ca a2 CLARIANT Effective date: January 2015 Form-QC-036 ; Revisi : 0 MSDS Ref. No. : 7002 RevisionNo. : 0 MATERIAL SAFETY DATA SHEET ActiSorb S 2 SECTION I PRODUCT AND COMPANY IDENTIFICATION ‘Trade Name and Synonyms : ActiSorb S 2 General Use 2 Catalyst Formula 3AL03, 28i02+ Zn10 Manufacturer PT. CLARIANT KUJANG CATALYSTS Kaujang Industrial Estate, Jl. Jend. A. Yani No. 39 PO Box 55, Cikampek 41373 West Java ~ Indonesia Phone No. : 62-264-318488, 62-264-318473 Fax No. : 62-264-318474 SECTION IL COMPOSITION/INFORMATION ON INGREDIENTS. ‘Substance / Mixture © Mixture Chemical nature © Mixture of zinc oxide and aliminasilicate Hazardous components This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). SECTION II HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. : GHS Label element ‘Not a hazardous substance or mixture. Other hazards The substance does not meet the criteria for PBT or vPvB substance. (MSDS ActiSorb § 2 - PT. Clariant Kujang Caralysis Page 1 of 9a CLARIANT SECTION IV FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : none : Remove to fresh air. Call a physician if irritation develops or persists. Call a physician if symptoms occur. : Before washing use a dry brush to remove dust from skin. ‘Wash area with mild soap and copious amounts of water. If skin irritation occurs: Get medical advice/ attention. —* : Do not rub affected area. Rinse immediately with plenty of lukewarm water, also under the eyelids, for at least 15 minutes. Get medical attention. : Route of exposure unlikely. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. : The possible symptoms known are those derived from the labelling (see section 2). No additional symptoms are known. : Prolonged or repeated contact under poor hygienic conditions may produce a papular, pustular eczema or dermatitis called oxide pox. OO SECTION V FIRE FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Further information MSDS ActiSorb § 2 - PT. Clariant Kujang Catalysts : The product itself does not bum. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : No information available. ‘None known. Used catalyst may have different hazards or properties than the original product. This MSDS does not apply to the used catalyst. . Contact Technical Services at +62 21 83701020 for more information. + Wear full protective clothing and NIOSH/MSHA- approved positive pressure, self-contained breathing apparatus, Page 2 of 9CLARIANT Special protective equipment : No special precautions required. for firefighters SECTION VI ACCIDENTAL RELEASE MEASURES Personal precautions, : Ensure adequate ventilation. protective equipment and Avoid dust formation. emergency procedures Use personal protective equipment. Environmental precautions Methods and materials for containment and cleaning up Avoid contact with skin, eyes and clothing. ‘Wearing appropriate personal protective equipment, contain spill and collect into a suitable container. Minimize airborne particulates. Keep container tightly closed. Material should be swept up or vacuumed, using ventilation to control the level of airborne dust. Avoid using compressed air or any method that creates airborne dust. If cleanup may create airborne dust, . personnel should wear eye, skin, and respiratory protection. ‘Do not use compressed air for cleaning purposes. Refer to Section 8 for more information. + Do not flush into surface water or sanitary sewer system, : Take up uncontaminated material and pass on for further processing. Take up contaminated material by mechanical means, load into clean containers, and dispose of in accordance with legal regulations. : SECTION VIL HANDLING AND STORAGE Advice on protection against fire and explosion Advice on safe handling Conditions for safe storage ‘Technical measures/Precautions MSDS ActiSorb $ 2 - PT. Clariant Kujang Catalysts + Incase of inappropriate handling, spent catalyst can be self- heating when in contact with air. : Avoid contact with skin, eyes and clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. ‘ Minimize dust generation and accumulation. : Keep tightly closed in a dry and cool place. : Keep container tightly closed and dry. Keep container tightly closed. Keep container dry. Page 3 of 9ea CLARIANT Materials to avoid : No materials to be especially mentioned. SECTION VIM EXPOSURE CONTROLS / PERSONAL PROTECTION : Use adequate exhaust ventilation and/or dust Components with workplace 1,000 °C Boiling point : Not applicable Flash point : Not applicable Evaporation rate : Not applicable Flammability (solid, gas): not determined [MSDS ActiSorb § 2 - PT. Clariane Kujang Catalysts . Page 4 of 9CLARIANT Upper explosion limit: not tested. Lower explosion limit _: not tested. Combustion number : not determined ‘Vapour pressure : Not applicable Relative vapour density = Not applicable Relative density + not tested. Density + not tested. : Bulk density 2 1.00- 1.25 kg/L Solubility(ies) Water solubility : insoluble Solubility in other solvents: not tested. Partition coefficient: n- __: not determined octanol/water Auto-ignition temperature: Not applicable Decomposition temperature : no data available Viscosity Viscosity, dynamic : Not applicable Viscosity, kinematic : Not applicable . } Flow time : Not applicable Explosive properties + no data available Oxidizing properties : not tested. ‘Sublimation point : not determined SECTION X STABILITY AND REACTIVITY Reactivity : Stable under recommended storage conditions. Chemical stability : The product is chemically stable. Possibility of hazardous : None known. reactions Conditions to aveid + None known, MSDS ActiSorb § 2- PT. Clariane Klang Catalysis PageS of 9 }a CLARIANT Incompatible materials : None known. Hazardous decomposition products: No decomposition if stored and applied as directed. SECTION XI ‘TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye contact Skin contact Ingestion 5 Inhalation Acute toxicity Product: Acute oral toxicity : Remarks: no data available Acute inhalation toxicity: Remarks: no data available Acute dermal toxicity : Remarks: no data available Skin corrosion/irritation Product ” Species: Rabbit Exposure time: 24 h Metho« raize Test Result: Mild skin irritant Remarks: Information based on the active ingredient. Serious eye damage/eye irritation Product: Species: Rabbit : Result: Mild eye irritant Exposure time: 24h Method: Draize Test Remarks: Information based on the active ingredient. Respiratory or skin sensitisation Product Remarks: no data available Carcinogenicity IARC Not listed OSHA Not listed NIP Not listed Experience with human exposure MSDS ActiSorb S 2 - PT. Clariant Kujang Catalysts Page 6 of 9a CLARIANT Product: General Information : The possible symptoms known are those derived from the labelling (see section 2). SECTION XIL ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: no data available Persistence and degradability Product: Biodegradability : Remarks: no data available Bioaccumulative potential Product: Bioaccumulation : Remarks: no data available Mobility in soil . Product Distribution among : Remarks: no data available environmental compartments Other adverse effects Product: Additional ecological : water endangering information SECTION XII DISPOSAL CONSIDERATIONS Disposal methods RCRA - Resource : This product, if discarded as sold, is not a Federal RCRA Conservation and Recovery hazardous waste. Authorization Act Waste Code TONE ‘Waste from residues + Dispose of this product in accordance with applicable + local, state and federal regulations. Recover metal components by reprocessing whenever possible. Contaminated packaging —_: Dispose of as unused product. ‘MSDS ActiSorb S$ 2- PT. Clartant Kwang Cataiysts Page 7 of 9‘ial CLARIANT SECTION XIV___ TRANSPORT INFORMATION DOT Regulation: Proper shipping name: Hazard class: Packing group: SUN/NA-number: Primary hazard class: Technical Name: Y IATA Proper shipping name: Class: Packing group: UN/D number: Primary risk: Remarks: Hazard inducer(s): IMDG Proper shipping name: Class: Packing group: UN no.: Primary risk: Hazard inducer(s): Marine pollutant: Ems: Environmentally hazardous substances, solid, n.0.s. 9 mW ‘UN 3077 9 zine oxide Environmentally hazardous substance, solid, n.0.s. 9 ‘ I UN 3077 9 Shipment permitted zinc oxide Environmentally hazardous substance, solid, n.0.s. 9 ini UN 3077 9 zine oxide Marine Pollutant F-AS-F Y SECTION XV REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards SARA 302 SARA 313 MSDS ActiSorb S 2 PT. Clariant Kujang Catalysts : Acute Health Hazard Chronic Health Hazard : No chemicals in this material are subject to the reporting, requirements of SARA Title III, Section 302. : This product contains the chemical or chemicals listed below which are subject to the supplier notification *- requirements of Section 313 of the Superfund ‘Amendments and Reauthorization Act of 1986 ("SARA") and the requirements of 40 CFR Part 372: Zinc compounds Not Assigned 95% Page & of 9aa CLARIANT Zine powder - zinc dust 7440-66-6 16% (stabilized) Clean Water Act Contains the following Priority Pollutant(s) at concentrations greater than 0.1%:, Zine ‘The components of this product are reported in the following inventories: TSCA All components of this product are listed or excluded from listing on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) Inventory. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (lapan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION XVI___ OTHER INFORMATION Further information NFPA: Fammabity 0 ry ‘Special Hazard ‘This information is supplied under the OSHA Hazard Communication Standard, 29 CFR 1910.1200, and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the : accuracy of this data, the hazards connected with the use of the material, or the results to be Gbtained from the use thereof. We assume no responsibility for damage or injury from the tse of the product described herein. Data provided here are typical and not intended for use as product specifications. MSDS ActiSorb § 2 - PT. Clariant Kujang Catalysts Se Page 9 of 9