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Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
The co – efficient of kinetic friction between the plane and the block is g 10m / s 2
From a solid sphere of mass M and radius R, a spherical portion of radius is removed as
R
7.
2
shown in figure. Taking gravitational potential V = 0 at r , the potential at the center of
the cavity thus formed is____(G = universal gravitational constant)
4 1 4 1
1) mv 0 i j 2) mv 0 i j
5 10 5 5
3 1 3 1
3) mv0 i j 4) mv0 i j
5 10 5 5
12. A process 1 2 using diatomic gas is shown on the P-V diagram below.
P2 2 P1 106 N / m 2 ,V2 4V1 0.4 m 3 .The molar heat capacity of the gas in this process
will be
1) 240 N 2) 30 N 3) 300 N 4) 90 N
15. Find the x-coordinate of centre of mass of a uniform plate bounded by the parabola
1 3 9 9
1) m 2) m 3) m 4) m
2 20 10 20
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16. A car is moving on a horizontal road whose acceleration versus position graph is drawn
below. At the initial moment of time when particle was at x 0 , its speed was 10 m / s .
Find the speed of the particle when it reaches at x 8 m .
1) 84 m / s 2) 10 m / s 3) 110 m / s 4) 11 m / s
17. Two blocks of mass 3kg and 6kg respectively are placed on a smooth horizontal surface
they are connected by a light spring of force constant k = 200 Nm-1. Initially the spring is
unstretched and velocities of 1 ms-1 and 2 ms-1 are imparted in opposite directions to the
respective blocks as shown in figure. The maximum extension of the spring will be
1) 15 cm 2) 20 cm 3) 25 cm 4) 30 cm
18. A heavy sheet of wood and a light ball is moving towards each other as sown in the figure.
What will be the speed of the ball after collision ?
1) 3v 2) 2v 3) v 4) v/2
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19. A long capillary tube of radius r is initially just vertically completely immersed inside a
liquid of angle of contact 00. If the tube is slowly raised then relation between radius of
curvature of meniscus inside the capillary tube and displacement (h) of tube can be
represented by
1) 2)
3) 4)
20. A man standing on an inclined plane of inclination θ with the horizontal, fires one bullet up
the plane and another bullet down the plane with speed ‘u’. Both the bullets get stuck to the
plane after hitting the inclined plane. The value of maximum possible distance between the
two bullets after they hit the inclined plane is:
2u 2 2u 2 u2 u2
1) 2) 3) 4
g g cos 2 g g cos 2
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. The centre of mass of a solid hemisphere of radius 8 cm is x cm from the centre of the flat
surface. Then value of 2x is _____.
22. A force of - Pk acts on the origin of the coordinate system. The torque about the point
a
b
x
(2, -3) is P ai b j , the ratio of is . Find the value of 5x.
2
3
28. Heat Q RT is supplied to 4 moles of an ideal diatomic gas at temperature T. how many
2
moles of the gas are disassociated into atoms if temperature of gas is constant?
n R3
in the figure. The volume of the upper part (spherical cap) is given as . Find the value
24
of n
30. Block ‘A’ is hanging from a vertical spring and is at rest. Block ‘B’ strikes the block ‘A’
with ‘v’ and sticks to it. Then the value of ‘v’ (in m/s) for which the spring just attains
natural length is
1)2 2) 3 3) 4 4) 8
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36. IUPAC name for the compound should be
Br CONH 2
COOH
CHO COCl
1) 4-Formyl-2-chloroformyl-3-carbamoyl-5-bromohexanoic acid.
2)5-Bromo-4-carbamoyl-2-chloroformyl-3-formylhexanoic acid
3)2- Chloroformyl-3-carbamoyl-4-formyl-5-bromohexanoic acid
4) 5- Bromo-3-carbomoyl-2-chloroformyl-4-formylhexanoic acid.
37. Resonance in carbonate ion CO32
Which of the following is true?
38. Which of the following is the correct plot for the probability density 2 r as a function of
1) 2)
3) 4)
39. The correct stability order of the following three quinone is
O O
O O
O II III
I
CH 3
CH 3
CH 3 H 3C
CH CH
1) 2) 3
3) 3
4)
46. The major product(s) obtained in the following reaction is/are:
i KOBu
ii 2eq O3 / Me2 S
Br
a) b) c)
1) c b a 2) a c b 3) b c a 4) a b c
48. Benzene on nitration gives nitrobenzene in presence of HNO3 and H 2 SO4 mixture, where:
1)both H 2 SO4and HNO3 act as an acids
2)both H 2 SO4and HNO3 act as a bases
3) HNO3 acts as an acid and H 2SO4 acts as a base
4) HNO3 acts as a base and H 2SO4 acts as an acid.
49. The structure of A and B formed in the following reaction are: Ph C6 H 5
O
AlCl3 2 eq Zn / Hg
+ O
A B
H 2O HCl
O
O
Ph
OH
A= OH , B= Ph
O
1) O
Ph
A= , B= Ph
O
OH
2)
O O
Ph
, OH
A= OH B=Ph
3) O
Ph
Ph
,
B=
A=
4) O
Cl
52. Find the value of x.
Br
Br
Br
x Alc.KOH
Aromatic Compound
Br
Br
Br
53. Find out the possible Number of electrons having l m value equal to zero in Cr.
54. For the Empirical formula xZnSO4 yH 2O of the following minerals that have the following
composition. ZnSO4 56.14, H 2O 43.86 .Find out x y ___
56. Optical activity of an enantiomeric mixture is 12.60 and the specific rotation of (+) isomer
is 300 .The optical purity is_______%.
57. A sample of 0.2 g of an organic compound when analysed by Duma’s method yields 22.4
mL of N2 gas which is collected over KOH solution at 170 C and at a pressure of 749 mm Hg.
The percentage of nitrogen in the given organic compound is_____(Nearest integer)
a) Aqueous tension of water at 290 k is 13 mm Hg
b) R=0.0821 L atm/ k.mole.
58. Find number of statement/s which is/ are incorrect
a) Bonding molecular orbital is denoted as MO A B
b) Anti bonding molecular orbital is denoted as AMO A B
c) The bond order of acetylide ion is same as CN
_
d) If 2s and 2p orbital’s of carbon are not mixing then C2 molecule is diamagnetic
e) If dipole moment of chlorobenzene is 1.8 Debye then metadichlorobenzene will have
dipole moment of √2 D (D = Debye)
f) As temperature increase pH of water decreases
59. According to the following figure the magnitude of enthalpy change of the reaction
A B C D in kJ/mole is equal to _____(nearest integer)
a
A B
b CD
a = 50, b = 40, c = 10
60. A chloro compound “A”,
i) Forms aldehydes on ozonolysis followed by the hydrolysis.
ii) When vaporized completely 1.53 g of A, gives 448 ml of vapour at STP.
The number of carbon atoms in a molecule of compounds A is______
3 5 7 2 4
61. If tan 1 .... cot 1 1 ... then the maximum
3! 5! 7! 2! 4! 2
value of equals to
1 1 1
1) 2) 1 3) 4)
2 2 2
n
1 1 1
n 1 n n 2 ..... n k 1
62. lim n nk
n 2 2 2
1
21 k
1
1) 2 2) e 2 3) 2 1 4) e2
2k
1 1
e x
2
x x2 1 ex 2
63. f x e e . If f x .
"
1 3 then ,
x x x4 x2
1 1 1 1
1) ,2 2) , 2 3) , 2 4) , 2
4 4 4 4
64. Let L be the line passing through the point P (1,2) such that its intercepted segment between
the Co – ordinate axes is bisected at P. If L1 is the line perpendicular to L and passing
through the point (-2, 1) then the point of intersection of L and L1 is
3 23 4 12 11 29 3 17
1) , 2) , 3) , 4) ,
5 10 5 5 20 10 10 5
65. One vertex of a rectangular parallelopiped is at the origin O and the lengths of its edges
along x,y and z axes are 3, 4 and 5 units respectively. Let P be the vertex (3,4,5). Then the
shortest distance between the diagonal OP and an edge parallel to z axis, not passing through
O or P is
12 12 12
1) 2) 12 5 3) 4)
5 5 5 5
1) Assertion is true, reason is true, and reason is correct explanation for assertion
2) Assertion is true, reason is true, and reason is not correct explanation for assertion
3) Assertion is true, reason is false
4) Assertion is false, reason is true
74. Let f x x 1 x for -1 x 3 where [x] is the integral part of x. Then the number of
values of x in [-1, 3] at which f is not continuous is.
1) 0 2) 1 3) 2 4) 4
75. Let A and B two 2×2 matrices. Consider the statements
I: AB O A O or B = O
II: AB I 2 A B 1
2
III: A B A2 2 AB B 2 Then
1) I and II are false, III is true 2) II and III are false, I is true
3) I is false II and III are true 4) I and III are false, II is true
values of K are
1) 2 2) 3 3) 8 4) 4
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. 4cos2 90 3 4cos2 270 3 4cos2 810 3 4cos2 2430 3
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1 1
82. Number of integers ≤10 satisfy the inequalities 2log 1 x 1 is____
3 log 2 8
2 x x
83. The sum of infinite terms of a decreasing GP is equal to the greatest value of the function
f x x3 3x 9 in the interval [-2,3] and the difference between the first two terms in
f 0 . If the common ratio of the GP is p/q then find the value of p + q? (where p,q are in
their lowest form)
84. Let p(x) be a polynomial of degree 4 having extremum at x = 1,2 and lim 1 p x 2
2 x 0 x
then the value of p(2) is _____
85 Let f be a twice-differentiable function such that f " x f x , f ' x g x ,
2 2
h x f x g x . If h 5 4 , then h 10 is ……
86. If denote the greatest integer then
1 2 3 ...... 120 is equal to
87. Let f be defined on the natural numbers as f(1) = 1 and for n > 1,
1 20
f n f f n 1 f n f n 1 then the value of
30 r 1
f r is , then
7
x 2 y 1 z 6 x 6 1 y z 8
88. The shortest distance between the lines and is equal to
3 2 2 3 2 0
__________
1
89. If Tr be the r th term of a sequence, for r = 1,2,3…..If 3Tr 1 Tr and T7 , then the
243
value of Tr .Tr 1 is ____
r 1
2 x 1
3
f(0) is ______