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Chemistry PART – II

SECTION – A

1. D
H
H H
B B
H
H H
H CH3 CH3
B 2 H6 B B
methylation
CH3
CH3
H

2. D
H
+
OH OH +
CH2 H
H+ ring. exp
+
-H2 O
HO HO
HO HO
OH HO
OH OH

+
H /excess
similar repetation
HO
HO

3. A
At nodal surface,  = 0
2 2
r  Å = 1Å
z z
4. C
+2
Co – ordination no of Fe in D is 6

-
+
- Na +2
Fe (a sandwhich compound)
C
-

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5. C
O
O
Zn(Hg) SOCl2
AlCl3 HCl
+ O

HO HO Cl O
O
A B O
O C
AlCl3

Br
NaBH4
NBS/CCl4 H2SO4

F E D
G OH O
ONa
OH
heat

H
6. C
O O O
H -
OH H OH
(a) -
+ OH
-

O-D D - OD D - OD
O O DO- O O
H
H -
- D D
(b)

-
DO
-
O O O
D O D D
D D H D - OD
D
D
D D
D

D H H
DO- DO - D -
OD

O O
O D D
D D D D
O-D D
D D
H
-
- D - OD
D D D D
D
DO - D

O O
D D
D D
D Repeat last two step
D
D D

D D D D D
D

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O O O
H
-
(d) H OH
OH -
H OH
HO - H

7. A
Synergic bonding.

8. A, B, C
K2 Ho  T2  T1 
log    K1 & K 2 are eq. cons tan t
K1 2.303R  T1T2 
K2 Ea  T2  T1 
log    K1 & K 2 are rate cons tan t
K1 2.303R  T1T2 

9. B

H3C Me CH3
+ 
H3C N OH -
H2C
CH3
H3C Me CH3
(Major product)

Due to greater probability of losing -H (9 : 3 ratio).

10. B, C
(b) conjugate base of H2PO4 is HPO24 

1
(c) pH of 0.1 M NaCl (aqueous solution) = pK w
2
11. A, C
A 3  3e  Al

4.5
Number of moles of Al produced   0.166
27
Number of moles of electrons used  3  0.166
1
H  e   H2
2
1
Number of moles of H2 produced   3  0.166
2
Volume of H2 produced  1.5  0.166  22.4  5.57  5.6
12. C
2nd step is r.d.s. in sulphonation reaction.

13. B

2nd step is fast step in nitration.

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14. A
 a
 P    V  b   RT
 V
on converting into virial equation from, we get
  a  
 b  2  2 3 
PV  RT  RT   b  b  ....... to higher power of n …(i)
V 2 4
 V V 
 
 
For Boyle’s temperature, 2nd virial co-efficient becomes zero
a
b 
RT 2
a
TB 
Rb
a
 TB2 
RB
2a
 Ti   Ti  2TB2
Rb

15. A

Let Boyle’s temperature, TB'

a
 TB 
Rb
8a a
TB'  2  2TB
R  2b Rb

16. D

b2 = 0.04
b = 0.2 lit/mol
Vreal = 4  22.4 + 4  0.2 = 90.4 lit
SECTION – B
1.  A  r  ,B  p,t  , C  q,s D  q,s  .
(A) Sic covalent carbide (Not hydrolysed)
(B) Al4 C3  12H2O  4Al  OH3  3CH4

(C) Cal2  2H2 O  Ca  OH2  H  C  C  H

(D) Mg2 C3  4H2 O  2Mg  OH 2  CH3  C  CH

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2.  A  p,q,s  , B  q , C  r,t D  q .

Al2  SO4 3  2Al3  3SO 4
0.2M 0.3M
3 3
AlPO 4  Al  PO 4

0.1M 0.1M
Urea 
 Urea
0.1M
MgCl2  Mg2  2Cl
0.1M 0.2M

SECTION – C
1. 4
Based on fact

2. 7
OH
-
B
O O
+
2Na HO B O B OH 8H2O
O -
O
B
OH

3. 3
OHC CHO CHO

, ,

Cl NO2 C
N

4. 3
OCH3 NH2
OCH3

, ,
H3CO OCH3 OCH3
H3CO

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5. 2
1 1 100
t 99  n100; t 90  n
K K 10
t 99 n100 2
  2
t 90 n10 1
hence x  2

6. 3

H H
S O

H Cl
C C C
, , Cl
H
0
O
S
H
H
0 0

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