Sec: XII-IC_CF WTM - 8 DATE: 20-06-022

Time: 03:00 Hrs XII-IC_CF Max Marks: 300

IMPORTANT INSTRUCTIONS :-

JEE MAIN_MODEL-2021

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs Marks
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 30) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 31 – 50) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 51 – 60)
(+/ - Decimal Numbers)
4 -1 10 20

Total 30 100

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 61 – 80) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 81 – 90)
(+/ - Decimal Numbers)
4 -1 10 20

Total 30 100
 PHYSICS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A small electric dipole is placed at origin with its dipole moment directed along positive x-axis. The

direction of electric field at point 2, 2 2, 0 is 
(A) along z-axis (B) along y-axis
(C) along negative y-axis (D) along negative z-axis 

2. An electric dipole of moment p is placed normal to the lines of force of uniform electric intensity E ,
then the work done in slowly deflecting it through an angle of 180° is
(A) pE (B) + 2 pE (C) –2pE (D) zero
3. Two opposite and equal charges 4 × 10 –8 coulomb when placed 2 × 10–2 cm away, form a dipole. If
this dipole is placed in an external electric field 2 × 10 –2 newton/coulomb, the value of maximum
torque and the work done in rotating it through 180° from mean position will be
(A) 32 × 10 –4 Nm and 32 × 10 –4J (B) 16 × 10–14 Nm and 16 × 10 –14J
–4 –4
(C) 64 × 10 Nm and 32 × 10 J (D) None of these
4. When a test charge is brought from infinity along the perpendicular bisector of the electric dipole the
work done is:
(A) Positive (B) negative (C) zero (D) none of these
5. An electric dipole is placed in a uniform electric field. The dipole, when its axis is inclined to field
direction at 30°, experiences a torque 0.2 N-m. If potential energy of the dipole, when its axis is
opposite to field direction, is 0 J, its potential energy, when its axis is along the field, will be,
(A) –0.4 J (B) –0.8 J (C) 0.4 J (D) zero
6. Two large, parallel conducting plates X and Y, kept close to each other, are given charges Q1 and Q2
(Q1 > Q2). The four surfaces of the plates are A, B, C and D as shown :
1 1 Q1 Q2
(A) the charge on A is (Q1  Q2 ) (B) the charge on B is (Q1  Q 2 )
2 2 A C
1
(C) the charge on C is (Q 2  Q1 ) (D) All of above
2 B D
7. A parallel plate capacitor with air as medium between the plates has a capacitance X Y of
10  F . The area of capacitor is divided into two equal halves and filled with two medium as shown in
the fig. having dielectric constant k1 =2 and k2 = 4. The capacitance of the system will now be

(A) 10 F (B) 20 F (C) 30 F (D) 40  F

8. The charge deposited on 4 F capacitor in the circuit is

(A) 6 × 10-6 C (B) 12 × 10-6 C (C) 24 × 10-6 C (C) 36 × 10-6 C

9. Electric charges q, q, –2q are placed at the corners of an equilateral triangle ABC of side l. The
magnitude of electric dipole moment of the system is:
(A) ql (B) 2ql (C) 3ql (D) 4 ql
10. Two charges 10C are placed 5.0 mm apart. Determine the electric field at (a) a point P on the axis
of dipole 15 cm away from its centre on the side of the positive charge, as shown in fig. and at (b) a
point Q, 15 cm away from O on a line passing through O and normal to the axis of the dipole as
shown in fig. (a << r)

(A) 1.33 × 105N/C, 2.67 × 10 5 N/C (B) 1.66 × 105 N/C, 2.67 × 105 N/C
(C) 2.67 × 105 N/C, 1.33 × 105N/C (D) 1.33 × 105N/C, 1.66 × 10 5 N/C
11. An electric dipole is placed at an angle of 30° to a non-uniform electric field. The dipole will
experience
(A) a torque only
(B) a translational force only in the direction of the field
(C) a translational only in a direction normal to the direction of the field
(D) a torque as well as a translational force
12. The electric potential due to an electric dipole is zero
(A) at all points on equatorial line (B) at only one point on equatorial line
(C) at all points on axial line (D) it is not zero anywhere
13. If the distance between parallel plates of a capacitor is halved and dielectric constant is doubled than
the capacitance
(A) Decreases two times (B) Increases two times
(C) Increase four times (D) Remains the same
14. An electric dipole is placed at the origin and is directed along the x-axis. At a point P, far away from
the dipole, the electric field is parallel to y-axis. OP makes an angle  with the x-axis.
1
(A) tan   3 (B) tan   2 (C)   45 (D) tan  
2
15. A parallel plate capacitor has two square plates with equal and opposite charges. The surface charge
densities on the plates are + and - respectively. In the region between the plates the magnitude of
the electric field is
 
(A) (B) (C) 0 (D) none of these
2 0 0
16. In the figure a capacitor is filled with dielectrics. The resultant capacitance is

2 0 A  1 1 1   A 1 1 1 
(A)     (B) 0    
d  K1 K 2 K 3  d  K1 K 2 K 3 
2 A
(C) 0  K1  K 2  K 3  (D) None of these
d
17. In a parallel plate capacitor, if the intervening medium of permittivity  between the plates is replaced

by another medium of permittivity , then its capacitance is
2
(A) halved (B) doubled (C) unchanged (D) quadrupled
18. A thin metal plate P is inserted between the plates of a parallel-plate capacitor of capacitance C in
such a way that its edges touch the two plates. The capacitance now becomes
(A) C/2 (B) 2C (C) zero (D) 
19. In an isolated parallel plate n capacitor of capacitance C, the four surface have charge Q1, Q2, Q3 and
Q4 as shown. The potential difference between the plates is
Q1 Q3

Q2 Q4

Q1  Q2  Q3  Q4 Q  Q3 Q  Q3 Q  Q4
(A) (B) 2 (C) 2 (D) 1
2C 2C 2C 2C
20. Four capacitors of each of capacity 3 F are connected as shown in the adjoining fig. The ratio of
equivalent capacitance between A and B and between A and C will be

(A) 4 : 3 (B) 3 : 4 (C) 2 : 3 (D) 3 : 2

SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions, but candidates have to attempt any 5 questions out of 10. The answer to each
question is a Numerical values comprising of positive or negative decimal numbers (place value ranging from
Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, -1 in all other cases.
21. If the area of each plate is S and the successive separations are d, 2d and 3d then the equivalent
nA 0
capacitance across A and B is . Find the value of n.
12d

22. Each capacitance shown in figure is in F. Find the charge on 6F in C.

23. A charge of 20 C is placed on the positive plate of an isolated parallel plate capacitor of capacitance
10F. Calculate the potential difference (in V) developed between the plates.
24. Figure shows four parallel plates kept at equal separation forming three parallel plate capacitors. The
capacitance between two adjoining plates is C. The equivalent capacitance between A and B is nC.
Find the value of n.
25. In the circuit shown, a potential difference of 60 V is applied across AB. The potential difference
between the points M and N is x × 10 V. Find the value of x.

26. Two electric dipoles each of dipole moment p  6.2 1030 C  m are placed with their axis along the
same line and their centres at a distance = 10–8 cm. The force of attraction between dipoles is
7n 10 9 N . Find the value of n. (assume that the distance between the charges is very small as
compare to 108 m)

27. The magnitude of electric field intensity at point (2, 0, 0) due to dipole of dipole moment, p  ˆi  3jˆ
n
kept at origin is k . Find the value of n. ( k  1/ 4 0 )
8

28. A dipole of dipole moment p  2iˆ  3jˆ  4kˆ is placed at point A (2, -3, 1). The electric potential due to
this dipole at the point B (4 - 1, 0) is n 109 volts . Find the value of n. All the parameters specified
here are in S.I. units.
29. Dipole is placed parallel to the electric field. If W is the work done in rotating the dipole by 60°,
when work done in rotating it by 180° is nW. Find the value of n.
30. Two small dipoles of moment p are placed as shown in fig. The force between the two dipole is
nkp 2
. Find the value of n.
2x 4
+ +

P x
_ _

CHEMISTRY Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. Which one of the two iodine will be more reactive in the S N1 and SN2 reaction?
I I
A B
(A) A will be faster in SN1 reaction but slower in SN2
(B) A will be faster both in SN1 and SN2 reaction
(C) A and B will be equally reactive
(D) B will be faster in SN1 and SN2 reaction
32. Which alkyl halide would you expect to be more reactive in an E2 reaction?
 Br
(A) (B) C6 H 5  CH 2  CH 2  CH  CH 3
|
Br
(C) C6 H 5  CH  CH 2  CH 2 CH 3 (D) C6 H 5  CH 2  CH 2  CH 2  CH 2  Br
|
Br
33. Arrange the following four alkyl halides in decreasing order with respect to the ratio of E2
elimination to SN2 substitution products expected in their reaction with C2 H5ONa/C2 H5OH
CH 3  CH  CH 2  I
CH 3  CH 2  I |
CH 3
(i )
(ii)
CH 3
| CH 3  CH  CH  Br
CH 3  C  CH 2  CH 2  Br | |
| CH 3 CH3
CH3
(iv )
(iii)
Select the correct answer from the codes given below:
(A) IV > III > II > I (B) IV > II > III > I
(C) IV > II > I > III (D) III > II > IV > I
34. Reaction intermediate of Elcb reaction is:
(A) carbocation (B) six membered cyclic TS
(C) carbanion (D) benzyne
35. The correct increasing order of nucleophilicity of
PhO– (I), CH3COO– (II), OH– (III), C2H5O– (IV) and C2H5COO– (V)
in methanol at 25°C is;
(A) II  V  I  III  IV (B) V  II  III  I  IV
(C) I  IV  V  III II (D) I  II  V  IV  III
36. The major product of given reaction is,
I
Et2O
+ (CH 3)2 CuLi Product
CH3
(A) (B) (C) (D)

37. Which alkyl halide has maximum density?

(A) C3 H 7 I (B) C 2 H 5 I (C) CH 3 I (D) CH 3 Br
38. Ethylene chloride and ethylidene chloride are
(A) Chain isomer (B) Functional isomer (C) Position isomer (D) not isomer
39. Which one of the following is most reactive for ArSN reactions?
Cl F Cl Cl

(A) (B) (C) (D)

NH 3 NH 3 NO2 CN

40. SN1 solvolysis of C6H5CH = CHCH2Cl in water produces

(A) C6 H 5CH 2 C  CH 2 (B) C6 H 5CH  CHCH 2OH
|
OH
(C) C6 H 5 C HCH  CH 2 (D) A mixture of B and C
|
OH
41. Which one of the following compounds will undergo SN1 mechanism with least ease
 H3C
O O 2N Br
(A) Br (B)

H3C
(C) Br (D) Br
42. Which is correct order of rates for SN1 for
I

I
O O

(a) (b)
(A) a = b (B) a > b
(C) a < b (D) can’t make any relation
43. The order of rate of SN2 reaction for following compounds follows
O
||
(I) CH3  CH 2  Br (II) CH3  C CH 2  Br
CH3
|
(III) CH3  CH  Br (IV) CH3  C  Br
| |
CH3 CH3
(A) I > II > III > IV (B) II > I > III > IV (C) IV > III > II > I (D) II > IV > III > I
44. Most reactive alkyl chloride for E1 reaction among the given compounds are
Cl Cl

Cl
(A) (B) (C) (D)

Cl
45. Methyl bromide reacts with AgF to give methyl fluoride and AgBr. This reaction is called:
(A) Finkelstein reaction (B) Fitting reaction
(C) Swarts reaction (D) Wurtz reaction
46. The substitution product of the reaction given will be,
CH3

Br
Substituion only
+ CH3OH Product

CH3
CH3
CH3 CH3

OCH3 OCH3
(A) (B) (C) Both (A) and (B ) (D)
CH3

CH3 CH3

47. Chlorobenzene can be prepared by reacting aniline with

(A) Hydrochloric acid
(B) Cuprous chloride
(C) Chlorine in presence of anhydrous aluminium chloride
(D) Ice cold nitrous acid followed by treatment with cuprous chloride and HCl.
48. Which of the following is the correct order of decreasing reactivity towards nucleophilic substitution?
(A) Vinyl chloride > Allyl chloride > Propyl chloride
 (B) Allyl chloride > Propyl chloride > Vinyl chloride
(C) Allyl chloride > Vinyl chloride > Propyl chloride
(D) Propyl chloride > Vinyl chloride > Allyl chloride
KOH(alc) Cl2 (g)
49. C 2 H 5 I   A   X; X can be
(A) vinyl chloride (B) allyl chloride (C) ethyl chloride (D) ethyl iodine chloride
50. Which of the following halide will have highest dipole moment?
(A) 1, 4-Dichlorobenzene (B) Dichloromethane
(C) Trichloromethane (D) m-Dichlorobenzene

SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions, but candidates have to attempt any 5 questions out of 10. The answer to each
question is a Numerical values comprising of positive or negative decimal numbers (place value ranging from
Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, -1 in all other cases.

51. Number of compounds which can give SN2 reaction in the presence of polar aproetic solvents is:
O

C6 H5 C CH 2Br CH3 I NO 2 CH2 Br

I II III

CH 3 CH 3

CH3 C Br CH3 C CH 2Br C6 H5 CH2 CH3

CH3 CH3

IV V VI
52. Number of substrate which always give Hofmann elimination are:
CH3 CH3 CH3
CH3 CH2 CH2 N CH3 OH CH3 CH2 CH2 CH2 S OH OH
CH3 CH3 N
CH3 CH3

I II III

CH3 F Br
CH3 CH CH2 CH N O CH3 CH2 CH CH3 CH3 CH2 CH CH3
CH3 H3C CH3

IV V VI

53. The percentage enantiomeric excess of a mixture containing 6 g of (+) – 2 – butanol and 4 g of (–) – 2
x
– butanol is , find x.
10
Cl
| (CH3 )3 COO-
54. CH 3  CH 2  CH  CH3    (P) major
Hydrogen will be removed from which position (according to IUPAC nomenclature).
 CH3
2 Cl
3 1
55.
4 6
5

Hydrogen will be removed from which position in E2 reaction

56. When neopentyl bromide is subjected to wurtz reaction, the product formed having number of
secondary carbon?
Sum of p + q + r + s is
Cl alc. KOH (A) major
57. CH3— CH2— CH — CH3
aq. KOH
(B) major

the sum of stereoisomer is (A) & (B) is

x
58. The Cl — C —Cl angle in 1, 1, 2, 2-tetrachloro-ethene will be x°, find ?
20
59. On monochlorination of 2-methyl butane, the total number of chiral compounds is
60. The number of stereoisomers obtained by bromination of trans-2-butene is

MATHEMATICS Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
x x
61. Let f  x   x
  1, then f is
e 1 2
(A) an odd function (B) an even function
(C) both odd and even (D) neither odd nor even
62. Fundamental period of the function f (x) = cos (sin x) + cos (cos x) is
  
(A) (B) (C)  (D)
3 6 2
63. Which of the following is an even function
a x  a x ax 1
(A) f  x   x (B) f  x  
a  ax a x 1
a x 1
(C) f  x   x x
a 1

(D) f  x   log 2 x  x 2  1 
64. A function whose graph is symmetrical about the y-axis is given by
sec 2 x  cosec2 x
 
(A) f  x   sin log x  x 2  1   
(B) f  x  
x 3  x 4 cot x
2
(C) f  x  y   f  x   f  y  x y  R (D) f(x) = x
65. The period of sgn  x   x   is (where [.] is G.I.F)
(A) any real number (B) 0
(C) 1 (D) non-periodic function
66. The period of x cos x is

(A) 2 (B)  (C) (D) none periodic
2
67. Let f  x  be periodic and k be a positive real number such that f  x  k   f  x   0 for all x  R .
Then the period of f  x  is
(A) k (B) 2k (C) 4k (D) 8k
x
9  1   2   1995 
68. If f  x   x then f  f    .........   
9 3  1996   1996   1996 
(A) 997 (B) 997.5 (C) 998 (D) 998.5
1
69. If f  x    a  x n  then fof  x 
n is
1
(A) x (B) a  x (C) x n (D) x n
1 1
70. If for non-zero x, af  x   bf     5, where a  b, then f  2  
x x
3  2b  3a  3  2b  3a  3  3a  2b  6
(A) (B) (C) (D)
2a  b 
2 2
2 a  b 
2 2
2 a  b 
2 2
ab
 x2  2 
71. Let f :  3, 3  R where f  x   x 3  sin x    be an odd function then the value of a is
 a 
(where [ ] represents greatest integer function)
(A) less than 11 (B) 11 (C) greater than 11 (D) 9
72. If f is an even function defined on the interval (–5, 5) then find the total number of real values of x
 x 1 
satisfying the equations f  x   f   are
x2
(A) 1 (B) 2 (C) 4 (D) 8
73. Let f be real valued function with domain R satisfying
2 3 4 1/5 5
f  x  k   1   2  5f  x   10 f  x   10 f  x   5 f  x   f  x  
 
for all real x and some positive constant k, then the period of the function f  x  is
(A) k (B) 2k (C) non periodic (D) 4
sin x  cos x
74. The period of the function f  x   is
sin x  cos x

(A) (B) 2 (C)  (D) 4
2
75. The period of the function f  x   sin 4x  cos 4x is
   
(A) (B) (C) (D)
2 8 4 3
76. 
f  x   ln x  1  x 2  is
(A) even function (B) odd function
(C) Neither even nor odd (D) Constant function
2
77. The entire graph of y  x  kx  x  9 is strictly above the X-axis if and only if
(A) K < 7 (B) –5 < K < 7 (C) K > –5 (D) K > 7
2
x 
78. Let f :  10, 10  R where f  x   sin x    (where [.] is G.I.F.) be an odd function then a
a 
(A) (–10, 10) – {0) (B) (0, 10) (C) [100, ) (D) (100, )
x  x  x  x   x 
79. The period of f  x   sin x  tan    sin  2   tan  3   .........  sin  n 1   tan  n  is
2 2  2  2  2 
 
(A) 2 (B) 2 n (D) 3 n 
(C) 2 n
3
2 2
80. If  
f x  cos  
   x  cos 
   x
 (where [x] stands for the greatest integer function) then
(A) f   / 2   1 (B) f     1 (C) f     0 (D) Both (A) and (C)

SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions, but candidates have to attempt any 5 questions out of 10. The answer to each
question is a Numerical values comprising of positive or negative decimal numbers (place value ranging from
Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, -1 in all other cases.

x  x   cos   x   cos  2  x  ........ cos n x 

81. The period of f  x   e (where [.] is G.I.F) is
n  n  1
82. The period of f  x    x    2x    3x    4x   .......... nx   x (where [.] is G.I.F) (where
2
n  N ) is
83. Total number of solutions of 2 x  3x  4 x  5x  0 is
1  1 
84. If f  x   x 3  3  4  x 2  2   13 then the value of f 2  3 is
x  x 
 
n
85. Find the natural number ‘a’ for which  f  a  k   16  2
k 1
n
 1 where the function

f satisfies the relation f  x  y   f  x  f  y  for all natural numbers x, y & further f (1) = 2
x
86. Let f (x)  , x  1 . Then, for what value of  + 1 is f (f (x))  x ?
x 1
    5
87. If f (x)  sin 2 x  sin 2  x    cos x cos  x   and g    1 , then (g o f )(x)  …..
 3  3 4
88. Let f (x)  sin x, g(x)  ln | x | . If the ranges of the composite functions fog and gof are R 1 and R 2
respectively, then R 1 maximum + R 2 maximum is
k
89. Total number of solution of 2cos x | sin x | in [2 ,5] is k, then is
2
90. Let f : N  N and a  b  f (a)  f (b) .  a, b  N . If f (f (n))  3n , then f (2)  .....