Date: 21-08-22

16-02-24
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62

Page No: 2
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. The potential energy of a particle varies with position x according to the relation U(x) =
3
2x4 – 27x the point x = is point of
2

A) Unstable equilibrium B) Stable equilibrium

C) Neutral equilibrium D) None of these

2. An object of mass m = 0.5 kg when attached to a vertical spring and lowered very
slowly to its equilibrium position stretches the spring by 10cm.If the same object is
attached to the same vertical spring but permitted to fall instead, then the maximum
speed of the mass will be (take
g = 10 m/s2)
1
A) 1m/s B) 2 m/s C) 2
m/s D) 1 m/s
2

3. In the figure, the ball A is released from rest when the spring is at its natural
(unstretched) length. For the block B, of mass M to leave contact with the ground at
some stage, the minimum mass of A must be

B M

A)2M B) M C)M/2

D) a function of M and the force constant of the spring

Page No: 3
4. A particle, which is constrained to move along the x-axis, is subjected to a force in the
same direction which varies with the distance x of the particle from the origin as

F(x) = – kx + ax3. Here k and a are positive constants. For x > 0, the functional form of
the potential energy U (x) of the particle is
U(x) U(x) U(x) U(x)

A) x B) x C) x D) x

5 1 kg block collides with a horizontal weightless spring of force constant 100 Nm, as
shown in the figure. The block compresses the spring 0.4 m from the rest position.
Assuming that the coefficient of kinetic friction between the block and the horizontal
surface is 0.9, the speed of the block at the instant of collision is approximately
(g = 10 m/s2)
v0
M

A) 4.8 m/s B) 5.6 m/s C) 1.4 m/s D) 5.8 m/s

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. A man of mass m is standing on a stationary flat trolly of mass M. The trolly can move
without friction on the horizontal rails. The man starts walking with speed v relative to
trolley, then work done by him (the trolly can move only along the rails)–
1
A) is greater than mv2 if he walks along rails
2

1
B) is less than mv2 if he walks along rails
2

1
C) is equal to mv2if he walks normal to rails
2

D) None of above

Page No: 4
7. The potential energy U in joule of a particle of mass 1 kg, moving in the XY plane,
obeys the law U = 3x + 4y, where (x, y) are the coordinates of the particle in metre. If
the particle is at rest at (6, 4) at time t = 0, then

A) the particle has constant acceleration

B) the work done by the external force from the position of rest of the particle and the
instant of the particle crossing X-axis, is 25 joule

C)the speed of the particle when it crosses the Y-axis is 10 m/s

D) the coordinates of the particle at time t = 4s are (–18, –28)

8. Figure shows net interaction force (Conservative) between two particles A and B
against the distance between them, when the distance between them varies from x1 to
x4 ? Then
Attraction

x1
O
x2 x3 x4
Repulsion

A) potential energy of the system increases from x1and x2

B) potential energy of the system increases from x2and x3
C) potential energy of the system increases from x3and x4
D) kinetic energy increases from x1to x2 and decreases from x2to x3 when particles
are allowed to move due their mutual interaction force freely.
9. Choose the correct options

A) Work energy theorem is valid in non-inertial frame if we take work done by pseudo
force also

B) Work done by non-conservative force is equal to change in mechanical energy

C) Work done by friction may be positive

D) Work done by force is frame dependent

Page No: 5
10. A particle of mass m is at rest in a train moving with constant velocity with respect to
ground. Now the particle is accelerated by a constant force F0 acting in the direction of
motion of train for time t0. A girl in the train and a boy on the ground measure the work
done by this force. Which of the following are incorrect

A) Both will measure the same work

B) Boy will measure higher value than the girl

C) Girl will measure higher value than the boy

D) Data is insufficient for the measurement of work done by the force F0

11. A force F = – kx3 is acting on a block moving along x-axis. Here, k is a positive
constant. Work done by this force is

A) positive in displacing the block from x = 3 to x = 1.

B) positive in displacing the block from x = –1 to x = –3.

C) negative in displacing the block from x = 3 to x = 1.

D) negative in displacing the block from x = –1 to x = –3

12. A block is suspended by an ideal spring of force constant K. If the block is pulled
down by applying a constant force F and if maximum displacement of block from its
initial position of rest is , then

F 2F
A) 
K K

2F
B) 
K

C) Work done by force F is equal to F

D) Increase in energy stored in spring is 1 K 2

2

13. One end of a light spring of force constant k is fixed to a wall and the other end is tied
to a block placed on a smooth horizontal surface. In a displacement, the work done by

the spring is 1 kx2. The possible case (s) may be –

2

Page No: 6
 A) The spring was initially stretched by a distance x and finally was in its natural
length

B) The spring was initially in its natural length and finally it was compressed by a distance
x

C) The spring was initially compressed by a distance x and finally was in its natural
length.

D) The spring was initially in its natural length and finally stretched by a distance x.

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. For the potential energy function shown in fig. How many equilibrium positions are
present

15. A spring of force constant 800 N/m has an extension of 5 cm. The work required to
extend it from 5 cm to 15 cm is.

16. A block of mass m = 1kg moving on horizontal surface with speed u = 2m/s enters a
rough horizontal patch ranging from x = 0.10 m to x = 2.00m. If the retarding force fr
on the block in this range is inversely proportional to x over this range i.e.

k
f r= 0.10 < x < 2.00
x

=0 for x < 0.10 and x > 2.00

If k = 0.5 J then the speed of this block as it crosses the patch is (use n 20 = 3) in m/s

is.

Page No: 7
17. A block (B) is attached to two unstretched spring S1 and S2 with spring constants k and
4k, respectively (see figure I). The other ends are attached to identical supports M1 and
M2 not attached to the walls. The springs and supports have negligible mass. There is
no friction anywhere. The block B is displaced towards wall 1 by a small distance x
(figure II) and released. The block returns to its initial position and moves a maximum
distance y towards wall 2. Displacements x and y are measured with respect to the
x
equilibrium position of the block B. The ratio is
y

M1 1 I
2 M2 S 2 S1
B
x
2 M2 M 1 II
S2 S1 1
B

18. In a spring , it is found that the spring force F and the extension in the spring x are
1
related as shown in figure. Then the value of the force constant of the spring is .Find
x

‘x’.
F

O
30º x

Page No: 8
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. Following two equilibrium is simultaneously established in a container

PCl5 (g)  PCl3 (g)  Cl 2 (g)

CO(g)  Cl 2 (g)  COCl 2 (g)

If some Ni(s) is introduced in the container forming Ni(CO) 4 (g) then at new
equilibrium

A) PCl3 concentration will increase

B) PCl3 concentration will decrease

C) Cl2 concentration will remain same

D) CO concentration will remain same

20. The equilibrium constant K p (in atm) for the reaction is 9 at 300 K.

A 2 (g)  B2 (g)  C 2 (g)

Calculate the average molar mass (in gm/mol) of an equilibrium mixture if total
pressure at equilibrium is 7atm.

Given: Molar mass of A 2 , B2andC 2 are 70, 49 & 21 gm/mol respectively.

A) 50 B) 45 C) 40 D) 37.5

21. The equilibrium constant for the equation,

N 2 (g)  O 2 (g)  2NO(g) is 5  104 at1500K.

In the presence of a catalyst the equilibrium is attained 8 times faster. Therefore the
equilibrium constant in presence of catalyst at 1500 K is

5
A)  104 B) 4  103 C) 5  104 D) Unpredictable
8

Page No: 9
22. In a container of 1 L which contains 4mol of NH 3 and 6 moles of H 2S at equilibrium.
Calculate the number of moles of H 2S that should be added such that at new
equilibrium, moles of NH 3 decreases by 50% of its value at previous equilibrium.

NH 4 HS(g)  NH 3 (g)  H 2S(g) K C  12 molar 1

A) 20 B) 22 C) 24 D) 18

23. The equilibrium constants K P1 and K P2 for the reactions, X  2Y and Z  P  Q,

respectively are in the ratio of 1:9. If the degree of dissociation of X and Z be equal
then the ratio of total pressure at these equilibria is:

A) 1: 36 B) 1:1 C) 1: 3 D) 1: 9

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. In which of the following situations equilibrium constant value  K c  is not affected?
Initial value of it is greater than one. Number of moles of gases increases during the
reaction.
A) On addition of inert gas at constant pressure
B) On addition of inhibitor
C) On multiplying the reaction by 2.
D) On increasing the total pressure of equilibrium.
25. Phase diagram of CO 2 is shown as following

Based on above find the correct statement(s)

Page No: 10
 A) 298K is the normal boiling point of liquid CO 2

B) At 1 atm & 190 K, CO 2 will exist as gas.

C) CO 2 (s) will sublime at above 195K under normal atmospheric pressure

D) Melting point & boiling point of CO 2 will increase on increasing pressure

26. The equilibrium between gaseous isomers A, B and C can be represented as

Reaction Equilibrium constant

A(g)  B(g) : K1  ?

B(g)  C(g) : K 2  0.4

C(g)  A(g) : K 3  0.6

If one mole of A is taken in a closed vessel of volume 1 litre, then

A) [A]  [B]  [C]  1M at any time of the reactions

B) Concentration of C is 4.1 M at the attainment equilibrium in all the reactions

1
C) The value of K1 is (nearly)
0.24

D) Isomer [A] is least stable as per thermodynamics.

27. Which of the following is/are INCORRECT?

A) There are two phases in the decomposition of CaCO3 in closed space and the
equilibrium is heterogeneous.

B) When liquid water is heated in closed vessel, boiling occurs at 373K.

C) As temperature decreases rate of endothermic reaction decreases and rate of

exothermic reaction increases in reversible reaction.

D) Irrespective of stoichiometric representation for the dissociation of

PCl5(g) to PC 3(g) & Cl 2(g) ;Kp is always greater than Kc (Consider T  250 C )

Page No: 11
28. Which of the following is/are correct for the formation of ammonia from dinitrogen
and dihydrogen.

A) On addition of inert gas at constant pressure yield of ammonia will decreases.

B) On addition of inert solvent to reaction vessel (rigid) yield of ammonia decreases.

C) Yield of ammonia can be increased by increasing pressure.

D) Yield of ammonia can be increased by increasing temperature.

29. Information

1. Lattice enthalpy of salt AB is greater than hydration enthalpy.

2. Lattice enthalpy of salt XY is less than hydration enthalpy

3. AB & XY are colour less.

Which of the following is/are correct?

A) On dissolving salt AB in the above solution, intensity of pink colour increases.

B) On dissolving salt XY in the above solution, intensity of blue colour increases.

C) On dissolving salt AB in the solution, intensity of blue colour increases

D) On dissolving salt XY in the above solution, intensity of pink colour increases.

Page No: 12
 1 1
30. N 2  g   O2  g   NO  g  ; H 0  90 kJ mol 1
2 2

1
NO  g   O2  g   NO2  g  ; H 0  74 kJ mol 1
2

Based on the above data; select the correct statement(s).

A) NO and NO2 both are endothermic compounds

B) NO2 is thermodynamically more stable than NO

C) Heat of formation of NO2 is 16 kJ mol 1

D) Heat of formation of NO2 is 74 kJ mol 1

31. Which of the following is/are correct?

A) Catalyst lowers the activation energy for forward and backward reactions by
exactly the same amount.

B)When inert gas is added at constant volume, increase in total pressure is

compensated by decrease in mole fraction of the gas and keeps partial pressure of
reacting gaseous species remains constant.

C) Chemical equilibrium is dynamic and rate of forward reaction is equal to rate of

backward reaction.

D) Addition of small amount of CaCO3 (S) to the reaction vessel contain the following
equilibrium reaction drives the reaction in forward direction(neglect the volume
change)

 CaO(S)  CO2 (g)

CaCO3 (S) 

Page No: 13
 SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. The following equilibria are established on mixing two gases A 2 and C.

3A 2 (g)  A 6 (g);K P  1.6atm 2

A 2 (g)  C(g)  A 2C(g);K P  'x 'atm 1

When A 2 (g)and C(g) are mixed in 2: 1 molar ratio the total pressure of gases at
equilibrium is found to be 1.4 atm and partial pressure of A 6 (g),0.2atm. The value of
'4x' is
33. To 500 ml of 0.9 M  AgNO 3 solution was added 500ml of 1.0M  Fe2 solution and

the reaction is allowed to achieve equilibrium at 25o C .

Ag  (aq)  Fe 2 (aq)  Fe3 (aq)  Ag(s) for 30ml of the solution, 25 ml of 0.06 M

acidified- KMnO 4 was required for oxidation of Fe2 present. The equilibrium constant

(in M 1 ) for the reaction at 25o C is

34. Enthalpies of combustion of CH 4 ,C 2 H 6 and C3H 8 are -210, -370 and -526 kcal / mol,
respectively. Magnitude of enthalpy of combustion of hexane (C 6 H14 ) is predicted as
X k.Cal / mol. Value of X/250 is (nearest integer)

35. The standard molar enthalpies of formation of cyclohexane(1) and benzene(1) at 298 K
are -156 and +49 kJ/mol, respectively. The standard enthalpy of hydrogenation of
cyclohexene (1) at 298 K is -119 kJ/mol. Use these data to estimate the magnitude of
the resonance energy of benzene which is 'XYZ' kj/mol. XYZ are the digits of the
value. Find X+ Y+ Z

36. The adiabatic flame temperature of CH 4 at constant pressure when one mole is burnt
with air which posses O 2 and N 2 in 1: 4 volume ratio is nearly 1000X K. (Cp of CO 2 is
37.1,H 2O is33.6, N 2 is 29.1J / K / mole, heat of combustion of methane is 900KJ/mol,

initial temperature of fuel is 300 K). The value of X is:

Page No: 14
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. If sin 6  sin 4  sin 2 then  must be, for some integer n, equal to
n  n  n
A) B) n  C) or n  D)
4 6 4 6 2
38. The number of solutions of the pair of equations 2sin 2   cos 2  0 and
2 cos 2   3sin   0 in the interval [0, 2] is

A) 0 B) 1 C) 2 D) 4
   1
39. If sum of all the solutions of the equation 8cos x  cos   x  .cos   x     1
6   6  2  

in [0, ] is k , then k is equal to

2 13 8 20
A) B) C) D)
3 9 9 9
40. If the trigonometric equation 1  sin 2 x  cos  has a non zero solution in  , then x must
be
A) an integer B) a rational number
C) an irrational number D) strictly between 0 to 1

41. The number of solution to sin( sin 2 ())  sin( cos 2 ())  2 cos  cos()  satisfying
2 
0    2 is

A) 1 B) 2 C) 4 D) 7
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
42. 4sin 4 x  cos 4 x  1 , If x is equal to (n  Z)
2 2n 
A) n B) n  sin 1 C) D) 2n 
5 3 4
43. sin 3   sin  cos   cos3   1 , if  is equal to (n  Z)
 
A) 2n B) 2n  C) 2n  D) n
2 2

Page No: 15
44. A set of values of  satisfying tan 2   cos 2  1 is (n  Z)
  
A) n   B) 2n   C) n  D) n
 4  4 4
45. A solution set of inequality sin 3 x cos x  cos3 x sin x , where x  (0, ) , is
  3    3
A)  ,  B)  , C)  0,  D)  , 

4 2   4   4  2 4 
46. If x  y   / 4 and tan x  tan y  1 , then (n  Z)
A) cos x cos y  0 B) sin x sin y  0
1 1
C) cos x cos y   D) sin x sin y  
2 2
2 sin x
47. If x  y  and  2 , then the
3 sin y
A) Number of values of x  [0, 4] are 4 B) Number of values of x  [0, 4] are 2
C) Number of values of y  [0, 4] are 4 D) Number of values of y  [0, 4] are 8
3x x
48. The values of x, between 0 and 2 , satisfying the equation cos 3x  cos 2x  sin  sin
2 2
are
 5 9 7
A) B) C) D)
7 7 7 3
3 1 3 1
49. The value of x in (0,  / 2) satisfying  4 2
sin x cos x
 5 7 11
A) B) C) D)
12 12 24 36
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
50. The number of different angles  satisfying the equation cos   cos 2  1 and at the
same time satisfying the condition 0    360º is
51. The number of integral values of k for which the equation 7 cos x  5sin x  2k  1 has a
solution, is
52. Number of solutions of the equation tan x  sec x  2 cos x lying in the interval [0, 2] is
53. If 0  x  2 , then the number of real values of x, which satisfy the equation
cos x  cos 2x  cos 3x  cos 4x  0
  n
54. The number of values of  in the interval   ,  such that   for n  0, 1, 2 and
 2 2 5
tan   cot 5 as well as sin 2  cos 4 is …..

Page No: 16