UNIVERSITY OF SANTO TOMAS

80 Faculty of Engineering
Chemical Engineering Department
70

60
3. If a silver strip were immersed in an aqueous solution containing Cu2+ ions, what would you expect to
happen? 50 P=2
A. Copper would be deposited on the silver strip.
t/oC

40
B. No reaction would occur.
C. Ag would30 be oxidized.
D. Cu2+ ions would be reduced.
20 P=1
4. Which statement is correct about the Daniell cell?
10 cell is an example of an electrolytic cell.
A. The Daniell
B. The spontaneous
0 cell reaction involves the reduction of Zn2+ to Zn.
2+
C. The spontaneous
0 cell
20reaction40involves60
the reduction
80 of Cu 100 to Cu.
D. The spontaneous cell reaction involves the oxidation of Cu by Zn2+.
Triethylamine (TEA) g/100 g soln

5. The molar conductivities of Cs+ and [SO4]2– are 0.772 × 10–2 and 1.600 × 10–2 S m2/mol respectively.
What is the molar conductivity
Fig 1of Cs2SO
Liquid 4?
–liquid phase diagram
A. 2.372 × 10–2 S m2/mol
B. 0.828 × 10–2 S m2/mol
410
C. 3.972 × 10–2 S m2/mol
–2 2
D. 3.144 × 10
405 S m /mol
1 atm
6. For the reaction: 2Ag+ + Zn → 2Ag + Zn2+, Eocell = 1.56 V. What is the corresponding value of
ΔGo? 400
A. –301 J/mol B. 301 kJ/mol C. 301 J/mol D. –301 kJ/mol
t/oC

395
7. For the reaction: 2H+ + Mg → H2 + Mg2+, ΔGo = –457 kJ/mol. What is the value of Eo(Mg2+/Mg)?
A. +2.37 V390 B. –2.37 V C. –4.74 V D. +4.74 V

385
8. If Eo(Ag+/Ag)0 = +0.800.2
V. What 0.4
is the value
0.6 of E (at
0.8298 K) when
1 the concentration of the Ag+
ions is 0.0150 mol/L? mole fraction A
A. +0.69 V B. +0.80 V C. +0.85 V D. +0.91 V
Fig 2 Liquid –vapor diagram of A
9.Consider the following reduction reaction with corresponding reduction potential (E0) in volts.
Au+(aq) + e– à Au(s) +1.68 V
2+ –
Pt (aq) + 2 e àPt(s) +1.20 V
Sn2+(aq) + 2 e– à Sn(s) -0.14 V
Cr3+(aq) + 3 e– à Cr(s) -0.74 V Given Half-reactions for Question in Module 5

The strongest reducing agent is _______, while the strongest oxiding agent is ________.
A. Au+(aq), Cr(s) B. Cr3+(aq), Au(s) C. Cr(s), Au+(aq) D. Au(s), Cr3+(aq)