Vidyamandir Classes:Innovating For Your Success

Utkarsh Batch (2024)

GeneralInstructions
1. The testIs of 3 hours duration and the maximum marksIs 300.
2. The question paper consists of 3 Parts (PartI: Physics, PartII: Chemistry, PartIII: Mathematics). Each Part has
two sections (Section 1 & Section 2).
3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICEIs correct.
4. Section 2 contains 5Integer/Numerical Value Type Questions.

5. For answering a question, an ANSWER SHEET (OMR SHEET)Is provided separately. Please fill your Test Code,
Roll No. and Group ProperlyIn the space givenIn the ANSWER SHEET.
6. For each question you will be given 4 MarksIf you have darkened only the bubble corresponding to the
correct answer and zero markIf no bubbleIs darkened.In all other cases, minus ONE (–1) mark (NEGATIVE
MARKING) will be given.

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (Negative Marking) for Incorrect answer, 0 for all other cases.

2. Section – 2: +4 for correct answer, (No Negative Marking).

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 Vidyamandir Classes:Innovating For Your Success

Part I : PHYSICS MARKS : 100

SECTION-1
SINGLE CORRECT CHOICE QUESTIONS

1. Figure shows a charge +Q a distance 2d from a charge −Q and a point X distance d from −Q. The field
strength at X is numerically, using SI units
2d d
X
+Q -Q

Q Q 3Q 2Q
(A) (B) (C) (D)
4o d 2 36o d 2 4o d 2 9o d 2
2. For the system of charges shown in the figure. q1 = +10−8C,
q2 = −2  10−8C, q3 = +3  10−8C, q4 = 2 10−8 C and
a =1 m. The potential at the centre of the square is
(approximately)
(A) 300 V (B) 500 V
(C) 200 V (D) 800 V

3. A hollow charged sphere of radius R has a constant surface charge density . The graph which shows the
variation of the electric field strength E with distance x from the centre of the sphere is
(A) E (B) E

x=R x=R

(C) E (D) E

x=R x=R

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 Vidyamandir Classes:Innovating For Your Success

4. Four equal charges of magnitude q each are placed at four corners of a square with its centre at origin and
lying in y-z plane. A fifth charge +Q is moved along x-axis. The electrostatic potential energy (U) varies
on x-axis as:

(A) (B)

(C) (D)
5. Unit of potential is:
(A) Joule (B) Volt (C) Coulomb (D) Ampere
6. Dipole moment is:
(A) Directed from negative charge to positive charge
(B) Directed from positive charge to negative charge
(C) Scalar quantity
(D) None of these
7. The spatial distribution of the electric field due to two charges (A, B) is shown in figure.
Which one of the following statements is correct?
(A) A is + ve and B is − ve and | A| > | B |
(B) A is − ve and B is + ve, | A| = | B |
(C) Both are + ve but A  B
(D) Both are − ve but A  B

8. The potential field of an electric field E = (y î + x ˆj ) is:

(A) V = - xy + constant (B) V= - (x + y)+ constant
(C) V = - (x2 + y2) + constant (D) V = constant

9. Figure shows three spherical and equipotential surfaces 1, 2 and 3 round a point charge q. The potential
difference V1 – V2 = V2 – V3. lf t1 and t2 be the distance between them. Then:

(A) t1 = t2 (B) t1 > t2 (C) t1 < t2 (D) t1 ≤ t 2

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 Vidyamandir Classes:Innovating For Your Success

10. Two identical positive charges are fixed on the y-axis, at equal distances from the origin 0. A particle
with a negative charge starts on the negative x-axis at a large distance from 0, moves along the x-axis,
passed through 0 and moves far away from 0. Its acceleration a is taken as positive along its direction of
motion. The particle’s acceleration a is plotted against its x-coordinate. Which of the following best
represents the plot?

(A) (B)

(C) (D)

11. A small electric dipole is placed at origin with its dipole moment directed along positive x-axis. The
direction of electric field at point (2, 2 2 , 0) is
(A) along z-axis (B) along y-axis
(C) along negative y-axis (D) along negative z-axis
12. An infinite long plate has surface charge density  . As shown in the fig. a point charge q is moved from
A to B. Net work done by electric field is :
q q
(A) (x1 – x2) (B) (x2 – x1)
20 20
q q
(C) (x2 – x1) (D) (2  r + r)
0 0
13. Figure shows an electric line of force which curves along a circular arc. The magnitude of electric field
intensity is same at all points on this curve and is equal to E. If the potential at A is V, then the potential
at B is :

(A) V – ER  (B) V – E2R sin
2

(C) V + ER  (D) V + 2ER sin
2
p ˆ
14. Two small dipoles pkˆ & k are located at (0, 0, 0) & (1 m, 0, 2 m) respectively. The resultant electric
2
field due to the two dipoles at the point (1 m, 0, 0) is :
9p ˆ −7 p ˆ
(A) k (B) k
32  0 32  0
7 p ˆ
(C) k (D) None of these
32  0

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1 1 1
15. Electrical potential ‘v’ in space as a function of co-ordinates is given by, v = + + . Then the
x y z
electric field intensity at (1, 1, 1) is given by :
(A) – ( iˆ + ˆj + kˆ ) (B) iˆ + ˆj + kˆ
1 ˆ ˆ ˆ
(C) zero (D) (i + j + k )
3
16. A graph of the x component of the electric field as a function of x in a region of space is shown. The Y
and Z components of the electric field are zero in this region. If the electric potential is 10 V at the
origin, then potential at x = 2.0 m is :

(A) 10 V (B) 40 V
(C) – 10 V (D) 30 V

17. In the figure shown, A is a fixed charged. B (of mass m) is given a velocity V perpendicular to line AB.
At this moment the radius of curvature of the resultant path of B is
(A) 0 (B)  (infinity)
4 0 r 2 mv 2
(C) (D) r
q2
18. Two point charges q1 and q2 are placed in an external uniform electric
field as shown. The potential at the location of q1 and q2 are v1 and v2
respectively, the effect of q1 , q2 are not included in v1 and v2 i.e. v1
and v2 are potentials at location of charges q1 and q2 due to external
unspecified charges only, electric potential energy for this configuration
of two charged particles is :
q1v1 + q2v2
(A) (B) q1v1 + q2v2
2
qq q1q2
(C) q1v1 + q2v2 + 1 2 (D)
40 r 40 r
19. non-conducting hollow cone has charge density  . A part ABP is cut and removed from the cone. The
potential due to the remaining portion of the cone at point ‘P’ is

5 R 5 R 5 R 5 R
(A) (B) (C) (D)
6 0 24 0 3 0 12 0
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20. Unit of charge is:

(A) Coulomb (B) Tesla (C) Volt (D) Ampere

INTEGER/NUMERICAL VALUE TYPE

−Q
1. In the figure, the potential at X due to the charges +Q and −Q is, using SI units is , find the value
no d
of n.
2d d
X
+Q -Q

2. A hollow sphere of radius 2R is charged to V volts and another smaller sphere of radius R is charged to
V/2 volts. Now the smaller sphere is placed inside the bigger sphere without changing the net charge on
V
each sphere. The potential difference between the two spheres would be , find the value of n
n

3. Two identical particles of charge q each are connected by a massless spring of force constant k. They are
placed over a smooth horizontal surface. They are released when the separation between them is r and
q2
spring is unstretched. If maximum extension of the spring is r, the value of k is , find the value of
n0 r 3
n. (neglect gravitational effect)

4. The electric field inside a sphere which carries a charge density proportional to the distance from the
 r2
from centre (r) is  =  r (  is a constant) is , find the value of n.
n 0
5. Figure shows three circular arcs, each of radius R and total charge as indicated. The net electric potential
Q
at the centre of curvature is , find the value of n.
n0 R

SPACE FOR ROUGH WORK

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Part II : CHEMISTRY MARKS : 100

SECTION-1
SINGLE CORRECT CHOICE QUESTIONS

1. Relative lowering in vapour pressure of a solution containing 1 mole K2SO4 in 54 g H2O is (K2SO4 is
100% ionized)
1 3 3 1
(A) (B) (C) (D)
55 55 4 2

2. Certain mass, say x g, of urea was dissolved in 500 g of water and cooled upto –0.5°C where by 128 g of
ice separates out from the solution. If cryoscopic constant for water is 1.86°C m–1, the value of x will be
(A) 6g (B) 8g (C) 12 g (D) 15 g
3. 2 moles of a sparingly soluble salt PbCl2 dissociates in 1 litre solution to give 1 mol of Pb+2 ions, what is
the osmotic pressure of the solution at 300 K.
(A) 98.52 atm (B) 73. 89 atm (C) 60 atm (D) 50.5 atm
4. Which of the following solution will have least vapour pressure?
(A) 0.1 M BaCl2 (B) 0.1 M urea (C) 0.1 M Na2SO4 (D) 0.1 M Na3PO4
5. During freezing of solution
(A) only solute molecules separate out.
(B) only solvent separates separate out.
(C) both solute and solvent molecules separate out.
(D) None of these
6. Density of a 2.05 M solution of acetic acid in water is 1.02 g/ml. The molality of the
solution is (Atomic mass: H = 1, C = 12, O = 16)
(A) 3.28 mol kg−1 (B) 2.28 mol kg−1 (C) 0.44 mol kg−1 (D) 1.14 mol kg−1
7. A 0.001 molal solution of Pt(NH3)4Cl4 in water had a freezing point depression of 0.0054°C. If Kf for
water is 1.80, the correct formula for the above compound assuming its complete dissociation is
(A) [Pt(NH3)4Cl3]Cl (B) [Pt(NH3)4Cl2]Cl2
(C) [Pt(NH3)4Cl]Cl3 (D) [Pt(NH3)4Cl4]
8. 1 molal aqueous solution of an electrolyte X3Y2 is 25% ionised. The boiling point of the solution is (Kb of
H2O = 0.52 K kg/mol)
(A) 375.5 K (B) 374.04 K (C) 377.12 K (D) 373.25 K
9. A 1.2% of solution of NaCl is isotonic with 7.2% of solution of glucose. Calculate the van’t Hoff’s factor
of NaCl solution
(A) 2.36 (B) 1.50 (C) 1.95 (D) 1.00

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10. Boiling point of chloroform was raised by 0.323 K, when 0.5143 g of anthracene was dissolved in 35 g of
chloroform. Molecular mass of anthracene is
( K b for CHCl 3 = 3.9 kg mol–1)

(A) 79.42 g/mol (B) 132.32 g/mol (C) 177.42 g/mol (D) 242.32 g/mol
11. The decrease in vapour pressure of a pure solvent is observed to be 10 mm Hg when a non-volatile solute
is added to the solvent. The mole fraction of the solute in the solution is 0.2. What should be the mole
fraction of same solvent if decrease in vapour pressure is to be 20 mm Hg ?
(A) 0.1 (B) 0.6 (C) 0.4 (D) 0.2
12. The molal depression constant K of water is 1.86ºC. If 34.2 g of sucrose and 12 g of urea dissolved in
1000 g of water, then freezing point of the resultant solution would be
(A) –0.558ºC (B) –2.8ºC (C) –9.3ºC (D) –1.86ºC
13. An azotropic solution of two liquids has a boiling point lower than either of them when it
(A) shows negative deviation from Raoult’s law
(B) shows no deviation from Raoult’s law
(C) shows positive deviation from Raoult’s law
(D) is saturated
14. The freezing point of equimolal aqueous solution will be highest for
(A) C6H5NH3Cl (anilinium chloride) (B) Ca(NO3)2
(C) La(NO3)3 (D) C6H12O6 (glucose)

15. For an ideal binary liquid solution with p*A p*B , which of the following relations between xA (mole
fraction of A in liquid phase) and yA (mole fraction of A in vapour phase) is correctly represented?
(A) xA yA (B) xA yA (C) xA yA

(D) xA and y A cannot be correlated with each other.

16. A binary liquid solution of n-heptane and ethyl alcohol is prepared. Which of the following statmeants
correctly represents the behavior of this liquid solution?
(A) the solution formed is an ideal solution
(B) the solution formed is nonideal solution with positive deviations from Raoult’s law.
(C) the solution formed is nondieal solution with negative deviations from Raoult’s law
(D) n-Heptane exhibits positive deviation whereas ethyl alcohol exhibits negative deviation from
Raoult’s law
17. The degree of dissociation ( ) of a weak electrolyte Ax By is related to van’t Hoff factor (i) by the
expression
i 1 i 1 x y 1 x y 1
(A) (B) (C) (D)
x y 1 x y 1 i 1 i 1

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18. Which of the following pairs of solutions can be expected to be isotonic at the same temperature?
(A) 0.1 M urea and 0.1 M NaCl (B) 0.1 M urea and 0.2 M MgCl2

(C) 0.1 M NaCl and and 0.1 M Na2SO4 (D) 0.1 M Ca(NO3) and 0.1 M Na2SO4

19. If a solute undergoes dimerization and trimerization, the minimum values of the van’t Hoff factors are
(A) 0.50 and 1.50 (B) 1.50 and 1.33 (C) 0.50 and 0.33 (D) 0.25 and 0.67
20. The van’t Hoff factors i for an electrolyte which undergoes dissociation and association in solvents are
respectively
(A) greater than 1 and greater than 1 (B) less than 1 and greater than 1
(C) less than 1 and less than 1 (D) greater than 1 and less than 1
INTEGER/NUMERICAL VALUE TYPE
1. At 323 K, the vapour pressure in millimetres of mercury of a methanol-ethanol solution is represented by
pA
the equation p 120 X A 140, where X A is the mole fraction of methanol. Then the value of lim is
X 1 A XA

2. The vapour pressures of ethanol and methanol are 44.5 mm Hg and 88.7 mmHg, respectively. An ideal
solution is formed at the same temperature by mixing 60 g of ethanol and 40 g of methanol. Calculate the
mole fraction of methanol in the vapour.
3. A solution contains 3.22 g of HClO2 in 47.0 g of water. The freezing point of the solution is 271.10 K.
Calculate the fraction of HClO2 that undergoes dissociation to H+ and ClO2 . Given : K f (water) = 1.86
K kgmol–1.
4. Calculate the amount of ice that will separate out on cooling a solution containing 50 g of ethylene glycol
in 200 g water to −9.3°C. Given: Kf for water = 1.86 K mole−1 kg.
5. An unknown compound is immiscible with water. It is steam distilled at 98°C and

P = 737 Torr. PH2O = 707 Torr at 98°C. This distillate was 75% by weight water. Calculate the molecular
weight of the unknown.

SPACE FOR ROUGH WORK

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PartIII : MATHEMATICS MARKS : 100

SECTION-1
SINGLE CORRECT CHOICE QUESTIONS

1. The equation x 2 − 4 x +  x  + 3 = x  x  , where  x denotes the greatest integer function, has:

(A) Exactly two solutions in ( −, ) (B) No solution

(C) A unique solution in ( −,1) (D) A unique solution in ( −, )

2. Let f ( x) be a function such that f ( x + y ) = f ( x). f ( y) for all x, y  N . If f (1) = 3 and

n
 f (k ) = 3279 , then the value of n is:
k =1
(A) 6 (B) 8 (C) 7 (D) 9
2x
2  1   2   2022 
3. If f ( x) = 2 x , x  R , then f  + f   + ...... + f   is equal to:
2 +2  2023   2023   2023 
(A) 2011 (B) 1010 (C) 2010 (D) 1011
4. Let f ( x) = 2xn + ,  R, n  N , and f (4) = 133, f (5) = 255 . Then the sum of all the positive
integer divisors of ( f (3) − f ( 2)) is:
(A) 61 (B) 60 (C) 58 (D) 59
x + 2x +1
2
5. Let f : R → R be a function such that f ( x) = . Then
x2 + 1
(A) f ( x) is many-one in ( −, −1) (B) f ( x) is many-one in (1,)
(C) f ( x) is one-one in 1, ) (D) f ( x) is one-one in ( −, )
log ( x +1) ( x − 2 )
6. The domain of f ( x) = 2log x , x  R is:
e e − ( 2 x + 3)
(A) R − 1 − 3 (B) ( 2, ) − 3 (C) ( −1, ) − 3 (D) R − 3

7. Consider a function f : N → R , satisfying f (1) + 2 f (2) + 3 f (3) + ... + xf ( x) = x ( x + 1) f ( x); x  2

1 1
with f (1) = 1 . Then + is equal to:
f ( 2022 ) f ( 2028 )
(A) 8200 (B) 8000 (C) 8400 (D) 8100
8. Suppose f : R → ( 0,  ) be a differentiable function such that 5 f ( x + y ) = f ( x ) . f ( y ) , x, y  R . If
5
f (3) = 320 , then  f ( n ) is equal to:
n =0
(A) 6875 (B) 6575 (C) 6825 (D) 6528

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9. The range of the function f ( x) = 3 − x + 2 + x is:

(A)  5, 10  (B)  2 2, 11  (C)  2, 13  (D)  2, 7 

       

10. If the domain of the function f ( x) =

 x , where  x is greatest integer  x , is ( 2,6) , then its range
1 + x2
is:
 5 2   9 27 18 9   5 2
(A)  , − , , ,  (B)  , 
 26 5   29 109 89 53   26 5 
 5 2  5 2
(C)  ,  (D)  , 
 37 5   37 5 
11. The absolute minimum value, of the function f ( x) =| x2 − x + 1| +  x2 − x + 1 , where [t] denotes the
 
greatest integer function, in the interval  −1, 2 , is:
3 3 1 5
(A) (B) (C) (D)
4 2 4 4
x2 + 2 x + 1
12. Let f : R − 2,6 → R be real valued function defined as f ( x) = 2 . Then range of f is:
x − 8 x + 12
 21   21 
(A)  −, −    0,  ) (B)  −, −   ( 0,  )
 4  4
 21   21   21
(C)  −, −    ,   (D)  −, −   1,  )
 4 4   4
 1 
13. Let f : R − 0,1 → R be a function such that f ( x) + f   = 1 + x . Then f (2) is equal to:
 1− x 
9 9 7 7
(A) (B) (C) (D)
2 4 4 3
14. If cos −1 x  cos −1 x 2 , then
(A) −1,0 (B) −1,0 1 (C) −1 0,1 (D) 0,1
15. Considering the principal values of the inverse trigonometric functions, the sum of all the solutions of the
equation cos−1 ( x ) − 2sin −1 ( x ) = cos−1 ( 2 x ) is equal to:
1 1
(A) 0 (B) 1 (C) (D) −
2 2
16. The number of real solutions of tan
−1
x ( x + 1) + sin −1 x 2 + x + 1 =  / 2 is:
(A) zero (B) one (C) two (D) infinite

17. ( )
The value of x for which sin cot −1 (1 + x ) = cos tan −1 x is:( )
1 −1
(A) (B) 1 (C) 0 (D)
2 2

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 43 
18. The principal value of tan −1  cot  is:
 4 
3 3  
(A) − (B) (C) − (D)
4 4 4 4
19. If the inverse trigonometric functions take principal values, then
 3   4  1   4 
cos−1  cos  tan −1    + sin  tan −1     is equal to:
 10   3  5   3 
  
(A) 0 (B) (C) (D)
4 3 6
 −1  1 
 2sin  2  
20. The domain of the function cos −1   4 x − 1   is:
  
 
 
 1 1
(A) R − − ,  (B) ( −, −1 1, ) 0
 2 2
 −1   1   −1   1 
(C)  −,    ,    0 (D)  −,  ,    0
 2  2   2  2 

INTEGER / NUMERICAL VALUE TYPE

1. If cos−1 x + cos−1 y + cos−1 z = 3 , then the value of x2 + y2 + z 2 − 3xyz =

1/3
 x−7 
2. For some a, b, c  N , let f ( x) = ax − 3 and g ( x) = xb + c, x  R . If ( fog )−1 ( x) =   then
 2 
( fog )(ac) + ( gof )(b) is equal to__________.

3. Let f : R → R be a function defined by f ( x) = log m ( )

2 ( sin x − cos x ) + m − 2 , for some m, such

that the range of f is 0, 2 . Then the value of m is __________.

3x + 2  −3 
4. Let f '( x) = , xR − , for n 2, define f n ( x ) = f 1 0 f n−1 ( x ) . If
2x + 3 2
ax + b
f 5 ( x) = , gcd ( a, b ) = 1 , then a + b is equal to__________.
bx + a
5. The number of real solutions of the equation:
  i +1 
 x  
i    x i  i
sin   x + x    = − cos    −  −  ( − x ) 
−1 −1
 i =1 
i =1  2   2
 i =1  2  i =1 
  
 1 1
Lying in the interval  − ,  is __________. (Here, the inverse
 2 2
   End of Test   

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Utkarsh Batch (2024) (Test-3)

Test Date 8.05.2023
ANSWER KEY

PHYSICS

1.(D) 2.(B) 3.(D) 4.(B) 5.(B) 6.(A) 7.(A) 8.(A) 9.(C) 10.(B)

11.(B) 12.(A) 13.(A) 14.(B) 15.(B) 16.(D) 17.(C) 18.(C) 19.(D) 20.(A)

1.(6) 2.(4) 3.(4) 4.(4) 5.(2)

CHEMISTRY

1.(D) 2.(A) 3.(A) 4.(D) 5.(B) 6.(B) 7.(B) 8.(B) 9.(C) 10.(C)

11.(C) 12.(A) 13.(C) 14.(D) 15.(C) 16.(B) 17.(A) 18.(D) 19.(C) 20.(D)

1.(260) 2.(0.65 3.(0.10) 4.(38.71) 5.(141.4)

MATHEMATICS

1.(D) 2.(C) 3.(D) 4.(B) 5.(C) 6.(B) 7.(D) 8.(C) 9.(A) 10.(D)

11.(A) 12.(A) 13.(B) 14.(B) 15.(A) 16.(C) 17.(D) 18.(C) 19.(C) 20.(D)

1.(6) 2.(2039) 3.(1) 4.(3125) 5.(2)

VMC 13 Utkarsh 2025