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= Ree ers Orqorwiomeballic cowed '~ ak lead ere M-Chimd. Sw additten to mittals, ola, Ac.and Aemimerals Buck as 8,61 M4, Se are wnatlend fo form orgomomebllic crmpd{ suck os or borane EyB, Grethylbovant. : ‘ cn ovqonomublbic chemusiy; shady fF ergauemebllic ceampels, 19-€ Lule + characterizing aud predicting Ale stability cf raedal Valance hell La M Con accomoctali total 18 € BL’ sx2el0y 15> Ixza2e0rnrd ZP-> 3x2=6e nd Ons HH) ertibedls . Atramaiken metal with 9 valence ockitads binds “vt Ligowds omeenel ve bending orbitals —-wantndengonkited (me) rendering ores Fling, all Lovo-lyinng bondime, ond wowdouncling obtla topires [ntQ-e) 1x2 = 1B. They config cesutks in. a Lange enirgy gop between Hs. Kighiod eceupled MO cee (HOMO) Wik Leweat wracerpled MO (2UMO) thus Atabilize Wu system, ~r Boeke bmelire ts pie COm Te atl god C7 Is%25%29" oF is*2sT ash ae 0 fas total 10€ 4% He criti orbitals. CER :cSO: aha : om th ; ; Te Be a thio dda om tt N as aPe BR Qe aoe aay Be, a es ) Mo (Cog => Me ice Ce + Ex geme = (Re J Rey Yin = RE ae Ye +Gxz)e aO41e =18e | | Dk anPhe | n+ Fe+300 | fe Qp-eo+arete ger eeraetae = Loe Wmupute 4 > B e+ BE +AxIe=Ias oe a oD g IN 2 1 0 ACS O 1S b\ | ve ot _ et co eo cb dp co M= Co Rh HeeeNg te EGNA ae ei, °C ais 48 rr le butadiene > 4e Oo ee at oyclopentaddemey 4 + sEoipsid-+e ~ OSH SHe, ch peg -arricot GQ > of been 6 “Geree + Qxze=182 2 ] O = ee opt —egebe cctarkekeorne->4 Ns) ase aflteyele NO ——> 3 € dene. (of- eatlo: >) cobb | [nee egal ud anpcth +3c0 te +6e F3XRE = 18, defect MN pe dnet ® Most ef the chemical Inductay wo based em the catalghe combinahi ct Awoll rmotaulo Auch oS Cty, Or a7 Hed eke. to give Large quctonles of economic tmportance ©. alcohols, aldehydes, acs, eat , pobymers eke, Homogimour/ tile mous cakelyter activels the wmaller— Wdctnles anc prerrote rr Union. Joitermodvater ane organomeklld Compols Catalyst > amouawr vate of a Duackom by Aower'ng He Ack vakion emLzqy . ath ston ennggeh ache Cumoabalyud) diy rp 6 (abubysect) a Auer yr 4 eackn. oridabive addivten A métecule XV pact wiha MLy, Auch that tw? atoms XY aek coovtimetid to M conilee te form ML y(x)CY), The new bend Yormect, 2€ of M ane utilica te form tuo nuso bunds. So Coorlimakion no. cnereaaca and ond” staki of rnetal dmueray by 2. x LyaM+ X-Y —> Loh @ covyainatively v & wat have non-bondinge —> acts ws Lewis baae avattable pore M Avwe clual rote > ours baae and alro ar Lewis auld fo vecaive ae 1e> each fo tts tuo bendn WX FY, DO age Crh > [pA M valence € 4 16(d8 2x4) 18 Cd64+ax6) Mon > 4 ————? 6 M oxs"ateh—> ta ——+> *4 ® [vb etceoncerha) x] + nel [ Hly cetdceryceodcrtha)] brava Cerrmpler rma we O Co), +1 ul WaVELA] © engin > cay Reductive Elliyrimation Revere of orerdakive addition. ead’ x Lol — Lam + X-Y- Red By eine way, vernove Amal rmateculis kuch as Hy » RAR . fe EDe. oe ve a Nd +0, 1” EN) eth Imacrkion ow aigand mugsakton guoac” ia Wat em Span punatid omolecle, ¥ bo cas plu ost Y dwavited btw” M aud X, Oc M-x ty — M-Y-X% Y= CO, deact, deme, HeecH, candene CeRe) X= abtyh, aryl, Arydrtole here is erncomce Hat VY mwuat coordinate m be poac”, Aloo there is evidemeo Wok iy la gv. K haemo: M—-\Y¥ > M-Y-X, co ° ben x, ‘yin 2 x cb a co oe FT Sco co co vag Weveed “ 0. wet Kog + fg —> Nye co cig GH Caralutic Mpplicalion Homogeneous catalytic hydregemakion of olefin walng, Wace Rh): 4 dex +n, Cas, tt. Lor eR, ce cals i ie dimeuakionst | os 2 Phy aN - j —ed Keduchye poreh “ ‘ vss cada” fextewarion 0 Ae L pxidative ema) oS we \ —H Lin, 7 ieee advan L H el ies Da be, wl 2 a a : = ; ee oy Ve Treomplacakion abicoms. 18e Monsanto acetic acta procearst syvtuas Mowsaseto acetic: attt pecan. CHhanot oxidinad be acotallebyde Cig CHOW +4 Og > CHa CHO + Hyd te ees Kt Hy CH3CWO-+ 4 Oy —* ClgCO3H : fae r A 2 5 Backerial eds fe produce ve cng + co LEO, By, coon Sieh Ra0H oe ec | : CHT. oo 37 ScD Swaeetion_ 2 L@ N ae i a Ty er 8 | Ree OK Ms ot he Se : (EO) 1 a Chy Coo = dishes op ko — ‘ whe 3col Nene Induabial method + mamutictyys 1 bo? A a 1966 that Ribsived fp reels feraprovee big Hencsancko Company oo

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