Date of first issue: 28.02.

2011
Date of last issue: 15.01.2015
Revision Date: 11.02.2016
Version: 1.5 Page 1 of 11

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AR-301

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: AR-301

Other means of identification:

1.2 Relevant identified uses of the substance or mixture and uses advised against
○ Identified uses: Steam reforming catalyst.

1.3 Details of the supplier of the safety data sheet

Manufacture
Company: Haldor Topsoe A/S
Address: Haldor Topsøes Allé 1, 2800 Lyngby
Denmark
Telephone: +45 4527 2000
Telefax: +45 4527 2999
E-mail address: catalyst-sds@topsoe.dk

1.4 Emergency telephone number

UK: +44 0844 892 0111
Other: +45 4527 2000

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

- Skin Sens. 1; H317
- Carc. 1A; H350i
- Carc. 2; H351
- STOT RE 1; H372
- Aquatic Chronic 3; H412

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

○ Product identifier: AR-301

○ Hazard pictograms

○ Signal word: Danger

○ Contains: Nickel

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Nickel oxide

○ Hazard statements
- H317: May cause an allergic skin reaction.
- H350i: May cause cancer by inhalation.
- H351: Suspected of causing cancer.
- H372: Causes damage to organs through prolonged or repeated exposure if inhaled.
- H412: Harmful to aquatic life with long lasting effects.

○ Precautionary statements
- P201: Obtain special instructions before use.
- P260: Do not breathe dust.
- P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
- P333 + P313: If skin irritation or rash occurs: Get medical advice/ attention.
- P308 + P313: IF exposed or concerned: Get medical advice/ attention.

2.3 Other hazards

No information available.

SECTION 3: Composition/information on ingredients

3.2 Mixture

REACH Registration
Components Classification %w/w
Number
Aluminum oxide 01-2119529248-35-0106 not to be classified >=2 - <=6
CAS-No.: 1344-28-1
EC-No.: 215-691-6
Nickel oxide 01-2119467172-41-0040 Carc. 1A; H350i >=10 - <=15
CAS-No.: 1313-99-1 STOT RE 1; H372
EC-No.: 215-215-7 Skin Sens. 1; H317
Aquatic Chronic 4; H413
Nickel 01-2119438727-29-0101 Carc. 2; H351 >=25 - <=35
CAS-No.: 7440-02-0 STOT RE 1; H372
EC-No.: 231-111-4 Skin Sens. 1; H317
Aquatic Chronic 3; H412
Spinel (Mg(AlO2)2) 01-2119457267-32-0009 not to be classified >=50 - <=60
CAS-No.: 1302-67-6
EC-No.: 215-105-9
Lantanum oxide not to be classified >=2 - <=5
CAS-No.: 1312-81-8
EC-No.: 215-200-5
For the full text of the H-Statements mentioned in this Section, see Section 16.

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SECTION 4: First aid measures

4.1 Description of first aid measures

○ General advice: IF exposed or if you feel unwell:, Get medical advice/ attention.
○ Inhalation: Remove to fresh air. IF exposed or if you feel unwell: Call a POISON
CENTER or doctor/ physician.
○ Skin contact: Take off contaminated clothing and wash it before reuse. Wash off with
plenty of water. If skin irritation or rash occurs: Get medical advice/
attention.
○ Eye contact: Immediately flush eye(s) with plenty of water. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists, consult
a specialist.
○ Ingestion: Clean mouth with water and drink afterwards plenty of water. Get medical
advice/ attention if you feel unwell.

4.2 Most important symptoms and effects, both acute and delayed
○ Inhalation: Inhalation of excessive amounts of dust may cause irritation of the
respiratory system; symptoms may include coughing and difficulty in
breathing.
○ Skin contact: May cause an allergic skin reaction. May cause skin irritation.
○ Eye contact: May cause eye irritation.
○ Chronic effects from long Substances known to be carcinogenic to man. May cause cancer by
term exposure: inhalation. Substances which cause concern for man owing to possible
carcinogenic effects but for which the available information is not
adequate for making a satisfactory assessment.

4.3 Indication of any immediate medical attention and special treatment needed
○ Symptoms: None known.

SECTION 5: Firefighting measures

The product itself does not burn.

5.1 Extinguishing media

○ Suitable extinguishing Product is compatible with standard fire-fighting agents.
media:

5.2 Special hazards arising from the substance or mixture

No hazards to be specially mentioned.

5.3 Advice for firefighters

Wear full protective clothing and self-contained breathing apparatus.

Further information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

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SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Do not handle until all safety precautions have been read and understood. Ensure adequate
ventilation. Avoid breathing dust. Avoid contact with skin and eyes. Use personal protective equipment.
Follow safe handling advice and personal protective equipment recommendations.

6.2 Environmental precautions

Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up

Clean up promptly by scoop or vacuum. Use approved industrial vacuum cleaner for removal.
Dispose of as hazardous waste in compliance with local and national regulations.

6.4 Reference to other sections

For personal protection see section 8. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Minimize dust generation and accumulation. Provide appropriate exhaust
ventilation at places where dust is formed. Routine housekeeping should be instituted to ensure that
dusts do not accumulate on surfaces. Avoid contact with skin and eyes. Do not eat, drink or smoke
when using this product. Handle in accordance with good industrial hygiene and safety practice.
Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent
respiratory disease should not be employed in any process in which this mixture is being used. Wear
personal protective equipment. For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities

Keep locked up or in an area accessible only to qualified or authorised persons. Keep container tightly
closed. Product may be damaged by water.

7.3 Specific end use(s)

Steam reforming catalyst.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Exposure Limit Values

Exposure limits may vary. It is recommended that information about locally applicable exposure limits
is obtained.

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Components Exposure Limit Values Source

Aluminum oxide (1344-28-1)

- inhalable dust TWA 10 mg/m3 EH40 (2011:12)
- Respirable dust TWA 4 mg/m3 EH40 (2011:12)

Nickel oxide (1313-99-1)

- (as Ni) TWA 0,5 mg/m3 EH40 (2011:12)

Nickel (7440-02-0)
- (as Ni) TWA 0,5 mg/m3 EH40 (2011:12)

Lantanum oxide (1312-81-8)

- inhalable dust TWA 10 mg/m3 EH40 (2011:12)
- Respirable dust TWA 4 mg/m3 EH40 (2011:12)

DNEL /PNEC
Aluminum oxide(1344-28-1)
Workers: DNEL: Inhalation - Long term effects - Systemic effects 3 mg/m3 (8 h) Respirable
dust
Environment: PNEC: Not derived
Nickel oxide(1313-99-1)
Workers: DNEL: Dermal - Acute - Systemic effects not required
DNEL: Inhalation - Acute - Systemic effects 520 mg Ni/m3
DNEL: Oral - Acute - Systemic effects not required
DNEL: Dermal - Acute - Local effects not required
DNEL: Inhalation - Acute - Local effects 3,9 mg Ni/m3
DNEL: Dermal - Long term effects - Systemic effects not required
DNEL: Inhalation - Long term effects - Systemic effects 0,05 mg Ni/m3
DNEL: Oral - Long term effects - Systemic effects not required
DNEL: Dermal - Long term effects - Local effects 0,024 mg Ni/cm2
DNEL: Inhalation - Long term effects - Local effects 0,05 mg Ni/m3
Environment: PNEC: Fresh water 3,6 µg Ni/l No
bioavailability correction
available
PNEC: Marine water 8,6 µg Ni/l No
bioavailability correction
available
PNEC: Fresh water sediment Pending outcome of
testing program
PNEC: Marine sediment Pending outcome of
testing program
PNEC: Soil 29,9 mg Ni/kg Based on
10th percentile of abiotic
soil parameters in EU.
Bioavailability correction
available
PNEC: Microbiological Activity in Sewage Treatment 0,33 mg Ni/l
Systems

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Nickel(7440-02-0)
Workers: DNEL: - no data available
Environment: PNEC: no data available
Spinel (Mg(AlO2)2)(1302-67-6)
Workers: DNEL: Inhalation - Long term effects - Systemic effects 10 mg/m3 inhalable dust
DNEL: Inhalation - Long term effects - Systemic effects 3 mg/m3 Respirable dust
Environment: PNEC: Not derived
Lantanum oxide(1312-81-8)
Workers: DNEL: - no data available
Environment: PNEC: no data available

8.2 Exposure controls

Individual protection measures, such as personal protective equipment
○ Eye/face protection Safety goggles
○ Skin protection
- Hand protection Wear protective gloves.
Glove material: Nitrile rubber
- Body Protection Full protective suit Safety shoes recommended when handling heavy
containers.
○ Respiratory protection Suitable mask with particle filter P3 (European Norm 143)
○ Other protection Wash hands thoroughly after handling. Remove contaminated clothing and
protective equipment before entering eating areas. Contaminated work
clothing should not be allowed out of the workplace. Change working
clothes after each workshift. Wash contaminated clothing before reuse.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Property Value
Appearance
○ Physical state: solid
○ Form: Tabletted pellets.
○ Colour: grey black
Odour: odourless
Odour Threshold: Not relevant.
pH: Not applicable
Melting point/freezing point: > 1.400 °C / > 2.550 °F
Initial boiling point and no data available
boiling range:
Flash point: Not relevant.
Evaporation rate: Not relevant.
Flammability (solid, gas): The product is not flammable.
Upper/lower flammability or explosive limits
○ Lower explosion limit / lower Not explosive
flammability limit:

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○ Upper explosion limit / upper Not relevant.

flammability limit:
Vapour pressure: Not applicable
Vapour density: Not relevant.
Density: Not applicable
Solubility(ies)
○ Water solubility: Negligible – metals leaching may occur.
○ Solubility in other solvents: Not relevant.
Partition coefficient: n- Not applicable
octanol/water:
Auto-ignition temperature: Not applicable
Decomposition temperature: No information available.
Viscosity: Not relevant.
Explosive properties: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.
9.2 Other information No information available.

SECTION 10: Stability and reactivity

10.1 Reactivity
Stable under normal conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Water and moisture for catalyst integrity.

10.6 Hazardous decomposition products

None known.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

○ Inhalation: Inhalation of dust may cause shortness of breath, tightness of the
chest, a sore throat and cough.
○ Eye contact: Dust contact with the eyes can lead to mechanical irritation.
○ Skin contact: May cause an allergic skin reaction. May cause skin irritation.
○ Ingestion: Ingestion may cause irritation of the mouth and throat and may cause
discomfort.
○ Long term effects: Substances known to be carcinogenic to man. Substances which

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cause concern for man owing to possible carcinogenic effects but for
which the available information is not adequate for making a
satisfactory assessment. Prolonged or repeated inhalation may cause
damage to the lungs.

Acute toxicity
» Oral
Aluminum oxide: (Rat): > 10.000 mg/kg
Nickel oxide: LDLo(Rat): > 9.990 mg/kg
Nickel: LD50 Oral(Rat): > 9.000 mg/kg
Spinel (Mg(AlO2)2): no data available
Lantanum oxide: no data available
Product: No toxicology information is available.

» Dermal
Nickel: no data available
Spinel (Mg(AlO2)2): no data available
Product: No toxicology information is available.

» Inhalation
Aluminum oxide: LC50(Rat): > 2,3 mg/l An LC50/inhalation/4h/rat could not be
determined because no mortality of rats was observed at the
maximum achievable concentration.
Nickel oxide: LC50(Rat, 4 h): > 5,08 mg/l
Nickel: No observed adverse effect concentration(Rat, 1 h): > 10 mg/l
Spinel (Mg(AlO2)2): LC50(Rat, 4 h): 3,5 mg/l
Product: No toxicology information is available.

Skin corrosion/irritation
Product: No information available.

Serious eye damage/eye irritation

Product: No information available.

Respiratory or skin sensitisation

Product: No information available.

Germ cell mutagenicity

Product: No information available.

Carcinogenicity
Nickel oxide: Listed in: IARC: Category 1
Listed in: NTP: K
Listed in: MAK: Category 1
Nickel: Listed in: IARC: Category 2B
Listed in: NTP: K
Listed in: MAK: Category 1
Product: No information available.

Specific target organ toxicity - single exposure

Product: No information available.

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Specific target organ toxicity - repeated exposure

Product: No information available.

Aspiration hazard
Product: No information available.

Further information
Product: No information available.

SECTION 12: Ecological information

12.1 Toxicity
Harmful to aquatic life with long lasting effects.

» Acute toxicity
No information available.
» Chronic toxicity
No information available.
» Other organisms relevant to the environment
No information available.

12.2 Persistence and degradability

Product: No information available.

12.3 Bioaccumulative potential

Product: No information available.

12.4 Mobility in soil

Product: No information available.

12.5 Results of PBT and vPvB assessment

Product: No information available.

12.6 Other adverse effects

Product: no data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Dispose of as hazardous waste in compliance with local and national regulations. Haldor Topsøe A/S
takes no responsibility for the classification of used or contaminated material.
Can be offered for metal recovery.

SECTION 14: Transport information

14.1 UN number: None

14.2 Proper shipping name: None

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14.3 Transport hazard class(es)

ADR/RID: Not classified
IMDG: Not classified
IATA: Not classified
49 CFR: Not classified

14.4 Packing group: None

14.5 Environmental hazards

ADR/RID: None
IMDG: None
IATA: None
49 CFR: None

14.6 Special precautions for user: No special precautions are needed in handling this material.

14.7 Transport in bulk according to Not applicable for product as supplied.

Annex II of MARPOL 73/78 and
the IBC Code:

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
○ The product is classified as dangerous in accordance with Regulation (EC) No. 1272/2008.
○ Take note of Dir 94/33/EC on the protection of young people at work.
○ Take note of Dir 92/85/EEC on the safety and health at work of pregnant workers.

15.2 Chemical safety assessment

No information available.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet
○ DNEL Derived No Effect Level
○ PNEC Predicted No Effect Concentration
○ Aquatic Chronic Chronic aquatic toxicity
○ Carc. Carcinogenicity
○ EH40 EH40/2005 Workplace exposure limits
○ Skin Sens. Skin sensitisation
○ STOT RE Specific target organ toxicity - repeated exposure
○ TWA Long-term exposure limit

Key literature references and sources for data

○ RTECS (Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety
and Health, 4676 Columbia Pkwy., Cincinnati, Ohio 45226, USA).
○ HSDB (Hazardous Substances Data Bank - TOXNET (Toxicology Data Network)).
○ IUCLID (European Commission, Joint Reserch Centre, Institute for Health and consumer Protection,
European Chemicals Bureau).

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Full text of H-Statements

○ H317 May cause an allergic skin reaction.
○ H350i May cause cancer by inhalation.
○ H351 Suspected of causing cancer.
○ H372 Causes damage to organs through prolonged or repeated
exposure if inhaled.
○ H412 Harmful to aquatic life with long lasting effects.
○ H413 May cause long lasting harmful effects to aquatic life.

NFPA 704: National Fire Protection Association

Health 2 Fire 0 Reactivity 0

0= minimal hazard, 1=slight hazard, 2=moderate hazard, 3=severe hazard,4=extreme hazard

The above information is believed to be accurate and is based on our present state of knowledge and experience. However, no
warranty or representation with respect to such information is intended or given. This information is intended to be used for
safety and environmental purposes only and should not be relied upon for any other purposes.
Information contained herein is confidential; it may not be used for any purpose other than for which it has been issued, and may
not be used by or disclosed to third parties without written approval of Haldor Topsøe A/S.

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