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Path to success KOTA (RAJASTHAN)

Acidic strength
1. Which of the following is strongest acid?
H H
+ H + H
N N N
+ H (C) + H
(A) NH4 (B) (D)

2. What is the major product obtained from the following reaction?

COOH
HO NaOH
1 mole
NH3Cl
+

COOH .. COOH COO

–

COO—
HO —O O
(B) HO (C) . . (D) . .
—
(A)
NH2 NH3 NH3
NH3 + +
+
3. Which of the following compounds has most acidic hydrogen?
H
N
O S O
C6 H 5
(A) C6 H 5 (B) C6 H 5 (C) (D) C6 H 5
N
O S N
H
H
4. The correct order of acidic strength is/are
–
COOH COOH COOH COOH
OH OH OH OH OMe
(A) > (B) >

COOH COOH
COOH COOH

(C) > (D) >

COOH HOOC
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5. With respect to the compounds I–V, choose the correct statement(s)

H
H H

(I) (II) (III) CH3 – H (IV) (V) H H

(A) The acidity of compound I is due to delocolisation in the conjugate base

(B) The conjugate base of compound IV is aromatic
(C) Compound II becomes more acidic, when it has a –NO2 substituent.
(D) The acidity of compounds follow the order
I > IV > V > II > III
6. The CORRECT order of acidic strength of given compound(s) is/are
OH OH OH
OCH3
(A) > >
OCH3
OCH3

H H H

N O O N O O N O
(B) > >
N
H

H H H
(C) > >

(D) HCOOH > CH3COOH > C6H5COOH

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Comprehension for Q.7 and Q.8

For the following compounds:
OH
OH CH 2 – OH OH
NO2
(P) (Q) (R) (S)

COOH

OH
OH
NO2 NO2

(T) H2CO3 (U) (V) CH3–OH (W)

NO2
NO2
7. Choose the possible pair(s) of binory mixture which is/are appropriate for the following scheme?

Aq.NaOH Salt of binary

mixture

Binary
mixture

Aq.NaHCO3
Compound 1 + Compound 2

(A) R and V (B) P and S (C) R and W (D) Q and U

8. Choose the correct option(s)
(A) Correct acidic strength order is U > W > T > S
(B) (S) has ‘5’ resonating structure
(C) Correct acidic strength order P > H2O > V > R
(D) Out of ‘8’ only ‘2’ an soluble in aqueous NaOH
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9. Matrix Match
Column-I Column-II
Compounds pKa values
O O
(A) (P) 3.5
O
O O
(B) (Q) 10.7

O O
(C) (R) 8.9
H H
O
O
(D) N (S) 0.4
H O
10. Find the number of compound which are more acidic than H2O
OH
(1) CH3CH2–OH (2) CH3–C º CH (3) HF (4)

(5) HCl (6) CH3 – COOH (7) H2CO3 (8) HBr

(9) NH3 (10) COOH (11) CH – SH

3