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Integration of Energy Storage into Energy Systems

Andreas Hauer and Amadeus Teuffel


ZAE Bayern, Garching, Germany

1 INTRODUCTION
steps: the charging, the storage itself, and the discharging.
Today energy storage is high on the public agenda within After the discharging, the energy storage is back at the same
the discussion on our future energy system design. This state as before the charging and can be charged again.
public debate has to remain on the surface, as the topic Energy storages try to preserve the exergy content of the
“energy storage” turns out to be quite complex, particularly charged energy, but owing to storage losses over time, it will
when observed as part of a complete system. Energy storage, decrease from the first principle.
in general, is strongly connected to the system, because it
is placed between an energy source and the final energy
consumer. Both sides may provide totally different require- 1.1.3 What is stored?
ments.
In order to offer a solid basis for further discussions, some The form of energy—electricity, heat, cold, mechanical
fundamental definitions will be given in this section. energy, or chemical energy—taken up by an energy storage,
will be also discharged in general. However, in many cases,
1.1 Energy storage definition the charged form will be transformed into another form
for storing (e.g., pumped hydro storage or batteries). For
1.1.1 What is energy? discharging, it will be converted again to be delivered in the
original form.
In order to define energy storage in general, “energy” has In some storage applications, the transformed form of
to be defined first. Energy is a fundamental physical value. energy will be delivered, for example, in power-to-gas or
Energy cannot be “produced” or “consumed” in a physical power-to-heat applications.
sense. Energy can only be transformed into another form of
energy (e.g., from electricity into heat). The sum of all forms
of energy within a closed system remains constant, which is 1.1.4 Energy storage/energy storage system
the first law of thermodynamics.
Any energy storage system consists of the following
The quality of energy and the ability to do “work,”
elements: charging unit, storage unit, and discharging unit.
however, can be “produced” or “consumed.” This ability
is called exergy and is usually decreasing within any The energy storage itself is connected to the energy system
transformation step or storage process. (“energy sources” and “energy consumer”) by the charging
and discharging unit. As an example, a power-to-gas storage
has the electrolysis as charging, the gas cavern as storage,
1.1.2 What is an energy storage?
and the fuel cell as discharging device.
Energy storages are able to take up energy and to deliver it at
a later stage. The storage process, in general, consists of three
1.1.5 Energy storage and its application
Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd. The technical and economic requirements of any energy
This article was published in the Handbook of Clean Energy Systems
storage are determined by the application within the energy
in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215 system. This is the reason why energy storage technologies
2 Integrated Storage Systems

can only be evaluated or compared within the context of an power are in this case complimentary. Another example
actual application. would be an efficient long-term thermal energy storage
The application defines the technical requirements (form (TCS) with high cost for the insulation of the system. Here
of energy, focus on energy or power, storage period, reaction efficiency, storage period, and cost are related.
time, etc.) of operation. The application also determines the So far, the properties were discussed as properties of the
economic environment in which the storage will be operated. storage technology. In the following articles, it will become
clear that the actual application of any storage system
influences very strongly all these properties. In general,
2 ENERGY STORAGE TECHNOLOGIES energy storage systems are linked to their application much
more intense than any other components within the energy
There are many possibilities to store energy. The different system! They are not only delivering a certain energy form
energy storage technologies can be assigned to the energy or consuming it. They have to do both and match supply and
form they are providing within an actual storage applica- demand.
tion. In this context, these technologies are referred to as
electrical, thermal, mechanical, or chemical. Energy storage
technologies can be classified by their storage properties. 2.2 Electrical energy storage

Electrical energy storages store electricity in most cases as


2.1 Energy storage properties mechanical or (electro-) chemical energy. Direct storage of
electricity, by supercapacitors or superconducting magnetic
In order to describe the different energy storage technologies, energy storage (SMES) is a topic of basic R&D today. The
some technical properties will be defined: by-far largest contribution of electricity storage today comes
from mechanical energy storage systems, as illustrated in
• Capacity: The storage capacity gives the possible
Figure 1, which shows that pumped storage hydro power
amount of energy stored within and finally delivered
stations (PSH), compressed air energy storage (CAES), and
from the storage unit. The capacity is linked to the
flywheels currently contribute to more than 99% of all elec-
energy density of the storage. The energy density is the
trical energy storage systems in terms of installed capacity.
capacity, the storage energy, related to the volume or
the mass of the storage.
• Power: The power—energy per time—defines how fast 2.2.1 Mechanical energy storage
the energy storage can be charged and discharged. The
power density gives the power of a certain unit related to Mechanical energy storages store electrical energy by
its volume or mass. converting it into mechanical energy. During discharge, the
• Efficiency: The efficiency of the energy storage is the mechanical energy is converted back into electrical energy.
ratio between the energy provided to the consumer and Mechanical energy storages are characterized by their
the energy charged to the storage. Usually, the effi- large storage capacities and electrical power, and they are
ciency is below 100% because of losses over the storage currently the most economical solution to store electrical
period or inefficiencies of the charging and discharging energy.
processes.
• Storage period: The storage period defines for how Redox-flow 10
long the charged energy can be stored until it will be Others 976
Flywheel 25
discharged. This time can go from seconds (or less!) to Nickel-cadmium 27
months. The storage period is limited by the losses of the
Lead acid 70
system.
Lithium-ion 100
• Cost: The cost of an energy storage system can refer
Sodiumsulphur 304
to either the capacity (money per energy, e.g., euro per
kilowatt hour) or the power (money per power, e.g., euro
per kilowatt). PSH 140000 CAES 440

The properties listed in this section are not independent


of each other. An energy storage system designed for high Figure 1. Current installed gird-connected electricity storage
power output is designed in a different way compared to a power in megawatts. Source: Created by the author using data from
system optimized for high storage capacity. Capacity and IEA, 2014a.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
Integration of Energy Storage into Energy Systems 3

In Figure 1, PSH, CAES, and flywheel energy storages generation flywheels are hence equipped with magnetic bear-
represent the most common mechanical energy storages ings and operated in vacuum housings. Storage capacities
currently used. and electrical power depend on the moment of inertia of the
PSH store electrical energy by converting it into poten- flywheel and its rotational speed and therefore on the strength
tial energy of water, which is pumped from a lower level of rotating materials and the bearing.
to an upper level storage reservoir. In order to discharge the For further reading on flywheel energy storages, see
storage, water flows in the opposite direction through water Flywheel Energy Storage Systems.
turbines that drive electricity generators. Overall storage effi-
ciencies of PSH range from 63% to 85% (Hauer, Quinnell,
2.2.2 Electrochemical energy storage
and Lävemann, 2013). The storage capacities depend on the
volume of water that can be used and on the difference in Electrochemical energy storages (battery/accumulator) store
altitude between the water reservoirs. Maximum electrical electrical energy by converting it into chemical energy.
power of PSH depends on the electrical power of the turbines There is a wide range of different battery technologies that
and therefore on their size. Generally, power and capacities differ in materials, voltages, power ranges, temperature
of current storages range from 1 MW up to several 100 MW ranges, and so on. If storage capacity and conversion unit
and MWh (Oertel, 2008). are not spatially divided, the capacity and electrical power
PSH can be used to store excess energy but also for are codependent (Sterner et al., 2010). This is the case for
ancillary services such as reactive power and voltage control sodium–sulfur, lithium-ion, lead-acid, and nickel–cadmium
or load following. batteries. In contrast, redox-flow batteries have separate
For further reading on PSH, see Pumped Hydro Energy storage and conversion units and therefore capacities and
Storage. power output can be chosen independently. Hence, there are
CAES convert electrical energy into potential energy different fields of application for these technologies ranging
of air, which is compressed and stored in underground from mobile use in vehicles to stationary applications and
caverns or pressure vessels. For discharge of the storage, from short-time power quality services to measures for
the compressed air is expanded in gas turbines (Crotogino, integration of renewables with larger storages.
2002). The storage efficiency of CAES depends on the For further reading on electrochemical storage, see
efficiencies of compression and expansion. The air entering Rechargeable Battery Energy Storage System Design, Flow
the gas turbines during discharge has to be heated up, Battery Technology, and Sodium–Sulfur Batteries.
which leads to a relatively low overall efficiency of around Figure 2 depicts power ranges and typical discharge
55% (Hauer, Quinnell, and Lävemann, 2013). In “adiabatic periods for different electrical energy storage technologies.
CAES,” the heat generated during the compression process Storages for the integration of renewable energies need
when charging the CAES can be stored in a separate heat discharge times of minimum 1 h and electrical power of
storage and later on be used to heat up the expanding air. 100 kW to have a considerable effect on the system (Hauer,
The efficiency can thus be increased up to 70% (Hauer,
Quinnell, and Lävemann, 2013). Nevertheless, the efficiency
decreases with time as the heat cannot be stored infinitely. Discharge period (h)
The storage capacities depend on the volume of and air CAES PSH
10
pressure in the storage volumes. Maximum electrical power NaS
Redox flow
of CAES depends on the power of the gas turbines. 1
For further reading on CAES, see Compressed Air Energy Lead acid
0.1 battery
Storage (CAES).
Flywheel energy storages convert electrical energy into Flywheel
0.01
rotating energy of a flywheel. During charging, the flywheel Double
is accelerated by an electrical motor, and thus the rota- 0.001 layer
tional speed increases. During discharge, the flywheel drives capacitor SMES

the electrical motor used as generator, which leads to a 0.0001


decreasing rotational speed of the flywheel (Oertel, 2008). 0.001 0.01 0.1 1 10 100 1000 10,000
Power rating (MW)
Efficiencies of about 85–95% can be reached with the latest
flywheel energy storage generation (Lang, 2003). Neverthe-
Figure 2. Electricity storage technologies: typical discharge
less, stored energy decreases at rates of 20% per hour because periods and power ratings. Source: Reproduced with permission
of mechanical losses that occur mainly because of frictional from Hauer, Quinnell, and Lävemann, 2013. © Wiley-VCH Verlag
losses in the bearing (Diekmann and Rosenthal, 2014). Latest GmbH & Co. KGaA.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
4 Integrated Storage Systems

Hiebler, and Reuß, 2013). From this viewpoint, PSH and Stored energy is proportional to the storage material’s mass
CAES but also redox-flow, sodium-sulfur, and lead-acid and its specific melting heat. At standard pressure, 1 kg of
batteries might be suitable solutions, whereas the discharge water needs 333.5 kJ of thermal energy to be melted/frozen.
periods of SMES, flywheels, and double-layer capacitors Compared to sensible thermal heat supply, 1 kg of water
are more suitable for short-time applications. could be heated by ΔT = 80 K with the same amount of
energy. Thus, high storage densities can be reached in latent
TES (Diekmann and Rosenthal, 2014).
2.3 Thermal energy storage As different materials show different melting tempera-
tures, storage materials have to be chosen according to
Another way to store energy is by thermal energy stor- the needed temperatures in the specific storage application.
ages(TES). Thermal energy can be stored in sensible and Exemplary applications for PCM storages are ice storage for
latent thermal storages or by converting the energy in ther- cooling purposes (see also Ice Storage) or micro encapsu-
mochemical reactions. lated PCM with melting temperature around 20◦ C to buffer
daytime heat changes in buildings. One drawback of PCM
2.3.1 Sensible thermal energy storage is their relatively low thermal conductivity, which leads to
poor charging and discharging power, although increasing
In sensible TES, the temperature of storage materials the surface of PCM storages is one way to approach this
changes when heat is charged or discharged. The stored problem (Zalba et al., 2003).
energy is proportional to the temperature difference, the For further reading on PCM, see PCM Storage.
mass, and the specific heat capacities of the storage material,
which is why materials with large specific heat capacities
2.3.3 Thermochemical thermal energy storage
are preferred. Water has a large specific heat capacity
besides being inexpensive and is therefore prevalently used In thermochemical energy storages (TCS), reversible chem-
as storage material. Common temperatures for sensible ical reactions are used to convert and store the thermal
thermal storages range from −10 to 100◦ C (Hauer, Quinnell, energy. One benefit of thermochemical storages is when reac-
and Lävemann, 2013). These relatively low temperatures tants are separated no thermal losses occur. This enables TCS
make sensible storage most suitable for heating/hot water for long-term thermal storage applications (Diekmann and
and cooling applications in buildings. Rosenthal, 2014; Abedin and Rosen, 2011).
A typical application is small hot-water tanks in combina- Most investigated TCS uses the sorption of water to/from
tion with solar thermal appliances in domestic use to account a storage substrate such as zeolite or silica gel as reac-
for daily or weekly fluctuations/mismatch in heat production tion to store thermal energy. During charging, heat is
and consumption. Larger sensible storage appliances are supplied to the substrate, which causes the water previously
thus able to account for seasonal fluctuations. Another absorbed/adsorbed to be separated from the substrate.
application is to store sensible thermal energy underground For discharging, humid air is fed to the substrate, water
in combination with heat pumps. In this combination, heat is is absorbed/adsorbed and heat of reaction is released.
discharged during wintertime at around 5◦ C and supplied to This leads to applications for thermal storage, industrial
the domestic heating circuit through the heat pump. During drying processes, and HVAC (heating, ventilation, and
warmer seasons, the cold ground serves as “cold” source air-conditioning).
for air-conditioning purposes. The storage material in the Analogous to PCM, thermochemical storage materials
ground can be water in aquifers or vessels but also, for (TCM) have relatively low thermal conductivity and mass
example, rock, sand, or soil (for more details on heat pumps, transfer rates, which results in poor charging/discharging
see Geothermal Heat Pumps). power and reduced efficiencies.
Figure 3 compares energy densities with respect to the
2.3.2 Latent thermal energy storage storage volume of different storage materials (or mate-
rial combinations) of TES technologies. TCS theoretically
During charging and discharging of latent TES, thermal reaches the highest energy densities compared to latent
energy is used to change the aggregate phase of the storage and sensible TES. Nevertheless, it applies to all thermal
material [hence the name phase change materials (PCM)], storage technologies that for higher energy densities, oper-
whereas the sensible temperature of the material does not ating temperatures have to be increased.
change (Mehling and Cabeza, 2008). Most applications The blue dotted line shows the theoretical sensible energy
use phase change from liquid to solid state, as large gas density for liquid water, which is impaired by the restricted
volumes at normal conditions are more difficult to handle. temperatures of the storage applications as well as by heat

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
Integration of Energy Storage into Energy Systems 5

to a certain amount, as other natural gas applications tolerate


600 only small amounts of hydrogen.
MgSO4 • 6H2O
For further reading on hydrogen energy storage, see
Storage energy density (kW/m3)

500
MgCl2 • 6H2O Hydrogen Energy Storage Systems for Grid and Community
400
Applications, Clean Energy-Based Production of Hydrogen:
TCM An Energy Carrier, and Hydrogen Blending in Natural Gas
NiCl2NH3
300 Pipelines.
CaCl2 • NH3 Silicagel • H O Zeolite • H2O
2
200 Nitrates
2.4.2 Renewable methane
Salt hydrates PCM lcohols
100 Sugar a
Paraffines Hydrogen can also be used to synthesize methane. In the
Water process of methanation, CO2 and H2 form methane (CH4 )
0
0 25 50 75 100 125 150 175 200
and water. Advantage is the versatility of methane. Fed to
Temperature (°C)
the existing natural gas infrastructure (with no limits), it
can be used in all fields of the energy sector (Trost et al.,
Figure 3. Thermal energy storage technologies: storage capacities 2012). The reconversion of electricity via gas turbines or
and temperatures. Source: Created by the author using data from fuel cells is an investigated option to bridge longer periods
ZAE Bayern. of insufficient renewable power supply (Stadermann, 2010).
When compressed or liquefied, methane can reach energy
differences in heat exchangers. The solid blue line represents densities that make it suitable for mobility applications.
a resulting reduced storage energy density. Methane, like conventional natural gas, can also be used for
Figure 3 depicts energy density under optimum boundary heating purposes.
conditions. Further it should be noticed that storage capacity Figure 4 depicts the basic concept of a renewable methana-
is not an intrinsic property of storage materials but of the tion plant. CO2 for the methanation can be extracted from the
particular storage system under its specific operating condi- atmosphere or separated from exhaust gas in power plants.
tions (Hauer, Quinnell, and Lävemann, 2013). The process of methanation links the electricity with the gas
sector and creates new ways of using excess power.
2.4 Energy storage by chemical conversion

Energy can also be stored by chemical conversion. For this 3 THE ROLE OF ENERGY STORAGE IN
purpose, energy is used to produce chemical energy carriers THE ENERGY SYSTEM
with high energy density and nearly infinite storage periods.
Most investigated energy carriers for conversion of elec- Whenever the energy supply does not match the energy
tricity (or heat) are hydrogen and methane. demand, energy storage can help balancing this mismatch.
Energy storage decouples energy supply and demand and,
2.4.1 Hydrogen energy storage by doing this, adds flexibility to the system.
Today, this flexibility needed by the system comes from
One way to generate hydrogen is using excess electrical fossil fuels, which are somehow the “ideal” fuel. They have
energy from renewables for electrolysis of water. In the a very high storage capacity (6.7–12.8 MWh/t) and can
process of electrolysis, water is split up into oxygen and provide very high power outputs. Their problem is only
hydrogen, which then can be stored. Hydrogen can also be that they need far too long to be charged again! Today,
generated by thermal split-up of water, but high tempera- “discharging” rate is so high that we soon have to face
tures are required for this process (Hamacher, 2014). During empty fossil “batteries.” One psychological problem for all
surplus energy periods, the generation of hydrogen is there- energy storage technologies is the fact that we are used to
fore a possible solution to store the energy. The reconversion these very high capacities and it is difficult to accept the
of electricity can follow in fuel cells or in gas turbines. Owing achievable storage capacities within our energy system.
to a relatively low energy density with respect to the volume, Best example is the mobility sector. Here, we are not
hydrogen has to be compressed to reach energy density levels willing to accept short distances and reduced power of our
of other fuels. After compression, hydrogen can also be used future vehicles. At the same time, we would not accept a
in transport. Hydrogen can be stored in caverns or engineered car without heating and air-conditioning and many other
tanks. It can also be fed to the natural gas network but only additional assets, which contribute to our personal comfort.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
6 Integrated Storage Systems

Electricity Natural gas


network network

Wind - For heat


- For transport
CHP,
Solar
turbines

Other
renewables Power generation

Power storage Gas storage

- Atmosphere H2O O2
- Biomass, waste H2
Electrolysis
- Industry H2-tank CH4
- Fossil fuels
CO2 Methanation
CO2 CO2-tank
H2O
Renewable power methane
plant

Figure 4. Basic concept of a renewable power to methane plant. Source: Reproduced with permission of Michael Sterner, 2009.
Power

Power

Surplus demand
from storage Surplus supply
to storage

Surplus supply Surplus demand


to storage from storage

Supply Demand

Demand Supply

Time Time
(a) Supply management (b) Demand management

Figure 5. (a, b) Supply and demand balancing. Source: Reproduced with permission from Hauer, Hiebler, and Reuß, 2013. © Fraunhofer
IRB.

It is impossible to keep the standards set by fossil fuels by to adapt to the consumer’s demand. Both possibilities are
battery-driven cars. quite rare in reality. Figure 5 shows two cases, where either
However, as the resources are limited, any future energy the supplied power is constant and the demand varies with
system will need the same flexibility and energy storage will time or the power demand is constant and the supply shows
be one of the possible solutions to this problem. a variation in time.
In case (a), energy is supplied, for example, by a conven-
3.1 Balancing supply and demand tional power plant based on the combustion of fossil fuels
and energy storage manages the variation of the demand in
Energy storage, in general, can be applied wherever there order to keep the operation of the plant in a constant and
is a power difference between energy supply and demand, optimal range without the need to follow the demand fluc-
which has to be balanced. Without any storage, the consumer tuations. As the energy storage in this application provides
has to include the energy as it is supplied or the supplier has energy for the demand peaks, the highest energy prices can

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
Integration of Energy Storage into Energy Systems 7

be achieved. A second example would be a combined heat Provided that the grid is able to transport the energy to the
and power unit running on biogas, which is operated at DES locations, DES could contribute to the storage demand
a constant electricity production. The heat is stored sepa- given by the fluctuations of larger wind and PV installations.
rately and supplied from the storage at times of actual heat In this case, a number of DES can be connected to build a
demand. larger storage capacity. In any case, the economic framework
In case (b), energy supply varies, for example, because it is and the communication between the distribution net and the
based on fluctuating renewable sources such as photovoltaic DES (e.g., by “smart grids”) are important questions.
(PV), wind, or solar thermal. The energy storage in this appli- DES can be “real” storage systems, such as a lithium-
cation is necessary to provide a base load at constant demand ion battery in a PV-system or a hot-water storage in a solar
to the consumer. In this context, energy storage systems are
thermal installation. In this case, electricity or heat will be
contributing to the integration of variable renewable ener-
charged and discharged later on demand. However, DES can
gies.
also be a “virtual” storage. An example is the conversion
In reality, the energy system of the future will face both
of electricity from wind power into cold, which can be
cases at the same time. There will be a growing fraction
of variable renewables as well as further diversified and stored thermally (“power-to-cold”): TES is used to create
highly nonconstant demand pattern on the demand side. a dispatchable load (in this case, the cold demand). No
This development clearly highlights the necessity of energy electricity can be discharged from this storage. However, this
storage capacities in our energy systems. DES can contribute to the integration of renewable energy
sources as well.
A variety of technologies can be used for decentralized
3.2 Distributed energy storage
energy storage applications (real and virtual). From the first
principle, mechanical, electrical, electrochemical, thermal,
Distributed energy storages (DES) can be defined by their
and chemical energy storages could be implemented. In
location within an energy system. They are generally located
at the consumer side, from household up to industrial appli- addition, hybrid solutions based on two or more technolo-
cations (Figure 6). In case of an electricity grid, this would gies could be promising. Some of the storage technologies
be the low voltage distribution grid, where the storage can be considered are operated (or under investigation) in different
placed at the transformation unit or even in the building. In applications such as peak shifting at the moment. One
case of a district heating net, it would be at the level of heat example is the use of ice storage in Japan in order to reduce
substations. Facing a growing impact of distributed renew- the electricity peak for air-conditioning.
able energy generation by PV, solar thermal, or biomass (via A diversified energy system based on a number of different
combined heat and power), DESs are most suitable to balance energy storage sizes and technologies is able to provide high
the storage demand at this level. system stability and reliability.

Renewable Distribution Distributed Consumer


energy energy storage

PV
EES
Electricity
Wind grid Final
TES energy
District demand
Bio/CHP
heat/cold

Solarthermal

TES Thermal energy storage EES Electrical energy storage

Figure 6. Location of distributed energy storages in the energy system. Source: Created by the author using data from ZAE Bayern, IEA
ECES Annex 28.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
8 Integrated Storage Systems

4 RELEVANT ENERGY STORAGE resources (e.g., wind and solar) in order to increase its
APPLICATIONS quality and value.
• Load following: The second continuous electricity
More than any other energy technology, energy storages balancing mechanism for operation under normal
are depending very strongly on the actual application. This conditions, following frequency regulation. Manages
application defines the energy input during the charging systems fluctuations on a 15-minute to hours timeframe
process as well as the energy output during the discharging and can be controlled automatically through automatic
process. The possible fields of applications are as diverse as generation control or manually.
the energy storage technologies described earlier. • Demand side integration—power-to-heat: The integra-
Any clean energy system of the future will be based on tion of renewable electricity can be achieved by conver-
the integration of renewable energies and an improvement sion into heat and TES technologies in order to match
in energy efficiency. These measures have to be applied to (electricity) supply and (heat) demand. This way of inte-
the electricity as well as the heat/cold supply. Energy storage gration was identified as the most inexpensive within
technologies can substantially contribute in all fields. the GIVAR Project “Grid Integration of Variable Renew-
The following will give a list of the most relevant energy ables” at the IEA (2014b).
storage applications within future energy systems. This list, • Peak shaving: Storing low priced energy during periods
however, is not complete. of low demand and subsequently selling it during high
priced periods. This service is particularly valuable in
systems with inflexible supply resources.
4.1 Integration of renewable electricity
• PV self-consumption: The self-consumption of
4.1.1 Grid stability distributed PV installation can be increased (from
about 30% to 70%) using local, distributed battery
• Frequency regulation: Balances continuously shifting systems. Connected to a “smart grid,” these batteries
supply and demand within a control area under normal can also be used as a “virtual electricity storage” for
conditions. Management is frequently done automati- other flexibility measures (see “Benefit Stacking”).
cally, on a minute-to-minute basis. • Off-grid: Off-grid energy consumers frequently rely on
• Voltage support: The injection or absorption of reactive diesel generators to provide power and other fossil or
power to maintain voltage levels in the transmission and biofuel resources to provide heat. To ensure reliable off-
distribution system under normal conditions. grid energy supplies, storage is necessary to fill gaps in
• Fast power reserve: In the case of an unexpected loss of variable supply resources with demand.
electricity supply, fast power reserves can be called upon
to rapidly compensate and keep the system balanced.
Reserve capacity is classified by the amount of time it
takes to bring the power online. 4.2 Integration of renewable thermal energy
• T&D congestion relief and infrastructure investment
deferral: In order to relieve congestion points in the
transmission and distribution grids, energy storage can • Solar thermal power plants: For concentrated solar
be added to facilitate the relief of this transmission. power based on solar-thermal power plants, high temper-
Moreover, energy storage can be used to defer the need ature TES technologies are able to provide a nonstop
for a large investment in transmission and distribution operation.
infrastructure. • Solar thermal process heat: Process heat for industrial
• Black start: In the very rare situation when the power applications can be provided by solar collectors (see
system collapses and all other ancillary mechanisms Solar Heating and Cooling Roadmap, IEA). In order to
have failed, black start capabilities allow electricity overcome the mismatch between supply and demand,
supply resources to restart without pulling electricity TES can be applied.
from the grid. • Solar thermal heating and cooling: Solar thermal energy
can be utilized for the heating and cooling of buildings.
TES systems can help to integrate this fluctuating energy
4.1.2 Grid balancing resource. In this context also long-term storages are able
to provide seasonal storage by charging solar heat in
• Variable supply resource integration: Energy storage can summer time and discharge this heat in winter at high
smooth and optimize the output from variable supply heating demand.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
Integration of Energy Storage into Energy Systems 9

4.3 Energy efficiency the energy storage device and would certainly lead to an
improved economic performance.
All relevant applications are listed in Table 1.
• Waste heat utilization: TES technologies are able to
utilize waste heat from industrial processes. The stored
thermal energy can be discharged whenever there is heat
demand. The overall efficiency of the processes will be
5 TECHNICAL COMPARISON OF
increased by this measure.
• Heating and cooling demand: Owing to the temperature
ENERGY STORAGE TECHNOLOGIES
difference between night and day in most climates, the
The main technical parameters, based on the energy storage
heating and cooling demand of building can be reduced
properties listed earlier, for several established and emerging
by storing day’s heat or night’s cold. Daily TES oper-
energy storage technologies are given in Table 2 (see refer-
ation can contribute remarkably to a heating/cooling
ences from Hauer, Quinnell, and Lävemann, 2013). These
demand reduction.
parameters are the typical storage capacity, power output
• Combined heat and power: If combined heat and power
and storage period, the energy density (related to mass
units are equipped with TES system, they would be able
and volume), expected efficiencies and lifetime, and some
to be operated only following the electricity demand
different cost metrics. The given data are rather examples
(may it be ruled by economic or technical means). This
of typical values from literature. For some parameters, no
would open new flexibility options and keep up the high
values are available, while others are determined under
energy efficiency given by the utilization of heat and
different assumptions (Hauer, Quinnell, and Lävemann,
power.
2013).
The first distinction among the different storage technolo-
Energy storage technologies may be able to cover several gies is the form of stored energy. The first six technolo-
of the listed tasks. This would lead to a multiple benefit of gies in Table 2 store electrical energy by different storage

Table 1. Relevant energy storage applications.


Application Output Focus on Power Size (MW) Discharge Duration Cycles (Typical) Response Time
(Electricity, Thermal) or Energy (s, min, h, d, a) (# per day) (s, min, h)
Frequency regulation e Power 1–2000 1–15 min 20–40 1 min
Voltage support e Power 1–40 1 s–1 min 10–100 ms–s
Fast power reserve e Power 10–100 15 min–2 h 0.5–2 <15 min
T&Da congestion relief e, t — 10–500 2–4 h 0.14–1.25 >1 h
T&Da infrastructure e, t — 1–500 2–5 h 0.75–1.25 >1 h
investment deferral
Black start e Power 0.1–400 1–4 h <1 per year <1 h
Variable supply resource e, t Power/energy 1–400 1 min to hours 0.5–2 <15 min
integration
Load following e, t Power 1–2000 15 min–1 day 1–29 <15 min
DSIb (power-to-heat) t Energy, power 0.001–10 Hours to days 0.5–10 <15 min
Peak shaving e, t Power, energy 0.001–1 Minutes to hours 1–24 <15 min
PVc self-production e Energy 0.001–1 Minutes to hours 1–24 <15 min
Off-grid e, t Power, energy 0.001–0.01 3–5h 0.75–1.5 <1 h
Concentrated solar power t Energy 0.5–150 6–8 h 2–4 10–15 min
Solar-thermal process t Energy 0.5–400 Minutes to hours 1–10 <15 min
heat
Solar heating and cooling t Energy 0.002–1 Hours, days to seasonal 0.003–1 <15 min
Waste heat utilization t Energy 0.25–10 1 h–1 day 1–20 <10 min
Heating and cooling of t Energy 0.002–1 Hours to days 0.5–1 <15 min
buildings
Combined heat and t Power, energy 0.25–5 Minutes to hours 1–10 <15 min
power
Source: Created by author using data from IEA, 2014a and ZAE Bayern.
a Transmission and distribution.
b Demand side integration.
c Photovoltaic.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
10

Table 2. Relevant energy storage technologies.


Storage Storage Power (MW) Capacity Storage Period Density Efficiency Lifetime Cost

DOI: 10.1002/9781118991978.hces215
Technology Mechanism (MWh) (time) (%) (# cycles)
kWh/t kWh/m3 $/kW $/kWh ct kW/h
Delivered
Integrated Storage Systems

This article is © 2015 John Wiley & Sons, Ltd.


Lithium ion Electrochemical <1.7 <22 Day to 84–160 190–375 89–98 2960–5440 1230–3770 620–2760 17–102
month
Sodium sulfur Electro 1–60 7–450 Day 99–150 156–255 75–86 1620–4500 260–2560 210–920 9–55
battery chemical
Lead -acid Electro 0.1–30 <30 Day to 22–34 25–65 65–85 160–1060 350–850 130–1100 21–102
battery chemical month
Redox/flow Electro <7 <10 Day to 18–28 21–34 72–85 1510–2780 650–2730 120–1600 5–88
battery chemical month

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
Compressed air Mechanical 2–300 14–2050 Day — 2–7 at 40–75 8620–17,100 15–2050 30–100 2–35
energy 20–80 bar
storage
Pumped hydro Mechanical 450–2500 8000–190,000 Day to 0.27 at 100 m 0.27 at 63–85 12,800–33,000 540–2790 40–160 0.1–18
energy month 100 m
storage
Hydrogen Chemical Varies Varies Indefinite 34,000 2.7–160 at 22–50 1 384–1408 — 25–64
1–700 bar

This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
Methane Chemical Varies Varies Indefinite 16,000 10 at 1 bar 24–42 1 — — 16–44
Sensible Thermal <10 <100 Hour to 10–50 <60 50–90 ∼5000 — 0.1–13 0.01
storage— year
water
Phase change Thermal <10 <10 Hour to 50–150 <120 75–90 ∼5000 — 13–65 1.3–6
materials week
Thermoche- Thermal <1 <10 Hour to 120–250 120–250 80–100 ∼3500 — 10–130 1–5
mical week
storage
Source: Reproduced with permission from Hauer, Quinnell, and Lävemann, 2013. © Wiley-VCH Verlag GmbH & Co. KGaA.
Integration of Energy Storage into Energy Systems 11

mechanisms—electrochemical and mechanical. The possi- of losses. Technologies such as batteries and sensible energy
bilities of direct storage of electricity by superconductors or storage have self-discharge or thermal losses, which effec-
SMES are not considered, as these technologies will not play tively reduce the efficiency over time. Mechanical and chem-
any relevant role in our energy systems until 2050. The next ical storage systems tend to have efficiencies that are some-
category of technologies deals with the conversion of elec- what independent of storage period because of extremely low
tricity into hydrogen or methane, where the possibility of losses.
supplying electricity again (e.g., by a fuel cell) is also given.
Finally, the different technologies of TES are listed (Hauer,
Quinnell, and Lävemann, 2013).
5.1 Energy storage technologies can only be
Looking at the storage forms that can provide electricity, compared within their actual application
they are generally differentiated by scale, both in size
and storage period. Mechanical energy storage units such A reliable comparison of energy storage technologies is not
as pumped hydro energy storage (PHES) and CAES are possible by only considering Table 2. It is only possible
mostly effective for large centralized applications and are to compare energy storage technologies with respect to an
highly dependent on the local geology. However, they actual application. The application gives the operating condi-
offer the largest capacity and power of all technologies tions and by this the requirements to the technology. Looking
with capacities between 2 MWh and 190 GWh and power at Table 1 containing the list of relevant applications and
outputs between 2 MW and 2.5 GW. Today, almost 99% matching this with the list of energy storage properties in
of all installed electricity storage capacity is based on Table 2 could lead to a matrix of suitable storage technologies
PHES (Hauer, Quinnell, and Lävemann, 2013). Today, for each application.
the use of chemical energy storages, for example, in a In this context, not only the technical properties of the
power-to-gas application for integration of renewable storage technology such as capacity and power, but also the
electricity, is focused on large-scale centralized units properties such as type of stored energy, scale and scope of
(ETOGAS GmbH, http://www.etogas.com). However, also the storage, and last but not least the economic factors of the
in the field of DES devices, activities have been started application are important.
(GP Joule GmbH, http://www.gp-joule.de). The typical
lower power and capacity of electrochemical storage are 5.1.1 Example: long-term energy storage for the
better suited to smaller scales, such as the transportation integration of renewable energies
sector.
The power and capacity of energy storage are related As an example, suitable energy storage technologies for
to the physical size via the energy density. In terms of long-term storage of renewable electricity should be iden-
energy density, the major distinction is the very high densi- tified. From Table 2, it can be derived that only chemical
ties of chemical fuels (16–34 MWh/t) compared with the storage and sensible thermal storage could be options for this
relatively low energy densities of all other technologies. purpose. Comparing these technologies, it becomes clear that
CAES and PHES typically have among the lowest energy a straight comparison based on the numbers in Table 2 is not
densities (0.27–7 kWh/m3 ). Meanwhile, at smaller DES sufficient.
scales, the differences in energy density between lithium- Assuming to take surplus electricity and convert it by elec-
ion (84–160 kWh/t) and lead-acid (22–34 kWh/t) batteries, trolysis (efficiency up to 80%) into hydrogen and producing
or thermochemical storage (120–250 kWh/t) and sensible again electricity via a fuel cell after the long storage period,
energy storage (10–50 kWh/t), are likely to have a substan- this system would end up with a round-trip efficiency in the
tial impact on the volume and mass of the storage, easily range around 35–40%. If the same surplus electricity from
becoming the critical factor for many applications. However, wind or PV will be used to run a heat pump, about 300%
a clear definition of the “energy density” of a certain energy usable heat can be produced. This heat can be stored over a
storage technology is missing. For some storage technolo- year with an efficiency of around 75%. The overall efficiency
gies, the density is exclusively related to the active storage of the complete system from renewable electricity to heating
material, for some to the actual storage component and others of a building will be around 225%.
consider the complete storage system. The big difference is that the first case provides hydrogen,
Storage generally degrades the overall efficiency of the which can be, for example, used in the mobility sector or the
energy system during charging and discharging (see Table 1), chemical industry, or electricity, which is also much more
except for thermochemical heat storage, where a heat pump valuable compared to low temperature heat. The second case
effect allows “efficiencies” over 100%! For many technolo- can only provide heat, but with a comparable high overall
gies, the efficiency depends on the storage period because efficiency. This example shows how crucial the application

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
12 Integrated Storage Systems

and the final energy demand—may it be fuel for transporta- The maximum acceptable storage cost results as
tion, electricity for lighting, or simply thermal energy for
heating—is. Cenergy 365
Cmax = ⋅ (€ ∕kWh) (2)
AF SCP

6 ECONOMICS OF ENERGY STORAGE where Cmax is the maximum acceptable storage cost in euro
per kilowatt hour, Cenergy the energy costs, and SCP the
Besides technical comparison, energy storage tech- storage cycle period. Cmax is therefore inversely proportional
nologies are evaluated regarding their economics. In a to the storage cycle period or—when related to the 365
bottom-up economic evaluation costs for R&D, manufac- days of the year—proportional to the number of storage
turing, installation, materials, and so on are considered cycles per year and proportional to the energy cost of energy
and combined to an overall storage cost estimate. A generated in power plants. Operational costs are neglected
problem of this approach is the wide variation of cost in this approach as well as varying energy costs over time.
estimates as many factors and cost uncertainties prevail. Nevertheless, this equation illustrates well the dependency
Estimates for the different technologies are shown in of acceptable storage costs on energy costs and storage cycle
Table 2. periods and is therefore a great alternative to estimate storage
costs.
Figure 7 depicts maximum acceptable storage costs
6.1 Maximum acceptable storage cost over storage cycle periods in a full log graph for the
different sectors described earlier. For each sector, two
Another way for economic evaluation is a top-down combinations of annuity factors and energy prices show
approach considering the maximum acceptable storage costs the typical range for these parameters in each sector. Red
in comparison with terminal costs of energy production
lines and blue lines represent industry sector and build-
(Hauer, Quinnell, and Lävemann, 2013). One benefit of
ings sector, respectively. Green lines represent the private
this approach is that detailed information about storage
or “enthusiast” sector. As can be seen from the graph,
technologies is not necessary. Economic operation of
maximum acceptable storage costs decrease with the length
storages is achieved when storage costs per kilowatt hour do
of storage cycle periods. Thus, for seasonal storage, the
not exceed costs of energy generated in power plants. This
maximum acceptable costs have to be less than for high
maximum acceptable storage cost can be calculated from
frequency storage. For example, in the buildings sector,
the payback period and the corresponding discount rate of
with energy prices of €0.06/kWh and AF = 10%, a seasonal
the investment, the storage cycle periods, and the energy
storage with storage cycle periods of 365 days maximum
price to be compared to.
acceptable storage costs are about €0.60/kWh. Comparing
In different areas of application, different payback
periods and discount rates apply. When defining “industry,”
“buildings,” and “private” as sectors in which investments
Maximum acceptable storage costs (€/kWh)

1000
in storage solutions are done, it has to be considered Buildings (7%, 0.1 €/kWh)
that these sectors show different investment behav- Buildings (10%, 0.06 €/kWh)
Private (4%, 0.16 €/kWh)
iors. 100 Private (6%, 0.12 €/kWh)
In the industry, investments are done with short payback
periods and high interest rates.
The annuity factor AF can be defined as 10

(1 + i)n ⋅ i
AF = (1) Industry (25%, 0.04 €/kWh)
(1 + i)n − 1 1
Industry (30%, 0.02 €/kWh)

where i is the interest rate and n the payback time. For


the industry sector, annuity factors from AF = 25–30% are 0.1
0.1 1 10 100 1000
required. In the buildings sector, longer payback periods
Storage cycle period (days)
and moderate interest rates are applicable, which leads to
AF = 7–10%. Private investors (or “enthusiasts”) that might Figure 7. Acceptable energy storage costs as function of annuity
do the investment by political or environmental motivation factor, energy price, and storage cycle period. Source: Reproduced
can accept even longer payback periods and smaller interest with permission from Hauer, Quinnell, and Lävemann, 2013. ©
rates, which leads to annuity factors of AF = 4–6%. Wiley-VCH Verlag GmbH & Co. KGaA.

Handbook of Clean Energy Systems, Online © 2015 John Wiley & Sons, Ltd.
This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215
Integration of Energy Storage into Energy Systems 13

these costs with the cost estimates given in Table 2, it The same holds for any economic evaluation. The actual
gets evident that only sensible heat storage reaches costs application delivers the achievable number of storage cycles
as low as this. All other storage technologies need cost and the economical environment where the storage will
reductions of one or more orders of magnitude to reach be operated. Both values can lead to maximum acceptable
economical operation. In contrast to this, storages with storage cost, which any chosen storage technology has to
cycle periods of 1 day can cost up to €219/kWh and still deal with.
be operated economically, which leads, when comparing
with estimates in Table 2, to a broader range of possible
technologies.
RELATED ARTICLES
When comparing different sectors, it becomes apparent
that in industry, acceptable storage costs are up to 30 times
Geothermal Heat Pumps
lesser than in the private/enthusiast sector. This illustrates
Ice Storage
the dependence of acceptable storage cost on storage cycle
PCM Storage
periods as well as the dependency on different investment
Hydrogen Energy Storage Systems for Grid and Community
boundary conditions.
Applications
In summary, it can be stated that for certain scenarios,
Pumped Hydro Energy Storage
multiple storage technologies can be operated economi-
Compressed Air Energy Storage (CAES)
cally; however, for a given storage cycle period, economics
Flywheel Energy Storage Systems
strongly depend on the investment environment, for example,
Rechargeable Battery Energy Storage System Design
the energy costs, interest rates, and payback periods.
Flow Battery Technology
Sodium–Sulfur Batteries

7 CONCLUSION

Future energy systems worldwide will have to face a growing


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This article is © 2015 John Wiley & Sons, Ltd.
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This article is © 2015 John Wiley & Sons, Ltd.
This article was published in the Handbook of Clean Energy Systems in 2015 by John Wiley & Sons, Ltd.
DOI: 10.1002/9781118991978.hces215

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