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ORGANIC CHLORIDE TEST METHODS Supplemental Modification to Industry Organic Chloride Test Methods for determination of Total and Inorganic Chloride content. The challenges facing the crude al market include the impact of chemical species on refineries, such as catalyst poisoning and ar conosion example of ths S excessive total chlesice crude ol that can cause ceresion and has detrenenta effects on catalysts. ‘The organic chiardes can form hydrochloric acidin hyeroteating or reforming reactors The acid accumulates in condensing regions ofthe refinery causing damaging corosion Organic cNorides are not known tabenatiraly occuring incrude ol, Trace Chiorde techniques were orginally developed for petrochemicas, ASTM has developed stander test methods for ur capabilities in the U.S. include: Crannelview Corpus Chist Cushing Deer Park Gonzales La Midand Texas Nederland New Orleans, LA New Yor Harbor Philadelphia Signal Hil ‘Toasty. Texas ao oe Pe = le abe caleb brett determination of Organic Corde content in the 204°C naphtha fraction of cruce oi Reiners also equi Organic Chore content in eavy. viscous opportunity barrels wich ‘ae being blended int cde obit don't hhave araphtha faction The intertek Test Method (73477) provides a supplemental ‘macificaton to methods ASTM D4929 and (081.50 alowing atonal sample preparation {ollwed by performance ofthese industry cepted methodologies. Ths ITM overcomes the hudles of running heavy, viscous samples ‘whe stil imiting significant potential interferences and maintaring igh method precision x Yes ves ves x ves ves ves x ves x ves x ves ves x ves x Yes Yes x ves ves ves x x x x x x x ves x ves ves x our Tests TESTING FOR CHLORIDE + Potentiometric after Sodium biphery reaction ASIMDS194 ops + Microcouiomet'y oe788 ASTMDS808 + XRay ‘ASIMD7535. + Jon Chromatography ASTMD7359 ‘TESTING FOR ORGANIC CHLORIDE ON ‘CRUDE OIL: + ASTM 04929 Procedure A + ASTM 04929 Procedue® + ASTM 04929 Procedure C + ASTMD8I50 ‘CRUDE Ol TEST FOR ORGANIC CHLORIDE HEAVY FUEL OIL TECHNIQUE FOR ‘ORGANIC CHLORIDE ITM 3477: + 04929, 8,C.ccD8150 foNient Ty () [~) 0

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