise of temperature of the target would be 2 0C s 1

D) The minimum wavelength of X-rays emitted is about 0.25 1010 m .

B) On increasing potential difference between the filament and target, frequency of X-

C) On increasing filament current, cut-off wavelength increases

D) On increasing filament current, intensity of X-rays increases

17. Choose the correct statement(s)

18. The atomic number of target atom is

19. The maximum current in the inductor is

CHEMISTRY: Max. Marks: 80

How many products are obtained in the above reaction.

In product P, functional group is attached to X numbered carbon, and degree of

26. How many of the following statement(s) is/are correct?

(D) Ammonia is reacted with oxygen using a Platinum-Rhodium gauze catalyst to

(E)Sodium on reaction with N2O5 forms a paramagnetic species

[ Dq  2100 cm 1 , Pairing energy = 28,000 cm-1]

A) Cr(CO) 6  Fe(CO)5  Ni(CO) 4 (Order of increasing CO bond strength)

B) [V(CO)6 ]  [Cr(CO) 6 ]  [Mn(CO) 6 ] (order of increasing M-C bond strength

C) [V(CO)6 ]  [Cr(CO)6 ]  [Mn(CO) 6 ] (Effective atomic no)

D) [V(CO)6 ]  [Cr(CO) 6 ]  [Mn(CO) 6 ] (Order of increasing CO bond strength)

30. Which of the following IUPAC names are correct?

A) K 2 [OsCl5 N] : Potassium pentachlordonitridoosmate (VI)

B) [Fe(NH 4C5  C5H 4 N)3 ]Cl 2 : Tris(bipyridine)iron(II) chloride

C) [Fe(C5 H 5 ) 2 ] : bis( 5 -cyclopentadienyl)iron(II)

D) [Pt(py) 4 ][PtCl 4 ]: Tetrapyridineplatinum(II) tetrachloridoplatinate(II)

31. Which of the following statement is incorrect?

A) geometrical isomerism is not observed in complexes of co-ordination number 4

B) CFSE for [Ti(H 2 O)6 ]3 is 0.4  0

C)  0 increasing order is [CrCl6 ]3  [Cr(NH 3 )63  [Cr(CN)6 ]3

D) In spectro chemical series, halide ions are arranged as I   Br   Cl  F

33. Which of the statement(s) is/are true?

A) [Ni(CN)4]2- B) [Cu(NH3)4]2+ C) [PtCl4]2- D) Fe(CO)5

35. Which in true in case of [Ni(CO)4] complex

A)The product P is a spiro compound

C)The product P contains two five membered rings

D)N2 gas is evolved in the reaction

In complexes of weak filed ligands,  0  P (pairing energy), the energy difference

 0  P (pairing energy), the energy difference between t 2g and eg sets is relatively

37. Which of the following is correct statement?

B) All complexes of Ni(II) are bound to be outer d-orbital complexes

Paragraph for Question Nos.39 to 40

39. The compound (A) is

A) NH 4 NO 2 B) NH 4ClO 4 C)  NH 4 2 Cr2O7 D) NH 4 NO3

40. The product/s obtained on hydrolysis of (D) is

A) Mixture of H 3PO3 and H 3PO 4 B) Only PH 3

C) Only H 3PO 4 D) mixture of H 3PO3 and H 3PO 2

it, where ,  N and  divides  , is 12 then the value of  is _____.

The smallest value of n for which this is possible is

43. The number of ways of arranging 11 objects A,B,C,D,E,F, , , , ,  so that every

here the arrangement ABCEFD is valid but ABCEFD is not)

If the sum of all the coefficients of the terms in the expansion of  x  y  z  w 

Find natural number n so that area bounded by y  nx 2 ,

A) There are exactly 3 Indian classic songs in top 5 is  5!

B) Top rank goes to Indian classic song is 6  9!

C) The ranks of all western songs are consecutive is 4! 7!

50. Using the elements –3, –2, –1 0, 1, 2, 3