Wta-18 Q.paper

Sri Chaitanya IIT Academy.,India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant

ICON Central Office - Madhapur - Hyderabad
Sec:Jr.C-120 2020_P1 Date: 04-12-22
Time: 09.00AM to 12.00PM WTA-18 Max. Marks:198
04-12-2022_Jr.C-120
Jee-Adv(2020-P1)_WTA-18_Weekend Test Syllabus
MATHEMATICS : 3-D Co-ordinate system, D.C's & D.R's (Complete)

PHYSICS : Fluids (Statics&Dynamics): upto Floating bodies
CHEMISTRY T-1 : Ionic Equilibrium (Complete)

CHEMISTRY T-2 : Alkynes: upto Reactions of alkynes
Name of the Student: ___________________ H.T. NO:

Sri Chaitanya IIT Academy 04-12-2022_Jr.C-120_Jee-Adv(2020-P1)_WTA-18_Q.PAPER
JEE-ADVANCE-2020-P1-Model
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs mark
Sec – I(Q.N : 1 – 6) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 7 – 12) 4 -2 6 24
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 13 – 18) 4 0 6 24
Answer Type
Total 18 66
CHEMISTRY:
Marks Marks Qs marks
Sec – II(Q.N : 25 – 30) 4 -2 6 24
Sec – III(Q.N : 31 – 36) 4 0 6 24
Answer Type
Total 18 66
MATHEMATICS:
Marks Marks Qs marks
Sec – II(Q.N : 43 – 48) 4 -2 6 24
Sec – III(Q.N : 49 – 54) 4 0 6 24
Answer Type
Total 18 66
Sec: Jr.C-120 Space for rough work Page 2

PHYSICS Max Marks: 66
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
• Each question has FOUR options. ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct option is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -1 In all other cases
1. A sphere of solid material of relative density 9 has a concentric spherical cavity, just
sinks in water. If the radius of the sphere be R , then the radius of the cavity (r) will be
related to R as :
8 3 2 3 8 3 2 3
A) r 3  R B) r 3  R R C) r 3 
D) r 3  R
9 3 3 3
2. A wide vessel with is filled with water of density 1 and kerosene of density 2 . The
thickness of water layer is h1 and that of kerosene layer is h2 . The gauge pressure at the
bottom of the vessel will be
h2 Kerosene
h1 Water
A) h11g B) h2 2 g
C) h11g  h2 2 g D) h12 g  h2 1g
3. A conical flask of mass 10 kg and base area 103 cm2 is floating in liquid of specific
gravity 1.2 as shown in the figure. The force that liquid exerts on curved surface of
conical flask is ( g  10 m / s 2 )
 10 cm
A) 20 N in downward direction B) 40 N in downward direction

C) 20 N in upward direction D) 40 N in upwards direction
4. The height of water in a vessel is h . The vessel wall of width b is at an angle  to the
vertical. The net force exerted by the water on the wall is
A
1
A)  bgh 2 g cos  B)  h 2 pg
3
1
C)  bh 2 g sec  D)Zero
2
5. In a hydraulic lift, used at a service station the radius of the large and small piston are in
the ratio of 20 : 1. What weight placed on the small piston will be sufficient to lift a car of
mass 1500 kg ?
A) 3.75 kg B) 37.5 kg C) 7.5 kg D) 75 kg
6. A cubical block of wood of specific gravity 0.5 and chunk of concrete of specific gravity
2.5 are fastened together. The ratio of mass of concrete to the mass of wood which
makes the combination to float with its entire volume submerged in water is
5 6 5 4
A) B) C) D)
3 5 2 3

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks: +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
7. An object is floating in a liquid, kept in a container. The container is placed in a lift. Choose
the correct option(s)
A) Buoyant force increases as lift accelerates up
B) Buoyant force decreases as lift accelerates up
C) Buoyant force remains constant as lift accelerates
D) The fraction of solid submerged into liquid does not change
8. A small solid ball of density p is held inside at point A a cubical container of side L,
filled with an ideal liquid of density 4 p as shown in the figure. Now, if the container
starts moving with constant acceleration a horizontally and the ball is released from point
A simultaneously, then
p Q
L/2
A a
L/2
R L S
A) For ball to hit the top of container at end Q, a = 3g
B) For ball to hit the top of container at end Q, a = 2g
L
C) Ball hits the top of container at end Q after a time t =
3g
2L
D) Ball hits the top of container at end Q after a time t =
3g
9. A block of mass ‘m’ is attached by means of a spring to the bottom of a tank of water as
shown in figure. At equilibrium, the spring is under compression. If the tank is now allowed
to fall freely, then choose the correct alternative(s)
A) the spring comes to its relaxed position

B) the spring compresses more than its equilibrium compression just after release.
C) the boyant force becomes zero
D) there will be some elongation is the spring
10. A sample of metal weights 210 g in air, 180 g in water and 120 g in liquid. Then Relative
Density (RD) of
A) Metal is 3 B) Metal is 7
C) Liquid is 3 D) Liquid is 7
11. A block of density 2000 kg/ m 3 and mass 10 kg is suspended by a spring of force constant
100 N/m. The other end of the spring is attached to a fixed support. The block is
completely submerged in a liquid of density 1000 kg/ m3 . If the block is in equilibrium

position.
A) The elongation of the spring is 1 cm
B) The magnitude of buogant force acting on the block is 50 N
C) The spring potential energy is 12.5 J
D) Magnitude of spring force on the block is greater than the weight of the block
12. A U-tube is partially filled with water. Oil which does not mix with water Is next poured
into one side until water rises by 25 cm on the other side. If the density of oil is 0.8, the
oil level will stand higher than the water level by
A) 6.25 cm B) 12.50 cm C) 31.75 cm D) 62.50 cm
SECTION – III
(NUMERICAL VALUE TYPE)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place designated
to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered;
Zero Marks: 0 In all other cases
13. A hollow conical vessel floats in water with its vertex downwards and a certain depth of
its axis immersed. When water is poured into it up to the level originally immersed, it
sinks till its mouth is on level with the surface of water. The fraction of its height was
originally under water is 21/ x then the value of x is________
14. A sphere of radius R has a concentric cavity of radius r. The relative density of the
material of the sphere is  . It just floats when placed in a tank full of water. The ratio
1/ x
r   1 
is    then the value of x is________
R   
 27 
15. A cone made of a material of relative density  s   and height 4 m floats with its apex
 64 
downward in a big vessel containing water. The submerged height of cone in water in cm
is_________

16. At rest, a liquid stands at the same level in the tubes. As the system is given an
acceleration a towards the right, a height difference h occurs as shown in the figure. The
aL
value of h is then the value of n is____________
ng
17. In the figure shown, the heavy cylinder (radius R) resting on a smooth surface separates
two liquids of densities 2 and 3. The height h for the equilibrium of cylinder must be
NR then the value of N is_______
h R R
18. A wooden plank of length 1m and uniform cross-section is hinged at one end to the
bottom of a tank as shown in figure. The tank is filled with water up to a height of 0.5 m.
The specific gravity of the plank is 0.5. then the value of cos  if angle  is that the
plank makes with the vertical in the equilibrium position is _______

0.5m

CHEMISTRY Max Marks: 66
SECTION – I
19. Which of the following is a buffer solution?
A) 500 mL of 0.1 M CH 3 COOH + 500 mL of 0.1M NaOH
B) 500 mL of 0.2 M CH 3 COOH + 500 mL of 0.1 M NaOH
C) 500 mL of 0.1 M CH 3 COOH + 500 mL of 0.2 M NaOH
D) 500 mL of 0.1 M CH 3 COOH + 500 mL of 0.1 M HCI
20. The pKb , value of ammonium hydroxide is 4.75. An aqueous solution of ammonium
hydroxide is titrated with HCI. The pH of the solution at the point where half of the
ammonium hydroxide has been neutralized will be :
A) 9.25 B) 8.25 C) 7.50 D) 4.75
21. The K sp of Ag 2CrO4 is 1.1  1012 at 298 K. The solubility (in mol) of Ag 2CrO4 in
0.1 M AgNO3 solution, is
A)1.1 10 11 B)1.1  1010 C)1.1  1012 D)1.1  10 9
R H
Birch
R R
reduction
H R source of two H atoms which
22. In the reaction,
are added to alkyne to give trans-alkene is:
A) NH 3 B) EtOH
C) Et  NH 2 D) Both (a) and (c)

NaliqN
. H3
(B)
(A)
EtOH
LiAl H4
23. (C)
Compounds (B) and (C) are:
A) Both are (I)
(II)
B) Both are
(III)
C) Both are
D) B is (I) and C is (II)

CuCI H2 + Ni2B Br2
2H H A B C
NH4CI (Major)
24.
The major amount of (C) is:
Br Br
Br
A)
Br B)
Br Br
Br Br
Br
Br Br Br
C) D)
SECTION – II
25. The concentration of sulphide ion in 0.1 M HCl solution saturated with H 2 S is
1.0 1019 M. If 10 mL of this solution is added to 5 mL of 0.04 M solution of the
following
MnCl2 K sp of MnS 2.5 1013 ZnCl2 K sp of ZnS 1.6 1021
CdCl2 K sp of CdS 8.0  1027 CuSO4 K sp of CuS 6.3  1036
In which of these solutions precipitation will take place?
A) Mn2 B) Zn 2 C) Cd 2 D) Cu 2 

26. Which one or more of the following operations will not change pH of an acidic or basic
buffer?
A) Diluting the mixture ten times
B) Adding a drop of HCl
C) Adding a drop of NaOH
D) Adding equal moles of each component of the buffer
HIn  H   In 
colourless Pink
27. For any weak acid indicator HIn ionizing as
Select correct statement(s).
[ In ] 1
A) Solution appears colourless when 
[ HIn] 10
[ In ]
B) Solution appears pink when  10
[ HIn]
C) Solution changes colourless to pink when p H changes from ( pK a  1) to ( pK a  1)
D) Solution changes colourless to pink when p H changes from ( pK a  1) to ( pK a  1)
28. Which of the statements are correct for alkyne with molecular formula C6 H10 ?
A) It shows 7 structural isomers.
B) It shows 4 terminal and 3 internal alkynes.
C) It shows 3 terminal and 4 internal alkynes.
D) Only one isomer is chiral.

Dil. H2SO4/Hg2+
(i) Hg(OAc)2,H2O
(A)  (B)
(ii) NaBH4 OH
(i) BH3/THF
(ii) H2O2/OH
29.
Compounds (B) is same when (A) is:
Me
Me Me B) H
A)
Me
Me
C)
H H D)
Na+liq.NH3 Br2/CCI4
R R' (A) B+C
30. +Et OH
Where (B) and (C) are:
A) Enantiomers if R  R '.
B) Diastereomers if R  R '.
C) Both are meso and hence the same compound if R  R '.
D) An equimolar mixture of (B) and (C) is a racemic mixture if R  R '.

SECTION – III
31. PbCl2 ( s)  Pb2  (aq)+ 2Cl  (aq). A graph is made between log[ Pb 2 ] and
log[Cl  ] as show below.

log(Pb2+)
log (Cl-)
What is numerical value of the slope of the line?
32. As mole fraction of A in a buffer of HA (weak acid) and A (conjugate base) is
increased, p H increases as shown below. What is the value of pK a of HA?
6

5.0 

4.5 
pH 4.0
0
0.2 0.4 0.6 0.8 XA
1.0

33. 6.02  10 y H ions are present in 1 mL solution of p OH  1. What is the value of y?
34. How many of the following are Lewis bases?

H 2 O, NH 3 , CH 3 NH 2 , C6 H 5 NH 2 , OH  , F  , H  , BF3 , FeCI 3
Br
Me 4 2 Me
1 ? NaNH
3
2 H
2HBr
Br Butyne
35.
Vicinal dihalides undergo double dehydrohalogenation to give terminal alkyne. How
many moles of NaNH 2 are used in the overall reaction?
36. The number of possible Alkyenes (structural) with molecular formula C5 H8 is

MATHEMATICS Max Marks: 66
SECTION – I
37. If (2, 1, 3), (3, 1, 5) and (1, 2, 4) are the mid points of the sides BC, CA, AB of ABC
respectively, then the perimeter of the triangle is
A) 2 6  3 B) 2( 5  6  3)
C) 2( 6  3) D) 6  3
38. The distance between the origin and the centroid of the tetrahedron whose vertices are (0,
0, 0), ( a , 0,0), (0,b,0), (0,0,c) is
2 2 2 a 2  b2  c 2
A) a  b  c B)
2
a 2  b2  c 2
C) D) 4 a 2  b 2  c2
4
39. The transformed equation of 2 x 2  3 y 2  z 2  4 x  6 y  4 z  0 when the axes are
translated to the point (-1, 1, 2) is
A) 2 x 2  3 y 2  z 2  10 B) 2 x 2  3 y 2  z 2  5
C) 2 x 2  3 y 2  z 2  15 D) 2 x 2  3 y 2  z 2  5
40. The angle between any two diagonals of a cube is

1  1   2  1 2
A) cos 1   B) cos 1    C) cos 1 
D) cos
 3  3  3 3
41. If the dc’s of two lines are given by l  m  n  0 , mn  2l n  lm  0 , then the angle
between the lines is
  
A) B) C) D)0
4 3 2
42. A line segment PQ has the length ‘63’ and d.r’s (3, -2,6). If the line obtuse angle with x-
axis then components of vector PQ are
A) -27,18,-54 B) -27,18,54
C) 7,8,-4 D) -7,8,-4

SECTION – II
43. OABC is a regular tetrahedron of unit edge. It’s volume is
1 1 1 1
A) B) C) D)
3 72 3 2 6 2
44. If l1 , m1 , n1 and l2 , m2 , n2 are the d.c’s of the two lines inclined at an angle 120 , then
d.c’s of the line bisecting the angle between them are
l  l m  m2 n1  n2 l  l m  m2 n1  n2
A) 1 2 , 1 , B) 1 2 , 1 ,
2 2 2 3 3 3
l  l m  m2 n1  n2
C) 1 2 , 1 , D) l1  l2 , m1  m2 , n1  n2
2 2 2
45. A mirror and source of light are kept at the origin and at a point on the positive x-axis
respectively a ray of light from the sources strikes the mirror and is reflected. If (1,-1,1)
are the d.r’s of a normal to the plane then the d.c’s of the reflected ray are
 1 2 2   1 2 2 
A)  , ,  B)  , , 
 3 3 3  3 3 3
 1 2 2   1 1 1 
C)  , ,  D)  , , 
3 3 3  3 3 3

46. A line passes through two points A(2,-3,-1) and B(8,-1,2). The coordinates of a point on
this line at a distance of 14 units from A are
A) (14,1,5) B) (-10,-7,-7) C) (86,25,41) D) None
47. If the direction ratios of a line are 1   ,1   , 2, and it makes an angle 60 with the y-
axis then  is
A)1  3 B) 2  5 C)1  3 D) 2  5
48. If (1,2,1), (1,-3,2) are the direction ratios of two lines and ( l , m, n) are the direction
cosines of a line perpendicular to the given lines, then l + m + n =
1 1 1
A)1 B) C) D) 
5 3 3 5 5 3
SECTION – III
49. If in a  ABC the mid points of the sides AB,BC,CA are respectively ( l ,0,0),(0,m,0) and
AB 2  BC 2  CA2
(0,0,n). Then  _____________
l 2  m2  n2
50. In ABC if A = (0,0, 4); AB=4, BC = 3, CA = 5, I = (1, 0, 1) is the incentre and the
internal bisector of A intersects BC at D ( ,  ,  ) then       __________

51. P(1,2,-2,) Q(8,10,11) R(1,2,3) S(3,5,7) if  denotes the length of projection of PQ on RS
then 29 2  29 is _____ ___________
52. If  ,  ,  are be angles which a line makes with positive direction of the axes then the
value of cos 2   cos(    ) cos(    )  ______________
53. The direction cosines of a line satisfy the relations  (l  m )  n and mn  nl  lm  0.
The value of  for which the two lines are perpendicular to each other, is _______
54. If a line in the space makes angles  ,  and  with the coordinates axes, then
cos 2  cos 2   cos 2  sin 2   sin 2   sin 2   ________

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant

MATHEMATICS : 3-D Co-ordinate system, D.C's & D.R's (Complete)

CHEMISTRY T-1 : Ionic Equilibrium (Complete)

Name of the Student: ___________________ H.T. NO:

Sec: Jr.C-120 Space for rough work Page 2

A) 20 N in downward direction B) 40 N in downward direction

vertical. The net force exerted by the water on the wall is

A) 3.75 kg B) 37.5 kg C) 7.5 kg D) 75 kg

Sec: Jr.C-120 Space for rough work Page 4

B) For ball to hit the top of container at end Q, a = 2g

A) the spring comes to its relaxed position

completely submerged in a liquid of density 1000 kg/ m3 . If the block is in equilibrium

B) The magnitude of buogant force acting on the block is 50 N

C) The spring potential energy is 12.5 J

oil level will stand higher than the water level by

A) 6.25 cm B) 12.50 cm C) 31.75 cm D) 62.50 cm

originally under water is 21/ x then the value of x is________

Sec: Jr.C-120 Space for rough work Page 7

Sec: Jr.C-120 Space for rough work Page 8

B) 500 mL of 0.2 M CH 3 COOH + 500 mL of 0.1 M NaOH

C) 500 mL of 0.1 M CH 3 COOH + 500 mL of 0.2 M NaOH

D) 500 mL of 0.1 M CH 3 COOH + 500 mL of 0.1 M HCI

0.1 M AgNO3 solution, is

A)1.1 10 11 B)1.1  1010 C)1.1  1012 D)1.1  10 9

C) Et  NH 2 D) Both (a) and (c)

Sec: Jr.C-120 Space for rough work Page 9

Compounds (B) and (C) are:

A) Both are (I)

D) B is (I) and C is (II)

Sec: Jr.C-120 Space for rough work Page 10

The major amount of (C) is:

Sec: Jr.C-120 Space for rough work Page 11

A) Diluting the mixture ten times

B) Adding a drop of HCl

C) Adding a drop of NaOH

D) Adding equal moles of each component of the buffer

A) It shows 7 structural isomers.

B) It shows 4 terminal and 3 internal alkynes.

C) It shows 3 terminal and 4 internal alkynes.

D) Only one isomer is chiral.

Sec: Jr.C-120 Space for rough work Page 12

Where (B) and (C) are:

C) Both are meso and hence the same compound if R  R '.

D) An equimolar mixture of (B) and (C) is a racemic mixture if R  R '.

Sec: Jr.C-120 Space for rough work Page 13

34. How many of the following are Lewis bases?

Sec: Jr.C-120 Space for rough work Page 14

40. The angle between any two diagonals of a cube is

Sec: Jr.C-120 Space for rough work Page 15

d.c’s of the line bisecting the angle between them are

Sec: Jr.C-120 Space for rough work Page 16

this line at a distance of 14 units from A are

A) (14,1,5) B) (-10,-7,-7) C) (86,25,41) D) None

cosines of a line perpendicular to the given lines, then l + m + n =

internal bisector of A intersects BC at D ( ,  ,  ) then       __________

Sec: Jr.C-120 Space for rough work Page 17

then 29 2  29 is _____ ___________

value of cos 2   cos(    ) cos(    )  ______________

53. The direction cosines of a line satisfy the relations  (l  m )  n and mn  nl  lm  0.

cos 2  cos 2   cos 2  sin 2   sin 2   sin 2   ________

Sec: Jr.C-120 Space for rough work Page 18

then 29 2  29 is _ _______