Sec: JR MPC ALL DATE: 10-11-2023

Time: 03:00 Hrs. WTM- 18 Max Marks: 300

IMPORTANT INSTRUCTIONS: -
JEE MAINS MODEL
MATHEMATICS:
+Ve - Ve No.of
Section Question Type Total marks
Marks Marks Q’S
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 30) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S Marks
Sec – I(Q.N : 31 – 50) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 51 – 60) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100
CHEMISTRY:
+Ve - Ve No.of
Section Question Type Total marks
Mark Marks Q’S
Sec – I(Q.N : 61 – 80) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 81 – 90) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100

JR MPC ALL WTM-18_10-11-2023 PAGE 1

MATHS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

01. Let f ( x)  5  x  2 and g ( x)  x  1 , x  R. If f (x) attains maximum value at  and g(x) attains

 x  1  x2  5 x  6 
minimum value at  , then lim 
x  x2  6 x  8
1 3 3 1
A) B)  C) D) 
2 2 2 2
x 4 1 x3  k 3
02. If lim  lim 2 2 , then k =
x1 x  1 x k x  k

3 3 4 8
A) B) C) D)
8 2 3 3
2
x 2  tan 2 x  2 tan x 
03. lim 4

x 0
1  cox2 x 
1 1
A) 4 B) 2 C) D)
2 4
y y
04. If cos 1 x  cos 1
  , where 1  x  1, 2  y  2, x  , then for all x, y,
2 2
2 2
4 x  4 xy cos   y is equal to :
A) 4sin 2  B) 2sin 2  C) 4sin 2   2x 2 y 2 D) 4 cos 2   2x 2 y 2
 1 1 1 
05. Lt     ......  nterms  
n  3.7 7.11 11.15
 
1 1 1
A) B) C) D) 0
12 4 3
sin  cos2 x 
06. lim is equal to
x 0 x2

A)  B)  C) D) 1
2

07. lim
1  cos 2 x  3  cos x  
x 0 x tan 4 x
1 1
A) 1 B) 2 C) D)
4 2
cos 7 x  cos 9 x
08. Lt 
cos 3 x  cos 7 x
x 0

5 2 7 4
A) B) C) D)
2 5 5 5
 1  1  1   1 
09. S  tan 1  2   tan  2
1
  ........  tan   , then tan S is equal to:
 n  n 1   n  3n  3   1   n  19  n  20  

JR MPC ALL WTM-18_10-11-2023 PAGE 2

 20 n 20 n
A) B) 2
C) 2
D)
401  20n n  20n  1 n  20n  1 401  20n
5.2n 1  2.3n 1
10. Lt 
n  3.2 n  7.3n

6 2 2 6
A) B) C) D)
5 7 7 7
1  x2  1  x  x2
11. lim 
x 0 3x  1
1 1
A) log9 B) C) log3 D)
log9 log 3
e x  esin x
12. lim 
x 0 2( x  sin x)

1 1 3
A) B) C) 1 D)
2 2 2
3 1 
13. If   cos1   ,   tan 1   , where 0   ,   , then    is equal to :
5 3 2
 9  1  9  1  9  1  9 
A) tan 1   B) cos   C) tan  14  D) sin  
 5 10   5 10     5 10 
x
 1x 1
x
1
x

2  27  8
14. Lt   
x  3 
 
 
A) 3 3 2 B) 2 3 2 C) 4 3 2 D) 6 3 2
   2 
15. A value of tan 1  sin  cos 1     is
   3 
 
   
A) B) C) D)
4 2 3 6
16. Let m and M respectively be the minimum and the maximum values of
 
f  x   sin 1 2 x  sin 2 x  cos 1 2 x  cos2 x, x  0,  . Then m + M is equal to :
 8
A) 1  2  B) 1  2  C)  2 D) 1  

17. Let P  lim 1  tan 2

x  0
 x  2x
then log p is equal to

1 1
A) 2 B) 1 C) D)
2 4
2
62  122  182  ....   6n 2 
18. Lt   
 
n 5  10  15  .....  5n  23  43  63  .......  8n3 

4 144 4 144
A) B) C) D)
5 5 25 25

JR MPC ALL WTM-18_10-11-2023 PAGE 3

  1  cos 2  x  2  
19. lim  
x 2  x2 
 
1
A) equals  2 B) equals C) does not exist D) equals 2
2
12 x    22 x   32 x   ......  n2 x 
20. Lt  where [.] is Greatest Integer Function.
n  n3
x x x
A) B) C) D) 0
2 3 6
SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will
be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
 
sin  x  
 6
21. Lt 

x 3
6  cos x
2
x cot(4 x )
22. Lt 
x0 sin 2 x cot 2 (2 x )

 1 5 1
23. tan  2 tan 1  sec 1  2 tan 1  is equal to
 5 2 8
f  3x  f 2x
24. Let f : R  R be a positive increasing function with lim  1. Then lim 
x f  x x f  x 

10 10 10

lim
 x  1   x  2   ......   x  10 

25.
x x10  1010
26. For each t  R , let  t  be the greatest integer less than or equal to t. then,

1  x  sin 1  x  sin  2 1  x  
Lt  
x1 1  x 1  x 
x  sin x
27. Lt 
x  x  cos 2 x
28. Given that the inverse trigonometric function take principal values only. Then, the number of real values of x
 3x   4x 
which satisfy sin 1    sin 1    sin 1 x is equal to :
 5  5 
 1  1   1 1 
29. 50 tan  3tan 1    2cos 1 
 2

 5 
  4 2 tan  tan 2 2 
2 
  is equal to _________.

JR MPC ALL WTM-18_10-11-2023 PAGE 4

 
30. The number of real roots of the equation tan 1 x  x  1  sin 1 x 2  x  1  is :
4

PHYSICS Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. A jar is filled with two non-mixing liquids 1 and 2 having densities ρ and ρ respectively. A solid ball,
made of a material of density ρ , is dropped in the jar. It comes to equilibrium in the position shown in
the figure. Which of the following is true for ρ , ρ and ρ ?

A) ρ < ρ < ρ B) ρ < ρ < ρ C) ρ < ρ < ρ D) ρ < ρ < ρ

32. The pressure on a swimmer 20 m below the surface of water at sea level is
A) 1.0 atm B) 2.0 atm C) 2.5 atm D) 3.0 atm
33. A body floats in water with 40% of its volume outside water. When the same body floats in an oil, 60%
of its volume remains outside oil. The relative density of oil is
A) 0.9 B) 1.0 C) 1.2 D) 1.5
34. Radius of one arm of hydraulic lift is four times of radius of other arm. What force should be applied on
narrow arm to lift 100kg?
A) 26.5 N B) 62.5 N C) 6.25 N D) 8.3 N
35. At a given place where acceleration due to gravity is ms , a sphere of lead of density kgm is
gently released in a column of liquid of density ρ kg m . If > ρ, the sphere will
A) Fall vertically with an acceleration ms
B) Fall vertically with no acceleration
C) Fall vertically with an acceleration
D) Fall vertically with an acceleration
36. A uniform tapering vessel shown in figure is filled with liquid of density 900 kgm . The force that acts
on the base of the vessel due to liquid is (take g =10 ms )
+

A) 3. 6 N B) 7.2 N C) 9. 0 N D) 12. 0 N
37. Figure shows the vertical cross section of a vessel filled with a liquid of density . The normal thrust per
unit area on the walls of the vessel at point , as shown will be

A) ℎ g B) g C) ( − ℎ ) g D) ( − ℎ) g cos θ

JR MPC ALL WTM-18_10-11-2023 PAGE 5

38. The spring balance reads 2 kg with a block of mass suspended from it. A balance reads 5 kg when
a beaker with liquid is put on the pan of the balance. The two balances are now so arranged that the
hanging mass is inside the liquid in a beaker as shown in figure

A) The balance will read more than 2 kg

B) The balance will read less than 5 kg
C) The balance will read less than 2 kg and will read more than 5 kg
D) The balance will read more than 2 kg and will read less than 5 kg
39. An artificial satellite moving in circle orbit around the earth has a total (kinetic + potential) energy .
Its potential energy and kinetic energy respectively are
A) 2 and −2 B) −2 and −3 C) 2 and − D) −2 and −
40. Fig. shows a U-tube of uniform cross-sectional area A accelerated with acceleration ‘a’ as shown. If
d is the separation between the limbs, then the difference in the levels of the liquid in the U-tube is

ad g
A) B) C) adg D) ad+g
g ad

41. A spaceship is launched into a circular orbit close to earth’s surface. The additional velocity that should
be imparted to the spaceship in the orbit to overcome the gravitational pull is (Radius of earth = 6400
km and g = 9.8 ms )
A) 11.2 kms B) 8 kms C) 3.2 kms D) 1.5 kms
42. Two concentric shells of different masses m1 and m2 are present as shown in figure. The field at
positions I , II and III are

JR MPC ALL WTM-18_10-11-2023 PAGE 6

 Gm1 G  m1  m2  Gm2 Gm
A) 0, , B) 2
, 0, 2 1
r2 2 r12 r2 r1
G (m1  m2 ) Gm1 G (m1  m2 ) G (m2 )
C) , 2 ,0 D) , ,0
r12 r2 r12 r2 2

43. The orbital velocity of an artificial satellite in a circular orbit just above the earth’s surface is . For a
satellite orbiting at an altitude of half of the earth’s radius, the orbital velocity is

A) B) C) D)
44. A satellite moves in elliptical orbit about a planet. The maximum and minimum velocities of satellites
are 3 × 10 ms and 1 × 10 ms respectively. What is the minimum distance of satellite from planet,
if maximum distance is 4 × 10 km?
A) 4 × 10 km B) 3 × 10 km C) 4/3 × 10 km D) 1 × 10 km
45. An artificial satellite is moving in a circular orbit around the earth with a speed equal to half the
magnitude of escape velocity from the earth. The height of the satellite above the earth’s surface will be
(radius of earth = 6400 km)
A) 6000 km B) 5800 km C) 7500 km D) 6400 km
46. A body is released from a point distance from the centre of earth. If is the earth and > , then the
velocity of the body at the time of striking the earth will be
( )
A) B) 2 C) D)

47. A vessel contains oil (density = 0.8 gm/cm3) over mercury (density = 13.6 gm/cm3). A homogeneous sphere
floats with half of its volume immersed in mercury and the other half in oil. The density of the material of the
sphere in gm/cm3 is
A) 3.3 B) 6.4 C) 7.2 D) 12.8
48. Two substances of densities 1 and  2 are mixed in equal volume and the density of mixture is 4. When they
are mixed in equal masses, the density of the mixture is 3. The values of 1 and  2 are
A) 1  6 and  2  2 B) 1  3 and  2  5 C)  1  12 and  2  4 D) None of these
49. A vertical U-tube of uniform inner cross section contains mercury in both sides of its arms. A glycerin (density
= 1.3 g/cm3) column of length 10 cm is introduced into one of its arms. Oil of density 0.8 gm/cm3 is poured
into the other arm until the upper surfaces of the oil and glycerin are in the same horizontal level. Find the
length of the oil column, Density of mercury = 13.6 g/cm3

A) 10.4 cm B) 8.2 cm C) 7.2 cm D) 9.6 cm

50. An incompressible liquid flows through a horizontal tube as shown in the following fig. Then the velocity v of
the fluid is

A) 3.0 m/s B) 1.5 m/s C) 1.0 m/s D) 2.25 m/s

JR MPC ALL WTM-18_10-11-2023 PAGE 7

 SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will
be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. A river of salty water if flowing with a velocity 2 ms . If the density of the water is 1.2 gcc , then the
kinetic energy of each cubic meter of water is _____ J
52. A cubical block is floating in a liquid with half of its volume immersed in the liquid. When the shole
system accelerates upwards with acceleration of g/3, the fraction of volume immersed in the liquid is
1
Where N is
N
53. An artificial satellite is moving in a circular orbit around the Earth. The height of the satellite above the
surface of Earth is R. Suppose the satellite is stopped suddenly in its orbit and allowed to fall freely. On
reaching Earth, its speed is xgR where x is

54. A ball whose density is 0.4 × 10 kg m falls into water from a height of 9 cm. To what depth (in cm)
does the ball sink?
55. Water is flowing in a pipe of diameter 4 cm with a velocity 3 m/s. The water then enters into a tube of diameter
2 cm. The velocity of water in the other pipe is ______ m/s
56. The hydraulic press shown in the figure is used to raise the mass M through a height of 5.0 mm by
performing 500 J of work at the small piston. The diameter of the large piston is 10 cm while that of
the smaller one is 2 cm. The mass M is 10x kg where x is ___

57. A solid sphere of radius ‘R’ has a concentric cavity of radius ‘R/2’ inside it. The sphere is found to
just float in water with the highest point of it touching the water surface. The specific gravity of the
material of the sphere is N/7 where N is
58. A raft of wood (density 600 kg/m3) of mass 120 kg floats in water. The weight that can be put on the
raft to make it just sink is ______ kg
59. A rectangular block of wood of density 800kgm-3 having a mass of 2kg is pushed in to water so that
it is completely submerged and then released. Neglecting viscous forces, the initial acceleration of
10
the block is m/s2. where k is _____ (g = 10 m/s2)
k
60. A tank accelerates upwards with acceleration a =1 m/s2 contains water. A block of mass 1 kg and
density 0.8 g/cm3 is held stationary inside the tank with the help of the string as shown in figure. The
x
tension in the string is where x is ____
100
(Given: density of water = 1000 kg/m3)

JR MPC ALL WTM-18_10-11-2023 PAGE 8

CHEMISTRY Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. Which of the following is the most stable carbocation (carbonium ion) ?
  
+
A) CH3CH2 B) (CH3 )2 C H C)  CH3 3 C D) C6H5 C H2.
62. The kind of delocalization involving sigma bond orbitals is called
A) Inductive effect B) Hyperconjugation effect
C) Electromeric effect D) Mesomeric effect
63. Which of the following statements is false about resonance contribution structures ?
A) Contributing structures contribute to the resonance hybrid in proportion of their relative
energies
B) Equivalent contributing structures make the resonance very important
C) Contributing structures represent molecules having no real existence
D) Contributing structures are less stable than the resonance hybrid
64. In which of the compounds given below is there more than one kind of hybridization (sp,
sp2, sp3) for carbon?
(i) CH3CH2CH2CH3 (ii) CH3CH=CHCH3
(iii)CH2=CH-CH=CH2 (iv) H-C  C-H
A) (ii) B) (iii) and (iv) C) (i) and (iv) D) (ii) and (iii).
65. The order of decreasing stability of the carbanions
 
(CH3)3C-(I); (CH3)2CH-(II); CH3CH2 (III);C6H5CH2  IV  is.
A) I > II > III > IV B) IV > III > II > I
C) IV > I > II > III D) I > II > IV > III
66. Which of the following is correct regarding the –I-effect of the substitutents?
A) –NR2 < -OR < - F B) – NR2> -OR < -F
C) – NR2< -OR > -F D) –NR2>-OR > -F
67. The most unlikely representation of resonance structures of p-nitrophenoxide ion is

A) B) C) (d)

68. Polarization of electrons in acrolein may be written as

   
A) C H2  CH  CH  O B) C H2  CH  CH  O

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    
C) C H2  CH CH  O D) C H2  CH CH  O
69. Consider the following carbocations
   
I. C 6H5 CH2 II. C6H5CH2 CH2 III. C 6H5 CH CH3 IV. C 6H5 C(CH3 )2
The correct sequence for the stability of these is
A) II < I < III < IV B) II < III < I < IV C) III < I < II < IV D) IV < III < I < II
70. The most stable carbocation is

A) B) C) D)
71. Which is the decreasing order of stability of the ions?
  
I. CH3  CH CH3 II. CH3  CH OCH3 III. CH3  CH COCH3
A) I > II > III B) II > III > I C) III > I > II D) II > I > III.
72. Using pK a values which is the strongest acid (HA is any acid)?
pK a HA
3.7 HCOOH
4.2 C6H5COOH
4.75 CH3COOH
15.5 CH3OH
A) Acetic acid B) Benzoic acid C) Methanol D) Formic acid

73. Rank the following compounds in order from most acidic to least acidic
OH OH OH OH

(1) (2) (3) (3) NO 2

A) 2 > 3 > 4 > 1 B) 4 > 3 > 1 > 2 C) 4 > 2 > 1 > 3 D) 1 > 4 > 3 > 2
74. Which of the following is the most acidic?
A) 1-butyne B) 2-butyne C) 1-butene D) Butane

75. The IUPAC name of the given structure

A) 6-Bromo-5-chlorocyclohexen-3-yne B) 5-Bromo-6-chloro-1-cyclohexen-3-yne
C) 6-Bromo-5-chloro-3-cyclohexen1-1-yne D) 4-Bromo-3-chloro-1-cyclohexen-5-yne

76. IUPAC name of is

A) 4-Bromo-2-hydroxybenzoicacid B) 1-Bromo-3-hydroxybenzoicacid
C) 1-Bromo-3-hydroxy-4-benzoicacid D) 1-Carboxy-2-bromophenol

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77. Select the correct IUPAC name of the following compound:

A) Bicyclo (4, 1, 0) heptane B) Bicyclo (4, 0, 1) heptane

C) Bicyclo (0, 1, 4) heptane D) Bicyclo (4, 1, 0) hexane
78. Compare basic strength

H3 C CH2 HC C H2C CH
(a) (b) (c)
A) b > c > a B) c > b >a C) a > b > c D) a > c > b

79. Which one among the following is the least basic?

A) CH3NH2 B) NH3 C) C2H5NH2 D) PhNH2
80. Write the correct order of basic strength for the given compounds?

Ph NH2 Ph N Ph Ph N Ph
H Ph
(X) (Y) (Z)
A) Z > Y > X B) X > Y > Z C) Y > Z > X D) Z > X > Y
SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will
be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. Find the number of molecules can show +M-effect from the following

F NH2 NH2 NO2 Cl OH CHO

OH OH
82. How many of the following can show both I-effect and M-effect
+
CH -Ph

 CH3 3 C  Ph3C  ; Ph C  CH 3 2 CH .3  C   C2 H 5 

83. Find the number of π electrons in O-nitrobenzoic acid

84. How many of the following are +M groups

-COOH, -COX, OH  ,  NH
 , Cl  :  Br
 : -CONH2, -COOR
2
85.
  
Find the number of -I groups from the following
-CN, -NR2, -NHR, -NH2, -OH, -CH3, C2H5, -NO2, -C3H7, -C2H3 -Ph
86. Find the number of α-hydrogen atoms present in

JR MPC ALL WTM-18_10-11-2023 PAGE 11

 CH3
|
H 5C2  C 
|
CH3
87. How many of the following can show resonance
+
CH2

C6H5 +
CH

+ -
Ph
88. Number of sp carbons in tetracyano ethaylene _________SSSSS
89. Number of sp2 hybrid orbitals in
OHC  CH  CH  C H  CH  CH 2
|
CH 2CH 2CH 2CH 3

90. Number of primary hydrogen atoms in are

JR MPC ALL WTM-18_10-11-2023 PAGE 12

 JR MPC ALL WTM-18 WTM-18 KEY SHEET

DATE: 10-11-2023

MATHS KEY:

1) A 2) D 3) D 4) A 5) A 6) B 7) B 8) D 9) C 10) D

11) B 12) B 13) D 14) D 15) D 16) A 17) C 18) B 19) C 20) B

21) 2 22) 1 23) 2 24) 1 25) 10 26) 0 27) 1 28) 3 29) 29 30) 0

PHYSICS KEY:

31) D 32) D 33) D 34) B 35) C 36) B 37) C 38) C 39) C 40) A

41) C 42) D 43) C 44) C 45) D 46) D 47) C 48) A 49) D 50) C

51) 2400 52) 2 53) 1 54) 6 55) 12 56) 4 57) 8 58) 80 59) 4 60) 275

CHEMISTRY KEY:

61) C 62) B 63) A 64) A 65) B 66) A 67) C 68) D 69) A 70) B

71) D 72) D 73) C 74) A 75) B 76) A 77) A 78) D 79) D 80) B

81) 5 82) 1 83) 10 84) 4 85) 8 86) 8 87) 3 88) 4 89) 15 90) 9

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 SOLUTIONS
MATHS :-
1)

2)

3)

4)

5)

6)

7)

8)

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9)

10)

11)

12)

13)

14)

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15)

16)

17)

18)

19)

20)

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21)

22)

23)

24)

25)

JR MPC ALL WTM-18_10-11-2023 PAGE 17

26)

27)

28)

29)

30)

PHYSICS:

JR MPC ALL WTM-18_10-11-2023 PAGE 18

31. ρ < ρ as denser liquid acquires lowest position ∴ the additional velocity to be imparted to the
of vessel. orbiting satellite for escaping is
ρ < ρ as ball sinks in liquid 1 and ρ < ρ as ball 11.2 −8 = 3.2 kms
doesn’t sinks in liquid 2, so 42.
ρ <ρ <ρ
32. Pressure at depth ℎ = +ρ ℎ
where is atmospheric pressure
= 1.01 × 10 Nm
∴ = 1.01 × 10 + 10 × 10 × 20
= 3.01 × 10 Pa = 3 atm
33. = 0.6
= 0.4
6
∴ 1=
4 43.
3 = = ,
∴ = = 1.5
2
34. By Pascal’s law
=
= ( + /2)
100g × ( )
or = = 2 2
( ×4 ) = =
3 3
= 6.25g = 62.5N
35. Apparent weight = actual weight – upthrust 44. If no external torque acts on a system, then angular
= − ρg momentum of the system does not change.
−ρ , If τ=0
⟹ = g
⟹ =0
36. Force on the base of the vessel
= pressure ×area of the base ∴ = constant
= ℎ g × = 0.4 × 900 × 10 × 2 × 10 Hence, =
×
= 7.2 N ⟹ =
37. Depth of below the free surface of water in the
vessel= (1 + ℎ). Since the liquid exerts 1 × 10 × 4 × 10 4
= = × 10 km
equal pressure in all direction at one level, 3 × 10 3
hence the pressure at = ( − ℎ ) g 45. Given that, the orbital velocity of satellite
38. The upward thrust ( buoyancy force) acts on the escape velocity
=
body and an equal and opposite force acts 2
on the water so the weight will be the sum ⟹ = ….( )
of the two = 600 + 40 = 640 g 2
But we know that,
39. KE = = − , and

PE = − =2 = and = 2
+ℎ
On putting these values in Eq. (i)
⇒ TE = KE + PE = − =
2
2
40. =
+ℎ 2
On squaring both sides, we obtain
41. For orbiting the earth close to its surface 2
=
+ℎ 4
= = , , = = g or 2 = ( + ℎ)
or 2 = + ℎ or =ℎ
∴ = (9.8 × 6.4 × 10 ) = 8 kms or ℎ = = 6400 km
For escaping from close to the surface of earth, 46. Using law of conservation of energy
1
1 2 − = −
= , = = 2g 2
2
= √2 × = 1.41 × 8kms = −
2
= 11.2 kms
JR MPC ALL (SHMPT) WTM-18_10-11-2023 Page 19
 −  M  m1  m 2 Av1  Av 2  1.5 A . v
=
 A  3  A  1.5  1 .5 A . v  v  1 m / s
−
= 51. Given, velocity of river, ( ) = 2ms
Density of water, ρ = 1.2 gcc
2 ( − ) Mass of each cubic metre,
=
1.2 × 10
= = 1.2 × 10 kg
47. (10 )
1
∴ kinetic energy =
2
1
= × 1.2 × 10 × (2)
2
= 2.4 × 10 J = 2.4kJ
52.
As the sphere floats in the liquid. Therefore its 53. Using conservation of energy.
weight will be equal to the upthrust force on 1
it − =0−
2 2
Weight of sphere 1
4 3 or = −
 R g 2 2
3 1
or =2 1−
…(i) 2
or =
But =

...... (i) ∴ =
Upthrust due to oil and mercury
2 2 or =
 R 3   oil g  R 3 Hg g
3 3 54. The velocity of ball before entering the water
…(ii) surface
Equating (i) and (ii) = 2 ℎ = 2 ×9
4 3 2 2 When a ball enters into water, due to upthrust of
R g  R 3 0 . 8 g  R 3  13 . 6 g
3 3 3 water the velocity of ball decreases (or
 2   0 . 8  13 . 6  14 . 4    7 . 2 retarded)
48. When substances are mixed in equal volume then The retardation,
1   2 apparent weight
density  4  1   2  8 =
2 mass of ball
.......(i) (ρ − σ)g (ρ − σ)g
When substances are mixed in equal masses = =
ρ ρ
21  2 0.4 − 1 3
then density  3 g=− g
1   2 0.4 2
 2  1  2  3( 1   2 ) .......(ii) If ℎ be the depth upto which ball sink, then
−3
By solving (i) and (ii) we get  1  6 and  2  2 0− =2× g ×ℎ
2
49. ⟹ 2g × 9 = 3gℎ
∴ ℎ = 6 cm
55. v 2 a1  r1 
2

a1 v1  a 2 v 2     
v1 a2  r2 
 v 2  3  (2) = 12 m/s
2

At the condition of equilibrium

56.
Pressure at point A = Pressure at point B
PA  PB 
10  1 .3  g  h  0 . 8  g  (10  h)  13 . 6  g
By solving we get h = 9.7 cm
50. If the liquid is incompressible then mass of liquid
entering through left end, should be equal to
mass of liquid coming out from the right end.

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 59.

60.

57.

58.

CHEMISTRY :-

61. (CH3 )3 C is the most stable carbocation. The actual order is :
   
(CH3 )3 C  C 6H5 C H2  (CH3 )2 C H  CH3 CH2 .
62. Hyperconjugation.
63. Contributing structures contribute to the resonance energy inversely in proportion of their
relative energies, i.e. structures with high energy contribute less while those with low energy
contribute more, Therefore, option (a) is wrong.
sp3 sp2 sp2 sp3
64. (ii) CH3  CH2  CH CH3
Structure (ii) has two types of hybridizations as shown above while in rest of the compounds
, there is only type of hybridization.
65. C6H5CH2  IV   CH3CH2  III    CH3 2 CH  II    CH3 3 C   I.
66. Greater the electronegativity, higher is the I-effect, i.e, – NR2 < – OR < – F.
67. In structure (c), N contains ten electrons in the valence shell which is not possible.
68. Due to – R-effect of the – CHO group, oxygen carries -charge while the terminal carbon
carries   Charge, i.e.,
 
CH2  CH  CH  O
69. IV is stabilized by +I-effect of two CH3 group and by dispersal of +ve charge on the benzene
ring by resonance. III is stabilized by + I-effect of one CH3 group and by dispersal of +ve
charge on the benzene ring. I is stabilized by dispersal of the +ve charge on the benzene
ring while II is not stabilized by any of three factors. Thus the overall order of stability is :
II < I < III < IV i.e., option (a) is correct.
70. Carbocation (a) is antiaromatic and hence is least stable. Carbocation (b), (c) and (d) are all
secondary but (b) and (c) are aromatic. Further since (c) is more strained than (b), therefore,
(b) is the most stable carbocation.
71. Carbocation (II) is most stable due to resonance,
 .. 
CH3  C H  O CH3  CH3  CH  O CH3
.. ..
II
Carbocation (III) is least stable due to electron withdrawing effect of the adjacent carbonyl
group while carbocation (I) is less stable than (II) because it is only stabilized by the + I-
effect of the two CH3 groups. Thus, the overall order of stability

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