VELAMMAL IIT ACADEMY

Sec. XI.IIT JEE MAIN MODEL DATE: 16/04/2022

TIME: 3Hrs Max Mark: 300
IMPORTANT INSTRUCTIONS
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 25) 4 0 5 20
(+/ - Decimal Numbers)
Total 25 100

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 26 – 45) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 46 – 50) 4 0 5 20
(+/ - Decimal Numbers)
Total 25 100

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 51 – 70) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 71 – 75) 4 0 5 20
(+/ - Decimal Numbers)
Total 25 100
PHYSICS Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
1. The minimum electrostatic force between two charged particles placed at a distance of 1
m is
(a) 2.3 × 10-28N (b) 6.2 × 10-34 N

(c) 1.02 × 1O-26N (d) 4.2 ×10-27 N

2. Two identical positive charges are fixed on the y-axis, at equal distances from the origin 0.
A particle with a negative charge starts on the negative x-axis at a large distance from O,
moves along the x-axis, passed through O and moves far away from O. Its acceleration a
is taken as positive along its direction of motion. The particle’s acceleration a is plotted
against its x-coordinate. Which of the following best represents the plot?

(a) (b)

(c) (d)
3. Two identical point charges are placed at a separation of L.P is a point on the line joining the charges, at a
distance 𝑥 from any charge. The field at P is E.E is plotted against 𝑥 for values of 𝑥 from close to zero to
slightly less than 𝑙.Which of the following best represents the resulting curve.

4. Two equal negative charges — q each are fixed at points (0, - a) and (0, a) on y-axis. A
positive charge Q is released from rest at the point (2a, 0) on the x-axis. The charge Q will
(a) execute simple harmonic motion about the origin

(b) move to the origin and remain at rest

(c) move to infinity
(d) execute oscillatory but not simple harmonic motion
5. A charge q is placed at the centre of the line joining two equal charges Q. The system of
the three charges will be in equilibrium if q is equal to
𝑄 𝑄 𝑄 𝑄
(a) − 2 (b) − 4 (c) + 4 (d) + 2

6. An electron of mass me, initially at rest, moves through a certain distance in a uniform
electric field in time t1. A proton of mass mp, also initially at rest, takes time t2 to move
through an equal distance in this uniform electric field, Neglecting the effect of gravity, the
ratio t2\t1 is nearly equal to :
(a) 1 (b) (mp/me)1\2 (c) (me/mp)1\2 (d) 1836

7. Six charges, three positive and three negative of equal magnitude are to be placed at the
vertices of a regular hexagon such that the electric field at O is double the electric field
when only one positive charge of same magnitude is placed at R. Which of the following
arrangements of charge is possible for, P. Q R, S, T and U respectively?

(a) +, -, +, -, -, + (b) +, -, +, -, +, - (c) +, +, -, +, -, - (d) -, +, +, -, +, -

8. Two charges q1 and q2 are kept on the x-axis, and the electric field at different points on the x-axis is
plotted against x. Choose the correct statement about the nature and magnitude of q1 and q2.

(a) q1 is positive, q2 is negative; |q1| > |q2| (b) q1 is positive, q2 is negative; |q1| < |q2|
(c) q1 is negative, q2 is positive; |q1| > |q2| (d) q1 is negative, q2 is positive; |q1| < |q2|
9. Three identical point charges, each of mass m and charge q, hang from three strings as shown in Fig.
The value of q in terms of m, L, and q is

(a) 𝑞 = √(16/5)𝜋𝜀0 𝑚𝑔𝐿2 𝑠𝑖𝑛2 𝜃 𝑡𝑎𝑛 𝜃

(b)𝑞 = √(16/15)𝜋𝜀0 𝑚𝑔𝐿2 𝑠𝑖𝑛2 𝜃 𝑡𝑎𝑛 𝜃
(c) 𝑞 = √(15/16)𝜋𝜀0 𝑚𝑔𝐿2 𝑠𝑖𝑛2 𝜃 𝑡𝑎𝑛 𝜃
(d) none of these
10. A block of mass m is suspended vertically with a spring of spring constant k. The block is made to
oscillate in a gravitation field. Its time period is found to be T. Now the space between the plates is
made gravity free, and an electric field E is produced in the downward direction. Now the block is
given a charge q. The new time period of oscillation is

𝑞𝐸 𝑞𝐸
(a) T (b) 𝑇 + 2𝜋√𝑚𝑑 (c) 2𝜋√𝑚𝑑 (d) none of the above
11. Four identical charges Q are fixed at the four corners of a square of side a. The electric field at a
𝑎
point P located symmetrically at a distance from the center of the square is
√2
𝑄 𝑄 2√2𝑄 √2𝑄
(a) 2 (b) (c) 𝜋𝜀 (d) 𝜋𝜀
√2𝜋𝜀0 𝑎 2 √2𝜋𝜀0𝑎 2 0𝑎
2
0𝑎
2

12. A point charge of 100 C, is placed at 3𝑖̂ + 4𝑗̂m. Find the electric field intensity due to this charge at
a point located at 9𝑖̂ + 12𝑗̂ m.
(a) 8000 Vm-1 (b) 9000 Vm-1 (c) 2250 Vm-1 (d) 4500 V m-1
13. A ring of charge with radius 0.5 m has 0.002  m gap. If the ring carries a charge of +1 C, the
electric field at the center is

(a) 7.5 × 107NC-1 (b) 7.2 × 107 NC-1 (c) 6.2 × 107 NC-1 (d) 6.5 × 107NC-1
14. Two particles of masses in the ratio 1 : 2, with charges in the ratio 1:1, are placed at rest in a uniform
electric field. They are released and allowed to move for the same time. The ratio of their kinetic
energies will be finally
(a) 2 : 1 (b) 8 : 1 (c) 4 : 1 (d) 1 : 4
15. Five point charges, each of value +q, are placed on five vertices of a regular hexagon of side L. The
magnitude of the force on a point charge of value - q coulomb placed at the center of the hexagon is
1 𝑞 2 2 𝑞 2 1 𝑞 2 1 𝑞 2
(a) 𝜋𝜀 (𝐿 ) (b) 𝜋𝜀 ( 𝐿 ) (c) 2𝜋𝜀 (𝐿 ) (d) 4𝜋𝜀 (𝐿 )
0 0 0 0

16. A non conducting ring of mass m and radius R is charged as shown. The charge density i.e. the
charge per unit length is 𝜆.It is then placed on a rough non-conducting horizontal plane. At time t =
0, a uniform electric field 𝐸̅ = 𝐸0 𝑖̂ is switched on and the ring starts rolling without sliding. The
frictional force acting on the ring when it starts rolling is

a)𝜆𝑅𝐸0 b)2𝜆𝑅𝐸0 c)2𝜆𝑅𝐸0 d)3𝜆𝑅𝐸0

17. A 4.00 kg block carrying a charge Q = 50.00 𝜇𝐶 is connected to a spring for which K = 100N/m.The
block lies on a frictionless horizontal track, and the system is immersed in a uniform electric field of
𝑉
magnitude 𝐸 = 5.00 × 105 𝑚, directed as shown in figure.If the block is released from rest when the
spring is unstretched (at x = 0).The maximum elongation of the spring is

a)0.1 m b)0.3m c) 0.5m d)0.8m

18. Charge over a nonconducting ring is distributed so that the linear charge density varies as
𝜆 = 𝜆0 sin 𝜃.What is the direction of force on a charge 𝑞0 placed at the centre.

a) along 1 if 𝑞0 is positive and 2 if 𝑞0 is negative

b) along 2 if 𝑞0 is positive and 1 if 𝑞0 is negative
c) along 3 if 𝑞0 is positive and 4 if 𝑞0 is negative
d) along 4 if 𝑞0 is positive and 3 if 𝑞0 is negative
19. Four positive charges (2√2 − 1)𝑄 are arranged at the four corners of a square.Another charge q is
placed at the centre of the square.Resulting force acting on each corner charge is zero if q is
−7𝑄 −4𝑄
a) b) c) -Q d) - (√2 + 1)𝑄
4 7
20. A pendulum bob of mass m carrying a charge q is at rest with it’s string making an angle 𝜃 with the
vertical in a uniform horizontal electric field E. The tension in the string is
𝑚𝑔 𝐸𝑞 𝐸𝑞
a)sin 𝜃 b)mg c)sin 𝜃 d) cos 𝜃
SECTION-II
(Numerical Value Answer Type)
21. A certain charge Q is divided into two parts q and Q-q, which are then separated by a certain
distance. To maximize the electrostatic repulsion between the two charges if q = Q/n, the value of n
is
22. Two particles A and B having charges 8 × 10−6 C and −2 × 10−6 C, respectively are held fixed with
a separation of 20 cm. The distance( in meter) of null point from B is
23. Excess electrons are placed on a small sphere so that it’s net charge is – 3.20 × 10−9 𝐶. Find the
number of electrons (in terms of × 1010 ) on the sphere.
24. Two identical charged spheres are suspended by strings of equal length. The strings make an angle
of 300 with each other. When suspended in a liquid of density 0.8 g/cc, the angle remains the
same. The dielectric constant of the liquid is (Density of material of the sphere is 1.6 g/cc.)
25. A charged particle of mass m = 2kg and charge 1𝜇𝐶 is projected from a horizontal ground at an
angle 𝜃 = 450 with speed 10 m/s. In space, a horizontal electric field towards the direction of
projection E = 2 × 107 N/C exists.The range of the projectile in meter is (g = 10 𝑚⁄𝑠 2 )
CHEMISTRY Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
26. Match the following
List - I List - II
1) O-,P - directing and ring activating a) - NO2
2) O-,P-directing and ring deactivating b) -Cl
3) m - directing and ring deactivating c) - OH
The carrect match among the following is
1 2 3 1 2 3
a) a b c b) c b a
c) b c a d) a c b
27. Benzene does not under go addition reaction easily because
a) It has six hydrogen atoms b) It has a cyclic structure
c) Double bonds present in benzene are strong d) Resonance stabilised system is to be preserved.
28. Arrange the following compounds in the descending order of their reactivity towards electro philic substitution.
a) Chlorobenzene b) Nitrobenzene c) Benzene d) Phenol e) Toluene
a) d > e> c > a > b b) b > a > c > e > d c) d > e > c > b > a d) e > d > c > a > b
29. The correct order of activating abiltity of fthe groups at benzene ring, towards electrophilic substitution.

a) -NH2> -NHR > - NR2 > -OH> -OR b) -OH > -OR > -NH2> -NHR > -NR2
c) -OR > -OH > -NR2> -NHR > -NH2 d) -NR2> -NHR > -NH2> -OR> - OH
30. Phenol 
Zn dust
 A 
C H COCl
 B.6 5

 AlCl 3

In the above sequence B is

a) Acetanilide b) Acetophenone c) Benzophenone d) N-Phenylacetamide
hv
A
31. +Cl2 A & B respectively are
B
FeCl3
a) Hexachlorocyclohexane & C H Cl b) Chlorobenzene & Hexachlorocyclohexane
6 5
c) o-and p-Dichlorobenzene & chlorobenzene d) Chlorobenzene & C H Cl
6 6 6
32. Which one of the following is benzene ring deactivating group towards electrophilic substitution.
a) -NHCOOH3 b) -N(NH3)2 c) -OH d) - Br
33. What is the end product of nitration of toluene ?
a) 0 - Nitro toluene b) p - nitrotoluene
c) 2, 4, 6 - Trinitro toluene d) 2, 4 - Dinitrotoluene

34. C6 H5 -CH3 

K 2Cr2O7
 X. Here 'x' is
H 2 SO 4

a) Benzaldehyde b) Benzoic acid c) Benzyl alcohol d) None

 O
O
HNO3 Br2
35. A; B
H2SO4 AlBr3 (Major)
In the above reactions A and B are respectively
O
O
NO2 O
O
, ,
NO2
a) Br b) Br
O
O NO2
NO2 O
O Br
,
, Br
c) d)
CF3
NH2
Br2 Br2
36. P OH Q
; (Major) ; P and Q are
AlBr3 (Major) CHCl3
O2N respectively

CF3 Br
CF3
NH2
NH2 OH
OH ,
O2N Br , O2N
a) Br b) Br
CF3
CF3 Br NH2
Br NH2 Br OH
OH ,
, O2N
O2N Br
c) d)
37. In chlorobenzene, the -Cl group
a) Activates benzene ring more via resonance effect than deactivating it via inductive effect
b) Deactivates the benzene ring more via inductive effect than activating it via resonance effect
c) Activates the benzene ring via resonance effect and deactivates it via inductive effect. Both
these effects are evenly matched
d) Is a net deactivating group with meta director characteristics
38.
Br2 / Fe
A; A is

Br

Br
a) b)
c) a and b are correct d) None of the above
O-CH3
CH3Cl
39. P; Most probable structure of P is
AlCl3
CN
OCH3
OCH3 OCH3
CH3
CN
H3C CN CN CH3
a) b) c)
d) Reaction will not take place due to strong deactivating nature of –CN
40. Give the order of decreasing reactivity towards an electrophile
CHCl2 CHF2 CH3 CH2Cl

1 2 3 4
a) 1 > 3 > 2 > 4 b) 2 > 1 > 4 > 3 c) 3 > 4 > 1 > 2 d) 4 > 1 > 2 > 3

Br2 / Fe H3O/ Monobromination

(P); P is
Monobromination
NH
41. O

Br Br

NH Br
COOH H2N Br O
a) b)
Br Br Br

H2N

c) H2N d) COOH H2N

 O
42. Nitration of the following compound H C N gives
3

O NO2
O
NO2
H3C N H3C N
a) b)
NO2 O O2N O

H3C N H3C N
c) d)
43. In case of nitration ortho to para ratio is highest in
a) Me-Ph b) Et-Ph c) Me2CHPh d) Me3CPh
44. Arrange the following in the increasing order of rate of reaction with HNO 3/H2SO4 is

O O O
O O O O O O
O O O

I II III
a) III < II < I b) II < III < I c) I < III < II d) I < II < III
45. Arrange the following in decreasing order of reactivity towards electrophilic aromatic substitution.
CH3 CD3 CT3

I II III
a) I > II > III b) III > II >I c) I > III > II d) III > I > II
SECTION-II
(Numerical Value Answer Type)
46. During ozonolysis of 1mole of benzene, number of molecules of ozone consumed is___
47. The number of mononitro products of I, II and III tribromobenzene are x, y, and z respectively, what is
(x + y + z)?
Br Br Br
Br Br

Br Br
Br
I II Br
III
 F CCl3 CH3

48. a) b) c)
O

NH2 O OEt
OEt
d) e) f)
O

H
N CH3

g)
O

Among these, how many are more reactive then benzene towards aromatic electrophilic substitution
H3C
2 3 11 12

49. In HO 4
NO2
1 10 7

6 5 9 8

At which position monobromination occurs predominantly?

CH (CH3)2

50. (i) MnO-4/OH-

X;
(ii) H3+O
Cumene

What is the number of moles of electrons involved permol of cumine?

MATHS Max Marks: 100

SECTION-I
(SINGLE CORRECT ANSWER TYPE)
 SECTION-II
(Numerical Value Answer Type)